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1 Si has been demonstrated to stimulate osteoblast differe
2 Si micropillars produced by MACE often show a porous Si/
3 Si-H insertion reactions represent an important method f
5 using the activated precatalysts rac-[Me(2) Si(indenyl)(2) ]ZrMe(2) and [Me(2) C(Cp)(fluorenyl)]ZrMe
6 N-heterocyclic silylene c-(CH)(2) (NtBu)(2) Si: proceeds directly to the corresponding tetrasilacycl
7 the centrosymmetric tetragonal magnet GdRu(2)Si(2) without a geometrically frustrated lattice by mean
11 Finally, WS(2) films as-deposited on SiO(2)/Si substrates were used to fabricate a backgated Field E
12 ehavior in a low SFE Fe(40)Mn(20)Cr(15)Co(20)Si(5) (at%) high entropy alloy, SFE ~ 6.31 mJ m(-2).
13 cide (U(3)Si(5)), uranium carbide (UC), U(20)Si(16)C(3), and uranium silicide (USi) phases can form a
14 terials yielding the interfacial phases U(20)Si(16)C(3), U(3)Si(5) and UC reveal a thermodynamic driv
17 or neurogenesis-dependent, as (56)Fe and (28)Si irradiation led to faster context discrimination in a
19 characterization and quantification by (29) Si NMR spectroscopy has received significant attention,
26 y long T(2) relaxation time of quartz in (29)Si and hence dramatically increasing the sensitivity.
27 ependent synthesis and comparison of its (29)Si{(1)H} NMR spectrum with that of the in situ reaction
28 ously assigned using (1)H, (13)C, (15)N, (29)Si, and (1)H DOSY NMR as well as X-ray diffraction studi
30 J-resolved SiH coupling and quantitative (29)Si measurements, diffuse reflectance IR, and elemental a
31 ids was conducted using high-sensitivity (29)Si NMR spectroscopy of isotopically enriched solutions c
33 and show that this signal correlates to (29)Si NMR signals from silicates in C-A-S-H, conflicting wi
34 large Si-rich microstructures in Al-12.2at.%Si alloy melt are probably aggregates comprising multipl
35 ucture in engineering-lightweight Al-12.2at.%Si alloy melt at 1100 degrees C, via melt-spinning (MS)
36 Si-rich microstructures exist in Al-12.2at.%Si alloy melt, and the large Si-rich microstructures dis
38 complexes of calcium and strontium, {(Me(3) Si)(2) N}M{B(NDippCH)(2) }(thf)(n) (M=Ca, n=2; M=Sr, n=3
40 )/U(IV) imide cyclometalate complex, [((Me(3)Si)(2)N)(2)(THF)U(mu-NH)(mu-kappa(2):C,N-CH(2)SiMe(2)NSi
41 [{((Me(3)Si)(2)N)(2)U(THF)}(2)(mu-N)][((Me(3)Si)(2)N)(2)U(eta(1)-CCPh)(mu(2)-NH)(mu(2)-eta(2):eta(1)-
42 V)/U(IV) nitride complex [Na(DME)(3)][((Me(3)Si)(2)N)(2)U(mu-N)(mu-kappa(2):CN-CH(2)SiMe(2)NSiMe(3))U
44 tylene to yield the imide acetylide [{((Me(3)Si)(2)N)(2)U(THF)}(2)(mu-N)][((Me(3)Si)(2)N)(2)U(eta(1)-
45 tionic U(IV)/U(IV) nitride complex, [{((Me(3)Si)(2)N)(2)U(THF)}(2)(mu-N)][BPh(4)] (THF = tetrahydrofu
46 rom C-H bond activation of toluene, [{((Me(3)Si)(2)N)(2)U(THF)}(2)(mu-N)][{((Me(3)Si)(2)N)(3)U(mu-NH)
48 {((Me(3)Si)(2)N)(2)U(THF)}(2)(mu-N)][{((Me(3)Si)(2)N)(3)U(mu-NH)U(N(SiMe(3))(2))}(2)(C(7)H(8))], 6.
49 cal [P(mu-NHyp)](2) (Hyp = hypersilyl, (Me(3)Si)(3)Si) with different isonitriles afforded a series o
52 (mu-NHyp)](2) (Hyp = hypersilyl, (Me(3)Si)(3)Si) with different isonitriles afforded a series of five
54 ck of continuous interaction between the U(3)Si(2) and SiC, reflects the diminishing driving force fo
56 the interfacial phases U(20)Si(16)C(3), U(3)Si(5) and UC reveal a thermodynamic driving force for ge
57 monstrate that triuranium pentasilicide (U(3)Si(5)), uranium carbide (UC), U(20)Si(16)C(3), and urani
58 ith demonstrated restricted formation of U(3)Si(5), UC, and U(20)Si(16)C(3)/USi phases at the interfa
60 tly light Si isotopes in EC-metals (delta(30)Si >= -6.94 +/- 0.09 per mille, Mg/Si = ~0.001) whereas
61 , causing the highest natural fluid delta(30)Si values measured to date (up to +5.2 +/- 0.2 per mille
62 the ocean with extremely high fluid delta(30)Si values, which can explain anomalies in the marine Si
65 r Si, B, and Sr isotope signatures (delta(30)Si, delta(11)B, and (87)Sr/(86)Sr, respectively) to stud
67 **))(eta(5)-Cp*)] (1) (Pn(**) = C(8)H(4)(1,4-Si(i)Pr(3))(2), Cp* = C(5)Me(5)) with ethene at atmosphe
69 tion of the uranyl cluster, [(UO(2))(3)(Cy(7)Si(7)O(12))(2)(Et(2)O)(MeCN)(2)] (2), as yellow rods in
70 )(OH)(3) in THF affords [U(OSiMe(3))(3)(Cy(7)Si(7)O(12))] (1) as orange plates in 24% isolated yield.
71 [UO(2)(N(SiMe(3))(2))(2)(THF)(2)] with Cy(7)Si(7)O(9)(OH)(3) in hexanes, followed by recrystallizati
72 iMe(3))(2))(2)(THF)(2)] with 1 equiv of Cy(7)Si(7)O(9)(OH)(3) in THF affords [U(OSiMe(3))(3)(Cy(7)Si(
74 a shell using tetraethoxysilane (TEOS), as a Si source, was stabilized on the surface of CDs via reve
76 ng-compatible macroporous architecture for a Si-graphite anode to maximize the volumetric energy dens
77 re serpentinization is directly related to a Si deficiency in the serpentine structure, which itself
78 eficial effects of a Ni(II) ion binding to a Si|PNP type surface as a result of significant thermodyn
79 his reaction, using a Cu-CHA catalyst with a Si/Al ratio of 15 and 2.6 wt% Cu, by X-ray absorption sp
80 e hydrogenated amorphous Si nanoparticles (a-Si:H NPs) offering ideal features for functional nanopho
81 the performance and reliability issues of a-Si:H, low-temperature polycrystalline silicon and amorph
83 w decades, hydrogenated amorphous silicon (a-Si:H) has been widely utilized as a TFT channel material
88 neering to synthesize hydrogenated amorphous Si nanoparticles (a-Si:H NPs) offering ideal features fo
93 though O sites in both framework Si-O-Al and Si-O-Si linkages are enriched simply on exposure to H(2)
96 dissimilarities between III-V materials and Si are the fundamental roadblock for conventional monoli
97 luded As, Be, Ca, Cd, Co, Cr, Fe, Mn, Ni and Si, and accumulated elements in the following order: Ama
98 h hexagonal closed-packed Te sublattices and Si-Si dimers occupying octahedral intercalation sites.
100 The active centers for this process are =Si-O-Y(OH)-O-Si= or =Si-O-Zn-O-Si-O= groups closely asso
101 d the following reductions in chipping area: Si (~ 23%), SiC (~ 36%), sapphire (~ 45%), and PSS (~ 33
102 650), largely outperforming state-of-the-art Si-nanowire strain sensors and even piezoresistive, piez
103 gh three-dimensional semiconductors, such as Si, are common in inorganic materials, imparting electri
106 rnary nano-crystals have to be described as (Si,Ti)(3)N(4) with N-vacancies resulting in the general
111 s adsorbed onto nanoporous p-type silicon (b-Si) photocathodes decorated with Ag nanoparticles (Ag NP
114 placement of the single biotin by the biotin-Si-NPs boosted on average a 30 fold chemiluminescent rea
115 ated that the new dot blot coupled to biotin-Si-NPs successfully detected Campylobacter from naturall
118 macroporous structure coated by the brittle Si nanolayer can withstand high pressure and maintain it
119 lopment in copper-catalysed C-C, C-N, C-B, C-Si and C-F bond-forming reactions using unactivated alky
120 the reversible reactions of cyclotrisilene c-Si(3) Tip(4) (Tip=2,4,6-triisopropylphenyl) with the N-h
121 thod for the efficient construction of new C-Si bonds, and typically, they are conducted in the prese
124 tanium nitride with the general composition (Si(1-x),Ti(x))(3)N(4) with x = 0 < x < 1 and spinel-type
125 ancies resulting in the general composition (Si(4+)(1-x) Ti(4+)(x-delta)Ti(3+)(delta))(3)N(4-delta).
126 where silica has grown on highly conductive Si(110) crystal facets, the silica-silicon conversion be
127 h significant concentrations of 5-coordinate Si bis-ligand complex being detected even under biologic
128 semblages containing 4-, 5-, or 6-coordinate Si centers have been identified, with significant concen
130 two equivalents of "silicocenium" cation [Cp*Si](+) as a source of low-valent Si(II), cleanly gives a
131 coating to reduce chipping when used to cut Si, SiC, sapphire, and patterned sapphire substrates (PS
136 s method relies on thermodynamically favored Si-F bond formation to generate a carbanion, therefore e
140 hows that although O sites in both framework Si-O-Al and Si-O-Si linkages are enriched simply on expo
141 transitions are confirmed to originate from Si and C impurities occupying shallow energy levels in t
144 o different TWIMS platforms (i.e., Synapt G2-Si and two Vion IMS QToF; bias within the threshold of +
148 rts have shown that C-H, N-H, B-H, O-H, S-H, Si-H, Ge-H, Sn-H and P-H insertion reactions are feasibl
152 nococcus oeni into SiO(2)-alginate hydrogel (Si-ALG) and the addition of lysozyme in wines inoculated
153 r of hydroxy groups to form hypercoordinated Si complexes, although formation constants may be orders
156 Southern Ocean that together show increased Si supply from deep mixing during the deglaciation with
159 ervations across the multi-level interfaces (Si/Li(x)Si/inner-SEI/outer-SEI), thus offering novel ins
161 intermolecular diarylcarbene insertion into Si-H bonds for the synthesis of silicon-stereogenic sila
163 t in Al-12.2at.%Si alloy melt, and the large Si-rich microstructures disrupt into small Si-rich micro
164 is of the MS alloys indicates that the large Si-rich microstructures in Al-12.2at.%Si alloy melt are
165 e report the presence of significantly light Si isotopes in EC-metals (delta(30)Si >= -6.94 +/- 0.09
166 ebular environment and vapor loss of lighter Si isotopes during planetary volatilization were also in
167 tegrating AlN actuators(14) on ultralow-loss Si(3)N(4) photonic circuits(15), we demonstrate voltage-
168 tructural analogues XM(YCH(2)CH(2))(3)N (M = Si, Ge, Sn, Pb, Ti, Al, Cr, Fe, Ni...; Y = O, NR, CH(2),
169 h as the short M-Si bonds, a nearly linear M-Si-M spine, long M-C bonds, and the presence of two plan
170 Hoff/Le Bel ptSi center, such as the short M-Si bonds, a nearly linear M-Si-M spine, long M-C bonds,
171 the metallasilylidyne complexes [Tp'(CO)(2)M=Si-M(CO)(2)(PMe(3))Tp'] with alkynes R(1)C=CR(2) and wer
174 s, which can explain anomalies in the marine Si budget like in the Cascadia Basin and which has to be
175 (delta(30)Si >= -6.94 +/- 0.09 per mille, Mg/Si = ~0.001) whereas its silicate phases are isotopicall
176 EC-silicates) = -0.33 +/- 0.11 per mille, Mg/Si = ~1.01) and closer to BSE (delta(30)Si(BSE) = -0.29
177 n technique for samples with low to moderate Si contents as it is inexpensive, simple to implement, a
178 of the cationic silicon center through an N-Si interaction and formation of a highly strained four-m
179 up by septuple atomic layers of N-Si-N-Mo-N-Si-N, which can be viewed as a MoN(2) layer sandwiched b
180 was built up by septuple atomic layers of N-Si-N-Mo-N-Si-N, which can be viewed as a MoN(2) layer sa
181 To demonstrate this concept, we prepared n-Si/Au nanoparticle Schottky junctions by electrodepositi
182 ral and optical properties of nanostructured Si(2)Te(3) hold great potential applications in optoelec
184 ies that large quantities of small (0-10 nm) Si-rich microstructures and small quantities of large (1
185 es and small quantities of large (10-240 nm) Si-rich microstructures exist in Al-12.2at.%Si alloy mel
186 biasing the framework Al arrangement (Al-O(-Si-O)(x)-Al, x = 1-3) among CHA zeolites of essentially
188 e centers for this process are =Si-O-Y(OH)-O-Si= or =Si-O-Zn-O-Si-O= groups closely associated with a
189 h O sites in both framework Si-O-Al and Si-O-Si linkages are enriched simply on exposure to H(2)(17)O
190 process are =Si-O-Y(OH)-O-Si= or =Si-O-Zn-O-Si-O= groups closely associated with adjacent silanol gr
191 r genes- Lsi1 and Lsi2 while the addition of Si further greatly induced their expression under Buta t
193 ilic nature allows for oxidative addition of Si-H, N-H, and even C-C bonds at the aluminum center.
195 t experimental evidence of the disruption of Si-rich microstructure in engineering-lightweight Al-12.
198 exposure to H(2)(17)O(l), the enrichment of Si-O-Al species is more rapid, with a more uniform frame
202 uptake assay demonstrated that 25 mug/ml of Si significantly stimulated hDFC cell proliferation.
204 and leaf and root anatomy, up-regulation of Si channel and transporter genes, ascorbate-glutathione
205 study was carried out to explore the role of Si (10 uM) in regulating Buta (4 uM) toxicity in rice se
206 ct in bulk centrosymmetric semiconductors of Si, TiO(2) and Nb-SrTiO(3) with high strain sensitivity
207 r alteration of serpentinites is a source of Si to the ocean with extremely high fluid delta(30)Si va
209 luorescence data show that the two suites of Si-based material sourced from the different reactor Uni
213 h quality cuprous iodide (CuI) film grown on Si and sapphire substrates by molecular beam epitaxy.
214 sized III-V photovoltaic (PV) cells grown on Si and silicon-on-insulator (SOI) substrates can be inte
219 m fixation of two CO(2) molecules across one Si=C bond, two different products could be isolated from
224 s for this process are =Si-O-Y(OH)-O-Si= or =Si-O-Zn-O-Si-O= groups closely associated with adjacent
225 of the discovered nano-sized ternary phase (Si(1-x),Ti(x))(3)N(4) embedded in gamma-Si(3)N(4) are id
226 The device is first fabricated on a planar Si wafer at the microscale and then transferred to trans
227 V), which is restored to the level of planar Si control (- 0.5 V) after removing SiO(x) in hydrofluor
228 imately 1000 times as compared to the planar Si in an electrolyte-insulator-semiconductor (EIS) struc
229 pillars produced by MACE often show a porous Si/SiO(x) shell on crystalline pillar cores introduced b
230 optoelectronic characteristics of the porous Si/SiO(x) shell correlated to their chemical composition
232 mbly, the growth of Ge wires on prepatterned Si (001) substrates with controllable position, distance
233 ubstituted phosphasilene forms two radicals (Si- and P-centred); and c) Mes-substituted phosphasilene
234 the voltage and power levels required to run Si electronics using common temperature differences.
237 on in the mantle wedge caused no significant Si isotope fractionation, implying closed system conditi
238 uggest that processes such as metal-silicate Si isotope fractionation at reduced nebular environment
239 utrients such as phosphate (P) and silicate (Si) by ferric iron (oxyhydr)oxides (FeOx) modulates nutr
241 nductor (EIS) structures as well as silicon (Si) nanowire (NW) field-effect transistors (FETs) covere
242 studies have indicated that dietary silicon (Si) is beneficial for bone homeostasis and skeletal heal
244 CM) memory(4,5), typically based on silicon (Si), has demonstrated a good analogue switching capabili
246 e Si-rich microstructures disrupt into small Si-rich microstructures with increasing of melt temperat
248 dy was to investigate the effects of soluble Si on osteogenic differentiation and connexin 43 (CX43)
252 hyrin, namely, silicon tetraphenylporphyrin (Si-TPP), by the deposition of atomic silicon onto a free
254 tential measurements in the dark reveal that Si|BisPNP-Ni also exhibits the most positive V(FB) value
255 Flow cytometric measurements revealed that Si (50 mug/ml) significantly increased CX43 protein expr
261 isopropylphosphino)xanthene) coordinates the Si-H bond of triethylsilane, 1,1,1,3,5,5,5-heptamethyltr
264 pump, the glacial-interglacial shift in the Si cycle may present an important control on Pleistocene
266 d the compound rearranges to incorporate the Si atom into the carbocyclic base to give an unprecedent
267 re positioned over a cavity, etched into the Si substrate, that provides thermal isolation and is des
270 structural and electronic properties of the Si-adsorbed and -substituted monolayer graphene systems
271 th the isolation and characterization of the Si-centered chiral silyl cation intermediates, finally a
272 stinct optoelectronic characteristics of the Si/SiO(x) shell can be beneficial for various sensor arc
275 re formed by single pulse irradiation on the Si substrate, and a twisted cone structure with a height
276 nnectivity of their sub-nanometer pores, the Si/Al ratio of the anionic framework, and the charge-bal
277 adatom-diversified geometric structures, the Si- and C-dominated energy bands, the spatial charge den
278 theory (DFT) calculations revealed that the Si=C bonds are involved in an expanded pai-conjugated sy
279 nts under catalytic conditions show that the Si|BisPNP-Ni substrate exhibits the most positive onset
280 ctionalities are directly linked through the Si-C bond, unlike the industry's traditional viscosifier
282 P Expedition 366 were investigated for their Si, B, and Sr isotope signatures (delta(30)Si, delta(11)
283 ted analysis cell based on an IR-transparent Si membrane with advantages of a robust design, flexible
285 e first dibenzo[a,e]disilapentalene with two Si=C moieties in the heteropentalene core has been prepa
286 l (Schottky) junctions formed between n-type Si and Au nanoparticles as light-addressable electrochem
289 standing different stages of AD by utilizing Si TL NW FET structures fabricated on the basis of cost-
290 cation [Cp*Si](+) as a source of low-valent Si(II), cleanly gives a borole half-sandwich pai-complex
291 iO(x) membrane on chemically etched vertical Si nanowires (SiNWs) in an electrolyte-insulator-nanowir
292 The optimized NiO(x) membrane on vertical Si nanowire in the EIN structure shows a good drift rate
294 dium (OIM) by itself and in combination with Si (25 mug/ml) significantly increased mineralisation in
295 e generators can be directly integrated with Si circuits and scaled up in area to generate voltages a
297 degrees C, via melt-spinning (MS) of Al(1-x)Si(x) (x = 0.03,0.07,0.122,0.2) alloy melts from differe
298 s across the multi-level interfaces (Si/Li(x)Si/inner-SEI/outer-SEI), thus offering novel insights in
299 th oxygen content of 4 sccm on planar SiO(x)/Si substrate shows good pH sensitivity of approximately