ライフサイエンスコーパス: MOF

1 MOF-525-J33 with 15.6 angstrom inter active-site distanc

2 MOFs synthesized with rare-earth (RE) elements, which in

3 MOFs with intrinsic thermocatalytic activity, as hosts f

4 At present, over 90,000 MOFs have been synthesized and over 500,000 predicted.

5 MOF-808 can produce up to 8.66 L(H2O) kg(-1)(MOF) day(-1), an extraordinary finding that outperforms

6 The utility of 2D MOFs in voltammetric sensing is measured by the detectio

7 thanide (Ln(3+)) materials, including Ln(3+) MOFs and Ln(3+) salts.

8 articles (NPs) embedded in a Zr-based UiO-67 MOF was subject to steady-state and transient kinetic st

9 The MOFs are then crosslinked into a MOF-polythiourea (MOF-PTU) composite material, maintaini

10 tradeoff between the catalytic activity of a MOF and its resistance to unzipping.

11 e of practical, rather than purely academic, MOF developments in the increasingly critical field of e

12 Here, we show that histone acetyltransferase MOF plays a critical role in this process through direct

13 us MOFs, monolayer MOF nanosheets, amorphous MOF liquids and glasses, polymers, metal nanoparticles,

14 n encoded in the newly formed SBUs drives an MOF-to-MOF conversion into bipartite nets compatible wit

15 the largest Forster distances observed in an MOF.

16 ps of Zr(6)O(8) nodes in the MOFs UiO-66 and MOF-808, which have different densities of vacancy sites

17 nships among these groups, node defects, and MOF stability, and how do reaction conditions influence

18 wis acid-base interaction), between F(-) and MOF host, a highly selective, sensitive, and reliable fl

19 ic acid) (pbdc) polymers in two archetypical MOF lattices (UiO-66 and IRMOF-1).

20 o tailor the size and shape of peptide-based MOF single crystals to specific applications.

21 Here, we report a series of lanthanide-based MOFs that allow fine tuning of the sheet stacking.

22 ein, the excitation bands of ytterbium-based MOFs are extended to 800 nm via the postsynthetic coupli

23 The linkage between MOF and tumor proliferation suggests that there are addi

24 s, to study and clarify interactions between MOFs and biological milieu, human whole blood plasma was

25 The impact of this concept on "breathing" MOFs is discussed. I(2) sorption, both from gas phase an

26 ap while it has no observable effect on bulk MOFs.

27 Conductive metal-organic frameworks (c-MOFs) have drawn increasing attention for their outstand

28 However, the majority of reported c-MOFs are based on 2D structures.

29 ional modes, can be observed for carboxylate MOFs by monitoring the red-shifts of carboxylate stretch

30 to screen 1632 experimentally characterized MOFs.

31 A new cobalt metal-organic framework (2D-Co-MOF) based on well-defined layered double cores that are

32 Electrochemical activation of a 2D-Co-MOF@Nafion-modified graphite electrode in aqueous soluti

33 omparison with previously explored concepts (MOF = constant; guest = variable).

34 electrode modified with a film of conductive MOF (M(3)HXTP(2); M = Ni, Cu; and X = NH, 2,3,6,7,10,11-

35 view of outstanding challenges in conductive MOFs.

36 core in a family of isostructural conductive MOFs with Mn(2+) , Zn(2+) , and Cd(2+) .

37 ere V(p) is the pore volume of corresponding MOFs.

38 ined data in the current study, the designed MOF can be introduced as a new desirable carrier for dru

39 The analytical performance of each MOF for detecting PFOA was correlated with both the calc

40 o enhance the efficiency of electrocatalytic MOFs should also consider other important kinetic parame

41 Upon laser exposure, MOF crystals shrank while metal oxide nanoparticles form

42 ve the CO selectivity from 74% for Ag/Zr-fcu-MOF-1,4-benzenedicarboxylic acid (BDC) to 94% for Ag/Zr-

43 dicarboxylic acid (BDC) to 94% for Ag/Zr-fcu-MOF-1,4-naphthalenedicarboxylic acid (NDC).

44 show that the thermostabilities of ferritin-MOFs can be tuned through the metal component or the pre

45 eraging the synthetic modularity of ferritin-MOFs, we investigated the temperature-dependent structur

46 We report a family of flexible MOFs based on derivatized amino acid linkers.

47 The targeted design of flexible MOFs demands control over the macroscopic thermodynamics

48 ralayer space of two-dimensional fluorinated MOFs for capturing acetylene from ethylene.

49 For MOF chemists, the chemical design space is a combination

50 tperforms any previously reported values for MOF-based systems.

51 demonstrate superior accuracy especially for MOFs with high surface area (i.e., S(BET) over ~3000 m(2

52 boxylate (BTC(3-) ) ligand reagents, to form MOF nanocrystals, and collect and characterise them on a

53 framework aperture (metal-organic framework (MOF) = variable; guest = constant) was probed for the fi

54 (2) -MIL-125(Ti), a metal-organic framework (MOF) constructed from TiO(x) clusters and 2-aminoterepht

55 res of a conductive metal-organic framework (MOF) electrode under operating conditions.

56 erately design a Th-metal-organic framework (MOF) for highly efficient separation of C(2)H(4) from a

57 in a dual-function metal-organic framework (MOF) is reported.

58 Metal-organic framework (MOF) nanoparticles, also called porous coordination poly

59 ein we report how a metal organic framework (MOF) synthetic route can be optimized using an in situ m

60 K-1, a water-stable metal-organic framework (MOF) with 1-D channels, was synthesized in basic water.

61 on of an iron-based metal-organic framework (MOF) yielded well-dispersed pyrite FeS(2) nanoparticles

62 s of a water-stable metal-organic framework (MOF), Fe-HAF-1, constructed from supramolecular, Fe(3+)-

63 ligand Zr(IV)-based metal-organic framework (MOF),with underlying fcu topology, encompassing the [Zr(

64 adiation study of a metal-organic framework (MOF).

65 the first plutonium metal-organic framework (MOF).

66 materials, such as metal-organic frameworks (MOF), has been extensively investigated over the past fe

67 ostmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials wi

68 nd modular nature, metal-organic frameworks (MOFs) are an excellent platform material for systematica

69 Metal-organic frameworks (MOFs) are an intriguing type of crystalline porous mater

70 Metal-organic frameworks (MOFs) are appealing heterogeneous support matrices that

71 orous, crystalline metal-organic frameworks (MOFs) are examined with regard to recent benchmark resul

72 Metal-organic frameworks (MOFs) are hybrid materials composed of metal ions and or

73 Metal-organic frameworks (MOFs) are intriguing host materials in composite electro

74 Metal-organic frameworks (MOFs) are promising materials for onboard hydrogen stora

75 layered conductive metal-organic frameworks (MOFs) as drop-casted film electrodes that facilitate vol

76 directly construct metal-organic frameworks (MOFs) as enzyme protective carriers is presented.

77 sis of ultraporous metal-organic frameworks (MOFs) based on metal trinuclear clusters, namely, NU-150

78 Porous metal-organic frameworks (MOFs) capable of storing a relatively high amount of dry

79 tigate a family of metal-organic frameworks (MOFs) containing triazolate linkers, M(2) X(2) (BBTA) (M

80 al conductivity in metal-organic frameworks (MOFs) has been an open question.

81 de perovskites and metal-organic frameworks (MOFs) has generated a new family of porous composite mat

82 rically conductive metal-organic frameworks (MOFs) has led to applications in chemical sensing and el

83 In that sense, metal-organic frameworks (MOFs) have been utilized to assemble unpreceded concentr

84 Metal-organic frameworks (MOFs) have drawn wide attention as candidate catalysts,

85 Semiconductive metal-organic frameworks (MOFs) have emerged in applications such as chemical sens

86 porous materials, metal-organic frameworks (MOFs) hold substantial promise as adsorbents for highly

87 Processing metal-organic frameworks (MOFs) into hierarchical macroscopic materials can greatl

88 e heterobimetallic metal-organic frameworks (MOFs) is now achieved by polymerization of molecular Ru(

89 Metal-organic frameworks (MOFs) offer a high potential for this application due to

90 for elaboration of metal-organic frameworks (MOFs) post-synthesis.

91 Conductive metal organic frameworks (MOFs) represent a promising class of porous crystalline

92 her development of metal-organic frameworks (MOFs) requires an establishment of hierarchical interact

93 ctures inherent to metal-organic frameworks (MOFs) together with the facile tunability of their prope

94 namic stability of metal-organic frameworks (MOFs) using a model set of eight isostructural zeolitic

95 Metal-organic frameworks (MOFs) with coordinatively unsaturated metal sites are ap

96 Metal-organic frameworks (MOFs), atomically precise hybrid materials that are synt

97 Metal-organic frameworks (MOFs), constructed from organic linkers and inorganic bu

98 ncapsulated inside metal-organic frameworks (MOFs), thereby allowing us to improve CO(2)RR electrocat

99 ased on sulfonated metal-organic frameworks (MOFs), UiO-66-X, X = SAG, NH-SAG, (NH-SAG)(2) (SAG: sulf

100 carboxylate-based metal-organic frameworks (MOFs), we present general evidence that challenges the c

101 Recently, metal-organic frameworks (MOFs), which are crystalline coordination polymers with

102 ) into porphyrinic metal-organic frameworks (MOFs).

103 from multivariate metal-organic frameworks (MOFs).

104 key properties of metal-organic frameworks (MOFs).

105 lass of materials, metal-organic frameworks (MOFs).

106 ticles or extended metal organic frameworks (MOFs)/metal-carbon composites, etc.

107 r work opens an avenue to develop functional MOF channels for selective ion conduction and efficient

108 defects, or "microstructure", in functional MOF design.

109 ery and development of stable and functional MOFs for practical applications.

110 recent innovations of aptamer-functionalized MOFs-based biosensors and their bio-applications.

111 Functionally, MOF is found in two distinct complexes: NSL (nonspecific

112 The resulting crystalline heterobimetallic MOFs are solid solutions of Ru(2) and Cu(2) sites housed

113 ion spectra of a two-fold interpenetrated Hf MOF, linked by 1,4-phenylene-bis(4-ethynylbenzoate) liga

114 more exposed active sites of this design, HP-MOFs exhibited an enhanced catalytic efficiency in styre

115 nker labilization for the construction of HP-MOFs have emerged.

116 e nanoparticles formed giving rise to the HP-MOFs.

117 In addition, the discovery of the new RE-hpt-MOF-1 and RE-ken-MOF-1 families of MOFs highlights the g

118 of several tens of thousands of hypothetical MOFs are evaluated at various thermodynamic conditions u

119 but dynamic bonding would explain important MOF phenomena in catalysis, postsynthetic exchange, nega

120 However, despite recent advances in MOF-based electrocatalysis, so far no attempt has been m

121 are discussed while recent breakthroughs in MOF processing are highlighted.

122 nected pores for efficient ion conduction in MOF/IL blends, whereas pore symmetry is a less stringent

123 ls after the training of the ML algorithm in MOFs.

124 Structural dynamics in MOFs, however, typically refers to the "breathing" behav

125 umber of Reviews have covered flexibility in MOFs.

126 anic qubit candidates have been installed in MOFs despite their structural variability and promise fo

127 cess the underlying free energy landscape in MOFs.

128 for characterizing adsorption mechanisms in MOFs.

129 l engineering of multiple catalytic sites in MOFs thus presents a unique opportunity to address outst

130 fer and inaccessibility of internal space in MOFs.

131 far to achieve efficient charge transport in MOFs.

132 od enables the good dispersion of individual MOF nanoparticles on a spiderweb-like network within eac

133 haracterization tools, which can interrogate MOFs under realistic synthesis as well as catalysis (or

134 sition dipoles) and then assembled them into MOFs.

135 directs the formation of new RE-MOFs, RE-ken-MOF-1 (RE: Y(3+), Ho(3+), Er(3+), Yb(3+)), that display

136 discovery of the new RE-hpt-MOF-1 and RE-ken-MOF-1 families of MOFs highlights the great opportunitie

137 hermodynamics of two flexible pillared-layer MOFs.

138 emonstrate that high conductivity in layered MOFs does not necessarily require a metal-ligand bond wi

139 d NH-linked analogs, CoPc-based and O-linked MOFs have lower activation energies in the formation of

140 ward the further practical application of Ln-MOF-based luminescent thermometers in various fields and

141 and temperature sensing behaviour of the Ln-MOF powder but also excellent mechanical properties, suc

142 ure and is water stable, highlighting FeNi-M'MOF as a promising material for C(2) H(2) /CO(2) separat

143 2) molecules and the binding sites of FeNi-M'MOF.

144 Mechanistically, MOF/FAO inhibition acts through reducing mitochondrial r

145 ncorporation of large polymers in mesoporous MOFs.

146 nkers to create mesopores within microporous MOFs at tens of milliseconds.

147 f of concept, the capacity to utilize the Mn-MOF for electrochemical CO(2) fixation and to spectrosco

148 e manganese 1,4-benzenedicarboxylate (MnBDC) MOFs with a precise control over their morphology (bulk

149 on and emission properties of these modified MOFs are maintained in the biological conditions of cell

150 ine)(3) ](NO(3) )(2) , CMOM-1S, is a modular MOF; five new variants in which counterions (BF(4) (-) ,

151 luding hierarchically porous MOFs, monolayer MOF nanosheets, amorphous MOF liquids and glasses, polym

152 within a complex cavity of a multicomponent MOF.

153 that metal-organic framework nanoparticles (MOF NPs) densely functionalized with oligonucleotides ca

154 the synthesis and characterization of a new MOF prepared with the use of bismuth and dithieno[3,2-b:

155 , we employed net-clipping to form three new MOFs built with zigzag ligands, each of which exhibits t

156 ction as model, our strategy exploits the NP@MOF interface to create a pseudo high-pressure CO(2) mic

157 c substrate in this study is fixed at the NP@MOF interface to facilitate spectroscopic investigations

158 oughs and milestones realized in the area of MOF-based small-scale swimmers.

159 first briefly summarizes this background of MOF nanoparticle catalysis and then comprehensively revi

160 werful tools for initial characterization of MOF materials and for studying processes of their intera

161 Maternal depletion of MOF acetyltransferase leading to H4K16ac loss causes abe

162 The spatial distribution of MOF functionalization reveals that postsynthetic modific

163 Dysregulation of MOF activity occurs in multiple cancers, including ovari

164 how that these variations in the enthalpy of MOF formation are in linear correlation to the readily a

165 Moreover, zygotic re-expression of MOF was neither able to restore embryonic viability nor

166 uture research possibilities in the field of MOF characterization.

167 r to tailor the electrocatalytic function of MOF-anchored active sites at the molecular level.

168 gests that there are additional functions of MOF that remain to be discovered.

169 -1s surface, so the possible interactions of MOF-1s with fibrinogen also studied using fluorescence s

170 s, understanding the fundamental kinetics of MOF-based molecular catalysis of electrochemical reactio

171 of Fe atoms centered in porphyrin linkers of MOF sets the first protective barrier to inhibit the Fe

172 nce that challenges the common perception of MOF metal-linker bonds being static.

173 MOF layer on anode and filling the pores of MOF with hydrophobic Zn(TFSI)(2) -tris(2,2,2-trifluoroet

174 um frameworks by metal-exchange reactions of MOF crystals at temperatures below those conventionally

175 w, the recent advances in the application of MOFs in heterogeneous catalysis are discussed.

176 to predict the hydrogen storage capacity of MOFs with different pore geometries.

177 , in the first instance, the cytotoxicity of MOFs (particularly those used for various biological app

178 he dynamics of PSM can support the design of MOFs with increasingly sophisticated architectures.

179 eview, recent advances in the development of MOFs for separation of selected groups of hydrocarbons a

180 ew RE-hpt-MOF-1 and RE-ken-MOF-1 families of MOFs highlights the great opportunities existing in RE-M

181 teen lanthanides are an intriguing family of MOFs from the standpoint of both structure and function.

182 me of the highest in the entire RE family of MOFs.

183 Peculiarities of MOFs interaction with specific gases and some inconsiste

184 er, solid CH(4) storage in confined pores of MOFs in the form of hydrates is yet to be discovered.

185 " approach utilizes the inherent porosity of MOFs and host-guest interactions.

186 ed at selected crystallographic positions of MOFs promoted their photocatalytic efficiency.

187 thod for studying sorption depth profiles of MOFs.

188 the well-established designer properties of MOFs and, therefore, increase the scope of possibilities

189 undoubtedly the most studied key property of MOFs, that allows the protection of active biomolecules

190 significant progress made on this series of MOFs since 2018 is summarized and an update on the curre

191 e underline the MIL-, UiO- and ZIF-series of MOFs which remain until now the most used materials in d

192 learning method to quantify similarities of MOFs to analyse their chemical diversity.

193 the O(2) affinity at the open metal sites of MOFs for applications involving the strong and/or select

194 The stability of MOFs is a key prerequisite for their potential practical

195 To further enrich the synthetic toolkit of MOFs, we report a controlled photolytic removal of linke

196 ed net-clipping to predict the topologies of MOFs containing zigzag ligands.

197 review highlights the advances in the use of MOFs in the elimination (adsorption and/or degradation)

198 methods should be applicable to a variety of MOFs, and scaling up synthesis possible via arrays of na

199 Single-crystal X-ray analyses on MOF-1 showed that Cu(+2) ion was 6-coordinated.

200 to get well-defined single site catalyst on MOF inorganic secondary building units, in particular th

201 nce in the next years concerning research on MOFs, to see if some of these materials may reach the en

202 w is expected to provide a timely summary on MOFs based on group 3 and 4 metals, which shall guide th

203 mples of delivery of multiple drugs from one MOF are rare, potentially hampered by difficulties in po

204 The optimized MOF-sensor had a CN(-) -detection limit of 0.05 mum, whi

205 erning nucleation and growth mechanisms in p-MOF systems.

206 The structural evolution of p-MOFs was probed by cryo-transmission electron microscopy

207 al sites in the acs net are retained in pacs MOFs; two thirds are used for pore-space partition.

208 way for the design and synthesis of periodic MOFs affording very efficient and fast ET to mimic natur

209 as low as about one-third of that for peroxo-MOF-74-Fe (66.8 kJ/mol).

210 tm and 298 K, more than twice that of peroxo-MOF-74-Fe, has been achieved even though the isosteric h

211 ion potentials have not yet surpassed peroxo-MOF-74-Fe, these robust CPMs exhibit outstanding propert

212 itions was constructed using a 5x5 pixelated MOF-based imager.

213 erves as the foundation for future plutonium MOF chemistry.

214 re then crosslinked into a MOF-polythiourea (MOF-PTU) composite material, maintaining the catalytic p

215 ng materials including hierarchically porous MOFs, monolayer MOF nanosheets, amorphous MOF liquids an

216 Importantly, DNA-modified porphyrinic MOF nanorods (PCN-222) were assembled into 2D superlatti

217 industrial limitations of typically powdered MOFs are discussed while recent breakthroughs in MOF pro

218 heir unique tripartite construction, protein-MOFs possess extremely sparse lattice connectivity, sugg

219 ed protein-metal-organic frameworks (protein-MOFs) as chemically designed protein crystals, composed

220 These values are the highest among all RE MOFs based on nonanuclear clusters and some of the highe

221 eport a series of mesoporous rare-earth (RE) MOFs that are constructed from an unusual 12-connected p

222 ights the great opportunities existing in RE-MOFs in terms of structural diversity that could lead to

223 edral linker directs the formation of new RE-MOFs, RE-ken-MOF-1 (RE: Y(3+), Ho(3+), Er(3+), Yb(3+)),

224 First, diverse structures of RE-MOFs are presented, divided into classes based on the co

225 Recently, MOF materials, featuring high surface areas, rich struct

226 Four water-resistant MOFs-ZIF-8, UiO-66, MIL88-A, and Tb(2)(BDC)(3)-were coat

227 ochromic molecules integrated inside a rigid MOF scaffold are discussed.

228 re trends on the structural design of robust MOFs with high connectivity is provided.

229 thermoplastic dispersal of a semiconductive MOF (SCU-13) through a commercially available polymer, p

230 However, examples of semiconductive MOFs within flexible electronics have not been reported.

231 inatively unsaturated metal sites of several MOF families.

232 empirical equations are validated by several MOFs with an average deviation of 5.4%.

233 on Cr-soc-MOF-1 vs smaller cavities of Y-shp-MOF-5.

234 unt of methane stored in the pores of Cr-soc-MOF-1 in the form of MH was found to be ~50% larger than

235 experimental case study performed on Cr-soc-MOF-1 vs smaller cavities of Y-shp-MOF-5.

236 In this study, an exceptionally stable MOF catalyst consisting of Pt nanoparticles (NPs) embedd

237 ut this review), and shows that for standard MOFs based on metals already present in active molecules

238 The rational design of 3D structures (MOFs, COFs, etc.) is presently limited by our understand

239 Switchable MOFs are a type of smart material that undergo distinct,

240 The synthesized MOF Azole-Th-1 shows a UiO-66-type structure with fcu to

241 The findings allow tailoring MOF microstructure to application.

242 We show how targeting MOFs toward mitochondria represents a valuable strategy

243 The Zn(TFSI)(2) -TFEP@MOF electrolyte protected Zn anode enables a Zn||Ti cell

244 The present study underscores that MOFs are promising to develop artificial LHCs, but that

245 The MOF acetyltransferase-containing Non-Specific Lethal (NS

246 The MOF can be loaded with organic molecules by immersion in

247 The MOF encapsulated Zn(TFSI)(2) -TFEP forms a ZnF(2) -Zn(3)

248 integrity of the POM, the catalyst, and the MOF after catalysis.

249 der Waals interaction between ethane and the MOF skeleton.

250 first quantifiable relationship between the MOF thermodynamics and the linker structure, suggesting

251 analytical method was achieved, despite the MOF-functionalized probe approach being ~40 times quicke

252 gher than the number of open Zr sites in the MOF lattice around each Pt NP.

253 We directly image defect nanodomains in the MOF UiO-66(Hf) over an area of ca. 1000 nm and with a sp

254 sized to arise from diffusion rates into the MOF that are slower than linker exchange.

255 maintaining the catalytic properties of the MOF and the flexibility of the polymer.

256 guest interactions by chemical tuning of the MOF backbone.

257 M is encapsulated within the cavities of the MOF by in situ synthesis, and then, the Rh catalytic com

258 of the MOF, magnetometry measurements of the MOF containing only N-oxide pillars demonstrated magneti

259 NPs are well dispersed on the surface of the MOF crystals and have a narrow size distribution.

260 th both the calculated binding energy of the MOF for PFOA and the relative change in the surface area

261 e relative change in the surface area of the MOF upon exposure to PFOA.

262 ntrol over the nanoparticle synthesis of the MOF, HKUST-1, is achieved using a nanopipette injection

263 solvent removal causes decomposition of the MOF, magnetometry measurements of the MOF containing onl

264 of the POM in the octahedral cavities of the MOF: one at the center of a UiO-67 pore with the Cp*Rh c

265 protein showed the maximum frequency on the MOF-1s surface, so the possible interactions of MOF-1s w

266 synthesis and are distributed throughout the MOF at defect sites by coordination to the metal cluster

267 s presented that can simultaneously tune the MOF loading, composition, spatial distribution, and conf

268 veals that most of the void space within the MOF is accessible to the solvent.

269 The MOFs are grown on Si/SiOx substrates modified with an or

270 The MOFs are then crosslinked into a MOF-polythiourea (MOF-P

271 romine intercalation is possible between the MOFs layers for the first time.

272 ities of OH groups of Zr(6)O(8) nodes in the MOFs UiO-66 and MOF-808, which have different densities

273 of Ag nanoparticles incorporated inside the MOFs with the increase of local CO(2) concentration.

274 drug to be postsynthetically loaded into the MOFs to yield nanoparticles loaded with cocktails of dru

275 dles for postsynthetic polymerization of the MOFs into functional materials.

276 situ Raman spectroscopy, we reveal that the MOFs are stable under operating conditions and that this

277 These MOF carriers can also serve as the disintegrating agents

278 nd versatile coordination modes within these MOFs endow the framework with high chemical stability, d

279 electrolyte from Zn anode by coating a thin MOF layer on anode and filling the pores of MOF with hyd

280 This MOF shows not only a remarkable volumetric C(2) H(2) upt

281 This MOF-PTU hybrid material was spray-coated onto Nyco texti

282 The phyiscal characteristics of this MOF family are insensitive to changes in the metal catio

283 ntrinsic redox character endow the 2D Cu-THQ MOF with promising electrochemical activity.

284 density of conjugated pai-systems throughout MOF pores.

285 Zn) and MUV-102(Cu), heterometallic titanium MOFs isostructural with archetypical solids such as MIL-

286 les the formation of heterometallic titanium MOFs not accessible under solvothermal conditions at hig

287 tablishes the importance of applying SOMC to MOF chemistry to get well-defined single site catalyst o

288 t have been reported for imparting motion to MOFs.

289 ed in the newly formed SBUs drives an MOF-to-MOF conversion into bipartite nets compatible with the c

290 with high precision, paving the way towards MOF lithography, which has enormous potential in sensing

291 cture, suggesting a route to design and tune MOF stability.

292 ecting a presynthesized microporous UiO-type MOF to ozonolysis, to confer it with mesopores sufficien

293 0.085x V(p) - 0.013x V(p) (2) for cage-type MOFs and n(tot) = 0.076x V(p) - 0.011x V(p) (2) for chan

294 076x V(p) - 0.011x V(p) (2) for channel-type MOFs, where V(p) is the pore volume of corresponding MOF

295 Relative to other ultraporous MOFs, NU-1501-Al exhibits concurrently a high gravimetri

296 particular, we highlight cases that utilize MOF instability to fabricate varying materials including

297 The work offers a further avenue to utilize MOFs in the pursuit of materials design for CO(2)RR.

298 ntrol efficient exciton displacements within MOFs, we first developed linkers with low electronic sym

299 A new layered mesoporous Zr-MOF of composition [Zr(30)O(20)(OH)(26)(OAc)(18)L(18)] w

300 We found that Zr-MOF-808 can produce up to 8.66 L(H2O) kg(-1)(MOF) day(-1