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1 Zn and/or polycyclic aromatic hydrocarbons (pyrene, phen
2 Zn(2+) has been shown to have a wide range of modulatory
3 Zn-DeAlBEA was found to be highly active for ethanol deh
4 Zn-HAB is shown to have microporosity with a band gap of
6 as the presence of the redox inactive 3d(10) Zn(2+) is expected to perturb the long range in-plane CT
7 oxide (HEO) Co(0.2) Ni(0.2) Cu(0.2) Mg(0.2) Zn(0.2) O material with mesoporous structure is prepared
9 h 3-center-2-electron sigma bonding in Ge(2) Zn or Ge(2) Cd triangles plays a vital role in the stabi
10 capsulated Zn(TFSI)(2) -TFEP forms a ZnF(2) -Zn(3) (PO(4) )(2) solid electrolyte interphase (SEI) pre
12 H-10 and the two polymorphs of 2(H(2)NMe(2))[Zn(2)(cpb)].1.5dmac, Zn-MOF-888 and CTH-11, show kgd-net
13 hX (X = I and Br) in the presence of NiCl(2)/Zn as the precursors for the assumed Ni(0) complexant to
15 2+), Mn(2+), Fe(2+), Al(3+), Ni(2+), Cu(2+), Zn(2+), Co(2+), Pb(2+) and Ru(3+)) and aqueous compatibi
16 ing from [2 Fe:9 Zn:6 protomers] to [8 Fe:21 Zn:12 protomers], these protein cages represent some of
20 antibacterial systems (Ti-Mg and Ti-Mg-3wt% Zn) that can selectively eradicate E. coli while not har
21 mothers of pre-term (Fe = 0.997, Cu = 0.506, Zn = 4.15 and I = 0.458 mg L(-1)) and mothers of full-te
22 morphs of 2(H(2)NMe(2))[Zn(2)(cpb)].1.5dmac, Zn-MOF-888 and CTH-11, show kgd-nets; [Cu(2)(cpb)(acetat
23 pitated Zn/Cu-bearing solids contained 33.6% Zn and 21.7% Cu, whereas the Fe content was less than 0.
25 e (66)Zn/(64)Zn ratio (expressed as delta(66)Zn value) shows an enrichment of the heavy isotope in ma
28 With stoichiometries ranging from [2 Fe:9 Zn:6 protomers] to [8 Fe:21 Zn:12 protomers], these prot
30 omposed of 5-17 B-repeats, each containing a Zn(2+)-binding G5 and a spacer subdomain, is responsible
31 alkaline phosphatase superfamily, contains a Zn(2+) ion at its active center, and is structurally sim
32 MOF electrolyte protected Zn anode enables a Zn||Ti cell to achieve a high average Coulombic efficien
33 eature within its CDR3 loop, which harbors a Zn(2+)-binding site that substitutes for a loop-stabiliz
34 e of 0.0047 % per cycle over 600 cycles in a Zn||MnO(2) full cell with a low capacity ratio of Zn:MnO
37 owledge, we present the first structure of a Zn(II)-dependent aromatic dehalogenase that does not req
38 small intestine villi of mice subjected to a Zn-enriched diet was imaged using the 0.6 mum spot size,
39 cal metalloenzyme inhibitors of Zn(II)-ACE1, Zn(II)-HDAC, Fe(II)/(III)-5-LO or Cu(II)-tyrosinase from
40 includes genes encoding Zn import (adcABC), Zn sparing (rpsN.2), and Zn scavenging systems (adcAII,
46 ront passivation approaches: (i) both Cd and Zn impurities beneficially reduce the high native net do
47 lays a key role in the evaporation of Cu and Zn at temperatures above 700 degrees C, while at relativ
48 cycles on physicochemical parameters, Cu and Zn concentrations, and isotopic composition in solution
50 formation of 1,3-butadine over Y-DeAlBEA and Zn-DeAlBEA does not occur via aldol condensation of acet
53 ing by combining soil column experiments and Zn speciation characterization in OWs and amended soils.
56 On the other hand, integrating Co, Mn, and Zn turns Li(2) S into a prelithiation agent, forming met
57 .3-1, 3-14 and 0.5-2 ppm for Fe, Cu, Mn, and Zn, respectively, and varied as a function of the origin
59 te tensile strength 646.69 +/- 12.79 MPa and Zn-0.8Li-0.8Mn alloy with elongation 103.27 +/- 20%.
60 ntent of minerals (Ca, Fe, K, Mg, Mn, Na and Zn), dietary fiber (total, soluble and insoluble), tanni
61 Results showed, the mean values of Pb and Zn were higher in crop than Food and Agriculture Organiz
71 ined in the acid and further precipitated as Zn/Cu-bearing solids by adjusting the solution pH to 9.
74 ious functional groups involved in bacterial Zn binding were identified by FT-IR spectroscopy and ele
75 a remarkably lowered binding energy between Zn(2+) and host O(2-) , which explains the favorable kin
76 e conformation of an unstructured bimetallic Zn(II) complex can be controlled by its inclusion in the
79 is more efficient for attracting and binding Zn(2+) via the essential histidines than the monomer or
84 dification of Mg with alloying elements (Ca, Zn), the degradation rates of Mg alloys were controlled,
85 n binding to OM at low concentrations and Ca-Zn competition, that is, typical conditions that occur i
86 oxy-cytidine dinucleotide near the catalytic Zn(2+), yet not in the catalytic position, where the int
87 incorporation of manganese (Mn) ions into Cd(Zn)-chalcogenide QDs activates strong spin-exchange inte
88 esentative metal ions were examined: Pb, Cd, Zn, Ce (III), Ba, Ni, Fe(II), Fe(III), Cu(II), Cr, Mo, C
89 t heterometallic supertetrahedral clusters, [Zn(6) Ge(16) ](4-) and [Cd(6) Ge(16) ](4-) , were direct
90 precursor [HNEt(3) ](2) [M(pdms)(2) ] (M=Co, Zn) allow for multiple charge transfers (CTs) between th
92 ystem selectively bound the thiol-containing Zn(II)-ACE1 inhibitors captopril and omapatrilat, and th
93 dvantage of the ability of His to coordinate Zn(2+) to promote metal ion bridges, and we have found t
98 erum and 12 elements (Mg, S, Mn, Fe, Co, Cu, Zn Se, Br, Rb, Mo, and Cs) in less than 250 000 cells.
99 nts (Mg, P, S, K, Ca, V, Cr, Mn, Fe, Co, Cu, Zn, Se, Br, Rb, Sr, Mo, I, Cs, and Ba) in 10 muL of seru
101 , heavy metals including Cr, Mn, Co, Ni, Cu, Zn, As, and Cd in 55 Thai local rice (4 varieties) were
102 near-complete extractions of Mn, Co, Ni, Cu, Zn, Cd, and Pb ions from natural water samples prior to
104 SOD, namely, the fully mature functional Cu,Zn state and the E,Zn-SOD state in which the Cu site is
105 guanosine (8-OHdG), superoxide dismutase (Cu-Zn SOD), and thiobarbituric acid reactive substances (TB
107 reaction of a stable monomeric variant of Cu/Zn superoxide dismutase (mSOD1), an enzyme responsible f
108 ng of SOD5 strongly deviate from those of Cu/Zn-SODs in its animal hosts, making Cu-only SODs a possi
109 Here, we examine the trajectory that Cu/Zn superoxide dismutase (SOD1) dimers take over the unfo
111 s high coulombic efficiency (ca. 97 %), deep Zn plating/stripping (10 mAh cm(-2) ), and long cycle li
112 bovine wound infection 'digital dermatitis', Zn/Cu-shellac adhered rapidly and robustly over pre-appl
114 ) O(5) -dissolution mechanisms for different Zn-salt aqueous electrolytes and their implications to t
115 sor was applied to wastewater with different Zn(2+) concentrations and the results showed that the de
118 experiment, and phosphate was found to drive Zn speciation in both OW and amended soils (i.e., amorph
121 entified by FT-IR spectroscopy and elemental Zn in bio-chelated cell lysate complex was confirmed by
123 The AdcR regulon includes genes encoding Zn import (adcABC), Zn sparing (rpsN.2), and Zn scavengi
124 developed dissolution method allowed Ca, Fe, Zn, and Mg determination in milk samples with adequate a
125 ntrations of 16 elements (K, Na, Mg, Ca, Fe, Zn, Hg, Se, As, Cu, Cd, Mn, Ni, Cr, Pb and Co) were dete
126 Micro-nutrient profiling showed Ca, Fe, Zn, P, K and Mn in the range of 2400.00-3400.00, 40.28-4
129 ro- (Mg, P, S, K, Ca) and micronutrient (Fe, Zn, Mn, Cu) concentrations of leaves and edible parts of
130 N, P, Ca, Na, K, Mg) and micronutrients (Fe, Zn, Co, Mn, I) were sufficient to contribute to daily di
131 Low phloem mobile nutrients Ca, Mn, Fe, Zn, and Cu showed the largest differences in correlation
133 can be attributed to a number of very fine, Zn/Ca-containing nanoscale precipitates, along with ultr
135 mice, indicating the direct competition for Zn between CP and proteins encoded by the GAS AdcR regul
137 results showed that the detection range for Zn(2+) was 20-100 muM, which covers common Zn(2+) safety
138 5 and a spacer subdomain, is responsible for Zn(2+)-dependent assembly leading to accumulation of bac
139 ion coordination geometries (tetrahedral for Zn(2+), tetrahedral to octahedral conversion for Co(2+),
141 on, the decomposition of solvated DMSO forms Zn(12)(SO(4))(3)Cl(3)(OH)(15).5H(2)O, ZnSO(3), and ZnS e
142 HsZnT8 forms a dimeric structure with four Zn(2+) binding sites within each subunit: a highly conse
143 to have square-pyramidal geometry with four Zn-N bonds in the equatorial plane and one Zn-OH(2) bond
145 Here, we separate aqueous electrolyte from Zn anode by coating a thin MOF layer on anode and fillin
148 a representative glass, namely ZIF-62 glass (Zn(C(3)H(3)N(2))(1.75)(C(7)H(5)N(2))(0.25)), is measured
150 highly active organometallic heterodinuclear Zn(II)/Mg(II) catalyst applied in a one-pot procedure to
151 nd filling the pores of MOF with hydrophobic Zn(TFSI)(2) -tris(2,2,2-trifluoroethyl)phosphate (TFEP)
153 accumulated in the soil surface layer, (iii) Zn uptake by lettuce increased with repeated OW applicat
155 ared to other pancreatic cells; importantly, Zn(II)-mediated hydrolysis triggers cargo activation.
156 applications, and (iv) no radical change in Zn speciation was observed at the end of the 12-week exp
157 he coordination mode of the oleate ligand in Zn-oleate to be achieved (including information on Zn...
158 )-H(2)O, in which DMSO replaces the H(2)O in Zn(2+) solvation sheath due to a higher Gutmann donor nu
159 of the ternary Zn-Li alloy system results in Zn-0.8Li-0.4Mg alloy with the ultimate tensile strength
163 Importantly, when the complex also included Zn(2+), a significant increase in cell membrane GLUT1 wa
164 THQ, the CT in Cu/Zn-THQ after incorporating Zn(2+) guest metal was also examined to uncover the cont
168 ansformation of V(2) O(5) atomic layers into Zn(3) V(2) O(7) (OH)(2) .2 H(2) O (ZVO) nanoflake cluste
172 r, their lifespan is limited by irreversible Zn anodes owing to water decomposition and Zn dendrite g
173 640 mV more positive than the isostructural [Zn(tpyPY2Me)](2+) analog containing the redox-inactive Z
176 id solution containing 23.5 g/L Fe, 4.45 g/L Zn and 2.81 g/L Cu, which was subjected to hydrothermal
179 ent compounds (Me(2)NH(2))(2)[M(2)L(3)] (M = Zn, Mn; H(2)L = 2,5-dichloro-3,6-dihydroxo-1,4-benzoquin
180 GAS counterstrategies to combat CP-mediated Zn limitation and the in vivo relevance of CP-GAS intera
181 itivity of the mutant strains to CP-mediated Zn limitation suggests distinct roles for individual Adc
183 cally synthesized ((Fc(2)PDI)MCl(2), M = Mg, Zn, Fe, and Co) and characterized crystallographically,
184 nclude alkali (Li/Na/K) and multivalent (Mg, Zn)-based electrolytes for conventional "sealed" batteri
185 twork structure is unperturbed at micromolar Zn(2+) concentrations, but strong bundle formation is ob
186 in LC-PUFAs and micro-nutrients (Cu, Fe, Mn, Zn), including species considered as potentially edible
187 foods, we analysed selected minerals (Fe-Mn-Zn-Cu-Mg) in wild-harvested and commercially available t
188 s of deviations between measured and modeled Zn concentrations reveal specific limitations of the cur
189 le, in particular metals such as Ca, Al, Na, Zn, and Fe and halogens like Cl and F, occurring in conc
191 hanesulfonyl)imide, this ketone formed a new Zn(4) L(4) tetrahedron 1 bearing twelve uncoordinated py
192 and the glucose, sucrose, Brix, Cd, Pb, Ni, Zn, and Cr values were found in the highland honeys; the
194 e production of crystals of MUV-101(Fe,Co,Ni,Zn) and MUV-102(Cu), heterometallic titanium MOFs isostr
195 this process are =Si-O-Y(OH)-O-Si= or =Si-O-Zn-O-Si-O= groups closely associated with adjacent silan
196 erence in reactivity reflects the ability of Zn to promote a rate-limiting C-H reductive elimination
203 is technology, the elemental distribution of Zn in small intestine villi of mice subjected to a Zn-en
204 meters controlling the environmental fate of Zn following OW application on cultivated soils is scant
205 this study highlighted that (i) the fate of Zn in water-soil-plant compartments was similar, regardl
206 ligand pai-pai stacking, as incorporation of Zn(2+) in Cu-THQ significantly reduced photoconductivity
207 ntal or clinical metalloenzyme inhibitors of Zn(II)-ACE1, Zn(II)-HDAC, Fe(II)/(III)-5-LO or Cu(II)-ty
209 olytes by 0.45 V and enable the operation of Zn/graphite dual-ion cells at 2.80 V with a long cycle l
212 the method by mapping metal-binding sites of Zn(7-x)MT species using a bottom-up MS approach with res
214 ate to be achieved (including information on Zn...O distances) and (ii) the mode of attachment of ole
216 The mechanism of interaction between SB-OP-Zn(2+) trio is investigated by spectrofluorometric, spec
219 porphyrin prisms using MTPyP (M = Co(II) or Zn(II), TPyP = 4-tetrapyridylporphyrin) and functionaliz
220 of Cu(II)-, Fe(III)-, Ga(III)-, Ni(II)-, or Zn(II)-IMAC resins to reversibly bind experimental or cl
222 In this work, porous Zn nanoparticles (P-Zn) were adopted as a model catalyst to investigate the
223 entially toxic elements (Cu, Cr, Mn, Fe, Pb, Zn, Ni) were analysed by atomic absorption spectrometer
227 xture of uncoordinated and coordinated (PPIX)Zn or all coordinated depending on the ratio of peptide/
230 olid electrolyte interphase (SEI) preventing Zn dendrite and further suppressing water decomposition.
232 cy depends upon the catalyst, and previously Zn(II)Mg(II) heterodinuclear catalysts showed good perfo
235 Zn(TFSI)(2) -TFEP@MOF electrolyte protected Zn anode enables a Zn||Ti cell to achieve a high average
236 upported lipid bilayers (SLBs), forming a PS-Zn(2+) complex with an equilibrium dissociation constant
237 Ni-N(4) /GHSs/Fe-N(4) endows a rechargeable Zn-air battery with excellent energy efficiency and cycl
239 t TLSB could be desorbed with HCl to recover Zn(II) and Cd(II) and with HNO(3) to recover Hg(II) afte
240 ly and plays an essential role in regulating Zn(2+) accumulation in the insulin secretory granules of
241 e electrochemical reaction during repetitive Zn(2+) insertion and extraction, as demonstrated by in s
242 dicate that Aap from S. epidermidis requires Zn(2+) as a catalyst that drives amyloid fiber formation
245 entation that coordinates to the active-site Zn(II) ions via a CN and that maximizes a pai-pai intera
246 then used for the synthesis of a metal soap (Zn-oleate) and the surface-functionalization of ZnO nano
247 zobacterial diversity; among these, the soil Zn contents decreased significantly across the rhizobact
248 tanding air cathode for flexible solid-state Zn-air batteries without the use of carbon paper/cloth a
249 ce of this inhibition.SIGNIFICANCE STATEMENT Zn(2+) is present along with glutamate in synaptic vesic
252 ous extraction conditions, and subsequently, Zn speciation was modeled using the generic non-ideal co
253 devices with ZnO layer result in substantial Zn diffusion, which can penetrate the full absorber thic
260 ubunits, and activation levels and show that Zn(2+) inhibits AMPARs in an activity-dependent manner,
268 action is over one billion years old but the Zn-fingernail appears only in VARP homologues in the lin
269 We performed mutagenesis to compromise the Zn(2+)-binding site and observed that this change severe
271 te in transmembrane domain (TMD) housing the Zn(2+) substrate; an interfacial site between TMD and C-
273 d C-terminal domain (CTD) that modulates the Zn(2+) transport activity of HsZnT8; and two adjacent si
276 y, the local coordination environment of the Zn center was determined to have square-pyramidal geomet
277 the type of soil and OW, (ii) >97.6% of the Zn input from OW accumulated in the soil surface layer,
279 residue, His(114), is hydrogen-bonded to the Zn(II)-bound water/hydroxide and likely functions as the
280 quencing, and metabolomics analyses in these Zn-deficient rats revealed the molecular basis of ESCC a
282 odel parameters, particularly with regard to Zn binding to OM at low concentrations and Ca-Zn competi
284 gate to bind a terpyridine zinc complex (Tpy-Zn), forming a fluorescent [Tpy-Zn]-SPP complex (K(ass)
285 complex (Tpy-Zn), forming a fluorescent [Tpy-Zn]-SPP complex (K(ass) 106,000 M(-1) in EtOH-CHCl(3)) w
287 ectively, OsZIP4 is involved in transporting Zn to the phloem of diffuse vascular bundles in the node
290 is needed to achieve the same effect as with Zn(2+), which suggests the importance of salt-protein in
291 FC biosensor have a linear relationship with Zn(2+) concentrations (0, 100, 200, 300, and 400 muM, re
292 ected cell volume expansion of CaBa(1-x)Pb(x)Zn(2)Ga(2)O(7) (0 <= x <= 1), which is a unique structur
293 evolution of the unit cell for CaBa(1-x)Pb(x)Zn(2)Ga(2)O(7) is due to the combination of the high ste
298 mine (NA) is a natural chelator of Fe, zinc (Zn) and other metals in higher plants and NA-chelated Fe