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1 Au protuberances growth on the surface of Au@Pt NPs allo
2 Au(191) has an anisotropic, singly twinned structure wit
3 Au@Rh-ICG-CM shows good biocompatibility, high tumor acc
5 6)H(11)NC)(2)Au](PF(6)) and [(C(6)H(11)NC)(2)Au](AsF(6)) contain single chains of cations and are vap
8 as the yellow polymorphs of [(C(6)H(11)NC)(2)Au](PF(6)) and [(C(6)H(11)NC)(2)Au](AsF(6)) contain sing
10 hereas neither polymorph of [(C(6)H(11)NC)(2)Au](PF(6)) nor [(C(6)H(11)NC)(2)Au](SbF(6)) is thermochr
11 ))(0.50)(AsF(6))(0.50), and [(C(6)H(11)NC)(2)Au](PF(6))(0.25)(AsF(6))(0.75) are vapochromic, whereas
13 PF(6))(0.75)(AsF(6))(0.25), [(C(6)H(11)NC)(2)Au](PF(6))(0.50)(AsF(6))(0.50), and [(C(6)H(11)NC)(2)Au]
14 reas the yellow crystals of [(C(6)H(11)NC)(2)Au](PF(6))(0.50)(SbF(6))(0.50) and [(C(6)H(11)NC)(2)Au](
15 the colorless mixed crystal [(C(6)H(11)NC)(2)Au](PF(6))(0.50)(SbF(6))(0.50) is thermochromic and conv
17 sform a crystal of the type [(C(6)H(11)NC)(2)Au](PF(6))(n)(AsF(6))(1-n) from colorless (blue-emitting
18 and are vapochromic, yellow [(C(6)H(11)NC)(2)Au](SbF(6)) does not form the same polymorph and is not
19 6)H(11)NC)(2)Au](PF(6)) nor [(C(6)H(11)NC)(2)Au](SbF(6)) is thermochromic, the colorless mixed crysta
20 g the effects of the concentrations of H(2), Au-Pd NPs, and resazurin on the color change response ti
24 ick reactions between Au(I) acetylides PPh(3)Au-C=CR, where R = nitrophenyl (PhNO(2)), phenyl (Ph), t
26 doamine) (PAMAM) dendrimer nanocomposite (3D-Au-PAMAM) covalently immobilized onto electrografted p-a
27 raldehyde (GA) on the amino groups of the 3D-Au-PAMAM-p-ABA-SPCE, where tau protein was sandwiched wi
29 l crater (0.6 mum x 130 nm ) morphology in a Au-coated glass target and carbon-coated silica wafer wa
33 ity of the achiral molecule to assemble on a Au(111) surface to a highly ordered layer composed of en
35 we report a rationally designed redox-active Au(I) bis-N-heterocyclic carbene that induces ICD both i
39 ns that the AMX (A = Ca, Sr, Ba; M = Cu, Ag, Au; X = P, As, Sb) compounds consisting of MX honeycomb
40 -induced emission gold clustoluminogens (AIE-Au) to achieve efficient low-dose X-ray-induced photodyn
42 nd in vivo experiments demonstrated that AIE-Au effectively triggered the generation of reactive oxyg
46 ubstantial deformation upon deposition on an Au(111) surface, as demonstrated by its pristine form in
47 nisotropic, singly twinned structure with an Au(155) core protected by a ligand shell made of 24 mono
48 (biTh), and dimethyl aniline (PhNMe(2)), and Au(I)-azide PPh(3)AuN(3) provide digold complexes of the
53 om Au alone exhibit low-index facets, Pt and Au form PtAu heterostructured nanoparticles with high-in
54 olayers (SAMs) of the wires in Au-SAM-Pt and Au-SAM-graphene junctions, from which the conductance pe
56 rostructured, multimetallic (Pt, Pd, Rh, and Au) tetrahexahedral nanoparticles was synthesized throug
57 arcodes and as ligand-free nano-segments and Au segments for ligand coating while maintaining both na
58 ttky) junctions formed between n-type Si and Au nanoparticles as light-addressable electrochemical se
59 and injectable DNA-mediated upconversion and Au nanoparticle hybrid (DNA-UCNP-Au) hydrogel is develop
60 o gold/lead clusters, [Au(8)Pb(33)](6-) and [Au(12)Pb(44)](8-), both of which contain nido [Au@Pb(11)
62 it for metal-coordination complexes, such as Au(CN)(2)(-) and Ag(CN)(2)(-) with linear geometries, wh
63 nner core and 66 surface atoms, arranged as [Au(3)@Au(23)@Au(63)]@Au(66) concentric shells of atoms.
66 s barcoding system, including ligand-bearing Au and ligand-free Fe nano-segments, is developed to ind
71 de of SAMs of n-alkanethiolates supported by Au were characterized with both dc and ac techniques, re
72 ed inner core structure of the ligand capped Au(191) nanomolecule provides the critical missing link,
74 s creates a bimetal single cluster catalyst (Au(4)Pt(2)/G) with exceptional activity for electrochemi
76 te an efficient deposition of singly charged Au(144) (SC(4) H(9) )(60) ions (33.7 kDa), which opens u
77 rt the synthesis of two gold/lead clusters, [Au(8)Pb(33)](6-) and [Au(12)Pb(44)](8-), both of which c
78 edral Au(7)Ag(6) units by sharing one common Au vertex can produce two temperature-responsive conform
80 duced the first examples of a low-coordinate Au(III) center with two cis accessible coordination site
83 ct has a lower conductance than the covalent Au-C interaction, which we propose occurs via an in situ
84 hange barriers separate Cu adatoms from a Cu-Au mixture, leaving behind a fluid phase enriched with A
86 odine and thiomethyl to show that the dative Au-I contact has a lower conductance than the covalent A
88 on ASV is 17.8 +/- 0.6% for 4.1 nm diameter Au NPs, 87.2 +/- 2.9% for 1.6 nm Au NPs, and an unpreced
89 ing replacement with 4.1 and 1.6 nm diameter Au NPs, respectively, consistent with qualitative change
92 eling revealed that nonuniformly distributed Au nanoparticles suffer from local depletion of surface
95 yst consisting of partially ligand-enveloped Au(4)Pt(2) clusters supported on defective graphene.
97 It is discovered that at the defect-free Au/TiO(2) interface electrons transfer from Ti(3+) speci
99 ecutive and pH-dependent transformation from Au(22) to both well-defined clusters and small Au(I)SR s
100 atom triggers the structural transition from Au(22) with a 10-atom bioctahedral kernel to Au(22)Cd(1)
101 noparticles of different compositions (e.g., Au and quantum dots) and shapes (e.g., spheres and rods)
104 e salt-induced aggregation kinetics of gold (Au) and silver (Ag) nanoparticles (NPs) at the prism int
105 phobic quasi-spherical and star-shaped gold (Au)NPs are synthesized to explore the antibacterial mech
106 n be utilized to form both heterobimetallic (Au(I)(-)/Ag(I)(+); Au(I)(-)/Ir(I)(+)) and organometallic
108 M(54) decahedron with the truncated homogold Au(49) kernel in similar-sized gold nanoparticles provid
109 then enclosed by a second shell of homogold (Au(47)), giving rise to a two-shelled M(54) (i.e. Au(52)
110 rm both heterobimetallic (Au(I)(-)/Ag(I)(+); Au(I)(-)/Ir(I)(+)) and organometallic/main group ion pai
111 f the F(n)ArH, followed by selective Au((I))/Au((III))-catalyzed coupling with electron-poor or -rich
112 (6) nanoclusters composed of two icosahedral Au(7)Ag(6) units by sharing one common Au vertex can pro
114 ly consistent cyclic voltammetric signals in Au surface cleaning experiments and detecting benchmark
115 -assembled monolayers (SAMs) of the wires in Au-SAM-Pt and Au-SAM-graphene junctions, from which the
116 odegradation compared to the other indicator/Au-Pd NP systems tested, (2) the observed redox chemistr
118 electrons transfer from Ti(3+) species into Au nanoparticles (NPs) and further migrate into adsorbed
119 vesicles were disassembled into small Janus Au-MnO nanoparticles (NPs) with promoted penetration abi
120 es))-based immunoassay coupled to thin layer Au-based electrochemical microfluidics operating at -0.2
121 nohydride protected by diphosphine ligands, [Au(22) H(4) (dppo)(6) ](2+) [dppo=1,8-bis(diphenylphosph
123 ed glassy carbon electrode (MNP/CNT/GCE, M = Au or Cu) and poly xylenol orange modified pencil graphi
124 onjunction with different capping materials (Au, Pt, and SiO(2)) and fuels (H(2)O(2) and alcohols).
125 ting nanoplastics with functionalized metal (Au)-containing nanoparticles (NPs), thus making them det
126 ranging from 1 to 50 nM, the AuNPs modified Au chip was proven to clearly be a better analytical too
127 ngle-component MOF superlattices, binary MOF-Au single crystals, and two-dimensional MOF nanorod asse
129 ffibody sealed methotrexate (MTX)-loaded MUA-Au NCs through charge effect, as well as leaving the res
131 hout a partnering gold ion only a distinct N-Au-P bending occurs, revealing a potential mechanism for
132 , from a pre-existing amorphous nanocluster (Au) or by coalescence of two separate amorphous sub-nano
133 violet (CV) and thiolated gold nanocluster ([Au(25)(Cys)(18)]) activated at a low flux levels of whit
134 xial process where initially nanocrystalline Au films gain texture, crystallographically orient with
135 eport the discovery of a Janus nanomolecule, Au(191)(SPh-tBu)(66) having both molecular and metallic
137 nanostructures, gold triangular nanoprisms (Au TNPs), gold nanorods (Au NRs), and gold spherical nan
138 angular nanoprisms (Au TNPs), gold nanorods (Au NRs), and gold spherical nanoparticles (Au SNPs).
140 ttering enhancement on chiral nanostructured Au films (CNAFs) equipped in the normal Raman scattering
141 and biphasic Rh-based core-shell nanosystem (Au@Rh-ICG-CM) is developed to address tumor hypoxia whil
142 hotothermal effect into a single nanosystem, Au@Rh-ICG-CM can readily serve as a promising nanoplatfo
143 hly-oriented [Formula: see text] nanotwinned Au films could be an ideal material in many gold product
145 (12)Pb(44)](8-), both of which contain nido [Au@Pb(11)](3-) icosahedra surrounding a core of Au atoms
147 tion of microscopic arrays composed of 50 nm Au nanoparticles situated underneath a graphene interfac
148 nm diameter Au NPs, 87.2 +/- 2.9% for 1.6 nm Au NPs, and an unprecedented full 100% Ag for 0.9 nm dia
149 the hue (color) value of thousands of 67 nm Au nanoparticles immobilized on a glass coverslip surfac
150 The proposed method is applied to obtain Au L-edge subtraction imaging of a Au-Ni grid test sampl
154 ) to create organometallic -ate complexes of Au(I) that serve both as WCAs and functional catalysts.
155 rated that a plasmonic thin film composed of Au nanoparticles embedded in a CuO matrix can be used to
156 ng an optical cavity substrate consisting of Au/Al(2) O(3) to enhance its absorption near the bandgap
158 fically, we demonstrate thermal dewetting of Au ultrathin metal films and growth of MoS(2) on NaCl at
161 red-shifting of the fluorescence emission of Au nanoclusters (AuNCs) into NIR-II region with improved
162 able the site-selective oxidative etching of Au(0), which leads to nonuniform growths along different
163 ontributed to the morphological evolution of Au-Ag nanocrystals synthesized with different DNA sequen
164 rimeter O(2) molecules (i.e., in the form of Au-O-O-Ti), facilitating O(2) activation and leading to
165 method based on core-satellite formation of Au nanoparticles was introduced for the detection of int
166 ying low-energy van der Waals integration of Au electrodes, we observed robust and optimized p-type t
168 better understand the molecular mechanism of Au-carbene binding to G-quadruplexes, we employed molecu
169 e support on directing the nanostructures of Au-based monometallic and bimetallic nanoparticles.
170 of each system with H(2) in the presence of Au-Pd NPs caused visual and irreversible color changes t
171 d in relation to the catalytic properties of Au-based monometallic and bimetallic nanoparticles using
174 triguingly, we show that the ligand shell of Au(25) nanoclusters becomes more fragile and rigid after
176 Au protuberances growth on the surface of Au@Pt NPs allowed their easy bioconjugation with antibod
177 se results highlight the untapped utility of Au catalysis in providing access to new macromolecular c
178 namics simulations to study the behavior of [Au(CH(3))(2))](-) in bulk and interfacial aqueous enviro
179 es of key hydrogen-bonded configurations of [Au(CH(3))(2))](-), combined distribution functions, and
181 nism shows that additional encapsulation of [Au(25)(Cys)(18)] into the CV treated polymer promotes re
182 reaction can be reversed by CO reduction of [Au(25)SR(19)](0), leading back to [Au(25)SR(18)](-) and
184 onolayer (SAM) and the influence of AuNPs on Au chip for Aflatoxin B(1) (AFB(1)) detection using SPRi
185 ingle-step aptasensor was developed based on Au nanocap-supported UCNPs (Au/UCNPs), which were partia
186 0'-(2,6-dimethylphenyl)-9,9'-bianthracene on Au(111) have been investigated by scanning tunneling mic
188 picture of photoinduced H(2) dissociation on Au clusters, which has important implications in plasmon
189 input from UV photoemission measurements on Au-protein systems, these striking differences in conduc
190 a brominated polycyclic aromatic molecule on Au(111) and demonstrate that standard STM measurements c
194 coordination sphere is closest to the other Au electrode, with which only physical contact is made.
196 Arrhenius studies during H(2) oxidation over Au/TiO(2) catalysts, we found different apparent activat
199 In this work, we designed and fabricated Pd/Au bimetallic thin film electrodes with isolated Pd nano
200 faces affect the nature and reactivity of Pd/Au surface electrochemistry including the adsorbed/absor
202 2)O(2) and 3-nitrotyrosine (3-NT)) at the Pd/Au thin film surfaces affect the nature and reactivity o
209 tween electrodes in a solid-state Au-protein-Au junction, have an orientation opposite that of WT Az
210 and rare-Earth metal ions (e.g. Ru, Ir, Pt, Au, Eu) in these applications by abundant ions are outli
213 e platinum/gold core-shell nanoparticles (Pt@Au NPs) as a signal probe, and a smartphone was develope
217 ed vdW interaction between the reconstructed Au(4)S(4) interfacial phase and TMD monolayers results i
218 or change response time within the resazurin/Au-Pd NP system revealed that the H(2)-sensing elements
222 than that on the oxygen vacancy (V(o))-rich Au/TiO(2) interface, at which electrons from Ti(3+) spec
226 ionalized lipoic acid AuNPs deposited on SAM Au chips followed by in situ activation of functional gr
228 polung of the F(n)ArH, followed by selective Au((I))/Au((III))-catalyzed coupling with electron-poor
229 o demonstrate this concept, we prepared n-Si/Au nanoparticle Schottky junctions by electrodeposition
230 ntational mobility was observed for a single Au-carbene binding at the second G-quadruplex surface.
232 lity of this method by producing single-site Au, Pd, Ru and Pt catalysts supported on carbon in a fac
234 (22) to both well-defined clusters and small Au(I)SR species was identified by ESI-MS and UV-vis spec
235 degradation simultaneously released smaller Au NPs as numerous cavitation nucleation sites and Mn(2+
236 sitioned between electrodes in a solid-state Au-protein-Au junction, have an orientation opposite tha
237 Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applicati
238 into allylic alcohols catalyzed by supported Au nanoparticles proceeds via an unsymmetrical concerted
241 ic peak current of VAN obtained with the T3T-Au electrode is 4.3 times greater than the bare Au elect
242 etermination of VAN was performed on the T3T-Au electrode using a differential pulse voltammetry (DPV
243 rformed on electroplated [Formula: see text] Au films show a hardness 47% greater than random and unt
245 n vitro and in vivo results demonstrate that Au@Rh-ICG-CM is able to effectively convert endogenous h
254 the manipulation of atomic structures at the Au/TiO(2) interface significantly alters the interfacial
255 Within the digold triazolate complexes the Au(I) atoms are held in close proximity but beyond the d
256 ulations predict lower work function for the Au/SnSe NHS compared to the SnSe NSs as the primary orig
257 xperimentally intriguing observations in the Au(I)-catalyzed cyclization of cyclic and acyclic acetal
258 the urease-bound aggregation kinetics of the Au and Ag NPs which has not been explored earlier by thi
263 n of the size transformation products of the Au(22)(SG)(18) nanocluster under representative working
264 y, we demonstrate selective promotion of the Au-C bond formation by controlling the bias applied acro
266 be explained by the observation that, on the Au electrode, water reduction improves with more alkalin
270 , despite limited electronic coupling to the Au electrode, demonstrating the potential of this approa
273 secondary pai-type interactions between the [Au@Pb(11)](3-) ligands and the gold core play a signific
274 H-related transformations suggests that the [Au(22) H(4) (dppo)(6) ](2+) nanohydride is a versatile m
275 The simulation results suggest that the [Au(CH(3))(2))](-) complex forms one and two gold-ion-ind
278 rs results in the transition from n-type TMD-Au Schottky contact to p-type one with reduced energy ba
279 d the extinction rates on the surface due to Au and Ag NPs aggregation and examined the variations du
280 at the sensors behaved almost identically to Au disk electrodes for the oxidation of an outer-sphere
281 ion regarding the bonding of aryl iodides to Au electrodes is a case in point, with ambiguous reports
283 Au(22) with a 10-atom bioctahedral kernel to Au(22)Cd(1) with a 13-atom cuboctahedral kernel, and cor
284 idene, binds even more strongly than NHCs to Au surfaces without altering the surface structure.
285 ction of [Au(25)SR(19)](0), leading back to [Au(25)SR(18)](-) and eliminating precisely one surface l
287 We then achieved direct bonding between two Au [Formula: see text] surfaces operating at 200 degrees
288 Whereas very restricted mobility of two Au-carbene ligands was found upon binding as a doublet t
290 veloped based on Au nanocap-supported UCNPs (Au/UCNPs), which were partially embedded in a solid subs
291 while also maintaining a partially uncoated Au surface to facilitate photocatalysis, were synthesize
295 u monitoring of cell-secreted dopamine using Au-coated arrays of micropyramid structures integrated d
296 , leaving behind a fluid phase enriched with Au adatoms that subsequently aggregate into supported cl
297 reen-printed carbon electrodes modified with Au nanoparticles decorated reduced graphene oxide flakes
298 ough an electrochemical sensor modified with Au nanostructures, LiClO(4) -doped conductive polymer, a