ライフサイエンスコーパス: Mossbauer

1 Mossbauer analyses revealed small quantities (<5%) of Fe

2 Mossbauer analysis and density functional theory (DFT) c

3 Mossbauer and electron paramagnetic resonance spectrosco

4 Mossbauer and EPR analyses show that 6b is a diiron(IV)

5 Mossbauer and EPR spectroscopies, along with X-ray struc

6 Mossbauer and infrared spectra are consistent with parti

7 Mossbauer characterization of the MiaB [3Fe-4S](0)-like

8 Mossbauer data for the tetrameric complexes 1-3 demonstr

9 Mossbauer hyperfine parameters for Fe(II)-reacted NAu-1

10 Mossbauer spectra of equivalent (57)Fe-enriched samples

11 Mossbauer spectra of whole cells were dominated by HS Fe

12 Mossbauer spectroscopic characterization of (57)Fe-enric

13 Mossbauer spectroscopic data for a set of reference dini

14 Mossbauer spectroscopic studies reveal that the alkylate

15 Mossbauer spectroscopy analysis of minerals precipitated

16 Mossbauer spectroscopy analysis revealed that nearly all

17 Mossbauer spectroscopy and ac magnetic susceptibility re

18 Mossbauer spectroscopy and magnetometry reveal strong ma

19 Mossbauer spectroscopy confirmed that all three imide co

20 Mossbauer spectroscopy confirmed the formation of transi

21 Mossbauer spectroscopy illustrates that the triflate sal

22 Mossbauer spectroscopy measurements confirmed that iron

23 Mossbauer spectroscopy of magnetite reacted with (56)Fe(

24 Mossbauer spectroscopy provides definitive evidence that

25 Mossbauer spectroscopy results indicate that a mixed-val

26 Mossbauer spectroscopy showed that the relative abundanc

27 Mossbauer spectroscopy suggests that substrate binding t

28 Mossbauer spectroscopy supports the structural observati

29 Mossbauer spectroscopy was used to detect pools of Fe in

30 Mossbauer spectroscopy, kinetic isotope effect, and gas

31 Mossbauer studies confirmed that the axially ligated der

32 Mossbauer studies of the peroxo state reveal a diferric

33 Mossbauer, rR, and XAS spectroscopic data indicated the

34 ng (LIESST) effect measurements, and, for 1, Mossbauer spectroscopy and diffuse reflectance data.

35 (PS-Fe(II)/Fe(III) ratio approximately 1.2 (Mossbauer) or 0.8 (XAS)).

36 which each Fe has a formal valence of 2.5+, Mossbauer spectroscopic and computational studies sugges

37 been characterized by electronic absorption, Mossbauer, and NMR spectroscopies, as well as X-ray crys

38 pic methods including UV-visible absorption, Mossbauer, EPR, and HYSCORE spectroscopies that these ad

39 For ((iPr)PDI)FeN(2)Ad, Mossbauer spectroscopy also supports spin crossover beha

40 spectroscopy, single crystal X-ray analysis, Mossbauer spectroscopy, and magnetic susceptibility meas

41 X-ray absorption and Mossbauer spectroscopy results indicate that reduction o

42 s was characterized by UV/Vis absorption and Mossbauer spectroscopy.

43 y diffraction, and electronic absorption and Mossbauer spectroscopy.

44 This intermediate has absorption- and Mossbauer-spectroscopic features similar to those of com

45 ron X-ray diffraction, DFT calculations, and Mossbauer spectroscopy, a unified understanding of the N

46 signatures for the iron-oxo chromophore, and Mossbauer and XAS measurements establish the presence of

47 l details, magnetic susceptibility data, and Mossbauer spectra demonstrate that 1 has a low-spin (S =

48 Both X-ray diffraction and Mossbauer analyses further confirm that increased nanopa

49 X-ray diffraction and Mossbauer spectroscopy confirm that the reduction occurs

50 K using single-crystal X-ray diffraction and Mossbauer spectroscopy in laser-heated diamond anvil cel

51 yA)2Fe2(L)](3+), where X-ray diffraction and Mossbauer spectroscopy indicate a metal-centered oxidati

52 s, in conjunction with X-ray diffraction and Mossbauer spectroscopy, reveal the presence of weak ferr

53 croscopy, neutron and X-ray diffraction, and Mossbauer and X-ray photoelectron spectroscopy to invest

54 of magnetochemistry, X-ray diffraction, and Mossbauer spectroscopic and computational studies establ

55 h sediment chemistry, X-ray diffraction, and Mossbauer spectroscopy on sediments retrieved from an or

56 , as revealed by detailed magnetic, DSC, and Mossbauer studies.

57 x is trapped and characterized using EPR and Mossbauer (MB) spectroscopies.

58 EPR and Mossbauer quantification of the various iron products, r

59 Quantitative interpretation of EPR and Mossbauer spectroscopic data indicates the presence of t

60 Here, EPR and Mossbauer spectroscopies allow electronic characterizati

61 ent analyses in conjunction with the EPR and Mossbauer spectroscopy measurements and the site-directe

62 e-based dioxygenase characterized by EPR and Mossbauer spectroscopy.

63 r has been characterized by UV-vis, EPR, and Mossbauer spectroscopies.

64 UV-vis, EPR, and Mossbauer spectroscopy of purified wild-type Apd1 and th

65 Optical, EPR, and Mossbauer studies show that the enzyme contains a nonhem

66 X-ray absorption fine structure (EXAFS) and Mossbauer spectroscopy combined with macroscopic sorptio

67 measurements, sequential Fe extractions, and Mossbauer spectroscopy of 12 h light-dark cycle incubate

68 yperfine sublevel correlation (HYSCORE), and Mossbauer spectroscopies as well as protein-film electro

69 as nuclear magnetic resonance, infrared, and Mossbauer spectroscopic studies on Fe(BF)(CO)(2)(CNAr(Tr

70 mbination of magnetic resonance, near-IR and Mossbauer spectroscopies and electrochemical methods, we

71 IR and Mossbauer spectroscopy, and elemental analysis on 2 and

72 ) (4), as evidenced by (1)H NMR, ATR-IR, and Mossbauer spectroscopies.

73 ons of these structures gave values of J and Mossbauer parameters in agreement with experiment.

74 ent magnetic susceptibility measurements and Mossbauer data show that the boron-centered Fe(14) clust

75 A combination of analytical methods and Mossbauer and EPR spectroscopies showed that reconstitut

76 We report the first optical and Mossbauer spectroscopic characterization of UndA, reveal

77 The magnetic properties and Mossbauer spectroscopy indicate that they undergo long-r

78 circular dichroism, EPR, resonance Raman and Mossbauer spectroscopies.

79 Characterization by resonance Raman and Mossbauer spectroscopy provides complementary insights i

80 nd electron microscopy, as well as Raman and Mossbauer spectroscopy, reveal magnetite nanoparticles i

81 V-visible absorption/CD, resonance Raman and Mossbauer) have been used to investigate the mechanism o

82 mperature arises from cation reordering, and Mossbauer spectroscopy supports this interpretation.

83 isible, electron paramagnetic resonance, and Mossbauer spectroscopic features of the homodimeric QueE

84 sis of X-ray diffraction, Raman spectra, and Mossbauer spectra confirm the presence of Fe(III) center

85 , XRD, X-ray photoelectron spectroscopy, and Mossbauer spectroscopy confirm the relationship between

86 Magnetic susceptibility and Mossbauer spectroscopy reveal the +1 oxidation state and

87 K-edge pre-edge absorption of 18 units, and Mossbauer parameters of DeltaE(q) = 1.65 mm/s and delta

88 both oxygenated intermediates by UV-vis and Mossbauer spectroscopy, proposed structures from DFT and

89 ants was explored by stopped-flow UV-vis and Mossbauer spectroscopy.

90 Infrared, UV-vis, and Mossbauer spectroscopies, together with magnetic suscept

91 Both UV-visible and Mossbauer experiments provide unambiguous evidence that

92 ve also been characterized by UV-visible and Mossbauer spectroscopies.

93 ray crystallography and (1)H NMR, XANES, and Mossbauer spectroscopy.

94 ical techniques including TEM, SEM, XAS, and Mossbauer analyses.

95 millitesla linewidth) were characterized by Mossbauer and EPR spectroscopy, respectively.

96 (2+), and the products were characterized by Mossbauer and EPR spectroscopy.

97 and [4(57)Fe-4S]H HydA1 was characterized by Mossbauer, HYSCORE, ENDOR, and nuclear resonance vibrati

98 place in pristine sediments as determined by Mossbauer spectroscopy (20 +/- 11% reduction).

99 upolar splitting of Fe(2+), as determined by Mossbauer spectroscopy.

100 from (57)Fe-enriched mice were evaluated by Mossbauer spectroscopy.

101 scopic probes that have been interrogated by Mossbauer spectroscopy and high-field EPR spectroscopy,

102 amount of Fe(3+) ions that was quantified by Mossbauer spectroscopy and confirmed by the TN values of

103 structures of the compounds were studied by Mossbauer spectroscopy, NMR spectroscopy, magnetochemist

104 Analysis of TsrM by Mossbauer and HYSCORE spectroscopies suggests that SAM d

105 Combined Mossbauer and crystallographic studies indicate that the

106 n explored via the collection of comparative Mossbauer data for all of the complexes featured and als

107 shifted to 765 cm(-1) in the (18)O complex; Mossbauer experiments show a signal with an delta = 0.02

108 Computational, Mossbauer, XAS, and NRVS studies indicate that protonati

109 dels of ToMOH and the theoretically computed Mossbauer spectra.

110 Conventional Mossbauer spectroscopy shows a diamagnetic ground state

111 r characterization by X-ray crystallography, Mossbauer spectroscopy, and high-field EPR spectroscopy.

112 d characterization by X-ray crystallography, Mossbauer spectroscopy, X-ray absorption spectroscopy (X

113 etylene inhibitors by X-ray crystallography, Mossbauer, and nuclear magnetic resonance spectroscopy.

114 racteristic molecular structure differences, Mossbauer spectra, magnetic circular dichroism spectrosc

115 copy) and phase analyses (X-ray diffraction, Mossbauer spectroscopy) reveal the formation of Fe(3)O(4

116 Operando experiments by X-ray diffraction, Mossbauer spectroscopy, and galvanostatic intermittent t

117 ished by a combination of X-ray diffraction, Mossbauer spectroscopy, magnetochemistry, and open-shell

118 igh-energy x-ray diffraction and time-domain Mossbauer spectroscopy, we show that nematicity and magn

119 EPR, ENDOR, Mossbauer, and EXAFS analysis, coupled with a DFT study,

120 orption and CD, resonance Raman, EPR, ENDOR, Mossbauer, and EXAFS studies of [2Fe-2S] Grx3/4 homodime

121 using electron paramagnetic resonance (EPR), Mossbauer, and UV-visible spectroscopies, we explored th

122 EPR, Mossbauer, and optical spectroscopies reveal that CmlA c

123 EPR, Mossbauer, and XAS spectroscopic results presented herei

124 terized using UV-vis absorption/CD/MCD, EPR, Mossbauer, and resonance Raman spectroscopies.

125 methods--XANES, EXAFS, X-ray, (1)H NMR, EPR, Mossbauer, and cyclic voltammetry--demonstrate that the

126 mplex has been characterized by UV-vis, EPR, Mossbauer, and HRMS and shown to be capable of oxidizing

127 I over the pH range of 3.9-9.5, using EXAFS, Mossbauer, and resonance Raman spectroscopies.

128 er was undetectable by chemical extractions, Mossbauer or X-ray Absorption spectroscopies.

129 Specifically, (57) Fe Mossbauer and X-ray absorption spectroscopy provided uni

130 Analysis of the (57) Fe Mossbauer spectra revealed two spectral components that

131 (57) Fe Mossbauer study discloses metal oxidation states of W(IV

132 A. intermediate (2), characterized by (57)Fe Mossbauer and Fe K-edge X-ray absorption (XAS) spectrosc

133 In this study, we combined (57)Fe Mossbauer and Fe K-edge X-ray absorption spectroscopic (

134 Both (57)Fe Mossbauer and infrared spectroscopic measurements identi

135 f kinetic measurements, freeze-quench (57)Fe Mossbauer and infrared spectroscopic measurements, deute

136 Based on (57)Fe Mossbauer and infrared spectroscopy (IR) data, the elect

137 A combination of (57)Fe Mossbauer and magnetic circular dichroism (MCD) spectros

138 both variable-temperature zero-field (57)Fe Mossbauer and magnetometry with a spin reversal barrier

139 d characterized by X-ray diffraction, (57)Fe Mossbauer and multinuclear NMR spectroscopy, and combust

140 ghly symmetric to fully asymmetric by (57)Fe Mossbauer and X-ray diffraction to explore the relations

141 (57)Fe Mossbauer data of the extremely oxidation-sensitive comp

142 s show an excellent correspondence to (57)Fe Mossbauer data; yet also can distinguish between subtle

143 spectroscopic signatures such as low (57)Fe Mossbauer isomer shifts and linear Fe-N-O units with hig

144 Zero-field (57)Fe Mossbauer parameters obtained for ((Ar)L)FeCl(N(p-(t)BuC

145 The (57)Fe Mossbauer quadrupole splittings and (1)H and (13)C NMR c

146 The (57)Fe Mossbauer spectra of 2, 6, 8, and 9 show a clear trend i

147 (57)Fe Mossbauer spectrometry shows that up to 6% of the total

148 structural Fe(III) in the clays using (57)Fe Mossbauer spectrometry.

149 X-ray crystallographic and (57)Fe Mossbauer spectroscopic investigations indicated that 2

150 by X-ray diffraction and (1)H NMR and (57)Fe Mossbauer spectroscopies.

151 (57)Fe Mossbauer spectroscopy and DFT-calibrated Huckel calcula

152 with H(2)S to FeS(2) was followed by (57)Fe Mossbauer spectroscopy and showed a clear biological tem

153 Herein, freeze-trapped (57)Fe Mossbauer spectroscopy and single-crystal X-ray crystall

154 land Gola di Lago (Switzerland) using (57)Fe Mossbauer spectroscopy and synchrotron X-ray techniques.

155 X-ray absorption spectroscopy (XAS), (57)Fe Mossbauer spectroscopy and X-ray diffraction, we followe

156 etween 1 and its reduction product by (57)Fe Mossbauer spectroscopy are discussed, and the reduction

157 tron paramagnetic resonance (EPR) and (57)Fe Mossbauer spectroscopy coupled with wave function based

158 otoelectron spectroscopy and in-field (57)Fe Mossbauer spectroscopy give unambiguous evidence that a

159 and solid-state magnetic studies, and (57)Fe Mossbauer spectroscopy has been applied to characterize

160 Results from (57)Fe Mossbauer spectroscopy indicate that both Al-substitutio

161 e observed in incubated sediments and (57)Fe Mossbauer spectroscopy revealed that Fe(III) associated

162 In addition, X-ray crystallography, (57)Fe Mossbauer spectroscopy, and EPR spectroscopy were used t

163 reactivity studies as well as in situ (57)Fe Mossbauer spectroscopy, key mechanistic features and spe

164 (57)Fe Mossbauer spectroscopy, X-ray photoelectron spectroscopy

165 spin Fe(III) species was confirmed by (57)Fe Mossbauer spectroscopy.

166 amagnetic resonance spectroscopy, and (57)Fe Mossbauer spectroscopy.

167 he Fe(4)S(4) clusters as indicated by (57)Fe Mossbauer spectroscopy.

168 -ray diffraction and NMR, UV-vis, and (57)Fe Mossbauer spectroscopy.

169 (1)H NMR, X-ray crystallography, and (57)Fe Mossbauer spectroscopy.

170 +), which is characterized by NMR and (57)Fe Mossbauer spectroscopy.

171 racterized the resulting solids using (57)Fe Mossbauer spectroscopy.

172 e3(mu(3)-NH) has a similar zero-field (57)Fe Mossbauer spectrum compared to previously reported [((tb

173 Moreover, the (57)Fe Mossbauer spectrum of 4 at 80K exhibits parameters (delt

174 ted by X-ray absorption spectroscopy, (57)Fe Mossbauer studies, and DFT calculations.

175 and (19)F nuclear magnetic resonance, (57)Fe Mossbauer, and electron paramagnetic resonance spectrosc

176 e2Mn(THF) was determined by (1)H NMR, (57)Fe Mossbauer, and X-ray fluorescence.

177 lectron paramagnetic resonance (EPR), (57)Fe Mossbauer, Fe X-ray absorption (XAS), and (54/57)Fe reso

178 Combined experimental data including (57)Fe Mossbauer, IR, UV-vis-NIR, NMR and Kbeta X-ray emission

179 UID magnetization methods, as well as (57)Fe Mossbauer, IR, UV/vis, multinuclear NMR, and dual-mode E

180 ely, as determined by EPR, zero-field (57)Fe Mossbauer, magnetometry, and single crystal X-ray diffra

181 been characterized by EPR, zero-field (57)Fe Mossbauer, magnetometry, single crystal X-ray diffractio

182 h cyclic voltammetry (CV), zero-field (57)Fe Mossbauer, near-infrared (NIR) spectroscopy, and X-ray c

183 n spectroscopic evidence from UV-vis, (57)Fe Mossbauer, resonance Raman, infrared, and (1)H/(19)F NMR

184 erized by X-ray diffraction analysis, (57)Fe Mossbauer, SQUID magnetometry, mass spectrometry, and co

185 (57)Fe Mossbauer, x-ray photoelectron, x-ray absorption, and el

186 perfine splitting in the zero-field (5)(7)Fe Mossbauer spectra at 4.2 K.

187 a ((1) H-NMR, UV-vis-NIR, infra-red, (57) Fe-Mossbauer, EPR), X-ray crystallographic characterization

188 his paper, we present field-dependent (57)Fe-Mossbauer and EPR data for Hase I, which, in conjunction

189 ray crystallography, NMR-, FTIR-, and (57)Fe-Mossbauer spectroscopy as well as by electronic absorpti

190 Zero- and applied-field Mossbauer spectroscopic measurements indicate diamagneti

191 High-field Mossbauer spectroscopy gave an (57)Fe A(dip) tensor of (

192 y photoelectron spectroscopy (XPS), in-field Mossbauer spectroscopy, and magnetization measurements e

193 Variable-field Mossbauer spectroscopy of 1-O indicates an intermediate-

194 Structures, zero-field Mossbauer data, and redox potentials are presented for e

195 Finally, zero-field Mossbauer spectra collected for 1 and 4 also reveal the

196 ady-state investigation, including the first Mossbauer spectroscopic characterization of diiron redox

197 B-co-loaded form provided an opportunity for Mossbauer analysis of NifB-co.

198 compared to pure ferrihydrite (inferred from Mossbauer-derived blocking temperatures), these samples

199 g mass spectrometry as well as UV-vis, FTIR, Mossbauer, XAS, and parallel-mode EPR spectroscopies.

200 he mixed-valent moiety do not have identical Mossbauer parameters.

201 gation of solvent molecules and variation in Mossbauer spectra, spin ground state, and intracluster F

202 n integrative biophysical approach involving Mossbauer and electronic absorption spectroscopies, elec

203 first quantum chemical investigation of IPC Mossbauer and NMR spectroscopic properties, as well as t

204 h were characterized by UV-vis-NIR, MCD, IR, Mossbauer, and XPS spectroscopy.

205 UV-vis-near-IR, Mossbauer, NMR, and EPR spectroscopies with magnetometry

206 Its Mossbauer spectra reveal that the intermediate possesses

207 as a high-spin iron(III) center based on its Mossbauer and EPR spectra and its quantitative reduction

208 5 K Mossbauer spectra of cells were dominated by a sextet du

209 erived from transient-state enzyme kinetics, Mossbauer spectroscopy, reaction product analysis, X-ray

210 ion of methods including transient kinetics, Mossbauer spectroscopy, and mass spectrometry, we demons

211 in Hhyd was demonstrated by an unusually low Mossbauer isomer shift of the distal Fe of the [2Fe]H su

212 SQUID magnetometry, Mossbauer spectroscopy, and DFT calculations reveal that

213 g studies, cyclic voltammetry, magnetometry, Mossbauer spectroscopy, UV-vis-NIR spectroscopy, NMR spe

214 atography, transmission electron microscopy, Mossbauer spectroscopy, and magnetic susceptibility meas

215 ansmission and scanning electron microscopy, Mossbauer, UV-vis and FTIR spectroscopy and X-ray powder

216 x) (UV-vis (lambda(max) = 435, 520, 600 nm), Mossbauer (delta = 0.45, |DeltaE(Q)| = 3.6 mm s(-1)), an

217 V-vis (lambda(max) = 300, 390, 530, 723 nm), Mossbauer (delta = 0.53, |DeltaE(Q)| = 0.76 mm s(-1)), r

218 by UV-vis (lambda(max) = 385, 460, 890 nm), Mossbauer (delta = 0.21, |DeltaE(Q)| = 1.57 mm s(-1)), R

219 high-resolution mass spectrometry, and NMR, Mossbauer, IR, and UV/Vis spectroscopy.

220 c methods, including (23)Na solid-state NMR, Mossbauer, and X-ray photoelectron spectroscopies, are e

221 Here, we obtained Mossbauer and EPR spectra of Escherichia coli cells prep

222 Good agreement of Mossbauer data with the empirical linear relationship fo

223 on of a nitrido species that on the basis of Mossbauer, magnetic susceptibility, EPR, and X-ray absor

224 ined the intermediate using a combination of Mossbauer and X-ray absorption spectroscopies.

225 unstable intermediate, and a combination of Mossbauer, EPR, and X-ray absorption spectroscopies iden

226 hows remarkable success on the prediction of Mossbauer spectroscopy of alpha-Fe, chi-Fe5C2 and theta-

227 temperature is faster than the time scale of Mossbauer measurements (<~10(-8) s).

228 Use of Mossbauer, EPR, NMR, UV/Vis, and IR spectroscopy, in con

229 these catalysts, we have performed operando Mossbauer spectroscopic studies of a 3:1 Ni:Fe layered h

230 Optical, Mossbauer, resonance Raman spectroscopies and native mas

231 Previous Mossbauer spectra of unenriched diseased human hearts la

232 flow UV-visible absorption and freeze-quench Mossbauer experiments identified a transient iron(IV)-ox

233 In situ freeze-quench Mossbauer spectroscopy during turnover reveals an iron-b

234 it by ultraviolet-visible, resonance Raman, Mossbauer and electrospray ionization mass spectrometric

235 haracterized by UV-visible, resonance Raman, Mossbauer, and EPR methods.

236 ysiological conditions, with optical, redox, Mossbauer, and NMR characteristics that are consistent w

237 dichroism, electron paramagnetic resonance, Mossbauer and resonance Raman spectroscopies.

238 products by electron paramagnetic resonance, Mossbauer, and nuclear resonance vibrational spectroscop

239 olarization surface enhanced NMR (DNP-SENS), Mossbauer spectroscopy, and computational chemistry were

240 tu X-ray absorption spectroscopy and ex situ Mossbauer spectroscopy.

241 In the present study, in situ Mossbauer and magnetic circular dichroism spectroscopic

242 d upon decay of the intermediate has a small Mossbauer quadrupole splitting parameter, implying that,

243 Using (119)Sn-Mossbauer spectroscopy, which is the most sensitive tool

244 Combined with freeze-trapped solution Mossbauer studies of reactions with primary alkyl halide

245 y UV/Visible and IR spectroelectrochemistry, Mossbauer and NMR spectroscopy, X-ray crystallography, a

246 to complementary structural, spectroscopic (Mossbauer, EPR/ENDOR, IR), and computational probes that

247 iffraction, X-ray fluorescence spectroscopy, Mossbauer spectroscopy, and gas-phase DART mass spectrom

248 le crystal X-ray diffraction and synchrotron Mossbauer source spectroscopy.

249 -pressure optical absorption and synchrotron Mossbauer spectroscopic measurements of iron-enriched de

250 estigated using transmission and synchrotron Mossbauer spectroscopy at high pressures and low tempera

251 Here we apply synchrotron Mossbauer source spectroscopy in laser-heated diamond an

252 Time-domain synchrotron Mossbauer spectroscopy (SMS) based on the Mossbauer effe

253 d using combined high resolution synchrotron Mossbauer spectroscopy and x-ray diffraction techniques

254 The room temperature Mossbauer spectrum of irradiated hematite shows the emer

255 The room-temperature Mossbauer spectrum confirms the 1:1 ratio of Fe(II) (del

256 CPO-I and P450-I using variable-temperature Mossbauer and X-ray absorption spectroscopies.

257 Variable-temperature Mossbauer data also corroborate a significant temperatur

258 r time scale, such that variable-temperature Mossbauer spectra reveal a thermally activated transitio

259 The Mossbauer parameters for 1-O include an unusually small

260 The Mossbauer spectroscopy of iron carbides (alpha-Fe, gamma

261 The Mossbauer spectrum at 90 K of the EPR-silent intermediat

262 The Mossbauer spectrum of 1 (S = 0) and TDDFT calculations,

263 The Mossbauer spectrum of CYP119-I is similar to that of chl

264 ing Tc oxidation is further supported by the Mossbauer spectroscopy and micro X-ray diffraction data

265 absorption spectroscopy (XAS) confirmed the Mossbauer results, and bulk As XAS indicated the prevale

266 tric hyperfine interactions deduced from the Mossbauer analysis suggests that NifB-co is either a 4Fe

267 Furthermore, the Mossbauer spectra reveal that the [4Fe-4S](2+) cluster o

268 ne sample of 1 displays three sextets in the Mossbauer spectrum at 4.2 K (H(ext) = 0) which converge

269 he low quadrupole splitting parameter in the Mossbauer spectrum observed for a ToMOH(peroxo) intermed

270 riflate salts corroborate the results of the Mossbauer and NMR spectroscopy and reveal substantial st

271 ation is associated with perturbation of the Mossbauer spectrum of the diferric cluster, especially t

272 lectron hopping is comparable to that of the Mossbauer time scale, such that variable-temperature Mos

273 on Mossbauer spectroscopy (SMS) based on the Mossbauer effect of (161) Dy has been used to investigat

274 The DFT calculations reproduce the Mossbauer parameters (A-tensors, electric field gradient

275 ce vibrational spectroscopy (NRVS) using the Mossbauer isotope (161) Dy has been employed for the fir

276 with internal fluctuations measured with the Mossbauer effect and neutron scattering.

277 We first explore the model with the Mossbauer effect.

278 Finally, field shift energies are related to Mossbauer isomer shifts, and equilibrium mass-independen

279 Here, we use Mossbauer spectroscopy on (57)Fe-labeled complex I from

280 Here we used Mossbauer spectroscopy combined with selective chemical

281 Using Mossbauer and EPR spectroscopies, X-ray crystallography,

282 rt-butylureaylato)-N-ethylene]aminato) using Mossbauer and dual-frequency/dual-mode electron paramagn

283 a2Delta mutant derived from W303 cells using Mossbauer and EPR spectroscopies and liquid chromatograp

284 ure of the accumulated Fe was examined using Mossbauer spectroscopy, EPR, electronic absorption spect

285 that we have characterized extensively using Mossbauer and parallel mode EPR spectroscopy.

286 treatment with chlorine and hydrogen, using Mossbauer and X-ray absorption spectroscopy.

287 ation was observed at high C/Fe ratios using Mossbauer spectroscopy and X-ray diffraction, and X-ray

288 protein by biochemical analysis and UV-vis, Mossbauer, resonance Raman, and EPR spectroscopy.

289 enzoic acid and characterized by UV-visible, Mossbauer and electron paramagnetic resonance spectrosco

290 UV/visible, Mossbauer, and X-ray absorption spectroscopies have been

291 anges in local coordination geometries where Mossbauer cannot.

292 ansitions to a new species (pKa = 13.1) with Mossbauer parameters that are indicative of an iron(IV)-

293 the heme iron dynamics in cytochrome c with Mossbauer spectroscopy and especially nuclear resonance

294 croscopic sorption experiments combined with Mossbauer and extended X-ray absorption fine structure (

295 apid mixing technologies in conjunction with Mossbauer, ultraviolet/visible, and x-ray absorption spe

296 lved Fe(2+) release to solution coupled with Mossbauer spectra and XRD analysis of solid phase produc

297 sotope fractionations in other elements with Mossbauer isotopes, such as platinum and uranium.

298 In the present work, Mossbauer spectroscopy and electron microscopy indicate

299 nt study, powder XRD, synchrotron-based XAS, Mossbauer spectroscopy, and TEM demonstrated unambiguous

300 characterized using X-ray diffraction (XRD), Mossbauer spectroscopy, and scanning electron microscopy