ライフサイエンスコーパス: aliphatic

1 e used directly in nucleophilic aromatic and aliphatic (18)F-fluorination reactions, obviating the ne

2 d-catalysed beta-C(sp(3))-H lactonization of aliphatic acids enabled by a mono-N-protected beta-amino

3 trifluoromethyl-substituted derivatives from aliphatic acids is developed.

4 Functionalization of the beta-C-H bonds of aliphatic acids is emerging as a valuable synthetic disc

5 f these reactions are incompatible with free aliphatic acids without exogenous directing groups.

6 disclosure of the beta-lactonization of free aliphatic acids, the use of peroxides in C-H activation

7 lkyl bromides, generating a diverse array of aliphatic acids.

8 carbon bonds via catalytic beta-scission of aliphatic alcohol derivatives with both aryl and alkyl h

9 ne and gamma iodide are incorporated onto an aliphatic alcohol in a single operation.

10 nzonitriles is demonstrated here by using an aliphatic alcohol-water system.

11 keton (3-hexanone) < aldehyde (1-hexanal) < aliphatic alcohols (2-hexen-1-ol and 1-hexanol) < phenol

12 are capable of directly photoreleasing both aliphatic alcohols and phenols upon irradiation via phot

13 hich allows selective remote alkenylation of aliphatic alcohols at unactivated beta-, gamma-, and del

14 Both benzylic and aliphatic alcohols could be utilized, and several functi

15 A photochemical method for converting aliphatic alcohols into boronic esters is described.

16 However, a competition between water and aliphatic alcohols is observed at 53%RH.

17 Abundant aliphatic alcohols represent the ideal feedstock for the

18 ionalization is illustrated by conversion of aliphatic alcohols to a diverse collection of alpha,beta

19 talyst, allowing benzylic and simple primary aliphatic alcohols to be employed as alkylating agents.

20 The structures varied from simple aliphatic alcohols to complex cyclic systems and highly

21 for the light-driven isomerization of cyclic aliphatic alcohols to linear carbonyl compounds.

22 ochemical oxidation of primary and secondary aliphatic alcohols using a pair of flavin and dialkylthi

23 mma-, and delta-C(sp(3))-N bond formation in aliphatic alcohols using mild basic conditions and readi

24 s with a wide range of primary and secondary aliphatic alcohols, affording synthetically important et

25 oupled with potassium aryl trifluoroborates, aliphatic alcohols, and nitriles without the assistance

26 Aliphatic alcohols, phenols, carboxylic acids, thiols an

27 the beta-methylene C(sp(3) )-H arylation of aliphatic alcohols, which has not been possible previous

28 hod for the modular ring expansion of cyclic aliphatic alcohols.

29 s that this enzyme functions as a long-chain aliphatic aldehyde dehydrogenase.

30 +) reveals an apolar binding site primed for aliphatic aldehyde substrate recognition.

31 ndensation of a secondary alkylamine with an aliphatic aldehyde to form an all-alkyl-iminium ion, whi

32 yls remains poorly developed, especially for aliphatic aldehydes and hindered substrate combinations.

33 By the same deoxygenation manifold with aliphatic aldehydes and ketones, we also enable a concis

34 Using this method, both aromatic and aliphatic aldehydes can be transformed into syntheticall

35 imal protocol for the trans-aziridination of aliphatic aldehydes did not require prereaction of the c

36 While aliphatic aldehydes gave the expected HWE product, aroma

37 imidazoheterocycles and N-heteroarenes with aliphatic aldehydes has been developed via oxidative dec

38 materials due to their easy preparation from aliphatic aldehydes through spontaneous condensation wit

39 STRs also accept short-chain aliphatic aldehydes to give enantioenriched alkaloid pro

40 a2 (Aldh3a2) enzyme that oxidizes long-chain aliphatic aldehydes to prevent cellular oxidative damage

41 amines and substituted aromatic/heterocyclic/aliphatic aldehydes under aerial conditions using mixed

42 ddition of aryl halides to both aromatic and aliphatic aldehydes using zinc metal as the reducing age

43 The reaction affords homocoupling of aliphatic aldehydes, as well as heterocoupling of alipha

44 ortant products and as well as to the use of aliphatic aldehydes.

45 ightly different for aryl aldehydes than for aliphatic aldehydes.

46 le Oleispira antarctica RB-8, which utilizes aliphatic alkanes almost exclusively as substrates, domi

47 e for the photocycloaddition of unconjugated aliphatic alkenes is the Cu-catalyzed Salomon-Kochi reac

48 complexes, nucleopalladations with terminal aliphatic alkenes typically deliver the nucleophile to t

49 nificant challenge for reactions with simple aliphatic alkenes.

50 Using an internal aliphatic alkyne bearing a propargylic ether group, diff

51 ing between ketone beta-C(sp(3))-H bonds and aliphatic alkynes using an in situ-installed directing g

52 Aliphatic allenes are incompatible with the reaction con

53 n array of functionalized and/or challenging aliphatic allylic electrophiles.

54 arboxylic acid reductase (Fub8) in making an aliphatic alpha,beta-unsaturated aldehyde.

55 Anodic oxidation of aliphatic alpha-amino acids in aqueous electrolytes can

56 -gluconate 2-epimerases, and one short-chain aliphatic alpha-hydroxyacid racemase among the tested en

57 col comprises mono-, di-, and trisubstituted aliphatic, alpha-amino, and alpha-oxy acids as well as a

58 Both aromatic and aliphatic amide derivatives could successfully deliver t

59 The initial beta-C(sp(3))-H activation of aliphatic amide, followed by maleimide insertion, trigge

60 catalytic C-H functionalization, the use of aliphatic amine coupling partners is limited.

61 C-H bonds beta to nitrogen in an imine of an aliphatic amine, a process that occurs through a four-me

62 ,6-dichloro-5-nitrobenzofuroxan 1 with eight aliphatic amines (characterized by very different basici

63 lective C(sp(3))-H functionalization of free aliphatic amines (cyclopropylmethylamines) enabled by a

64 novel fluorinated amino acids, anilines, and aliphatic amines - valuable building blocks for medicina

65 n light of the ever-increasing importance of aliphatic amines across the range of chemical sciences,

66 While free primary aliphatic amines are common, versatile intermediates in

67 n reaction, the selective mono-alkylation of aliphatic amines by unactivated, hindered halides persis

68 A wide range of cyclohexyl and linear aliphatic amines could be fluorinated selectively at the

69 reactions that are able to construct complex aliphatic amines from simple, readily available feedstoc

70 ding was compatible with aromatic as well as aliphatic amines including tautomerizable N-heteroarenes

71 eactions of methylene C-H bonds in secondary aliphatic amines lead to the formation of trans-disubsti

72 e found that the aromatic ring of the phenyl aliphatic amines may form cation-pi interaction with the

73 ds for the chemoselective reaction of either aliphatic amines or anilines are also described, reveali

74 etero)arylation of amino acids and analogous aliphatic amines selectively at the remote delta-positio

75 diet (MedDiet) are rich in polyamines, small aliphatic amines with potential cardioprotective effects

76 a wide variety of triketones and aromatic or aliphatic amines, yielding only water as a by-product.

77 all-molecule catalyzed kinetic resolution of aliphatic amines.

78 dical oxidant NO(3)(*) in its reactions with aliphatic amino acids and di- and tripeptides, suggestin

79 y of cysteine derivatives in comparison with aliphatic amino acids.

80 yl ketone substrates while the corresponding aliphatic analogs remain elusive.

81 AMPY)(MA)(3)Pb(4)I(13) and the corresponding aliphatic analogue (3AMP)(MA)(3)Pb(4)I(13)-based ones.

82 Various heteroaryl and bicyclo-aliphatic analogues of zwitterionic biaryl P2Y(14) recep

83 allylations and crotylations of a variety of aliphatic and (hetero)aromatic aldehydes with differentl

84 Both aliphatic and aromatic anhydrides are formed on convenie

85 the organic matter consists of a mixture of aliphatic and aromatic compounds and functional groups s

86 carbohydrates, and some low-molecular-weight aliphatic and aromatic compounds) aggregate to form comp

87 es encode enzymes for anaerobic oxidation of aliphatic and aromatic compounds, including those of can

88 It was applied to a broad range of aliphatic and aromatic ester precursors and to the synth

89 Compared with Sp, Ms held more surface O-H, aliphatic and aromatic groups, while Sa had more phenoli

90 ed the ectopic deposition of suberin and its aliphatic and aromatic monomers.

91 atic aldehydes, as well as heterocoupling of aliphatic and aromatic ones.

92 ed into a material consisting of alternating aliphatic and aromatic segmented polymer strands, interw

93 was illustrated by synthesizing an array of aliphatic and aromatic substituted 2,3-dihydro-4 H-pyran

94 atalyzed protocol tolerates a broad range of aliphatic and aromatic substrates, offering an efficient

95 n of p-cresol-based N-phenylbenzoxazine with aliphatic and aromatic thiols was investigated in solven

96 Several primary and secondary aliphatic and aryl-substituted amines couple with a wide

97 lyzed gamma-C(sp(3) )-H functionalization of aliphatic and benzoheteroaryl aldehydes has been develop

98 enables the direct conversion of both strong aliphatic and benzylic C-H bonds into the corresponding

99 e present the controlled monochlorination of aliphatic and benzylic hydrocarbons with only 1 equiv of

100 Aliphatic and electron-deficient aromatic aldehydes affo

101 Aliphatic and electron-rich aromatic boronic esters prov

102 deforested catchments export relatively more aliphatic and heteroatomic DOM sourced from microbial bi

103 APPI is useful for uncovering low-intensity aliphatic and peptide-like components in autochthonous D

104 e the ring-opening hydroboration reaction of aliphatic and styrenic epoxides with pinacolborane (HBpi

105 g a large number of isomeric compounds, both aliphatics and cyclics.

106 catalytic systems are general for aromatic, aliphatic, and acetylenic aldehydes, giving high yields

107 h of the 19 standard amino acids, biothiols, aliphatic, and aromatic amines and amino alcohols.

108 nd to low bounds of pK(a) values of phenols, aliphatic, and aromatic carboxylic acids, and ketoacids.

109 Aryl, aliphatic, and unsubstituted allylic chlorides bearing a

110 ly observed a stabilizing role for interface aliphatics, and that interface aromatics physicochemical

111 ace in the case of the aromatic, but not the aliphatic, anion.

112 ompounds ionized by LDI can be classified as aliphatic, aromatic, and condensed aromatics in approxim

113 which a range of organotrisulfides covering aliphatic, aromatic, as well as cysteine and sugar group

114 changes on the enzyme-mediated hydrolysis of aliphatic-aromatic polyesters and will therefore have im

115 d responses to specific aldehydes, alcohols, aliphatics/aromatics, ketones, and amines through the SS

116 tion to afford N-heterocyclic products using aliphatic azide substrates.

117 enantioselective C(sp(3) )-H amination with aliphatic azides.

118 Thiol, hydroxyl, and aliphatic-based side chains at the i-1 position had high

119 roperties of several CNS-directed, uncharged aliphatic bis-oximes holding promise for use as protonat

120 Site-selective aliphatic C(sp(3))-H bond oxidation reactions serve as t

121 Activation of aliphatic C(sp(3))-H bonds in the presence of more activ

122 borylation of aromatic C(sp(2))-H bonds over aliphatic C(sp(3))-H bonds(4).

123 In addition, the aliphatic C-F bond is the preferred acceptor in the pres

124 An unprecedented intermolecular aliphatic C-F...H-C interaction was observed in the X-ra

125 Surprisingly, in P4H, a strong aliphatic C-H bond is activated, while thermodynamically

126 diates the thioetherification of unactivated aliphatic C-H bonds directed by resident silylperoxides.

127 n aminate a variety of benzylic, allylic and aliphatic C-H bonds in excellent enantioselectivity with

128 een unsaturated hydrocarbons and unactivated aliphatic C-H bonds via a metal-hydride pathway.

129 lenation of primary, secondary, and tertiary aliphatic C-H bonds was developed.

130 that catalyze the silylation of aromatic and aliphatic C-H bonds.

131 molecular functionalizations of unactivated, aliphatic C-H bonds.

132 f nitrogen-centered radicals in unactivated, aliphatic C-H chlorinations.

133 tivated, while thermodynamically much weaker aliphatic C-H groups, that is, at the C(3) and C(5) posi

134 y against oxidative damage of the ligand via aliphatic C-H oxidation.

135 rogress in the development of site-selective aliphatic C-H oxidations over the past decade, the abili

136 protection strategies known to enable remote aliphatic C-H oxidations.

137 in warmer transect regions accumulated less aliphatic-C (lipids, waxes) and retained more O-alkyl-C

138 zed amination is reported that occurs at the aliphatic C3-substituent of various quinolones and pyrid

139 achieved in the asymmetric hydrogenation of aliphatic carbocyclic and heterocyclic tetrasubstituted

140 n the selective, direct coupling of abundant aliphatic carbon-hydrogen bonds using hydrogen atom tran

141 nt in the selective oxidation of a series of aliphatic (carbon chain from C(1) to C(10) ) and aromati

142 ntermediates that can abstract hydrogen from aliphatic carbons (R-H).

143 t conformation of Lys73, with its side chain aliphatic carbons tracing along the edge of imidazole ri

144 Aliphatic carboxylic acids and sulfonamides could not be

145 the presence of two alpha-methyl groups; (2) aliphatic carboxylic acids containing alpha-hydrogens ar

146 direct decarboxylative functionalization of aliphatic carboxylic acids using N-xanthylamides.

147 Both aromatic and aliphatic carboxylic acids were converted to the corresp

148 n and decomposition routes for furanoids and aliphatic carboxylic acids, and mechanistic pathways for

149 n decarboxylate a wide range of aromatic and aliphatic carboxylic acids, have multiple reusability, a

150 Compared to the aliphatic cation of the same size (AMP = (aminomethyl)pi

151 ocol for the synthesis of (18)F-radiolabeled aliphatic CF3-containing compounds, enabling the prepara

152 e/absence of an internal double bond in each aliphatic chain (unsaturated and saturated compounds, re

153 his functionality in combination with a long aliphatic chain or a chain carrying an appropriate aroma

154 a chelating metal-binding group, and a long aliphatic chain that facilitates solvent-dependent self-

155 NDIs) symmetrically functionalized with long aliphatic chains (C(28) and C(33)) and their self-assemb

156 Inclusion of long aliphatic chains on these ligands allows the assemblies

157 aphyne has been envisaged by decoration with aliphatic chains R = n-CnH2n+1.

158 ys a dominant role in the arrangement of the aliphatic chains, as it exclusively favors interdigitati

159 ntrast to recent reports that suggest higher aliphatic composition of primary particles.

160 by permanganate to form nitrogen-containing aliphatic compounds and benzoic acid-containing compound

161 c carbon into soil carbohydrate, protein and aliphatic compounds and differentiate these from existin

162 e cobalt assay is applicable to aromatic and aliphatic compounds and yields strong CD signals at high

163 matics in approximately equal measure, while aliphatic compounds dominated the ESI spectra of SRFA.

164 Desaturation of aliphatic compounds generally proceeds through two conse

165 s indicated that they are mostly composed of aliphatic compounds.

166 llowed by secondary lignin-like and tertiary aliphatic compounds.

167 from carbon surfaces as compared to typical aliphatic compounds.

168 c matter was comprised of smaller and highly aliphatic compounds.

169 depending on the solvent nature-aromatic or aliphatic-cone-shaped C(3)-symmetric subphthalocyanine 1

170 bstrate scope using substituted aromatic and aliphatic derivatives.

171 efficients for the reaction of NO(3)(*) with aliphatic di- and tripeptides suggest that attack occurs

172 opane intermediate forms and serves as a 1,2-aliphatic dianion equivalent, inserting into the 1,2-die

173 rganic carbon and nitrogen (DOC and DON) and aliphatic DOM contribution for five decades.

174 xazole, aminoisothiazole, amino uracils, and aliphatic enamines has been developed in an aqueous medi

175 ted quinolines from anilines and aromatic or aliphatic epoxides.

176 -disrupting activity of CLR01 by introducing aliphatic ester arms into each phosphate group to act as

177 des and furans dominate in wort, whereas the aliphatic esters and alcohols predominate in the followi

178 numbers (TON) up to 10 000 are observed for aliphatic esters.

179 n and diversity of cyclic sesquiterpenes and aliphatic esters.

180 unexplored the specificity of esterases for aliphatic esters.

181 PP gene cluster and find that it installs an aliphatic ether cross-link at an unactivated carbon cent

182 Aliphatic ethers were oxidized by this method, as demons

183 e method provides access to a broad range of aliphatic fluorides, including primary, secondary, and t

184 es the relative lipophilicity modulations of aliphatic fluorination motifs.

185 r structures, relative distribution of ester aliphatics, free acid end-groups and free hydroxyl group

186 Here we report that in Arabidopsis, aliphatic GLS levels are regulated by the auxin-sensitiv

187 The cngc19 mutants are deficient in aliphatic glucosinolate accumulation and hyperaccumulate

188 CNGC19 modulates aliphatic glucosinolate biosynthesis in tandem with BRAN

189 phanin, and, despite an up-regulation of the aliphatic glucosinolate genes, no increase in alkenyl gl

190 rexpression of BoMYB29 gene up-regulates the aliphatic glucosinolate pathway in Brassica oleracea pla

191 vealed an unexpected association between the aliphatic glucosinolates (GLS) and the Gln-related trait

192 ferences, which account for the diversity of aliphatic glucosinolates across Brassica accessions.

193 Further analyses of the aliphatic glucosinolates also showed a positive correlat

194 side chain elongation of methionine-derived aliphatic glucosinolates is catalyzed by methylthioalkyl

195 his study aims at correlating the content of aliphatic glucosinolates to the expression of genes invo

196 vealed 20 mostly acylated anthocyanins, five aliphatic glucosinolates, and four indolic glucosinolate

197 cultivated Brassica species possess diverse aliphatic glucosinolates, which are important for plant

198 and the determinants of side chain length in aliphatic glucosinolates.

199 reactive, could be efficiently coupled with aliphatic Grignard reagents at room temperature in high

200 pecies and concurrent solution enrichment of aliphatic groups unassociated with carboxylic acids.

201 ving electron-withdrawing/electron-releasing/aliphatic groups under "metal-free" conditions.

202 Derived calibrations for total-GSLs, aliphatic-GSLs, glucoraphanin and 4-methoxyglucobrassici

203 Host-guest studies show that T1 binds small aliphatic guests, whereas T2 binds larger aromatic molec

204 fied pyrrolobenzodiazepines with a C8-linked aliphatic heterocycle provide a new class of broad-spect

205 We suggest a multi-component material (aliphatic hydrocarbon resin), including alkanes, fatty a

206 imide in the catalytic aerobic oxidations of aliphatic hydrocarbons characterized by relatively high

207 aldehydes, alcohols, ketones, aliphatic hydrocarbons, aromatics, mono-and sesquiterpen

208 spectra show the clear presence of saturated aliphatic hydrocarbons, esters, free carboxylic acids, a

209 tiple mechanisms to produce DOM that is more aliphatic in nature and contains novel high molecular we

210 lines with olefins (acrylates, styrenes, and aliphatic) is reported.

211 The acetate-initiated aliphatic isocyanate trimerization to isocyanurate was i

212 d, thereby linking it to nucleotide base and aliphatic isoprenoid modification.

213 y by stereoselective ketal formation with an aliphatic ketone.

214 (3))-rich N-heterospirocycles from feedstock aliphatic ketones and aldehydes with a broad selection o

215 ction of the picolinamide directing group in aliphatic ketones by using the ammonia-Ugi 4-CR reaction

216 llyl)boration of acetyl arenes/hetarenes and aliphatic ketones possible with high diastereoselectivit

217 ctive beta-C(sp(3) )-H arylation reaction of aliphatic ketones using a chiral TDG.

218 e site mutations to accept linear and cyclic aliphatic ketones with notable efficiency, regioselectiv

219 olefin ring-closing metathesis reactions for aliphatic ketones.

220 of the isolated carbonyl functional group of aliphatic ketones.

221 opants, THF-doping yielded spectra with more aliphatic-like and N-containing compounds than toluene-d

222 tones, carbenoid-free formal homologation of aliphatic linear ketones and deconstructive pyrazole syn

223 7) with non-, partially- and per-fluorinated aliphatic (linear or branched at the alpha-carbon) and a

224 binding pocket (EBP) of the receptor via an aliphatic linker of variable lengths.

225 ifunctional phosphonates employing different aliphatic linkers (C(6)H(12), C(8)H(16), C(10)H(20), C(1

226 d imidazole scaffold which are appended with aliphatic linkers that enable coupling to bioactive carr

227 inated compounds, with 28 novel experimental aliphatic log P values, are involved in discussing vario

228 Importantly, aliphatic long-chain fatty acids, including biomass-deri

229 e motif in the C2B domain and Ca(2+)-binding aliphatic loops on both C2A and C2B domains, are known.

230 m (Mg(2+))-mediated partial insertion of the aliphatic loops, alongside weak interactions with the an

231 al separation of benzene from gasoline using aliphatic MOF materials.

232 ogenation of electron-deficient and strained aliphatic molecules is rare.

233 The selective C-H functionalization of aliphatic molecules remains a challenge in organic synth

234 ylalanine, benzoic acid, heteroaromatic, and aliphatic monomers) with different electronic and steric

235 zation of highly functionalized aromatic and aliphatic monomers.

236 Aliphatic nitriles are used in industry as solvents and

237 A biocatalytic approach toward linear aliphatic nitriles being widely used as industrial bulk

238 rug-like", and this is particularly true for aliphatic nitro groups.

239 hich a CF(3) group successfully replaced the aliphatic NO(2).

240 Ph-O bond is cleaved rather than the weaker aliphatic O-R bond.

241 ctivated acrylates and styrenes; unactivated aliphatic olefins) demonstrates the robustness of the de

242 e molecular recognition of a wide variety of aliphatic or aromatic aldehydes and ketones, as demonstr

243 n a chemoselective manner in the presence of aliphatic or aromatic ketones.

244 hem from three harvests, associating data of aliphatic organic acids (AOA) determined by capillary el

245 This signature is characteristic of aliphatic organic matter and is mainly localized on a br

246 Aliphatic organochlorine exceeds aliphatic organobromine but is positively correlated wit

247 Aliphatic organochlorine exceeds aliphatic organobromine

248 mean hydrophobic moment of 0.50 and favoring aliphatic over aromatic hydrophobes in 18-aa windows of

249 elow the 2.0 eV energy limit, absent for the aliphatic PeBr; these additional anionic states for PhBr

250 h individual amino acid residue, which makes aliphatic peptide sequences highly vulnerable to NO(3)(*

251 the reaction of NO(3)(*) with side chains in aliphatic peptides.

252 Among sulfonic acid aliphatic PFAS, chemical potencies were correlated with

253 This principle allowed aliphatic photocoupling between redox-active carboxylate

254 Long-chain aliphatic polyamides could bridge the gap between tradit

255 d that HsvA displays a preference for linear aliphatic polyamines as the amidino acceptor substrate,

256 self-assembly of a new class of amphiphilic aliphatic polyesters are presented.

257 A similar series of aromatic-aliphatic polyesters based on diethyl-2,5-furandicarboxy

258 nalysis of the enzymatic hydrolysis of eight aliphatic polyesters by two fungal esterases (FsC and Rh

259 , has an enormous potential for biodegrading aliphatic polyesters thanks to a unique and abundantly s

260 to characterize the architecture of aromatic-aliphatic polyesters with varying degrees of branching.

261 previous thinking, we have established that aliphatic polyols do not require a threo pair of hydroxy

262 for the generation of new MOF materials with aliphatic pore environments and properties previously un

263 n developed, enabling efficient synthesis of aliphatic potassium acyltrifluoroborates (KATs) in high

264 Aliphatic primary amines are prevalent in natural produc

265 mines starting from linear or alpha-branched aliphatic primary amines or secondary amines.

266 ucturally diverse benzylic, heterocyclic and aliphatic primary, secondary and tertiary amines as well

267 only, we exploit (i) the narrow resonance of aliphatic protons in free substrate for selective radio-

268 ins with unactivated alkyl halides, yielding aliphatic quaternary carbons.

269 B-5 adopts a cubic architecture but features aliphatic, rather than aromatic, pore surfaces.

270 mation in solution from soluble aromatic and aliphatic reagents was not studied.

271 work bridges a gap in the cross-coupling of aliphatic redox-active esters with aryl zinc reagents.

272 tunnel is lined primarily by small polar and aliphatic residues essential for anion conductance.

273 lecular features are very different from the aliphatics-rich permafrost NOM.

274 rium labeling experiments suggested that the aliphatic secondary alcohols undergo oxidation reaction

275 nces with a sterically hindered alpha-chiral aliphatic side chain.

276 rs in cyclic iodonium salts substituted with aliphatic side chains in the carbon bridge.

277 studies are the first to point to simple C3 aliphatic side-chain modification of MTM as an effective

278 gyroid surface while semiperfluorinated and aliphatic side-chains fill their respective separate cha

279 tions enable the streamlined construction of aliphatic structures and have thus been the subject of i

280 This protocol accommodates both aromatic and aliphatic substituents and a broad range of functional g

281 ly electron-donating groups (31-73%); cyclic aliphatic substrates provide low yields (24-38%).

282 there are few examples involving unactivated aliphatic substrates.

283 Based on analysis of tertiary aliphatic sulfonamides published in the Cambridge crysta

284 A series of tertiary aliphatic sulfonamides was studied by crystallographic a

285 activation was therefore selected to access aliphatic sulfonamides, applying a single-step hydrosulf

286 To test whether aliphatic sulfonic acid PFAS cause the same toxicity phe

287 Aliphatic synthetic intermediates with high added value

288 ssing a halogen atom at a particular site in aliphatic systems is extremely limited.

289 position of the steroid ring (LKM38) or the aliphatic tail (KK174), we mapped a binding pocket in mV

290 We demonstrate that the aliphatic tail length (i) can be used as a handle to sys

291 e hydrophobic tunnel, which accommodates the aliphatic tale of LTA4 during EH reaction.

292 tem, the reaction of both acyclic and cyclic aliphatic tertiary amines led to the formation of 2- N,

293 nging mixture of structurally similar cyclic aliphatic (tetrahydrothiophene) and aromatic (thiophene)

294 phobic pocket that is selective for branched aliphatic thioalcohol ligands.

295 ives an unusual regioselectivity switch from aliphatic to aldehyde hydrogen atom abstraction upon deu

296 to ketones and aldehydes (both aromatic and aliphatic) to form 5-(1-hydroxyalkyl)tetrazoles in a hig

297 l method for the synthesis of functionalized aliphatic trifluoromethyl-substituted derivatives from a

298 the light oil comprised a range of high O/C aliphatic, unsaturated, and aromatic compounds.

299 Cuticular wax is a mixture of aliphatic very-long-chain molecules, ranging from 22 to

300 (including acids, carbonyls, aromatics, and aliphatics) were calculated to characterize the exhaust