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1 TFA absorbs as a strong sharp peak (1675 cm(-1)) within
2 TFA content had decreased in this product category, whil
3 TFA content ranged between 0.17 g and 0.22 g/100 g produ
4 TFA estimation using network component analysis is an ef
5 TFA protocols were validated by homogeneous quantificati
6 TFA titration study of 4c using UV-vis and fluorescence
7 TFAs and polyunsaturated fatty acids (PUFAs) in the food
8 m 2 to 40% methanol modifier containing 0.1% TFA as an acidic additive was applied for the optimized
14 s was performed by a chemical method with 2M TFA at 100 degrees C and 120 degrees C and a combined ac
17 djusted geometric means for the sum of the 4 TFAs were 81.4 mumol/L (95% CI: 77.3, 85.6 mumol/L) and
18 s, [Pd4(CO)4(OAc)4Pd(acac)2] 1 and [Pd4(CO)4(TFA)4Pd(acac)2] 2, and an infinite Pd-Pt heterometallic
19 rboxylate (L-DMTC) with simple Bronsted acid TFA is reported as the suitable synergistic catalyst for
20 ork, a strategy to produce trans fatty acid (TFA) free (or low TFA) products from partially hydrogena
21 e relation between dietary trans fatty acid (TFA) intake and coronary artery disease risk is well est
24 Bs) in combination with trifluoracetic acid (TFA) vapor exposure for the imaging of lipids in mouse b
25 sulfonic acid (BA) and trifluoroacetic acid (TFA) as the mixed ion-pairing reagents was developed and
27 ppression effects from trifluoroacetic acid (TFA) in a typical peptide mapping method can be effectiv
29 study on the effect of trifluoroacetic acid (TFA) on the hydrogen atom transfer (HAT) reactions from
30 oacetic acid (TCA) and trifluoroacetic acid (TFA) resulted in lower recovery compared to AA (37% and
31 des on hydrolysis with trifluoroacetic acid (TFA) results in peptides that have a 4-formyl-benzamido
32 gas-phase reaction of trifluoroacetic acid (TFA) with two Criegee intermediates, formaldehyde oxide
34 In dichloromethane or trifluoroacetic acid (TFA), the reaction between 1 and ethylene produces Au(OA
39 -carbonitriles in neat trifluoroacetic acid (TFA); (2) a Pd(OAc)2 (10 mol %) or CuI (10 mol %) mediat
43 icantly higher amounts of trans fatty acids (TFA) were found in hard margarines (up to 28.84% of tota
44 cy, in terms of yields of total fatty acids (TFA), was in the order: chloroform/methanol>ethanol>hexa
46 erning the declaration of trans fatty acids (TFAs) content in the nutritional facts panel of processe
47 ts of naturally occurring trans fatty acids (TFAs) from ruminant animals (rTFA), such as vaccenic aci
49 nada to reduce industrial trans fatty acids (TFAs) in foods include mandated inclusion of TFA content
54 when the sum of SFAs and trans fatty acids (TFAs) was theoretically replaced by total UFAs, PUFAs, o
57 ans isomeric fatty acids [trans fatty acids (TFAs)] with the availability of long-chain polyunsaturat
60 structing the transcription factor activity (TFA), which makes use of the gene expression data and pr
61 length graphitized carbon columns and adding TFA as an acid modifier to a formic acid/reversed phase
62 ion was used to test whether energy-adjusted TFA intake in 1-SD increments was associated with incide
64 diradicaloids, while the longer dication ANA-TFA(2+) and dianion ANA(2-) have closed-shell ground sta
67 in assays using thermofluorimetric analysis (TFA) can limit matrix interference and promote multiplex
70 mparing fTRA (single or biradial access) and TFA (single or bifemoral or combined radial and femoral
71 d that the optimum conditions for pH, BA and TFA condition, type of separating column and flow rate,
73 echnical success was comparable for fTRA and TFA in different Japanese CTO score subgroups after mult
78 l approach (fTRA) and transfemoral approach (TFA) in a large prospective European registry adopting t
79 opean HFC-1234yf emissions were deposited as TFA within Europe, while the remaining fraction was expo
80 should be improved by replacing atherogenic TFA and SFA with beneficial ones, in order to avoid adve
81 rage, and the precipitation-weighted average TFA concentration of all analyzed wet deposition samples
85 ow that sex modifies the association between TFA intake and stroke; for every 2-g/d increase in TFA i
86 ignificant inverse associations seen between TFAs and LC-PUFAs in pregnant women in 3 different Europ
87 henyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; TFA = trifluoroacetate] has been reported to give quanti
88 henyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; TFA is trifluoroacetate] converts benzene, ethylene, and
89 n-carbon bond-forming step is accelerated by TFA and is a rare example of Bronsted acid catalysis in
90 lization on the sample surface is removed by TFA exposure uncovering a wider range of lipid species i
91 sought to determine whether plasma 18-carbon TFA and PUFA concentrations might decrease over time and
92 Total TFA values as well as total 18-carbon TFA values in umbilical vein wall lipids were significan
93 rsely to 18-carbon TFAs but not to 16-carbon TFAs, and at the sixth month of lactation arachidonic ac
95 rse correlations were seen between 18-carbon TFAs and arachidonic and docosahexaenoic acids in both a
96 related significantly inversely to 18-carbon TFAs but not to 16-carbon TFAs, and at the sixth month o
98 oncentration, reactant ratio, acid catalyst (TFA or BF3.OEt2), concentration of acid catalyst, oxidan
100 ogic pathways that may influence circulating TFAs by evaluating associations between common genetic v
101 as cooperative reoxidation of Rh(II) with Cu(TFA)2 and V2O5 proved essential in providing monoalkenyl
102 ompared to a base case of no ban and current TFA intakes, elimination of iTFA was estimated to preven
105 romatography with flame ionisation detector, TFA was estimated in six commonly used fat/oils in India
106 e development of a rapid method to determine TFAs <1% in edible oils (palm, peanut, soybean and sunfl
107 hange at the meso-positions with deuteriated TFA, and this observation indicates that protonation is
114 , (13)C, and (15)N NMR spectroscopy in DMSO, TFA, and DMSO/TFA solutions, where the azide-tetrazole e
115 15)N NMR spectroscopy in DMSO, TFA, and DMSO/TFA solutions, where the azide-tetrazole equilibrium cou
116 ibution percentiles were calculated for each TFA and their sum by age, sex, and race/ethnicity (non-H
117 dated assessment and longitudinally evaluate TFA amounts in the food supply and to determine whether
118 egories had a large proportion that exceeded TFA limits: dairy-free cheeses (100%), frosting (72.0%),
119 ave stearic acid replaced with the following TFA isomers (percentage of energy): 0.1% mixed isomers o
120 discovered glycine as a simple additive for TFA mobile phases, which mitigates ion suppression throu
121 d intake studies have provided estimates for TFA concentrations in the US population; however, there
124 hiral ruthenium complex formed in situ from (TFA)2Ru(CO)(PPh3)2 and (R)-BINAP is found to catalyze th
130 of TFAs in modifying fetal growth; however, TFA exposure may be a confounding parameter in studies t
132 s of iodine-based reagents [I2, ICl, ICl3, I(TFA)3, I2O4, I2O5, (IO2)2S2O7, (IO)2SO4] indicated that
139 The discovery of this glycine additive in TFA mobile phases provides a simple and conventional app
143 There has been an impressive improvement in TFA amounts in the Canadian food supply since the termin
145 adjusted models, a 1-SD (2-g/d) increase in TFA intake was associated with an increased risk of any
146 take and stroke; for every 2-g/d increase in TFA intake, there was a 14% increase in the risk of stro
147 Is for overall NHL risk per 1 SD increase in TFA level and assessed histologic subtype-specific assoc
148 t that the higher reaction rates observed in TFA and TFE compared with CH2Cl2 arise from stabilizatio
149 The results indicate an overall reduction in TFA concentrations in the US population and provide a va
151 o heating/frying demonstrated an increase in TFAs (p<0.001), saturated fatty acids (p<0.001) and decr
152 s have resulted in significant reductions in TFAs in the diets of Canadian breastfeeding mothers and
158 nada set voluntary TFA limits for industrial TFAs added to food and encouraged substitution of TFAs w
159 ctly adding a small amount (e.g., 2 mM) into TFA mobile phases without compromising the chromatograph
161 urage the food industry to voluntarily limit TFA content in all vegetable oils and soft margarines an
162 food manufacturers and restaurants to limit TFAs in foods have resulted in significant reductions in
163 produce trans fatty acid (TFA) free (or low TFA) products from partially hydrogenated soybean oil by
165 (P < 0.05) among some foods with the lowest TFAs, such as cookies, brownies and squares, cakes with
167 ples from 1999-2000 and 2009-2010.Four major TFAs [palmitelaidic acid (C16:1n-7t), trans vaccenic aci
173 rcentage of fat, proportion of foods meeting TFA limits, and saturated fat amounts in foods with high
182 by proton NMR spectroscopy, but addition of TFA gave rise to the formation of weakly diatropic dicat
184 ochromic properties in solution: addition of TFA leads to the opening of the furan ring and addition
188 No longitudinal follow-up assessment of TFA amounts in foods has occurred in Canada since termin
190 the study include the lack of recent data of TFA intake and the small sample sizes used to estimate i
191 information regarding the wet deposition of TFA as well as general data on the spatial and temporal
196 onsidering the undesirable health effects of TFA, appropriate guidelines for heating/re-frying of edi
198 TFAs) in foods include mandated inclusion of TFA content on food labels and recommendations by Health
201 percentage of energy): 0.1% mixed isomers of TFA (control), approximately 3% VA, approximately 3% iTF
202 calculated by comparing the current level of TFA intake to a counterfactual setting where consumption
204 The direct-readout, differential nature of TFA also promoted assay consistency and minimized calibr
205 comprehensive overview of the occurrence of TFA in precipitation by a systematic and nation-wide fie
207 with a pyrrole dialdehyde in the presence of TFA, followed by oxidation with DDQ, afforded good yield
208 with a pyrrole dialdehyde in the presence of TFA, followed by oxidation with ferric chloride, to give
209 The consequences are explored for removal of TFA from the atmosphere by reaction with biogenic Criege
210 these results future occasional sampling of TFA in the atmospheric environment should be considered.
212 ysis suggested an enhanced transformation of TFA precursors in the troposphere in the summertime due
213 be cleaved from carboxyl with 2-3% (v/v) of TFA in acetonitrile (0-10 degrees C), without affecting
214 This study was a cross-sectional analysis of TFAs, cis-MUFAs, SFAs, and PUFAs measured in plasma befo
215 This change in plasma concentrations of TFAs is consistent with changes in fatty acid compositio
219 linear correlation between the percentage of TFAs in the diet and human milk fat established by Craig
220 ible to draw firm conclusions on the role of TFAs in modifying fetal growth; however, TFA exposure ma
222 lation; however, there is a need for data on TFA blood concentrations in the population.The objective
223 o seen to be significantly less dependent on TFA-ion pairing, making it ideal for MS applications whe
224 n in sweet bakery products, with emphasis on TFA, on the Swedish market and compare fatty acid compos
230 l course of amidopalladation in the (IMes)Pd(TFA)2(H2O)-catalyzed aerobic oxidative amidation of alke
231 In this study, the mechanism of (IMes)Pd(TFA)2(H2O)-catalyzed oxidative heterocyclization of (Z)-
232 ed as arylating agents in the presence of Pd(TFA)2 and a chiral, commercially available, bisoxazoline
233 minimal kinetic influence on the rate of Pd(TFA)2-catalyzed dehydrogenation of cyclohexanone to cycl
234 ective of this study was to determine plasma TFA concentrations in a nationally representative group
235 ime trend (R(2) = 0.167, P < 0.0001), plasma TFAs decreased by 13.5%/y (95% CI: -22.7, -3.2%/y; absol
236 ks of CVD mortality when replacing SFAs plus TFAs with total UFAs [HR in quintile 5 compared with qui
237 ontinuous analyses, replacement of SFAs plus TFAs with total UFAs, PUFAs, or cis MUFAs (per 5% of ene
238 ow that homogeneous, one step (mix-and-read) TFA methods can be extended to the analysis of both a sm
239 ce TFAs in foods that exceed the recommended TFA limits and to minimize the use of saturated fats in
240 n by the food industry is required to reduce TFAs in foods that exceed the recommended TFA limits and
245 styrene using the Rh(I) catalyst ((Fl)DAB)Rh(TFA)(eta(2)-C2H4) [(Fl)DAB = N,N'-bis(pentafluorophenyl)
246 , we report that the Rh catalyst ((Fl)DAB)Rh(TFA)(eta(2)-C2H4) [(Fl)DAB is N,N'-bis(pentafluorophenyl
250 genome-scale metabolic model (GEM) of strain TFA, which has been manually curated, includes informati
252 mass spectrometry detection sensitivity than TFA mobile phases for LC-MS-based characterization of bi
253 imated from the TFA human milk fat data that TFA intake of Canadian breastfeeding mothers was 0.9%, 0
255 important proof of principle indicating that TFA-12 could be a potential therapeutic compound for mye
256 e data for the adult US population show that TFA concentrations were 54% lower in NHANES 2009-2010 th
258 uation of mouse EAE spinal cords showed that TFA-12 treatment reduces inflammation, astrogliosis, and
264 t is derived from fat, we estimated from the TFA human milk fat data that TFA intake of Canadian brea
265 ign revealed a pronounced seasonality of the TFA concentration and wet deposition flux of collected s
268 n of the reaction medium with respect to the TFA/TFAA mixture (substrate concentration) have a remark
270 tadelta(13)C(EA/LC-IRMS) = 8.8 per thousand, TFA Deltadelta(13)C(EA/LC-IRMS) = 6.0 per thousand).
271 onary intervention is a valid alternative to TFA with a high rate of success, low complication rates,
273 ean of 0.5% energy per day (corresponding to TFA intake only from nonindustrial sources, e.g., dairy
275 ide d-Hot horizontal lineTap is resistant to TFA and thus can serve as a bioorthogonal modification o
278 We observed a positive association of total TFA levels with diffuse large B cell lymphoma (DLBCL) ri
281 mportant diffuse source of trifluoroacetate (TFA) to the nonmarine environment, information regarding
285 tionally predicted main-group p-block Sb(V) (TFA)(5) complex selectively functionalizes the C-H bonds
290 present in this peptide and evaluate whether TFA affects the stability of GXXGlp during thermal stres
293 (53.6% female) in highly urban counties with TFA restrictions and 3.3 million adults (52.3% female) i
294 pre-post study of residents in counties with TFA restrictions vs counties without restrictions from 2
297 triction implementation, the population with TFA restrictions experienced significant additional decl
299 protected mono- and pseudodisaccharides with TFA in anhydrous CH2Cl2 and 3,4-(methylenedioxy)toluene