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1 MeOH and THF permeance increased when MOFs were embedded
2 MeOH displayed excellent chromatographic performance (se
3 d bound DMF molecules for methanol to give 1-MeOH, complete desolvation of the framework at 180 degre
4 aration (5min separation using acidified 10% MeOH isocratic flow in a CORTECS C18 column) to allow un
10 of some of the norbornene, but even in 100% MeOH, the norbornyl chloride products of ion pair return
12 ed in MeOH/H2O ratios ranging from 0 to 100% MeOH and analyzed with untargeted reversed phase LC-MS s
14 theoretical predictions, and by employing 2% MeOH/toluene as solvent, the Heck-Matsuda reaction provi
15 stalline solid solutions (M,M')(NPBA)2(NO3)2(MeOH)2 (M, M' = Co2+, Ni2+, or Zn2+, 13-16), where mixtu
16 Molecule Magnet (SMM) [MnIII6O2(sao)6(O2CH)2(MeOH) 4] (1) (where sao2- is the dianion of salicylaldox
17 HCO2- in the molecule [MnIII6O2(sao)6(O2CH)2(MeOH)4] (1), with Et-sao2- (Et-saoH2 = 2-hydroxypropioph
20 e demonstrate important aspects of the CO(2)/MeOH/H(2)O system on nine chiral stationary phases with
22 (THF = tetrahydrofuran) solvent mixtures, 2-MeOH is characterized by a LMCT band at lambda(max) = 51
23 pon addition of HO(2) to 1 and converts to 2-MeOH at a rate of 65(1) s(-1), which is consistent with
26 organic framework (MOF), [Bi(BTC)(H2O)].2H2O.MeOH denoted CAU-17, was synthesized and found to have a
28 ns in urea, MD-derived structures in CHCl(3)/MeOH reveal multiple determinants of membrane interactio
33 M Tris, pH 8, sheath liquid containing 50/50 MeOH/10 mM HCO(2)NH(4) delivered at 5 microL/min, spray
34 used reconstitution solvent mixture of 50/50 MeOH/H2O, our results indicate that the small fraction o
35 PSPEP sorbent and elution with 100muL of 50% MeOH) were combined with a fast UHPLC separation (5min s
39 by a nucleophilic attack on the nitrogen, a MeOH-assisted [1,3]-proton transfer, and subsequent loss
40 -H of the dihydropyridyl ring and the O of a MeOH and also via an N...H-O interaction between the N c
44 is to obtain analyte-laden eluates with ACN/MeOH (90:10, v/v) in unsupervised mode for direct inject
48 ves the fitting for TFE, MeCN/H(2)O 2:1, and MeOH but at the expense of that for tertiary alkanols.
50 In the solvents investigated (CH(2)Cl(2) and MeOH), the most favorable mechanism is addition of perox
51 seful as food additives, such as MeOH-2, and MeOH-3, completely devoid of hepatotoxic components.
52 ea-mediated tetramer dissociation (pH 7) and MeOH-facilitated fibril formation similar to those of WT
54 strating why the presence of excess base and MeOH or H2O is required for efficient and enantioselecti
55 ed pyrrolidines using 4 N HCl in dioxane and MeOH gave the corresponding enantiomers of 2-substituted
60 equently used solvent systems, ACN/H(2)O and MeOH/H(2)O, revealed that the antimony(III)-tartrate dia
65 d k(D)/k(T) values, is the same in water and MeOH/water mixtures, implicating similar trajectories fo
67 tion species react with nucleophiles such as MeOH by clean second-order kinetics with rate constants
68 pon the addition of a proton source, such as MeOH, or by running the reaction under a hydrogen atmosp
69 extracts, useful as food additives, such as MeOH-2, and MeOH-3, completely devoid of hepatotoxic com
72 e than the 6-fluoropurine compound with both MeOH/DBU/MeCN and iPentSH/DBU/MeCN and was more reactive
74 Likewise, complex 2 can replace acetone by MeOH and H2O to form [Fe(bpp)(H2L)](ClO4)2.1.25MeOH.0.5H
75 axane and its dumbbell precursor in a CH2Cl2/MeOH (3:2) mixed solvent and liquified by adding the oxi
76 te constant for reaction of the Cp2Ti(III)Cl-MeOH at ambient temperature was 7.5 x 10(4) M(-1) s(-1).
78 estigate how the adsorption of the cosolvent MeOH changes with pressure and temperature and how this
79 MeOH vapor affords [Au(im(CH(2)py)(2))(2)(Cu(MeOH))(2)](PF(6))(3) (2), which produces green luminesce
81 adoxical previous observation that decreased MeOH concentration leads to increased competing intermol
82 DMF, followed by recrystallization from DMF/MeOH, yields (Et(4)N)(5)[Mo(2)(CN)(11)] x 2DMF x 2MeOH (
83 m of methylcobalamin (Me-Cbl) in a mixed DMF/MeOH solvent in 0.2 M tetrabutylammonium fluoroborate el
86 dicated that weaker donors (THF, MeCN, DMSO, MeOH, and even H2O) likewise promote this pathway, at ra
87 ylamines (e.g., H(2)NOMe and MeHNOMe) in dry MeOH at room temperature give three different types of p
88 lly investigate the effects of simple (i.e., MeOH and EtOH) and fluorinated (i.e., trifluoroethanol,
89 ometrically rigidified by H-bonding to eight MeOH molecules and encapsulation of two benzene guests.
90 ontains a sacrificial electron donor, either MeOH or triethanolamine (TEOA), and titanium dioxide (Ti
91 re dissolved in MeOH and diluted with either MeOH (0.1% HCl) or buffers to obtain final concentration
92 e upon preparative TLC purification (eluent: MeOH/CHCl(3) saturated with NH(3)) and equilibrium studi
93 HPCCC separation under use of heptane-EtOAc-MeOH-H2O mixtures in normal-phase and reverse phase mode
94 nt systems viz. toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum separation and
95 ent systems viz.toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum separation and
96 s and two solvent systems viz. toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum
97 es and two solvent systems viz.toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum
101 d to measure the diffusion coefficient of Fc(MeOH)2 in gels under a wide range of experimental condit
102 t for 3.0% NIPA gel, the concentration of Fc(MeOH)2 in the collapsed phase was approximately 6 times
105 cs (QM/MM) calculations, the free energy for MeOH reduction of o-PQQ when MeOH is hydrogen bonded to
107 I(2) sorption, both from gas phase and from MeOH solution, into CTH-7 were studied by time of flight
109 te constant (kH) were measured on going from MeOH and TFE to isooctane (kH(isooctane)/kH(MeOH) = 5-12
112 ss-specific methanol formation rate of 524 g(MeOH)kg(cat)(-1)h(-1) at 220 degrees C, 3.3 times higher
114 Whereas alternative protic solvents (e.g., MeOH vs HFIP) provide products of the conventional 3,6-c
117 SDS samples (via direct dilution with GnHCl/MeOH solution) is necessary to ensure accurate quantitat
118 olvent, e.g., hexane > toluene > DCM > THF > MeOH > H2O, an effect also noted by emission variation i
119 SA, in tert-butylbenzene (t-BuPh) and in H2O/MeOH afforded, with CF3COOH, k(d) 28-fold larger in H2O/
120 ed, with CF3COOH, k(d) 28-fold larger in H2O/MeOH than in t-BuPh, whereas it was only 4-fold larger w
121 ty, we developed HPLC and UHPLC methods (H2O/MeOH/MeCN/HCOOH) which we applied and validated by analy
123 haracterized with low O/C < 0.5; and hexane, MeOH, ACN, and H2O solvents increase the number and type
124 where A(-) = H2PO4(-) and CF3CO2(-) and HX = MeOH, PhOH, and Me2NOH or Et2NOH) are examined by photoe
126 traction methods [methanol/sodium hydroxide (MeOH/NaOH) and methanol/ammonium hydroxide (MeOH/NH4OH)]
132 ct with calcium hypochlorite (Ca(OCl)(2)) in MeOH to give respectively dimer-type ketals 2-(2',4',6'-
134 deprotection conditions [0.05 M K(2)CO(3) in MeOH, room temperature, 24 h and MeNH(2) (approximately
137 r increased significantly with 1 and BrCl in MeOH, but MeOH had little affect on the other reactions.
138 le beta-formyl ester 21, whereas cleavage in MeOH followed by reduction with thiourea led to hemiacet
139 Ph2P-(C6H4) (2-F) with a binding constant in MeOH exceeding that of 1-Mes2B-4-MePh2P-(C6H4) ([1]+) by
143 meters such as solvent composition (EtOAc in MeOH), extraction temperature, pressure, flushing, stati
145 ng D-aldopentoses by reaction with NH3(g) in MeOH solvent, isolated in solid form, and characterized
146 wing the Ugi reaction, treatment with HCl in MeOH achieves deprotection of the isopropylidene group a
151 ubsequent dihydroxylation, using OsO4/NMO in MeOH conditions, resulted in an exceedingly diastereo- a
152 generic modifier (0.2% NH(4)OH, 5% H(2)O in MeOH) that enables the widespread transition of SFC to d
156 SO2, CF3SO2) react with hydrogen peroxide in MeOH, THF, MeCN or AcOH to form the corresponding C-N co
158 sogeny Broth medium samples reconstituted in MeOH/H2O ratios ranging from 0 to 100% MeOH and analyzed
165 malononitriles 13 in 84-92% yields, while in MeOH the (Z)-2-[2-phenyl-4-(arylimino)-1H-imidazol-5(4H)
166 nding thiophenes 6 in good to high yields in MeOH as the solvent at 50-100 degrees C in the presence
169 iables quantity of sample (g), volume of KOH/MeOH (mL) and ultrasound time (s) were investigated in t
170 xime or 2-hydroxybenzaldeyhyde oxime and L = MeOH, EtOH) via the use of derivatized oxime ligands and
171 icities of [Rh2(micro-O2CCH3)2(eta1-O2CCH3)L(MeOH)]+ (L=dppz, 7; L=dppn, 8) relative to [Rh2(micro-O2
172 l sites of Ni(II) to give the complex [Ni(L)(MeOH)(2)] in which a Ni(II) center is bound in an octahe
173 n be achieved using weak proton sources like MeOH and PhOH, the facile heterolytic cleavage of the C-
176 sensitivity and shorter gradient times make MeOH an excellent organic modifier for the use in nanoLC
178 phenolic compounds with O/C > 0.5; methanol (MeOH) has higher selectivity toward compounds characteri
180 TBP), in buffer solvent with added methanol (MeOH), 2-propanol (2-PrOH), and dimethyl sulfoxide (DMSO
181 amines to formate, formamides, and methanol (MeOH) is a promising approach to streamlining carbon cap
182 lohexane, acetonitrile (MeCN), and methanol (MeOH) was investigated under steady-state conditions.
183 such as trifluoroethanol (TFE) and methanol (MeOH), indicating a lower propensity of the oxidized pro
184 reductively couples NO(g) at RT in methanol (MeOH), giving a structurally characterized hyponitrito-d
185 tion was evaluated on the basis of methanol (MeOH) and tetrahydrofuran (THF) permeances and rejection
186 rt, we demonstrate that the use of methanol (MeOH) as the organic modifier improves the detection lim
187 obile phases, aqueous solutions of methanol (MeOH/H(2)O = 40/60 and 30/70, v/v) and aqueous solutions
188 aride mixtures were compared using methanol (MeOH)-, isopropanol (IPA)-, and acetonitrile (ACN)-based
189 ies into chloroform (CHCl(3)) with methanol (MeOH) as cosolvent, consistent with MeOH competitively d
190 es of the ethyl acetate (EtOAc), methanolic (MeOH) and aqueous extracts from the Micromeria nervosa a
191 the used 2-MeTHF, scale-up, ratio of 2-MeTHF/MeOH, utilized hydroxide, temperature, and reaction time
194 : inorganic (nonligated) uranyl, UO2Ac(H2O)n(MeOH)m(+), and UO2Ac2(H2O)n(MeOH)(m)H(+) (n = 1, 2, 3,..
195 ion, and a unique ester reduction with NaBH4-MeOH catalyzed by NaB(OAc)3H that not only achieves exce
196 o form 100% of the 9-cation, then with NaOMe-MeOH, provided 29% of re-formed substrate (configuration
197 cycloadducts has been demonstrated by an NBS-MeOH mediated stereospecific efficient access to fully s
200 itation with an appropriate solvent (Et(2)O, MeOH, or EtOAc), followed by filtration through a SPE pr
202 ic acid-base titrations carried out in H(2)O/MeOH (9:1 vol.) afford pK(R+) values of 7.3(+/-0.07) for
203 ion, fluoride titration experiments in H(2)O/MeOH (9:1 vol.) show that the fluoride binding constants
205 pathway depends on the alcohol: addition of MeOH induces a transition to a superhelical structure th
206 ing in peak area response by the addition of MeOH to H2O, 5%, is outweighed by the fraction of compou
209 ial unfolding; however, further additions of MeOH result in the formation of a non-native beta-struct
211 dies also indicate that the concentration of MeOH produced is independent of catalyst concentration,
214 a clear impact on the metabolome coverage of MeOH extracted biological samples, highlighting the impo
216 data is proposed in which one equivalent of MeOH activates the epoxide electrophile via a hydrogen b
217 a hydrogen bond while a second equivalent of MeOH chelates the side-chain nucleophile and glycal ring
218 ratios as a function of the mole fraction of MeOH in dichloroethane showed that the homoadamantyl chl
219 f 2 to atmosphere produces a partial loss of MeOH accompanied by a luminescence color change to yello
221 sure of 2 to vacuum affords complete loss of MeOH, and the luminescence changes to yellow-orange (lam
222 roduce, in combined high yield, a mixture of MeOH, C2H6, and MeOOH along with water-soluble n-Pr4N[(d
229 yclic carbene (NHC) complex; the presence of MeOH promotes in situ protonation of the C-Cu bond and l
231 gate the topic of the ruthenium promotion of MeOH electro-oxidation over nanoscale platinum catalysts
232 lear relationship between the sensitivity of MeOH adsorption to the stationary phase and the robustne
233 zation reaction is second-order dependent on MeOH, and the glycal ring oxygen is required for second-
235 Previous work from our laboratory optimized MeOH-inducible expression of the P. falciparum malarial
237 in disulfides suspended in NaPO(4) buffer or MeOH was assessed, and no differences in total normalize
238 Reaction of 1 with either liquid MeOH or MeOH vapor affords [Au(im(CH(2)py)(2))(2)(Cu(MeOH))(2)](
239 f the resulting sulfonyl chalcones in THF or MeOH/THF at 25 degrees C; and then (iii) Amberlyst-15 me
240 conventional techniques (e.g., using TMS or MeOH/benzene dual referencing) is demonstrated to be imp
242 n the electrode is able to decompose/oxidize MeOH to form (adsorbed) methoxy groups that can further
246 In 10% MeOH/H(2)O at pH 1 or 11 or in pure MeOH, assembly is driven exclusively by the TPP ring, le
248 ibution of pyrene (PY), 1-pyrenemethanol (PY-MeOH), and 1-pyrenebutanol (PY-BuOH) into the C18 statio
250 (2) and the ferrous end-product [Fe(II)(PY5)(MeOH)](OTf)(2) estimates the strength of the O-H bond in
251 )O}(n) (1-SS) and {[Co(II)((R,R)-iPr-Pybox) (MeOH)](3)[W(V)(CN)(8)](2).5.5MeOH.0.5H(2)O}(n) (1-RR).
252 no-bridged chains, {[Co(II)((S,S)-iPr-Pybox)(MeOH)](3)[W(V)(CN)(8)](2).5.5MeOH.0.5H(2)O}(n) (1-SS) an
253 Br and Cl), R = CNH+ (with X = Cl), and R = MeOH+ (with X = Br), the corresponding beta-aryl-alpha-h
254 n addition, the use of NH(4)OH in water-rich MeOH modifiers was compared to other commonly used basic
255 , Zn2+, Mn2+, Cu2+, Ag+; A = NO3-, OAc-; S = MeOH, H2O; a = 0, 1, 2; b = 0, 1, 2, 4; and c = 0, 2.
257 and the mixed Co/Os (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)0.92Os(III)0.08(CN)6]}.7MeOH (Mn2Co/Os.7M
258 metal Co/Os analogue (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)0.92Os(III)0.08(CN)6]}.7MeOH were underta
259 r new complex salts, (PPN){[Mn(III)(salphen)(MeOH)]2[M(III)(CN)6]}.7MeOH (Mn2M.7MeOH) (M = Fe, Ru, Os
262 caffolds have unique potential for selective MeOH detection from other solvents, especially EtOH.
264 sily removed by treatment with MeMgBr or TFA/MeOH, which affords the NH-aziridines in good yield.
265 gen bonded to Asp-297-CO(2)(-), we find that MeOH returns to be hydrogen bonded to Glu-171-CO(2)(-) a
269 The lower the pressure, the stronger the MeOH adsorption to the stationary phase; in addition, at
273 CN to solution and solid-phase esters in THF/MeOH/50% aqueous NH2OH increases the efficiency of their
275 D) showed that the ZnCar framework adapts to MeOH and H2 O guests because of the torsional flexibilit
278 Simply switching the solvent (from MeCN to MeOH) or chelating unit (from bidentate to tridentate) i
283 free energy for MeOH reduction of o-PQQ when MeOH is hydrogen bonded to Glu-171-CO(2)(-) and the crys
289 NH(4)OH and H(2)O levels in conjunction with MeOH/CO(2) served to furnish a generic modifier (0.2% NH
290 ethanol (MeOH) as cosolvent, consistent with MeOH competitively displacing PBAT from H-bond donating
294 NH2/MeCN), F > Cl approximately Br > I (with MeOH/1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)/MeCN), and
295 success rate of protein identification with MeOH-based nanoLC-ESI-MS/MS was 100%, with multiple prot
297 shown that all aldoxime ethers reacted with MeOH by clean second-order kinetics with rate constants
299 s spectrometry, and 13 has been trapped with MeOH to afford methyl 1,3-cyclopentadiene-1- and -2-carb