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1 Al(3)O(4)(+) exhibits a cone-like structure with a centr
2 Al(IV)-2 sites result either from framework crystallizat
3 Al@Al is fully wetted by a 4 m potassium bis(fluorosulfo
4 wavelength of 414.234 (Fe I) nm and 396.054 (Al I) nm, and the kurtosis of spectra at wavelength rang
5 Ca(12)Ga(14)O(33) analogue compared to Ca(12)Al(14)O(33) synthesized using the same wet chemistry tec
7 that the compound is isostructural to Ca(12)Al(14)O(33,) however, with a significantly larger lattic
9 Relative to other ultraporous MOFs, NU-1501-Al exhibits concurrently a high gravimetric Brunauer-Emm
10 rformances for hydrogen and methane: NU-1501-Al surpasses the gravimetric methane storage U.S. Depart
11 rd the trithiocarbonate species [K(OEt(2) )][Al(NON(Dipp) )(CS(3) )] 1 or the ethenetetrathiolate com
12 olymorphs of the feldspars anorthite (CaSi(2)Al(2)O(8)), albite (NaAlSi(3)O(8))(,) and microcline (KA
13 se of atenolol was achieved from FAU (SiO(2):Al(2)O(3) = 80:1) into phosphate buffer for 24 h followe
15 ation at the Si(II) atom with [H(OEt(2))(2)][Al{OC(CF(3))(3)}(4)] induces formal oxidation, and the c
16 Na(+), K(+), Mg(2+), Ca(2+), Mn(2+), Fe(2+), Al(3+), Ni(2+), Cu(2+), Zn(2+), Co(2+), Pb(2+) and Ru(3+
17 characteristic features observed in both (27)Al and (71)Ga NMR spectra result from both the deviation
20 d with computational modeling, extensive (27)Al MQMAS experiments at multiple field strengths, and (1
21 a variety of nuclei ((1)H, (13)C, (19)F, (27)Al, and (93)Nb) with a range of one- and two-dimensional
24 eferences, we combine solid-state (17)O, (27)Al, and (71)Ga magic angle spinning (MAS) NMR spectrosco
26 A correlation between the size of the (27)Al/(71)Ga quadrupolar coupling and the distortion of the
27 mmercially available alane amine adduct (H(3)Al.NMe(2)Et) in toluene resulted in the formation of a c
28 gnetic Al addition in the CoFeNi(0.5)Cr(0.5)-Al(x) (x: 0, 0.5, 1, and 1.5) complex concentrated alloy
29 l characterisation of the CoFeNi(0.5)Cr(0.5)-Al(x) composition and attempt to relate it to the interf
30 ores how rapid formation of ettringite [Ca(6)Al(2)(SO(4))(3)(OH)(12).26(H(2)O)], a common mineral for
31 hermal-driven structural ordering in a Ce(65)Al(10)Co(25) metallic glass, and a reverse disordering p
33 nd N), and lignin composition (inherited (Ad/Al)s and C/V) were not completely consistent in reflecti
34 a dual OSDA and exfoliating agent to affect Al siting and to eliminate the need for postsynthesis ex
37 simulations of SCN(-) near the neutral alpha-Al(2)O(3)(0001)/H(2)O interface show that the vSFG respo
38 sing large volume fractions of primary alpha-Al dendrites and ultrafine Al-Si eutectic of lamellar mo
40 the concentrations of Mn, Fe, and aluminum (Al) in the soil solution of subsurface samples, whereas
42 ss increased with extractable soil aluminum (Al) (r(2) = 0.97; p < 0.1), but Al had no significant re
43 eposition (ALD) of a few-nanometer amorphous Al(2) O(3) layers onto atomically thin single-crystallin
44 st for oxygen vacancies, while the amorphous Al(2) O(3) facilitates the generation and stabilization
47 materials, a number of dual-ion battery and Al-ion battery technologies are experiencing booming dev
49 y absorption measurements reveal that Cu and Al enable a favourable Cu coordination environment that
54 (2) dissolution of poorly crystalline Fe and Al oxides by 1 M HCl, releasing P occluded by these oxid
55 g interface charges between the graphene and Al(2)O(3) as compared to use of a 2 nm Al buffer layer.
57 monstrated benchmarked against NMC, NCA, and Al-Mg-codoped NMC (NMCAM) of identical Ni content (89 mo
60 t configuration analysis for the undoped and Al and/or Ga-doped LLZO variants uncovers an interplay b
61 The reactivity of the electron-rich anionic Al(I) aluminyl compound K(2) [(NON)Al](2) (NON=4,5-bis(2
62 ing on biasing the framework Al arrangement (Al-O(-Si-O)(x)-Al, x = 1-3) among CHA zeolites of essent
63 and 8 ML) to achieve the same composition as Al(0.4)Ga(0.07)In(0.53)As quaternary random alloy (RA).
64 zation characteristics of In(0.53)Ga(0.47)As/Al(0.48)In(0.52)As superlattice avalanche photodiodes (I
68 bnormally smaller and increased in number at Al-12.2at.%Si, compared with 800 degrees C MS alloys, wh
69 an optical cavity substrate consisting of Au/Al(2) O(3) to enhance its absorption near the bandgap ed
70 ne with BF(3).Et(2)O unexpectedly led to a B/Al metathesis with the preservation of the pincer struct
71 t of this research indicated that SERS based Al-QS could be a suitable candidate for the early diagno
73 y correlation strength and direction between Al and base cations, total organic carbon, turbidity, an
74 y results from the complex interplay between Al-mediated lattice distortion (due to its larger atomic
78 il aluminum (Al) (r(2) = 0.97; p < 0.1), but Al had no significant relationship with litterfall, sugg
79 lyses suggest that the particles enriched by Al tend to agglomerate in a needle-shaped structure.
82 exagonal lattices, such as those provided by Al(2)O(3)(0001) and (111) oriented cubic perovskites, ar
86 odic table, in particular metals such as Ca, Al, Na, Zn, and Fe and halogens like Cl and F, occurring
88 )-containing environment, aluminium cations (Al(3+)) was incorporated into a layered surface film com
93 e that this second tetrahedrally coordinated Al site (denoted Al(IV)-2) experiences an increased chem
95 /G ratio, proline, pH, conductivity, Fe, Cu, Al, and Mn values were found in the chestnut honeys.
97 m bonds with short metal-metal distances, Cu-Al = 2.3010(6) angstrom and Cu-Ga = 2.2916(5) angstrom.
98 mputational studies that suggest that the Cu-Al alloys provide multiple sites and surface orientation
99 thodology for modelling of disorder in delta-Al(2) O(3) and twinning in theta-Al(2) O(3) and show tha
101 the two different intergrowth modes of delta-Al(2) O(3) have different transformation characteristics
102 tics and that a significant portion of delta-Al(2) O(3) is stabilized with theta-Al(2) O(3) even afte
103 d tetrahedrally coordinated Al site (denoted Al(IV)-2) experiences an increased chemical shift and un
107 rk Ga at framework sites comprised of either Al or Ga reveal a site-specific preference for stabilizi
112 ing an aluminum-powder-coated aluminum foil "Al@Al," without any modification of the support surface
113 eversible recognition of monomer 4 and P for Al(3+) was also proved in presence of Na(2)EDTA by both
114 e determination of polar pesticides (fosetyl-Al and its metabolite, phosphonic acid, and ethephon) an
116 FI zeolites with tetrahedral extra-framework Al into Al-enriched mesoporous ZSM-5 nanoboxes with low
118 emplate N atoms bind to a specific framework Al site to expand its coordination to the unusual octahe
119 fects of SDA siting on biasing the framework Al arrangement (Al-O(-Si-O)(x)-Al, x = 1-3) among CHA ze
120 ents demonstrate that at least two framework Al(IV) sites with hydroxyl groups can exist in acidic ze
122 ctions in acidic deposition, high freshwater Al concentrations continue to threaten acidified ecosyst
123 a metal-organic framework (MOF) built from (Al-OH)(n) secondary building units and a mixture of 2,2'
124 entrations of immobile trace elements (e.g., Al, Fe, Ti) far exceed global riverine and open ocean me
129 lar supports such as carbon materials, gamma-Al(2)O(3), and zeolite, which is vital to their practica
132 erminal hydroxyls existed on nanosized gamma-Al(2)O(3) can lead to single-atom silver dispersion, the
135 d determination of oxygen structure of gamma-Al(2)O(3) by using two-dimensional (2D) solid-state NMR
140 selectively removed pdac ligands to generate Al(2)(OH)(OH(2)) sites, which were subsequently triflate
143 cts marketed in Europe: aluminium hydroxide (Al(OH)(3) ) is the most frequently used adjuvant, with m
144 istribution, and morphology of hypereutectic Al-17wt.%Si and Al-20wt.%Si alloys have been investigate
148 (10-240 nm) Si-rich microstructures exist in Al-12.2at.%Si alloy melt, and the large Si-rich microstr
149 e band gap by nearly 1 order of magnitude in Al(2)O(3) (<6 x 10(10) cm(-2)) and in HfO(2) (<3.9 x 10(
151 es that the large Si-rich microstructures in Al-12.2at.%Si alloy melt are probably aggregates compris
153 em by patterning an elongated epitaxial InAs-Al island embedded in an Aharonov-Bohm interferometer.
154 a tunable anomalous Josephson effect in InAs/Al Josephson junctions measured via a superconducting qu
155 ns of secondary phases (mainly intermetallic Al-Fe-Be) were observed inside grains, along dislocation
156 tes with tetrahedral extra-framework Al into Al-enriched mesoporous ZSM-5 nanoboxes with low silicon-
161 oxide to afford the oxygen analogue of 3, [K{Al(NON(Dipp) )(O(2) C)}](2) [4](2) containing the hither
166 A high mass difference between the light Al and heavy matrix components limits mass interference.
167 ch microstructure in engineering-lightweight Al-12.2at.%Si alloy melt at 1100 degrees C, via melt-spi
168 13 metal beta-diketiminates M(BDI(Dip)) (M = Al or Ga; BDI(Dip) = N,N'-bis(2,6-diisopropylphenyl)pent
170 trate, enabled us to prove that the measured Al signal represents the real distribution of Al nanopar
171 lytic activity of the main-group metals (Mg, Al and Ca) in oxygen reduction reaction is severely hamp
172 nce was assessed using 16 variables (Na, Mg, Al, V, Co, Ni, As, Se, Rb, Sr, Mo, Hg, delta(2)H, delta(
174 s, but several elements (Ba, Ca, Mg, Sr, Mn, Al, Co, Ni, Se) were marked as characteristic of honey t
175 d shape-controlled synthesis of monodisperse Al nanocrystals remains an open challenge, limiting thei
176 ines in all regimes, and inorganic monomeric Al is projected to exceed the 15 mug L(-1) threshold for
177 s from partially bonded framework (SiO)(4-n)-Al(OH)(n) species that significantly increase catalyst r
178 Understanding cation (H(+) , Li(+) , Na(+) , Al(3+) , etc.) intercalation/de-intercalation chemistry
179 desolvated particles of eight elements (Na, Al, Ag, Sr, Ca, Mg, Fe, and Be) were injected into the c
180 red aluminum and nickel oxide nanoparticles (Al(2)O(3) and NiO NPs) on plant growth, oxidative stress
181 action (likely controlled by nanoparticulate Al and Fe oxyhydroxide minerals) and estuarine processin
184 h anionic Al(I) aluminyl compound K(2) [(NON)Al](2) (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-
186 C=N stretch region originates from a SCN-H-O-Al complex, suggesting the surface site specificity of t
187 that although O sites in both framework Si-O-Al and Si-O-Si linkages are enriched simply on exposure
188 sure to H(2)(17)O(l), the enrichment of Si-O-Al species is more rapid, with a more uniform framework
191 enhanced atomic layer deposition (PE-ALD) of Al(2)O(3) on graphene for top gated field effect transis
192 ry widely with the number and arrangement of Al (1-5 per 36 T-site unit cell), but cannot be describe
193 a novel dedicated model sample consisting of Al nanoparticles buried under a 50 nm thick Cu thin film
195 centrated and non-protective coordination of Al species can facilitate post-synthetic treatment to pr
197 d enable for the first time the detection of Al and H association on a dry HZSM-5 catalyst, i.e., und
199 he chemosensor HMBP for the determination of Al(3+) in real food samples, drinking waters and herbal
200 ) was developed for further determination of Al, Ca, Cr, Cu, Fe, K, Mn, Mo and Ni in rice samples by
202 l signal represents the real distribution of Al nanoparticles and does not originate from the artifac
203 , regimes are distinguished by a gradient of Al-base cation decoupling as Ca and Mg concentration app
204 al variation of Al to quantify the impact of Al on human health, water treatment, and aquatic organis
209 ificantly increased under 50 and 100 mg/L of Al(2)O(3) NPs or 50 mg/L of NiO NPs treatment, but was s
211 at 1100 degrees C, via melt-spinning (MS) of Al(1-x)Si(x) (x = 0.03,0.07,0.122,0.2) alloy melts from
213 edge gap by identifying seasonal patterns of Al and their drivers in 16 rivers across Nova Scotia, Ca
214 nge in structure and gas phase reactivity of Al(3)O(4)(+) upon Fe-substitution, which is correctly pr
217 like "isomorphous substitution" structure of Al(2)FeO(4)(+) to be the most stable one, except for fun
218 tance of understanding seasonal variation of Al to quantify the impact of Al on human health, water t
222 cent sensors for selective detection of only Al(3+), due to the challenge of identifying a suitable l
223 lymer P exhibit high selectivity toward only Al(3+) with no interference from other metal ions, havin
227 Sorption to redox-inert aluminum oxide (Al(2)O(3)) was recently found to affect the redox proper
230 tisation increase is strange as paramagnetic Al addition dilutes the ferromagnetic Fe/Co/Ni additions
231 he change in magnetisation with paramagnetic Al addition in the CoFeNi(0.5)Cr(0.5)-Al(x) (x: 0, 0.5,
232 cally modulate the carrier density in planar Al-doped ZnO (AZO) metasurfaces without any associated t
233 trochemical stability of Al@Al versus planar Al is not related to differences in potassiophilicity (n
235 ed by the intercalation of highly polarising Al(3+) ions should be considered when designing new elec
236 heory, in contrast, predicts a less reactive Al(3)O(4)(+)-like "isomorphous substitution" structure o
237 search highlights the complexity of seasonal Al dynamics and the importance of understanding seasonal
239 ion by X-ray crystallography reveals a short Al-N distance, which is thought primarily to be due to t
240 reaction, using a Cu-CHA catalyst with a Si/Al ratio of 15 and 2.6 wt% Cu, by X-ray absorption spect
242 ctivity of their sub-nanometer pores, the Si/Al ratio of the anionic framework, and the charge-balanc
243 t has been discovered in a relatively simple Al(0.3)CoFeNi high entropy alloy (HEA) or complex concen
246 earth metals Tm and Lu partially substitute Al atoms in the structure of the Zintl phase Ca(14)AlBi(
248 loped a ternary liraglutide/tannic acid (TA)/Al(3+) nanoparticle system based on hydrogen bond format
249 s to a planar bicyclic frame with a terminal Al-O(*-) radical site, accompanied by a change from the
251 , a new site created by a second tetrahedral Al atom and its hydroxyl group protons in zeolite HZSM-5
260 he bond formation and bond activation at the Al sphere: thus, not only does it undergo electron redis
261 his second acidic proton site created by the Al(IV)-2 species are shown to be controlled via postsynt
262 ng of Crystal Violet and Rhodamine 6G by the Al-QS was driven up to single molecule sensing (femtomol
267 er of Mo and Y/Sc and Kagome ordering of the Al atoms, as evident from X-ray diffraction and electron
269 Moreover, the imposed restriction on the Al nanoparticle location, i.e., only on the sample subst
270 ents of liquid steel tend to be uniform, the Al(2)O(3)-TiO(x) inclusions will decompose and disappear
271 resis (0.9 V) when compared to FETs with the Al layer (V(Dirac) = - 6.1 V and hysteresis = 2.9 V).
273 tructure in the range where delta- and theta-Al(2) O(3) are formed represents a formidable challenge,
274 er in delta-Al(2) O(3) and twinning in theta-Al(2) O(3) and show that explicitly accounting for the d
275 of delta-Al(2) O(3) is stabilized with theta-Al(2) O(3) even after prolonged high-temperature exposur
276 XM(YCH(2)CH(2))(3)N (M = Si, Ge, Sn, Pb, Ti, Al, Cr, Fe, Ni...; Y = O, NR, CH(2), S), i.e., substitut
279 r 60 or 42 days of exposure, rats exposed to Al and EWH did not show memory or cognitive dysfunction
280 pect to C-H bond activation, very similar to Al(8)O(12)(+) which also features the terminal Al-O(*-)
282 The response of the chemosensor HMBP towards Al(3+) was attributed to the strategies of blocking the
285 The ability of in vitro cell detection using Al-QS was analyzed with three cell lines, mammalian fibr
286 h temperature to eliminate oxygen vacancies, Al is doped into the ZnO nanosheet, and the memristive b
289 etically viable reaction mechanisms by which Al-O and Si-O bonds rapidly and reversibly break at 300
290 ximately equal parts of Co and Ni along with Al, Cr, Ta and W that possess strengths in excess of 1.1
291 he binding constant of chemosensor HMBP with Al(3+) from the Benesi-Hildebrand equation was determine
293 y) O(2) (NMC) and LiNi(1-) (x) (-) (y) Co(x) Al(y) O(2) (NCA) are the cathode materials of choice for
294 Herein, a high-Ni LiNi(1-) (x) (-) (y) Mn(x) Al(y) O(2) (NMA) cathode of desirable electrochemical pr
295 ynamically stable, atomically thick CuCr(1-x)Al(x)O(2) interfacial layer is the critical element for
297 the framework Al arrangement (Al-O(-Si-O)(x)-Al, x = 1-3) among CHA zeolites of essentially fixed com
298 erials with general formula of LiNi(x) Fe(y) Al(z) O(2) (x + y + z = 1), termed as the lithium iron a
299 z)Co(1-y-z)O(2) (NMC) and Li(x)Ni(y)Co(1-y-z)Al(z)O(2) (NCA) show reduced first cycle Coulombic effic