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1 atoms) or Na(+) ions (a single plane of four oxygen atoms).
2 er pathway dissociation to dinitrogen and an oxygen atom.
3 ong 105 kcal mol(-1) C-H bond and insert one oxygen atom.
4 enzyme and/or effects on the proximal ligand oxygen atom.
5 c addition of diaminocarbene to the carbonyl oxygen atom.
6 ion of H2, with water serving as a source of oxygen atom.
7 ) in stabilizing protonation at the carbonyl oxygen atom.
8 ycolylneuraminic acid (Neu5Gc) differ by one oxygen atom.
9 c acid N-acetylneuraminic acid (Neu5Ac) by 1 oxygen atom.
10 that differs from tartaric acid by a single oxygen atom.
11 e bond through interaction with the carbonyl oxygen atom.
12 AM with incorporation of a second O2-derived oxygen atom.
13 ether with a double bond between silicon and oxygen atoms.
14 m three to six atoms and contained up to two oxygen atoms.
15 ectivity between subtly nonequivalent acetal oxygen atoms.
16 t differ in length and structure by only two oxygen atoms.
17 oamides and amides with isotopically labeled oxygen atoms.
18 excursions in the direction of the acceptor oxygen atoms.
19 s over the weaker C-H bonds located alpha to oxygen atoms.
20 shorter, is lined by backbone and side-chain oxygen atoms.
21 MW, 1.632(5) A], despite the presence of two oxygen atoms.
22 es outer core 5s and 5p orbitals to bind the oxygen atoms.
23 gas- and particle-phase ON possessing 4 to 9 oxygen atoms.
24 e in spite of the displacement of equatorial oxygen atoms.
25 en the platinum metal center and the surface oxygen atoms.
26 g to its complexity and unusual placement of oxygen atoms.
27 interactions between alkane carbon and water oxygen atoms.
28 ferent electronic properties of its carbonyl oxygen atoms, a directed binding of the substrate to the
29 helix where they are coordinated by backbone oxygen atoms, a recurrent motif found in multiple protei
30 ese results indicate that even with a strong oxygen atom acceptor, such as PMe(3), the oxygen atom tr
31 f 64CaO glass structures with few subtracted oxygen atoms (additional electrons) confirm this observa
32 to NAD except for one substitution, where an oxygen atom adjacent to the anomeric linkage bearing nic
34 e Au atoms which are adjacent to chemisorbed oxygen atoms, almost doubling the activation energy for
35 ence of disubstitution adjacent to the ester oxygen atom, an allyl boron migration rearrangement lead
36 tions with the naphthyl moiety such that the oxygen atoms analogous to the carbinolamine and beta-hyd
37 on the interaction between the heterocyclic oxygen atom and receptor proteins as well as the importa
39 egies that allow for controlled placement of oxygen atoms and other functionality remains a challenge
40 parent compound La4Ni3O10-x by removing two oxygen atoms and rearranging the rock salt layers to flu
41 volving the lone pairs of electrons on water oxygen atoms and the antibonding orbital of the BPL carb
42 ur atoms of the thiazoline-2-thione rings by oxygen atoms and/or by replacing the coordinating sulfur
43 s, NAs + O (oxidized NAs with one additional oxygen atom), and NAs + 2O (oxidized NAs with two additi
44 ntaining two carbons, two nitrogens, and one oxygen atom, and they exist in different regioisomeric f
45 rocarbon, including carbon number, number of oxygen atoms, and number of aromatic ring structures, le
46 ult due to involvement of two axially bonded oxygen atoms, and often requires a catalyst to lower the
49 ptophan side chains are cross-linked and two oxygen atoms are inserted into one of the indole rings.
51 ng complex, in which two adjacent equatorial oxygen atoms are shared with the vertices of a FeO6 octa
52 ron transfer-oxygen transfer reactions where oxygen atoms are transferred from the polyoxometalate to
54 8P) can be reversed by replacement of the 5'-oxygen atom at the scissile phosphate by sulfur (5'-PS),
55 ides that replaced bridging and non-bridging oxygen atoms at (and near) the scissile bond with sulfur
58 increased (>25-fold) by the introduction of oxygen atoms at selected 2'-positions through deoxyribo-
61 on source was used to produce a hyperthermal oxygen-atom beam, which allowed for sufficient collision
62 dergo rather untypical attack with attacking oxygen atom being nearly perpendicular to the attacked C
64 ethyl ester (PABAOMe) occurs at the carbonyl oxygen atom both in isolation and when one water molecul
66 defects resulting from the spillover of the oxygen-atom conduction-band wavefunctions are resolved.
68 ent on the substituents at the CbDI-core and oxygen atom containing BfDIs are more prone to reduction
69 d with delocalized electron density on basal oxygen atoms contrasting the Am(III) and Cm(III) borates
71 sentative members of taxanes containing five oxygen atoms, decinnamoyltaxinine E (2) and taxabaccatin
72 (5)-pentamethylcyclopentadienyl) reacts with oxygen atom donors (e.g., H(2)O(2), PhIO, IO(4)(-)) in T
73 (IV)-OH-PFOM and Mn(V)-OH-PFOM are very poor oxygen-atom donors; however, both are highly reactive in
74 such as amines, amides, carbonyls, and ether oxygen atoms, etc., have been classified on the HalA sca
75 de (N-arachidonoyl ethanolamide) by a single oxygen atom even as the two are metabolically related.
77 n additional 10% (for a total of 28%) of the oxygen atoms exchange with water, suggesting that some o
78 een metals and underlying highly coordinated oxygen atoms, followed by facile hydroxide, hydronium or
79 e stabilities of protonating at the carbonyl oxygen atom for PABAH(+).(H(2)O)(0-6) and PABAOMeH(+).(H
83 ArsI is a dioxygenase that incorporates one oxygen atom from dioxygen into the carbon and the other
84 te H5PV2Mo10O40 mediates the insertion of an oxygen atom from H5PV2Mo10O40 into the tin-carbon bond o
87 g to these two peaks) involve binding to two oxygen atoms from carboxyl groups (the most superficial
88 probable binding configuration involves two oxygen atoms from each of the charged moieties of the PS
89 nificantly closer contacts with non-bridging oxygen atoms from each phosphate group of ATP and three
90 t UO2(2+) is coordinated to five carboxylate oxygen atoms from four amino acid residues of the super
91 s (the most superficial binding peak) or two oxygen atoms from phosphate groups (the most internal pe
92 ne could also act as the transfer channel of oxygen atoms from the top side across the C atomic layer
93 jet expansion has been used to determine the oxygen atom geometry in three isomers of the nonamer and
97 ion results from the ability of the bridging oxygen atom in phenoxazine to serve as both a pi-electro
98 esent studies show that the first and second oxygen atom in the [2]pseudorotaxanes 2-5 subsetCBPQT(4+
99 afluoroborate) of alcohols containing a beta-oxygen atom in the presence of pyridine yield dimeric es
100 evelopment of two strategies that utilize an oxygen atom in the substrate to accelerate the desired h
101 e presence of a conformationally flexible C6 oxygen atom in the sugar-derived lactol donors is requir
103 (1874.6 A(3)), containing 16 silicon and 32 oxygen atoms in its asymmetric unit, which would be very
104 absence of aqueous Mn(II), about 18% of the oxygen atoms in manganite exchange with the aqueous phas
106 99)Tc is likely bound to two of the four W-O oxygen atoms in the alpha(2)-[P(2)W(17)O(61)](10-) defec
107 ng experiments, which demonstrated that both oxygen atoms in the difunctionalized products were deriv
108 tate NMR data confirm that two-thirds of the oxygen atoms in the encapsulated carbonate derive from p
110 have two major coordinations, one with nine oxygen atoms in the first coordination shell similar to
111 was shown that introducing triple bonds and oxygen atoms in the n-butyl linker of the molecule great
112 e of either H2(18)O or (18)O2, the origin of oxygen atoms in the newly synthesized chlorophylls was i
113 sis of reactions under (18)O2 show that both oxygen atoms in the nitro function of CAM derive from O2
114 ive electrostatic potential generated by the oxygen atoms in the ONO(2) group that scatters the incom
115 rs (S-oligomers), one of the two nonbridging oxygen atoms in the phosphate moiety of the sugar-phosph
116 phosphoric acid group and multiple phosphate oxygen atoms in the phosphodiester bonds are exposed to
118 nduce a modulated charge distribution on the Oxygen atoms, in remarkable agreement with recent X-ray
119 Isotope labeling studies confirmed that the oxygen atom incorporated was derived exclusively from H2
121 -KG-dependent non-heme iron enzyme catalyzed oxygen atom insertion into an olefinic moiety in various
122 ed to model possible products resulting from oxygen atom insertion into the iridium-carbon and/or iri
123 H activation and SiMe4 extrusion rather than oxygen atom insertion, resulting in the alkoxide complex
125 e residue for Zta) whose side chain hydroxyl oxygen atom interacts with the two half sites differentl
126 and CO(2), followed by insertion of a CO(2) oxygen atom into the Ni-OH bond to generate a four cente
133 oaded HA-Fe3O4 materials has six neighboring oxygen atoms likely in an octahedral geometry with avera
135 The diffusion coefficients of trehalose oxygen atoms most distant from the glycosidic linkage fl
136 specific local Li-excess environments around oxygen atoms necessarily lead to labile oxygen electrons
137 ole, an analogue of 2-undecylpyrrole with an oxygen atom next to the site of C-C bond formation, and
139 yl radical ((*)OH), (2) nitrite (NO2(-)) and oxygen atom (O((3)P)), and (3) peroxynitrite (ONOO(-)).
140 buted by 2p orbitals of the nearest-neighbor oxygen atom (O(NN)) with two dangling bonds and 3d orbit
142 sites evolve from metal atom pairs (*-*) to oxygen atom (O*-O*) pairs and ultimately to Pd cation-la
143 -linked) of asparagine side chains or to the oxygen atom (O-linked) of serine and threonine side chai
144 tic reactions, such as those of ground state oxygen atoms, O((3)P), with unsaturated hydrocarbons (al
146 nner involving interaction of the endocyclic oxygen atom (O5) found in such sugars with the C1 substi
147 sidue is attached to the N7, N3, or carbonyl oxygen atom, (O6), of guanine and to the N7, N3, or N1 p
148 The deprotonation can occur either at the oxygen atom (observed for the zinc complexes) or at the
150 the increase in water uptake is a result of oxygen atoms occupying the vacancies in the hydrophilic
152 f a strong interaction between Li(+) and the oxygen atom of both DMF and DMA that increases the exten
153 drogen bonding interaction with the carbonyl oxygen atom of Gly48 of protease as examined in the stru
155 , the Gly238 carbonyl O atom, and the distal oxygen atom of O(2) will promote protonation and hence f
158 The nitrogen atom of the thiazine and the oxygen atom of the carboxamide bind to Arg-120 and Tyr-3
159 Water is the solvent, the source of the oxygen atom of the carboxylic acid group, and the actual
160 ture exhibits squaramide (NH)2 binding to an oxygen atom of the enolate nucleophile, while the nitroa
161 ential to recognize the functionality of the oxygen atom of the ester carbonyl group via noncovalent
164 between the chalcogen atom and the internal oxygen atom of the peroxyl radical, which is nominally b
165 d, premised on nucleophilic additions to the oxygen atom of the positively charged nitrogen-oxygen do
166 66 is at hydrogen bonding distance to the C3 oxygen atom of the substrate and can stabilize the keto-
167 lex between the benzyloxyl alpha-C-H and the oxygen atom of the substrates followed by hydrogen abstr
169 omplex crystal structure, the nucleophile O4 oxygen atom of the xylose molecule is found in close pro
171 and the further rotation of the nonbridging oxygen atoms of alpha- relative to the beta- and gamma-p
172 topic labelling confirms that the carbon and oxygen atoms of CO2 originate from CS2 and H2O, respecti
173 rmediate with one of the side chain carboxyl oxygen atoms of D534, via either electrostatic or covale
176 alcohol, subsequent reaction with one of the oxygen atoms of taxifolin's catechol moiety, and finally
177 There is a crucial hydrogen bond between the oxygen atoms of the anesthetics and the hydroxyl of Tyr-
178 s of C-H bonds of the substrate lie near the oxygen atoms of the boryl ligands, participating in a se
180 , substrate bonds are formed through the two oxygen atoms of the carboxylate group and the amino grou
181 via hydrogen bonds between the two terminal oxygen atoms of the catalyst phosphate group and the hyd
182 ion located midway between the inner Odelta1 oxygen atoms of the catalytic aspartic acid residues.
183 obtained from the (18)O/(16)O ratios in the oxygen atoms of the compound add support to the deductio
184 toms made surprisingly close contacts to the oxygen atoms of the corresponding pyrimidine nucleobase
185 d to an eclipsed position of the nonbridging oxygen atoms of the gamma- relative to the beta-phosphat
190 the residues at positions 2, 9 and sidechain oxygen atoms of the residue at position 12 (N(2)-OE(12)/
191 are directly coordinated to the non-bridging oxygen atoms of the scissile phosphate; for the latter,
192 The phosphate groups and the carbon and oxygen atoms of the sugars are used to superimpose helix
193 luggish oxidant, as both proximal and distal oxygen atoms of this species have prohibitively high bar
196 tes of Au16 tends to attack a nearby lattice oxygen atom on the TiO2 (110) surface rather than the ne
197 lic, particularly because of the nonbridging oxygen atoms on the disordered silicate chains which ser
198 or either K(+) (cage made from two planes of oxygen atoms) or Na(+) ions (a single plane of four oxyg
200 tivity for the C-H bonds located beta to the oxygen atoms over the weaker C-H bonds located alpha to
203 hances the nucleophilicity of the respective oxygen atom, permitting an even faster reaction for diol
204 K(+)-intercalated crown ether involving six oxygen atoms (PFCn6:K(+)) for bulk-heterojunction polyme
208 h coordinatively unsaturated gold atoms, two oxygen atoms preferentially share a gold atom with a bon
210 acidic alpha-H protons in CBPQT(4+) and the oxygen atoms present in the glycol chain can take place
211 labeled (18) O2 unambiguously show that the oxygen atoms present in the Mn(IV) dimers originate from
212 ic interaction is present between carbon and oxygen atoms previous to the formation of the C-O bond.
213 atinum-oxygen bond order was investigated by oxygen atom projection in the occupied and unoccupied sp
214 ions confirmed that these negatively charged oxygen atoms promote the overall transformation by stabi
215 vacancy defect is found to be healed by the oxygen atom released during the dissociation process.
217 acid substitution, a single-atom change (an oxygen atom replacing a sulfur atom), blocked the vasodi
218 d NAs + 2O (oxidized NAs with two additional oxygen atoms), respectively) under the experimental cond
224 uctures to interrogate asparagine side-chain oxygen atoms that are both acceptors of a hydrogen bond
226 methoxy through C-H scission with the bridge oxygen atoms that are readily available from the reducib
228 couplings with simultaneous extrusion of the oxygen atom, thus enabling a traceless strategy for alke
229 06(3), despite the heaviest element being an oxygen atom, thus unambiguously confirming the results f
230 e generation of 2 entails the addition of an oxygen atom to 1 and the loss of one positive charge.
231 clopropane ring bond and the shifting of the oxygen atom to an alternative location engendered a new
233 n structure imposed by changing the epimeric oxygen atom to carbon appear to render the enzyme incapa
235 complex" proved capable of transferring one oxygen atom to phosphine, generating phosphine oxide and
238 cations and then couple with surface lattice oxygen atoms to form -CH3O with a following dehydrogenat
239 len reaction kinetics, which utilize lattice oxygen atoms to reoxidize the reduced metal centers whil
242 erentiation of the metal centers involved in oxygen atom transfer (Mn) or redox modulation (Fe).
244 -bis(trifluoromethyl)phenyl]borate) with the oxygen atom transfer (OAT) reagent 2-tert-butylsulfonyli
245 , and computational studies are reported for oxygen atom transfer (OAT) to the complex V(N[t-Bu]Ar)3
249 ng oxygen atom acceptor, such as PMe(3), the oxygen atom transfer chemistry from Mn(3)MO(4) cubanes i
250 action was studied by comparing the rates of oxygen atom transfer for various para-substituted triary
251 nd aryl enals undergo beta-hydroxylation via oxygen atom transfer from electron-deficient nitrobenzen
253 luble ferriheme model Fe(III)(TPPS) mediates oxygen atom transfer from inorganic nitrite to a water-s
254 ng the {FeNO}(7) intermediate, represents an oxygen atom transfer from the iron bound nitrite to a se
255 which allowed us to observe fast dynamics of oxygen atom transfer from the Ru(IV) horizontal lineO ox
257 e(II) Mn(II) vs. Fe(III)3 Mn(II) ) influence oxygen atom transfer in tetranuclear Fe3 Mn clusters.
261 at a distal metal site leads to a change in oxygen atom transfer reactivity by ca. two orders of mag
264 e the first example of a synthetic cycle for oxygen atom transfer that makes use of light to generate
266 hanics to investigate the reaction paths for oxygen atom transfer to phosphine from Mn(III)(2)Mn(IV)(
268 ion of the oxorhenium(VII) moiety (classical oxygen atom transfer) rather than through initial intern
269 calculations, a two-electron transfer (i.e., oxygen atom transfer) reaction pathway is proposed.
270 n to be a competent oxidant in an intermetal oxygen atom transfer, C-H bond activation and olefin epo
274 gests a decreasing contribution of concerted oxygen-atom transfer (Fe(V) --> Fe(III)) concomitant wit
275 Mn(V)(O)(TBP8Cz) has a dramatic influence on oxygen-atom transfer (OAT) reactivity with thioether sub
276 carbons, e.g., propane and butane as well as oxygen-atom transfer (OAT) to unsaturated hydrocarbons,
278 ndergoes a four-electron reduction including oxygen-atom transfer in reactions with excess tri-tert-b
279 ramatic rate variations in hydrogen-atom and oxygen-atom transfer reactions, with faster rates corres
281 e in simultaneous nitrene-group transfer and oxygen-atom transfer to generate an intermediate metal t
282 fer, (5) fundamental transformations such as oxygen-atom transfer, (6) nitrogen-atom transfer, (7) O2
283 *+) and concomitantly a CH2F(*) radical, and oxygen-atom transfer, yielding the observable ionic prod
284 ch can be recycled to produce more 7 through oxygen-atom-transfer oxidation of CO to produce CO(2).
288 9 oxidized lipids with up to four additional oxygen atoms were annotated based on the accurate mass r
289 monolayer became disordered, and equatorial oxygen atoms were displaced towards the surface; (iii) t
290 ric H-bond (between O1 donor and O2 acceptor oxygen atoms), whereas the H2 proton undergoes rapid exc
291 cell has a much lower number of neighboring oxygen atoms, which is manifested in the whiteline broad
292 Earth's crust in that carbon binds to three oxygen atoms, while silicon is bonded to four oxygens.
293 the adsorbed uranyl ions share an equatorial oxygen atom with a phosphate tetrahedron of the amorphou
294 vity filter provide a ring of three carbonyl oxygen atoms with a radius of approximately 3.6 A, prese
295 p' proton tunnelling between hydrogen-bonded oxygen atoms with a typical donor-acceptor distance of 2
297 oscillators the fluctuations in the ratio of oxygen atoms with respect to that of carbon, hydrogen an
298 lectrodes obtained by replacing stepwise the oxygen atoms with sulfur atoms in the carboxylate groups
299 lyses and DFT calculations, the heterocyclic oxygen atom within DPD appears necessary to promote hydr
300 tionalized, possessing between six and eight oxygen atoms within each carbon number group, and is not
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