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1 CH was associated with older donor and recipient age.
2 CH-3-8 binding to the colchicine-binding site in tubulin
3 CH-3-8 is hydrophobic with an aqueous solubility of 0.97
4 CH-3-8 significantly inhibited the proliferation of thes
6 ystem in individuals with CH as follows: (1) CH was consistently present in myeloid cells but varied
7 e (i.e., CD(3)NO(2), CH(3)(15)NO(2), and (13)CH(3)NO(2)), revealing this easy-to-handle compound as a
8 N-CH(3,) -CDH(2,) -CD(2)H, -CD(3), and -(13)CH(3) groups into pharmaceutical amines thus has been de
9 1 and CHCl(3), CCl(4), HCFC-141b, HCFC-142b, CH(2)Cl(2), and HCFC-22, indicating co-location of the e
11 he known cyclometallated complex [Th{N(CH(2) CH(2) NSiPr(i) (3) )(2) (CH(2) CH(2) SiPr(i) (2) CHMeCH(
12 (Tren(TIPS) )(OCP)] (2, Tren(TIPS) =[N(CH(2) CH(2) NSiPr(i) (3) )](3-) ), with RbC(8) via [2+2+1] cyc
13 n of (R,R)-((iPr) DuPhos)Co(CO)(2) C(O)CH(2) CH(2) Ph, which upon hydrogenolysis under 4 atm H(2) pro
14 x [Th{N(CH(2) CH(2) NSiPr(i) (3) )(2) (CH(2) CH(2) SiPr(i) (2) CHMeCH(2) )}] (4) by thermolysis; ther
15 with the N-heterocyclic silylenes c-[(CR(2) CH(2) )(NtBu)(2) ]Si: (R=H or methyl) with saturated bac
16 (Me) L={(2,6-(i) Pr(2) C(6) H(3) )NC(Me)}(2) CH), was isolated via reaction of [(Me) LZnSCPh(3) ] (1)
17 complex [Th{N(CH(2) CH(2) NSiPr(i) (3) )(2) (CH(2) CH(2) SiPr(i) (2) CHMeCH(2) )}] (4) by thermolysis
18 lts show that (CH(3) (CH(2) )(3) NH(3) )(2) (CH(3) NH(3) )Pb(2) Br(7) (n = 2) layers undergo two dist
19 uranium-alkyl dimer, [Li(THF)(4) ](2) [U(2) (CH(3) )(10) ], as well as a seven-coordinate uranium-met
20 he magnitude and patterns of C loss (CO(2) , CH(4) and dissolved organic carbon) and soil-water quali
21 nm) exhibits ultra-high CO(2) /N(2) , CO(2) /CH(4) , and C(2) H(2) /C(2) H(4) binary selectivity, bnn
22 rganocatalysts with benzhydrylium ions (Ar(2)CH(+)) and structurally related quinone methides, common
23 t to Ar(2)I(+)) and LB (with respect to Ar(2)CH(+)) indicates that different factors control the ther
26 dreds of their structural analogues XM(YCH(2)CH(2))(3)N (M = Si, Ge, Sn, Pb, Ti, Al, Cr, Fe, Ni...; Y
27 zolidin-2-iminato groups (L is (NHC(R)=N)(2)(CH(3))P, where NHC(R) is an N-heterocyclic carbene).
28 hways for F(-) + CH(3)CH(2)Cl and PH(2)(-) + CH(3)CH(2)Cl using the activation strain model and Kohn-
29 rbon age measurements of inland water CO(2), CH(4) and dissolved and particulate organic carbon in no
31 opologues of nitromethane (i.e., CD(3)NO(2), CH(3)(15)NO(2), and (13)CH(3)NO(2)), revealing this easy
32 ies with similar sizes (CO(2)/N(2) and CO(2)/CH(4)), via precise mechanical control of the pore size
34 ed elimination (E2) pathways for F(-) + CH(3)CH(2)Cl and PH(2)(-) + CH(3)CH(2)Cl using the activation
35 for F(-) + CH(3)CH(2)Cl and PH(2)(-) + CH(3)CH(2)Cl using the activation strain model and Kohn-Sham
36 2)I(7) (with MA = CH(3)NH(3), and BA = CH(3)(CH(2))(3)NH(3)), and 3D MAPbI(3) using the magnetic fiel
38 (2) B(9) H(9) }Dy{eta(2) :eta(5) -C(6) H(4) (CH(2) )(2) C(2) B(9) H(9) }(2) Li] 3Dy and show that dic
39 HF)(3) (mu-H)(3) Li](2) [{eta(5) -C(6) H(4) (CH(2) )(2) C(2) B(9) H(9) }Dy{eta(2) :eta(5) -C(6) H(4)
40 CMOM-11R; 3-Cl, CMOM-21R; 4-Cl, CMOM-31R; 4-CH(3) , CMOM-41R) and the existing CF(3) SO(3) (-) varia
41 two-electron reduction in 0.1 M NBu(4)PF(6)/CH(2)Cl(2), cyclic voltammetry studies indicate a 1.8 x
42 dium(II)-oxo cluster [Pd(24) O(44) (OH)(8) ((CH(3) )(2) As)(16) ] (Pd(24) ) can be considered as a bi
43 dium(II)-oxo cluster [Pd(16) O(24) (OH)(8) ((CH(3) )(2) As)(8) ] (Pd(16) ) comprises a cyclic palladi
45 However, deeper sources of H(2) and abiotic CH(4) are missing from current models, which mainly invo
49 of the same lipid class with two additional CH(2) and three double bonds (Deltam/z = 0.0025) and the
52 ities of GHGs into the atmosphere (CO(2) and CH(4) ) when subjected to anthropogenic interferences (e
53 F with a modern signature for both CO(2) and CH(4) fluxes implying a microbial preference for the mor
57 uting to ecosystem respiration (R(eco) ) and CH(4) , while we continuously monitored soil temperature
63 s, indicate an unusual carbohydrate-aromatic CH-pai bonding that promotes glycopeptide self-assembly.
64 ics simulations to study the behavior of [Au(CH(3))(2))](-) in bulk and interfacial aqueous environme
65 The simulation results suggest that the [Au(CH(3))(2))](-) complex forms one and two gold-ion-induce
66 MA)Pb(2)I(7) (with MA = CH(3)NH(3), and BA = CH(3)(CH(2))(3)NH(3)), and 3D MAPbI(3) using the magneti
68 rboxylic acids and cyclopropylamines bearing CH(2)F, CHF(2), and CF(3) substituents were synthesized
69 studies establishing an association between CH and hematopoietic malignancy, discuss features of CH
70 el reaction, the Menshutkin reaction between CH(3)I and pyridine in three solvents of varying polarit
71 associated with the major abiotic and biotic CH(3)Cl sinks in the environment, namely, CH(3)Cl degrad
72 ical oxidation of CH(4) to methyl bisulfate (CH(3)OSO(3)H) at ambient pressure and room temperature w
75 h the unsaturated N-heterocyclic silylene c-(CH)(2) (NtBu)(2) Si: proceeds directly to the correspond
77 , chloroform (CHCl(3)), and methyl chloride (CH(3)Cl), are gases not regulated by the Montreal Protoc
78 3)][((Me(3)Si)(2)N)(2)U(mu-N)(mu-kappa(2):CN-CH(2)SiMe(2)NSiMe(3))U(N(SiMe(3))(2))(2)] (DME = 1,2-dim
80 eptic Fe(HMTO)(RO) [RO=(CH(3) )(2) CF(3) CO, CH(3) (CF(3) )(2) CO, or Ph(CF(3) )(2) CO] prepared in s
81 he PDF of microsites that produce or consume CH(4) and N(2) O, such that a range of microsites occurs
82 may complex with starch through non-covalent CH-pai bonds along alpha-(1 -> 4) glycosidic chains.
83 s, which are among the first eddy covariance CH(4) exchange data reported for any tropical peatland,
84 thaw and autumn freeze using eddy covariance CH(4) measurements from three Arctic sites with multi-ye
85 hich predominates the much higher cumulative CH(4) emission during autumn freeze (1,212.31 +/- 280.39
88 orocarbons, here defined as dichloromethane (CH(2)Cl(2)), perchloroethene (C(2)Cl(4)), chloroform (CH
93 ticulum (SR) Ca(2+) content increased during CH then decreased in HF (from 32 to 15 mum l(-1) ) poten
96 We identified 5 cases of donor-engrafted CH, with 1 case progressing into myelodysplastic syndrom
97 eased methane (CH(4)) emissions and enhanced CH(4) production rates throughout the entire soil profil
99 induced elimination (E2) pathways for F(-) + CH(3)CH(2)Cl and PH(2)(-) + CH(3)CH(2)Cl using the activ
101 (~ 950, ~ 1200, ~ 1400, ~ 1500 ng cm(-2) for CH(3), OH, COOH and NH(2) SAMs) were consistent with: sp
102 We did not observe higher concordance for CH within MZ twin pairs as compared with that within DZ
103 totroph community is an important driver for CH(4) production and its highly dynamic accumulation in
104 ematopoietic compartment (a common model for CH) displayed an exaggerated response to TLR9 agonism, i
105 e leads to an initial loss of formamidinium [CH(NH(2))(2) (+)] ions, leaving behind a partially unocc
106 Moreover, the partitioning of total fossil CH(4) emissions (presently 172 to 195 teragrams CH(4) pe
107 r times higher contribution of autumn freeze CH(4) emission to total annual emission than that of spr
111 mangrove F(CH4) reached a peak of over 0.1 g CH(4) -C m(-2) day(-1) during the summertime owing to a
112 heaters emitted 2390 [95% CI: 2250, 2540] g CH(4) yr(-1) on average, 0.93% [0.87%, 0.99%] of their n
114 ean annual CH(4) emission was 11.7 +/- 0.4 g CH(4) -C m(-2) year(-1) while the annual net ecosystem C
116 anges over the natural forest (9.1 +/- 0.9 g CH(4) m(-2) year(-1) ) were around twice as high as thos
123 enon in the context of clonal hematopoiesis (CH) and the development of therapy-related myeloid neopl
128 gnificantly lower in cerebellar hemispheres (CH) (1.239 vs. 1.280.5 x 10(-3) mm(2)/s, p = 0.045), tha
131 Autumn freeze exhibits significantly higher CH(4) flux (0.88 +/- 0.03 mg m(-2) hr(-1) ) than spring
132 om the formation of compensated hypertrophy (CH) until signs of heart failure (HF) are apparent using
137 anol under mild acid-catalyzed conditions in CH(2)Cl(2) followed by oxidation with DDQ (2,3-dichloro-
141 The chemical shifts of the (1)H nuclei in CH(3) and NH(3) remained constant with increasing temper
143 rvations showed a clear diurnal variation in CH(4) exchange over the natural forest where the GWL was
147 O flux to 0.06 g m(-2) yr(-1) and increasing CH(4) 8-fold to 0.8 g m(-2) yr(-1), the meadow now offse
148 delta(18)O-delta(34)S correlation indicates CH(4) advection at the studied site during the Early Hol
149 eaction of the simplest Criegee intermediate CH(2)OO with methane has been performed using the densit
154 ests resulted in that they emitted at 340 kg CH(4) d(-1) during flooded periods despite their substan
155 emonstrated a clear and consistent diel lake CH(4) flux pattern during stratification and mixing peri
156 ng emissions of other (isotopically-lighter) CH(4) source terms is dominating the increase in global
157 report the synthesis of a vinylene-linked (-CH=CH-) covalent organic framework, COF-701, directly fr
158 nductors, 2D (BA)(2)(MA)Pb(2)I(7) (with MA = CH(3)NH(3), and BA = CH(3)(CH(2))(3)NH(3)), and 3D MAPbI
162 the relationship between rumen metabolites, CH(4) production and diets, as well as showing that meta
167 to account for over half of annual methane (CH(4) ) emissions and can offset summer photosynthetic c
168 The AD-composting process avoids methane (CH(4)) emissions from landfilling, but emissions of othe
169 ctive C sinks of the biosphere, but methane (CH(4)) emissions can offset their climate cooling effect
170 ing a relatively high amount of dry methane (CH(4)) in the adsorbed phase are largely explored; howev
173 The accelerated increase in global methane (CH(4)) in the atmosphere, accompanied by a decrease in i
174 Our compound exhibits a higher methane (CH(4)) sorptivity as compared to CO(2) at 25 degrees C a
175 Warming exponentially increased methane (CH(4)) emissions and enhanced CH(4) production rates thr
176 sumption of nitrous oxide (N(2) O), methane (CH(4) ), and carbon dioxide (CO(2) ) are affected by com
178 ling simulations allow the study of methane (CH(4)) sources and sinks at any geographic location.
179 ls, and ~63,000 active wells, whose methane (CH(4)) emissions remain largely unquantified at levels b
180 ur novel 4AP derivatives containing methyl (-CH(3)), methoxy (-OCH(3)) as well as trifluoromethyl (-C
182 ) compared to the intact PSF (4.0 +/- 2.0 mg CH(4) m(-2) hr(-1) ) due to prolonged higher WT and more
183 igher in fire-affected areas (7.8 +/- 2.2 mg CH(4) m(-2) hr(-1) ) compared to the intact PSF (4.0 +/-
184 nese(II) to form lithium manganate [Li(2) Mn(CH(2) SiMe(3) )(4) ] enables the efficient direct Mn-I e
186 ependent clones in individuals with multiple CH mutations; and (3) telomere shortening determined in
187 st rate of methane production was 0.15 mumol CH(4) g(-1) oil d(-1) , orders of magnitude lower than o
189 tionalized phosphinines, starting from a 3-N(CH(3) )(2) -substituted 2-pyrone and (CH(3) )(3) Si-C=P.
190 such as the degree of pyramidality of the N(CH(2))(3) moiety-the positive end of the molecular dipol
191 and the known cyclometallated complex [Th{N(CH(2) CH(2) NSiPr(i) (3) )(2) (CH(2) CH(2) SiPr(i) (2) C
192 of [Th(Tren(TIPS) )(OCP)] (2, Tren(TIPS) =[N(CH(2) CH(2) NSiPr(i) (3) )](3-) ), with RbC(8) via [2+2+
194 ic CH(3)Cl sinks in the environment, namely, CH(3)Cl degradation by hydroxyl ((.)OH) and chlorine ((.
198 e, Sn, Pb, Ti, Al, Cr, Fe, Ni...; Y = O, NR, CH(2), S), i.e., substituted 5-azabicyclo[3.3.3]undecans
199 In this work, we show that [Fe(II)(Me(3)NTB)(CH(3)CN)](CF(3)SO(3))(2) (Me(3)NTB = tris((1-methyl-1H-b
200 ception of (R,R)-((iPr) DuPhos)Co(CO)(2) C(O)CH(2) CH(2) Ph, which upon hydrogenolysis under 4 atm H(
202 onoxide to give a cyclic five-membered P(=O)-CH(2)-B compound, the product of reductive cleavage of c
203 reduce the uncertainty in the estimation of CH(4) emissions from a globally important ecosystem, pro
204 hematopoietic stressors in the evolution of CH to acute myeloid leukemia or myelodysplastic syndrome
205 ematopoietic malignancy, discuss features of CH that are predictive of leukemic progression, and expl
206 S as a novel tool to reconstruct the flux of CH(4) emissions in geological records and to indirectly
208 iations between PTH-CH and family history of CH (OR 3.32, 95% CI 1.31 to 8.63), chronic form (OR 3.29
210 we performed high-resolution measurements of CH(4) flux from several lakes, using an automated and se
211 eport selective electrochemical oxidation of CH(4) to methyl bisulfate (CH(3)OSO(3)H) at ambient pres
214 r findings demonstrate a high sensitivity of CH(4) emissions to global change with important implicat
216 e among the largest anthropogenic sources of CH(4) emissions, but the precise magnitude of these cont
219 Finally, we examine stressor effects on CH(4) emissions from VCEs and we hypothesize that future
220 tigate the influence of heritable factors on CH, we performed deep targeted sequencing of blood DNA f
221 II(8-14) and full-length fibronectin (FN) on CH(3)-, OH-, COOH-, and NH(2)-terminated alkane-thiol se
223 lling 'side-on' orientation and unfolding on CH(3) SAM; greater numbers of FN molecules arranged 'end
226 regioselectively yielded either 5'-dAdo. or .CH(3), and indeed, each of the three SAM S-C bonds can b
227 rbon dioxide to give a bicyclic product by P-CH(2) attack on CO(2) combined with internal P=O to boro
228 e derivatives PBN-CH(2)NHAc, 4-AcNHCH(2)-PBN-CH(2)NHAc, and 4-MeO-PBN-CH(2)NHAc were the easiest to o
231 ry low concentrations (0.1-10 muM), with PBN-CH(2)NHAc and 4-HOOC-PBN being the two most promising ag
233 ol cohort included 553 patients with primary CH without any history of trauma who attended the headac
235 evealed significant associations between PTH-CH and family history of CH (OR 3.32, 95% CI 1.31 to 8.6
239 ental evidence of gas-phase methyl radicals (CH(3) (.) ) in the ODHP reaction over boron-based cataly
242 s due to Ab-induced membrane-associated ring CH (MARCH) E3 ubiquitin ligase-mediated ubiquitination a
243 d or mice that lack membrane-associated RING-CH 8 (MARCH8), the E3 ubiquitin ligase responsible for M
244 The use of heteroleptic Fe(HMTO)(RO) [RO=(CH(3) )(2) CF(3) CO, CH(3) (CF(3) )(2) CO, or Ph(CF(3) )
247 Through several mechanisms, including short CH...F contacts, bifurcation, and long-range dispersion,
250 eter, water level, soil temperature and soil CH(4) fluxes explained 54% of the variance in stem CH(4)
252 d phase are largely explored; however, solid CH(4) storage in confined pores of MOFs in the form of h
256 ated that contemporary N addition suppresses CH(4) sink in global grassland by 11.4% and concurrent N
257 ut the entire soil profile; although surface CH(4) production rates remain much greater than those at
258 4) emissions (presently 172 to 195 teragrams CH(4) per year)(2,3) between anthropogenic and natural g
260 ventory estimates total emissions of 0.53 Tg CH(4)/yr [0.40-0.71 Tg CH(4)/yr, 95% CI] and corresponds
261 (2) and total CH(4) emission is 13.8-17.7 Tg CH(4) year(-1): 11.2-14.4 Tg via diffusion and ebullitio
262 emissions of 0.53 Tg CH(4)/yr [0.40-0.71 Tg CH(4)/yr, 95% CI] and corresponds to a loss rate of 2.9%
265 itionally, we report for the first time that CH-pai interactions at Phe28 directly contribute to AF9'
270 for both hydrogen atom abstraction from the CH reagent and the selective formation of the C-O coupli
271 ffluents and high temperatures, while in the CH test chamber, the samples were exposed mainly to fire
276 perimental results show that a lens with the CH structure has good focusing intensity and can focus a
281 seagrass ecosystems are about 0.33-0.39 Tmol CH(4) -C/year-an addition that increases the current glo
282 normoxic ventilation with acclimatization to CH, indicating this is a distinct mechanism from the inc
284 of the base and subsequently hydrogenated to CH(3)OH at relatively mild temperatures (100-140 degrees
285 , we review proposed mechanisms that lead to CH, specifically in the context of stem cell biology, ba
287 ea of lakes is 1,095 x 10(3) km(2) and total CH(4) emission is 13.8-17.7 Tg CH(4) year(-1): 11.2-14.4
289 f appliances, contributing to 0.14% of total CH(4) emissions from the NG sector in the United States.
293 rt a Mars van Krevelen redox mechanism where CH(4) is activated by reaction with a hematite surface o
296 ) at equivalent oxidant concentrations, with CH(3)C(O)OO(*) as the most abundant carbon-centered radi
297 Salinity was negatively correlated with CH(4) emissions from salt marshes, but not seagrasses an
299 the hematopoietic system in individuals with CH as follows: (1) CH was consistently present in myeloi