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1  nucleophiles to conjugate acceptor systems (Michael reaction).
2 he nucleophile to this and, finally, a retro Michael reaction.
3 ted pyrrolidine 15 by way of a tandem Wittig-Michael reaction.
4 saminase-triggered double intramolecular aza-Michael reaction.
5 followed by base-mediated intramolecular aza-Michael reaction.
6 propenone-phosphine ligation and the phospha-Michael reaction.
7 ol acrylates via dual C-H activation and aza-Michael reaction.
8 nd formation through palladium-catalyzed aza-Michael reaction.
9 on, which relies on an omega-TA-mediated aza-Michael reaction.
10  of the individual steps of a tandem Michael/Michael reaction.
11  through Trost's domino ene-yne coupling/oxa-Michael reaction.
12 T study of bicyclic guanidine-catalyzed thio-Michael reaction.
13 fenate anions generated in situ, via a retro-Michael reaction.
14 ed early in the sequence using an asymmetric Michael reaction.
15  a Diels-Alder like transition state for the Michael reaction.
16 ed, synthesized, and utilized for asymmetric Michael reactions.
17 equent ADCs by impairing the undesired retro-Michael reactions.
18 temperature (rt), catalyst-free dynamic thia-Michael reactions.
19  ring-closing metathesis, and intramolecular Michael reactions.
20 assembled rapidly via Baylis-Hillman and aza-Michael reactions.
21 kaiyama-Michael reactions and tandem Michael-Michael reactions.
22  the stereochemical course of intramolecular Michael reactions.
23 conditions has not been well established for Michael reactions.
24 ave substantially broadened the scope of oxa-Michael reactions.
25 ty in murine hepatoma cells paralleled their Michael reaction acceptor activity.
26 raphane or a bis-2-hydroxybenzylideneacetone Michael reaction acceptor.
27 ts of thiol groups), and two closely related Michael reaction acceptors [bis(2- and 4-hydroxybenzylid
28 enzylidene-alkanones and -cycloalkanones are Michael reaction acceptors whose inducer potency is prof
29  ways: as a donor in a highly selective anti-Michael reaction and as an acceptor in a consecutive Hen
30 ovalent exchange occurs via both dynamic aza-Michael reaction and catalyst-free transesterification.
31 bromonitrostyrene followed by intramolecular Michael reaction and elimination steps.
32 ated by screening potential catalysts of the Michael reaction and in solvent optimization experiments
33 tions that characterize the current standard Michael reaction and used for facile preparation of orga
34 systems are also applicable in the Mukaiyama-Michael reactions and tandem Michael-Michael reactions.
35  compounds include the Stetter reaction, the Michael reaction, and Friedel-Crafts acylation.
36 were added to omega-keto alkynyl esters in a Michael reaction, and the incipient vinyl anions were tr
37 hed via a TBSOTf-mediated intramolecular aza-Michael reaction, and the relative stereochemistry of th
38 n only be achieved when base-initiated thiol-Michael reactions are carried out first, as radical-medi
39 has been demonstrated for various asymmetric Michael reactions at 5 mol % catalyst loading and afford
40 dented organocatalyzed asymmetric vinylogous Michael reaction between 3-cyano-4-methylcoumarins and m
41 y tested for their ability to accelerate the Michael reaction between acetylacetone and trans-beta-ni
42     The reaction happens through an uncommon Michael reaction between aromatic derivatives as aromati
43       A refined stereocontrolling TS for the Michael reaction between cyclohexanone and nitrostyrene
44 e tertiary amine that is able to promote the Michael reaction between enolizable carbonyl compounds a
45  formation, followed by an unprecedented aza-Michael reaction between isatin derived N-Boc ketimines
46 xanols was achieved by using a tandem Henry--Michael reaction between nitromethane and 7-oxo-hept-5-e
47    These catalysts are also effective in the Michael reaction between other enones and malonates.
48 e carbonyl group of 2-OP which facilitates a Michael reaction between Pro-1 and the acetylene compoun
49 amine the two key processes of the catalytic Michael reaction between propanal and beta-nitrostyrene
50                                       An aza-Michael reaction between the resulting amidate and alpha
51                      Subsequently, the thiol-Michael reaction between the thiophenol anion and electr
52 s of reversible intramolecular Michael-retro-Michael reactions between adjacent amine groups that mov
53 tereochemical outcome of the organocatalytic Michael reactions between benzylic aldehydes and nitrost
54 us was obtained by a cascade of transannular Michael reaction, carbonate elimination, butenolide form
55    We systematically explored a transannular Michael reaction cascade for stereoselective synthesis o
56 verse-electron-demand hetero-Diels-Alder/oxa-Michael reaction catalyzed by modularly designed organoc
57  be released by sequential retro-aldol/retro-Michael reactions catalyzed by aldolase antibody 38C2.
58 vely removed by sequential retro-aldol-retro-Michael reactions catalyzed by antibody 38C2.
59 xpression) of a series of triterpenoids with Michael reaction centers were closely correlated with th
60                     Catalytic and asymmetric Michael reactions constitute very powerful tools for the
61 catalyzed stereoselective intramolecular oxa-Michael reaction, E-selective ring-closing metathesis, D
62 mmation depends on the presence of activated Michael reaction (enone) functions at critical positions
63    In these reactions, a catalyst-controlled Michael reaction followed by a substrate-controlled Henr
64 lementary strategies: (i) an organocatalyzed Michael reaction followed by a tandem Robinson-aza-Micha
65  heterocyclic systems is initiated by an aza-Michael reaction followed by intramolecular cyclization.
66 rans through a cascade S(N)2'-intramolecular Michael reaction, followed by aromatization.
67 es, we designed and achieved a catalyst-free Michael reaction for the preparation of an N1-alkyl pyra
68 nes and activation of nitro-alkene for nitro-Michael reactions for the first time.
69 xamples of one-pot tandem sulfamoylation/aza-Michael reactions for the preparation of oxathiazinane d
70                     The key steps are an aza-Michael reaction from an alpha,beta-unsaturated diazoket
71 emestane is an extended system of conjugated Michael reaction functions, which is also characteristic
72       The organocatalytic intramolecular aza-Michael reaction gives access to enantiomerically enrich
73 ine-squaramide organocatalyst for asymmetric Michael reactions has been elaborated.
74 ue, biomimetic asymmetric intramolecular oxa-Michael reaction/hydrogenation sequence that allows dias
75                                     The thia-Michael reaction, i.e., the addition of a thiol to an al
76                                          Oxa-Michael reactions, i.e. addition reactions of oxygen nuc
77 aziridines followed by an intramolecular aza-Michael reaction in a domino fashion.
78 arbon diacid and induced to undergo a double Michael reaction in situ.
79 formations including aldol, retro-aldol, and Michael reactions in aqueous buffer via an enamine mecha
80 ivity of base- or nucleophile-promoted thiol-Michael reactions in complex mixtures of multiple thiols
81 vations on catalytic aqueous Diels-Alder and Michael reactions in heterogeneous fashion employing a d
82 gates that are completely resistant to retro-Michael reactions in the presence of biological thiols a
83 been synthesized and utilized for asymmetric Michael reactions in water as the sole reaction medium.
84 ors and nucleophiles (i.e., the nucleophilic Michael reaction) is a historically useful organic trans
85 lder, [1,3]-H shift, [1,3]-trityl migration, Michael reaction) leading to architecturally complex mol
86 ented reaction sequences via Michael and aza-Michael reactions, leading to two of the four intended i
87  elements specific for 3C protease undergo a Michael reaction mediated by nucleophilic addition of th
88  and where a retro-double intramolecular aza-Michael reaction mediates a dynamic kinetic resolution a
89   The fluoride-promoted vinylogous Mukaiyama-Michael reaction of 2-[(trimethylsilyl)oxy]furan with di
90     The reaction proceeds via intermolecular Michael reaction of 2-oxo-2-(2-oxo-2H-chromen-3-yl)-1-(p
91 ylamino)cyclopropenimine catalyzes the rapid Michael reaction of a glycine imine substrate with high
92 talyzed, enantioselective intramolecular oxa-Michael reaction of alcohols to tethered, low electrophi
93 been found to be efficient catalysts for the Michael reaction of alkenones and alkynones with malonat
94                     The enantioselective oxa-Michael reaction of alkoxyboronate strategy was demonstr
95 ue complexes have been shown to catalyze the Michael reaction of dibenzyl malonate and cyclohexenone
96 cedented enantioselective intramolecular oxa-Michael reaction of enols has been described.
97 er (49) was prepared by the enantioselective Michael reaction of ethyl 2-nitropropionate (51) and met
98 lpha-amino acids can be prepared by a double Michael reaction of p-anisyl ethynyl ketone and a tether
99 The stereochemical outcome of the asymmetric Michael reaction of pseudoephedrine amide enolates chang
100                                The Mukaiyama-Michael reaction of pyridones 27a/b with O-silyl ketene
101                                         Thus Michael reaction of the benzylimines of oxycodones and o
102 to a bis enone followed by an intramolecular Michael reaction of the enolate to the other enone, aldo
103 efficient and selective lipase-catalyzed aza-Michael reaction of various amines (primary and secondar
104 n effective hydrogen-bond-donor catalyst for Michael reactions of a series of water-insoluble nitro-o
105                                          The Michael reactions of alkynones, unlike those of alkenone
106 emote stereocenters in the direct vinylogous Michael reactions of beta, gamma-unsaturated butenolides
107 tomeric products generated by the asymmetric Michael reactions of cyclic carbon acids with beta,gamma
108 yzed enantioselective and diastereoselective Michael reactions of cyclic ketoesters and enones to ins
109 II) salts as highly active catalysts for the Michael reactions of traditionally unreactive beta,beta'
110 ANs are reprocessed via either a dynamic aza-Michael reaction or a catalyst-free transesterification
111 nce for the formally disfavoured 5-endo-trig Michael reaction over the formally favoured 5-exo-trig D
112 y regioselective ring opening by a retro aza-Michael reaction promoted by the gold(I) catalyst, event
113 y regioselective ring opening by a retro aza-Michael reaction promoted by traces of water, eventually
114 gulation of phase 2 enzymes may involve both Michael reaction reactivity and radical quenching mechan
115                   An unusual stereodivergent Michael reaction relies on basic vs. Lewis acidic condit
116 icylaldehyde reduces further to make the oxa-Michael reaction reversible.
117 ynine, employing a proline-catalyzed Mannich-Michael reaction sequence as the key transformation.
118 y diastereoselective reductive amination/aza-Michael reaction sequence to achieve rapid construction
119 hodology employs a cascade alkynyl Prins-aza-Michael reaction sequence to deliver the products in goo
120 ones via a K-enolate mediated domino Michael-Michael reaction sequence with moderate to good yield an
121 covered a rare duumvirate stereocontrol: the Michael reaction sets the enantioselectivity, but both t
122  two alpha,beta unsaturated carbonyl groups (Michael reaction sites) in the side chain of the avicin
123 ehyde, diastereoselective Cu(OTf)2-catalyzed Michael reaction/tandem aldol cyclizations, and one-pot
124 in a simple and reliable way through a sulfa-Michael reaction that proceeds with high yield and chemo
125 tic strategy is predicated on a transannular Michael reaction that provides both natural products fro
126 g on the Trost's domino ene-yne coupling/oxa-Michael reaction that we choose for its ability to contr
127  insights into the design of selective thiol-Michael reactions that can be used for the synthesis and
128 undamental study of the selectivity of thiol-Michael reactions through a series of 270 ternary reacti
129 ghlights a rare example of the catalytic aza-Michael reaction to alkenylazaarenes but also proves to
130 ing the intrinsic reversibility of the thiol-Michael reaction to be tuned in a predictable manner.
131  positions, respectively, a Pd-catalyzed oxa-Michael reaction to construct the tetrahydropyran ring,
132  antibody 38C2 efficiently catalyzed a retro-Michael reaction to convert a novel, cell-permeable fluo
133 reoselective (dr >/=96:4) acid-catalyzed aza-Michael reaction to give trans-2,5-disubstituted pyrroli
134 leoside analogues were synthesized using the Michael reaction to introduce the 4'-substituent and Pd-
135 onding tert-butyl ester 3 was initiated by a Michael reaction to introduce the cyclohexyl ring.
136               We report the use of a phospha-Michael reaction to label proteins and peptides modified
137 In addition, developing a tandem Mannich-aza-Michael reaction to obviate the need for a Curtis/acylat
138  These approaches employ thiol-ene and thiol-Michael reactions to form homopolymers of a single nucle
139                        An intramolecular oxy-Michael reaction under basic conditions was used to cons
140 d to be inactive toward the transannular bis-Michael reaction under the conditions evaluated.
141 o-3-methyl-2-butenoate underwent the phospha-Michael reaction upon simple trituration of the reagents
142          Bismuth nitrate-catalyzed versatile Michael reaction was developed to reduce the complicatio
143                                      The aza-Michael reaction was first observed when the starting en
144 llurium-based chalcogen-bond-catalyzed nitro-Michael reaction was reported ( Angew.
145 reagents for a sequential Ugi/6-exo-trig aza-Michael reaction, water as a solvent, and microwave irra
146 -pot quaternary, and sequential senary thiol-Michael reactions were designed and their selectivities
147 on of DSSO in anhydrous solution via a retro-Michael reaction, which may reduce the active ingredient
148 elimination of the maleimide through a retro-Michael reaction, which results in loss of drug-linker f
149 s favored by glutathione, indicating a retro-Michael reaction, which unveils new implications of cyPG
150                              Second, using a Michael reaction whose kinetics depends on the redox sta
151 ) also determines the outcome of combining a Michael reaction with a porphyrin-based supramolecular s
152 recursor to irofulven) were also prepared by Michael reaction with acrolein.
153 ne to participate in an autocatalysis of the Michael reaction with enzyme cysteine residues.
154 beta-diketones undergo facile domino Michael-Michael reaction with nitro-olefins to afford the corres
155 ding and affords up to 99% ee for asymmetric Michael reactions with aldehydes and nitro-olefins.
156 talyst enables highly enantioselective nitro-Michael reactions with oxazol-4(5H)-ones as nucleophilic
157 umaranone by following the kinetics of their Michael reactions with p-quinone methides and arylidenem
158 framework was generated by an intramolecular Michael reaction within precursor 16a involving the carb
159 ntoxic, easily hydrolyzed HMPT catalyzes the Michael reaction within seconds at room temperature in t

 
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