ライフサイエンスコーパス: allyl

1 complex at the branched position of the pai-allyl.

2 t the reaction proceeds via a Rh(III)-eta(3)-allyl.

3 ctivity for the branched position of the pai-allyl.

4 o be the first reported examples of allyl-to-allyl 1,4-Rh(III) migration.

5 Alkenyl-to-allyl 1,4-rhodium(I) migration enables the generation of

6 ion of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.

7 m of these reactions involves the alkenyl-to-allyl 1,4-rhodium(III) migration.

8 arkers (chavibetol, chavibetol acetate and 4-allyl-1,2-phenylene diacetate).

9 4-carboxamide] and WEE1 inhibitor AZD1775 [2-allyl-1-(6-(2-hydroxypropan-2-yl)pyridin-2-yl)-6-((4-(4-

10 (-) pockets, the barbiturate photolabel R-5-allyl-1-methyl-5-(m-trifluoromethyl-diazirynylphenyl) ba

11 A variety of C3-allyl 1H-indazoles with quaternary stereocenters were ef

12 e optimized condition used AdBrettPhos/[PdCl(allyl)]2 as the catalyst system.

13 lylbenzene, 4-allylanisole, isoeugenol and 4-allyl-2,6-dimethoxyphenol against the S. aureus NorA eff

14 h norfloxacin against the SA 1199B strain, 4-allyl-2,6-dimethoxyphenol eugenol and isoeugenol caused

15 Similar effects were observed when 4-allyl-2,6-dimethoxyphenol, allylbenzene and isoeugenol w

16 monstrating favorable interactions between 4-allyl-2,6-dimetoxypheno and the NorA pump mediated by hy

17 for a number of substituted and unreactive N-allyl-2-furfurylamines under biomimetic conditions, with

18 ave been synthesized (R = H (1), Me (2), and allyl (3)), and their electrocatalytic properties were e

19 degrees C for simultaneous quantification of allyl, 3-butenyl, 4-(methylthio)butyl, benzyl and phenet

20 Recently, R-1-methyl-5-allyl-5-(m-trifluoromethyl-diazirinylphenyl) barbituric

21 omidate) and mephobarbital [[(3)H]1-methyl-5-allyl-5-(m-trifluoromethyl-diazirynylphenyl)barbituric a

22 ally, the Pd(II)-catalyzed arylation of an N-allyl-5-methylisoxazole-3-carboxamide afforded the E-cin

23 DME solvent at 60-70 degrees C, alpha-methyl allyl acetate 1a (100 mol%) reacts with primary (hetero)

24 onic esters when treated with stoichiometric allyl acetate and a palladium catalyst.

25 tioselective catalytic reductive coupling of allyl acetate with acetylenic ketones occurs in a chemos

26 -O-benzylidene-alpha-d-idopyranoside bearing allyl, acetyl, and tert-butyldiphenylsilyl (TBDPS) prote

27 enes, boryl and silyl substitutions, hydride-allyl additions to alkenyl boronates, and additions of b

28 cent yield, >98:2 diastereomeric ratio (for allyl additions) and 99:1 enantiomeric ratio.

29 mber of catalytic enantioselective conjugate allyl additions-related 1,6-additions and processes invo

30 are proposed to rationalize the Z-selective allyl additions.

31 ged heterocyclic product and gave only a bis-allyl adduct, while more substituted versions gave novel

32 aining, and cell viability after exposure to allyl alcohol and acetaminophen demonstrated the in vitr

33 compared to other CAPs, where both diol and allyl alcohol products compete with each other.

34 ted from insertion of palladium to O-H of an allyl alcohol, that is responsible for the C-O bond clea

35 trated using the example of the amination of allyl alcohol.

36 The approach employs allyl alcohols as an efficient alternative to preactivat

37 y coordinating carbonyl-directed coupling of allyl alcohols at the C-4 position of indole derivatives

38 ch to nonracemic beta,beta-diarylsubstituted allyl alcohols is described.

39 The obtained allyl alcohols were applied in the synthesis of nonracem

40 tive organometallic reagents includes alkyl, allyl, alkynyl, aryl, and heteroaryl compounds including

41 xible cross-metathesis approach for terminal allyl amide synthesis, and a late-stage Z,Z-selective Su

42 ification and haloesterification reaction of allyl amides is reported.

43 t examples of a catalytic isomerization of N-allyl amides to form nonpropenyl disubstituted, tri- and

44 for the isomerization of a broad range of N-allyl amides to form Z-di-, tri-, and tetrasubstituted e

45 d enantioselective vicinal dihalogenation of allyl amides.

46 like bilayer film of polyelectrolytes (Poly (allyl amine hydrochloride/poly(sodium 4-styrene sulfonat

47 hibiting specific chemical moieties, namely, allyl, amine, carboxylic acid, thiol, aldehyde, and cate

48 Various allyl-amine-type conduramines were synthesized in a dias

49 giodivergent Rh-catalyzed hydrothiolation of allyl amines and imines is presented.

50 A variety of useful alpha-allyl amino esters were prepared, including crotylated p

51 o- and diastereoselective synthesis of alpha-allyl amino esters.

52 rences in the conformational behavior of 3-O-allyl and 3-O-acetyl-alpha-d-idopyranoside derivatives c

53 equential 1,4- and 1,2-addition reactions of allyl and 3-substituted allylsilanes to indolizidine and

54 in the presence of a broad range of benzyl, allyl and alkyl halides.

55 icient catalytic methods for the addition of allyl and allenyl organoboron reagents to fluorine-subst

56 ubiquitous, resonantly stabilized radicals, allyl and benzyl radicals.

57 al allylic/benzylic C-H functionalization of allyl and benzyl silyl ethers was achieved using rhodium

58 ent of the number of nonbonding electrons in allyl and benzyl, are in fact calculated to be factors t

59 However, allyl and Cl ligands remain behind after electron irradi

60 process but remove only minor amounts of the allyl and Cl ligands.

61 y of dinuclear Pd(I) complexes with bridging allyl and related ligands.

62 ide range of electrophiles, including alkyl, allyl, and benzyl halides and carbonyl compounds, follow

63 sigmatropic rearrangement reactions of aryl allyl anilines, which deliver exclusively C-H functional

64 rategy toward the preparation of substituted allyl aryl ethers from benzoic acids via a dearomatizati

65 )-catalyzed intramolecular hydroarylation of allyl aryl ethers using an amide directing group for the

66 ction, providing a variety of functionalized allyl aryl ethers.

67 bsequent reductive elimination furnishes the allyl-aryl coupled product.

68 tive, and stereospecific palladium-catalyzed allyl-aryl coupling reaction.

69 s the barrier for benzyl lower than that for allyl, as Huckel theory predicts should be the case.

70 essfully applied to radical bicyclization of allyl azidoformates to construct aziridine/oxazolidinone

71 icient catalytic additions of easy-to-handle allyl-B(pin) (pin=pinacolato) compounds to ketones and a

72 l Cu-boryl intermediates can be converted to allyl-B(pin) rather than add to an alkene.

73 stereoregular copolymers by [(mesitylene)Ni(allyl)][BAr(F)4] (Ni-1).

74 tive Exponential Growth (IEG) wherein chiral allyl-based IEG oligomers are subjected to thiol-ene rea

75 a,alpha-disubstituted aldehyde enolates with allyl benzoate is described.

76 ed twofold unsymmetrical annulation of 3-O/N-allyl benzoic acid derivatives with isocyanates for the

77 Allyl, benzyl and phenethyl isothiocyanates were detecte

78 from a variety of alcohols containing alkyl, allyl, benzyl and propargyl C-H bonds.

79 ol successfully converts a variety of alkyl, allyl, benzyl, and heterobenzyl bromides into the corres

80 lective precipitation to separate lipophilic allyl-benzyl-capped silicon nanoparticles into monodispe

81 metric decarboxylative allylic alkylation of allyl beta-ketoesters.

82 ubstantially different mode of action to the allyl boronate congener.

83 ketimines in situ, which then react with a Z-allyl boronate.

84 mine to afford allylic hydroxyl allenes, and allyl boronates add to alkynyl imines to form 1,3-alkeny

85 introduced that allow access to a variety of allyl boronates and silanes that contain a difluoroalken

86 well as aryl substituted substrates, afford allyl boronates bearing a difluoroalkene moiety (up to 9

87 What is more, Z-trisubstituted allyl boronates may be used.

88 ially available aminophenol may be used, and allyl boronates, which may contain an alkyl-, a chloro-,

89 major route for both vinyl bromide (68%) and allyl bromide (53%).

90 tion of physisorbed vinyl bromide (ViBr) and allyl bromide (AllBr) on Cu(110) at 4.6 K was studied ex

91 romide salts via coupling of thioamides with allyl bromide derivatives is described.

92 computational studies of an alkylation with allyl bromide implicate a bis-diamine-chelated-monomer-b

93 thon, S(N)2 displacement of a functionalized allyl bromide, and ring closing metathesis to obtain the

94 vinyl ketones or Morita-Baylis-Hillmann-type allyl bromides as electrophiles.

95 ample sulfide, benzyl, benzyl carbamate, and allyl carbamate were well tolerated.

96 was demonstrated that the use of nonracemic allyl carbamates enables the synthesis of enantioenriche

97 nt and a ring-closing metathesis reaction of allyl carbamates is presented as a method for the prepar

98 As demonstrated, a rearrangement of (S,Z)-allyl carbamates provides (S)-teriary allylamines, where

99 rearrangement reactions of the corresponding allyl carbamates.

100 A general method for generation of allyl carbenium ions from propargyl silanes via a 1,2-si

101 using the long-established principles of oxy-allyl cation chemistry.

102 rapping (CNT) sequence, involving a reactive allyl cation intermediate.

103 deling process accesses synthetically useful allyl cation intermediates that conduct to valuable ally

104 tion step to form an enantiodiscriminant oxy-allyl cation prior to the stereodefining nucleophilic ad

105 e barriers to rotation of a CH2 group in the allyl cation, radical, and anion are 33, 14, and 21 kcal

106 aternary anomeric position substituted by an allyl chain ready for further functionalization.

107 rpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, te

108 novel role for this cocatalyst to recycle an allyl chloride byproduct generated in the course of the

109 a procedure using a dihydropyridine-derived allyl chloride for the synthesis of (-)-(S)-tert-butyl-3

110 allylic phosphates showed the importance of allyl chloride intermediates, which form either by the a

111 idazole-4,5-dicarboxylic acid functionalized Allyl chloride, and significant improvement of its perfo

112 tive addition to racemic seven-membered-ring allyl chlorides for the first time.

113 , a series of mechanistic studies on the [Pd(allyl)Cl]2/P(t)Bu3 catalyzed synthesis of imidazolinium

114 (=K[A']) with MgX(2) (X=Cl, Br) produces the allyl complex [K(2) MgA'(4) ] (1).

115 ange of interactions (e.g., electrophilic pi-allyl complex formation, Lewis acid activation, allenyli

116 he resting state of the catalyst is a Ni-pai-allyl complex, and the outer-sphere nucleophilic attack

117 The turnover frequency of classic Pd pi allyl complexes was compared to that of 1 to determine t

118 equilibrating mixture of isomeric copper(I) allyl complexes, from which Curtin-Hammett kinetics dete

119 be superior precursors for generation of pai-allyl complexes, which lead to trifluoromethylated produ

120 tions indicate that in isolation, an eta(3) -allyl configuration on Mg is energetically preferred ove

121 The strategy is based on a [3,3]-allyl cyanate sigmatropic rearrangement from enantioenri

122 The key step is allyl cyanate-to-isocyanate rearrangement.

123 h hydroformylation substrates vinyl acetate, allyl cyanide, 1-octene, and trans-1-phenyl-1,3-butadien

124 The unstrained S-allyl cysteine amino acid was site-specifically installe

125 ounds, such as alliin and N-gamma-glutamyl-S-allyl cysteine, could notably be detected in lower amoun

126 geometry of the double bond of the starting allyl derivative.

127 e second series, the study of C-6 versus C-7 allyl derivatives led to the best aromatase inhibitor 13

128 nd R-mTFD-MPAB (chirality; 5-propyl versus 5-allyl) determines selectivity for intra- versus intersub

129 c strain controlled retro-ene reaction of an allyl diazene, i.e., an allylic diazene rearrangement.

130 Using this strategy, a broad range of allyl diazoacetate substrates were efficiently cyclized

131 yl-gamma-lactone 1a has been contemplated as allyl electrophile donor for allylic arylation via pi-al

132 Herein, we report the use of allyl electrophiles in nickel-catalyzed conjunctive cros

133 tive union of readily available epoxides and allyl electrophiles is disclosed.

134 tions and is compatible with a wide range of allyl electrophiles.

135 th the exception of the alpha,alpha-dimethyl allyl ester, which required more forcing conditions and

136 own that [3,3]-sigmatropic rearrangements of allyl esters are useful for the construction of fluorine

137 asymmetric allylic alkylation of alpha-nitro allyl esters to afford acyclic tetrasubstituted nitroalk

138 zylic nitronates and sterically encumbered 2-allyl esters.

139 from the corresponding alpha-aryl-beta-keto allyl esters.

140 ive enolization of alpha,alpha-disubstituted allyl esters.

141 f the catalytic aerobic partial oxidation of allyl ether to its acrylate ester derivative.

142 namely a methacrylate type PCE (PCEM-P), an allyl ether type PCE (PCEA-P), and an isoprenyl ether ty

143 ses presented, almost complete conversion of allyl ether with near complete chemo-selectivity towards

144 s consisting of double bond isomerization of allyl ethers and amines and subsequent intramolecular re

145 s of the 1,3-dipolar cycloaddition of chiral allyl ethers and emphasizes a stabilizing hyperconjugati

146 Z-selective isomerizations are observed for allyl ethers under conditions that compare favorably to

147 cess is very attractive for the oxidation of allyl ethers.

148 ty is independent of the substituents on the allyl ethers; rate and computational data show that the

149 OMe)2 serve as the co-catalyst to accelerate allyl exchange and 1,3-borotropic shift processes.

150 Allyl fluorides have been shown to be superior precursor

151 Mechanistic studies indicate that Ni-allyl formation is irreversible and related to the natur

152 and stereospecific 1,3-transposition of the allyl fragment enabled by an aromatization-driven Cope r

153 ng isomeric bisphenol cores substituted with allyl functions.

154 sed on poly(ferrocenyldimethylsilane)-b-poly(allyl glycidyl ether) (PFS-b-PAGE) decorated with trieth

155 Meanwhile, the addition of an allyl group (C(3)H(5)) to ketones is among the most comm

156 up was the best substituent, followed by the allyl group and next by the hydroxyl group.

157 nd allows for the installation of the parent allyl group as well as a range of 2-substituted allylic

158 SAR study indicated that the allyl group could be replaced with other substituents, w

159 pathway, wherein the nucleophile attacks the allyl group externally.

160 lasticity of the amino acids surrounding the allyl group of the prenyl donor.

161 Introduction of a vinyl or allyl group to the epoxide produced the diene derivative

162 copper-catalyzed borylation/ortho-cyanation/allyl group transfer cascade was developed.

163 ditions of propargyl and 2-boryl-substituted allyl groups to acyclic dienoates with high selectivity.

164 quence for the formal two-carbon scission of allyl groups to carboxylic acids has been developed.

165 ctionalizable moieties, such as propargyl or allyl groups, into acyclic alpha,beta,gamma,delta-doubly

166 ree separate potential catabolic products of allyl-GSL or closely related compounds affect growth and

167 These GSLs include allyl-GSL, a defense metabolite that is one of the most

168 Oxygen substitution in the allyl halide is tolerated and the products can be functi

169 The method couples racemic allyl halide starting materials with sp(2)-hybridized bo

170 Heavier allyl halides constitute the major part of heavier multi

171 tion/allylation of alkynyl oxime ethers with allyl halides has been established.

172 tallation, and selective reactivity of the S-allyl handle towards tetrazines should be readily extend

173 ry unsaturated oleyl chain is oxidized to an allyl hydroperoxide, which surprisingly is immune to fur

174 nal amino-iodination of an in situ generated allyl imidate.

175 conjugate addition of the lithium anion of N-allyl imine (prepared from allylamine and benzophenone)

176 er to rotation is higher for benzyl than for allyl in the cations and in the anions.

177 putatively proceeds through a Cp*Ir(III)-pai-allyl intermediate and demonstrates exclusive regioselec

178 configurational fluxionality of the rhodium-allyl intermediate is exploited to develop a novel diast

179 for the C-O bond cleavage to generate the pi-allyl intermediate is proposed.

180 3/2 surface, oxidative addition to an eta(1)-allyl intermediate only occurs on the S = 1/2 surface.

181 e component assembly allows trapping of a pi-allyl intermediate, after the initial migratory insertio

182 s delivered to the branched position of a Rh-allyl intermediate.Reduction of allenes poses several ch

183 as governed by the asymmetric nature of pai-allyl intermediates.

184 ng the starting material via formation of an allyl iodide intermediate.

185 We quantify the rate of Cu-catalyzed allyl iodide isomerization and identify a series of cond

186 which the formation and racemization of the allyl iodide occurs.

187 and crystallographic characterization of an allyl-Ir(III) intermediate, followed by a subsequent oxi

188 possible reaction mechanism involving a pai-allyl iridium intermediate was proposed and supported by

189 at the more electrophilic carbon of the pai-allyl iridium intermediate.

190 ta(2)-Allylic alcohol)iridium(I) and (eta(3)-allyl)iridium(III) complexes were synthesized and charac

191 As demonstrated, the resultant allyl isocyanates can be directly trapped with various n

192 e cyclization and subsequent, stereospecific allyl-isomerization and C-C bond-forming reductive elimi

193 alenol (alpha-ZOL) on a solution model using allyl isothiocyanate (AITC) and also determines the bioa

194 Inhaled allyl isothiocyanate (AITC) evoked atropine-sensitive br

195 packaging based on the controlled release of Allyl isothiocyanate (AITC) from mustard seed was design

196 psulation and controlled release of volatile allyl isothiocyanate (AITC) molecules.

197 activated by electrophilic compounds such as allyl isothiocyanate (AITC) through covalent modificatio

198 ctive ingredients of these plants - menthol, allyl isothiocyanate (AITC), and capsaicin, respectively

199 The effect of allyl isothiocyanate (AITC), in combination with low tem

200 aicin, acid (hydrogen chloride, pH 3.5), and allyl isothiocyanate (AITC).

201 intravenous injection of the noxious stimuli allyl isothiocyanate (AITC).

202 h increasing doses of the chemical irritants allyl isothiocyanate (AITC; also known as mustard oil) o

203 ically activated by natural products such as allyl isothiocyanate (mustard oil), cinnamaldehyde (cinn

204 the nociceptive and inflammatory response to allyl isothiocyanate (the agonist of TRPA1) and reversed

205 hey responded to the electrophilic compounds allyl isothiocyanate and cinnamaldehyde as well as heat.

206 nd corresponding quenching when activated by allyl isothiocyanate or heat suggest lipid bilayer-indep

207 ely, activation of TRPA1 by the electrophile allyl isothiocyanate was abolished by glutathione, but w

208 d to capsaicin, menthol, and/or mustard oil (allyl isothiocyanate) at concentrations found in foods a

209 s capable of desensitizing TRPA1, and unlike allyl isothiocyanate, it failed to induce nocifensive be

210 Unlike the covalent agonist allyl isothiocyanate, which elicits channel desensitizat

211 oducing a significant potentiating effect on allyl isothiocyanate- and diclofenac-induced currents of

212 Here we show that AITC (allyl isothiocyanate; mustard oil) and menthol represent

213 The pungent component of mustard, allyl-isothiocyanate (AITC), activates the extreme cold

214 (AsFMO) was previously proposed to oxidize S-allyl-l-cysteine (SAC) to alliin, an allicin precursor.

215 Preincubation with S-allyl-l-cysteine and isoliquiritigenin increased MMP in

216 is an unprecedented coordination mode for an allyl ligand bound to Mg.

217 here dinuclear Pd(I) complexes with bridging allyl ligands have been detected in catalytic reactions,

218 ymer, in which the Mg is surrounded by three allyl ligands.

219 er with both bridging and terminal (eta(1) ) allyl ligands.

220 operating as a catalyst itself, via a eta(3)-allyl mechanism, or, after spin inversion to give R21 an

221 in which alkene isomerization occurs by the allyl mechanism.

222 We found that allyl mercaptan with NADPH was the preferred substrate-c

223 ve with l-cysteine, N-acetyl-l-cysteine, and allyl mercaptan.

224 generated on the gold surface modified with allyl mercaptane.

225 onomers, including vinyl methacrylate (VMA), allyl methacrylate (AMA), and N,N-diallyl acrylamide (DA

226 These reactions occur between allyl methyl carbonates and unstabilized copper(I) enola

227 human milk as well as in human urine, namely allyl methyl sulfide, allyl methyl sulfoxide and allyl m

228 l methyl sulfide, allyl methyl sulfoxide and allyl methyl sulfone.

229 in human urine, namely allyl methyl sulfide, allyl methyl sulfoxide and allyl methyl sulfone.

230 crocycles bearing dual directional (up/down) allyl moieties on their rims is reported.

231 ve 1,6-conjugate addition of multifunctional allyl moieties to easily accessible alpha,beta,gamma,del

232 boronates, and additions of boron-containing allyl moieties to N-H ketimines.

233 ncommon instance of conjugate addition of an allyl moiety and afford the desired products in up to 83

234 amolecular 7-endo attack of a silyl-tethered allyl moiety on a tertiary radical using photoredox cata

235 The allyl moiety provides not only the electrophile but also

236 ly coordinating directing group to allow the allyl moiety to bind and facilitate C(sp(3) )-C(sp(3) )

237 red in good to excellent yield by treating N-allyl, N-alkyl methanesulfonamides with n-BuLi, followed

238 Conjugate addition of either lithium (R)-N-allyl-N-(alpha-methylbenzyl)amide or lithium (R)-N-(but-

239 The use of challenging unsymmetrical N-allyl-N-methylglycine esters is also tolerated under the

240 -dehydrogenation of carbonyl compounds using allyl-nickel catalysis.

241 Ga(I)-catalyzed C-C bond formations between allyl or allenyl boronic esters and acetals, ketals, or

242 hly functionalized oxygen heterocycles using allyl or benzyl alcohols as alkylating agents is present

243 ar Pd(I) complexes are supported by bridging allyl or related ligands such as cyclopentadienyl or ind

244 rdingly, aryl, heteroaryl, alkynyl, alkenyl, allyl, or alkyl ketones that contain an alpha-stereogeni

245 Exclusive allyl over styrenyl product selectivity as well as E ste

246 s that relies on a neighbouring cationic pai-allyl palladium complex.

247 ctrophile donor for allylic arylation via pi-allyl palladium intermediate using 1.5 equiv of aryl bor

248 A putative pai-allyl palladium radical-polar crossover path is proposed

249 re we report a new class of initiators, (pai-allyl)palladium carboxylate dimers, which polymerize eth

250 a enediolates is reported through the use of allyl-palladium catalysis.

251 -dehydrogenation of amides is reported using allyl-palladium catalysis.

252 The telescoping of allyl-palladium catalyzed ketone dehydrogenation with or

253 s several limitations of previously reported allyl-palladium-catalyzed oxidation, and is further leve

254 and O-allylation of phenols via a common pi-allyl Pd complex.

255 Cationic pi-allyl Pd intermediates, derived from allylic ester carbo

256 for ketone alpha,beta-dehydrogenation using allyl-Pd catalysis, and a Pd-catalyzed protocol to conve

257 olving in situ generation of allenamide, pai-allyl-Pd complex formation, and decarboxylative allylic

258 esting state from the Pd(I) dimer into a pai-allyl-Pd(II) species.

259 terminal alkyl and aryl alkynes with simple allyl phosphates and 2-substituted allyl phosphates is d

260 th simple allyl phosphates and 2-substituted allyl phosphates is described.

261 ) acetates into the corresponding gamma-keto allyl phosphonates in 70-93% yields is described herein.

262 membered intermediates that contain pairs of allyl phosphonium/allenic enolate functionalities.

263 ) and of the OH groups with the aromatic and allyl pi-systems, as confirmed by FT-IR spectroscopy and

264 d 1.8kcal/mol compared to the most activated allyl position.

265 each of which may be formed from the same N-allyl precursor by stereodivergent alkene isomerization.

266 The allyl protecting group could be removed in good yield us

267 isopentenyl pyrophosphate (IPP) to dimethyl allyl pyrophosphate (DMAPP) and vice versa.

268 pproximately 3 kcal/mol less stable than the allyl radical, which was attributed to the inability to

269 on and hyperconjugation was shown to benefit allyl radicals to a greater degree than benzyl radicals,

270 to more efficient radical delocalization in allyl radicals.

271 fording linear products when monosubstituted allyl reagents are used.

272 isulfide and diallyl trisulfide can transfer allyl side chains to low molecular weight thiols.

273 ons afford a variety of delta-functionalized allyl silyl ethers with high diastereo- and enantioselec

274 ate the dynamic behavior of intermediated Cu-allyl species and account for various selectivity profil

275 ormation of a highly electrophilic eta(3) Pd-allyl species and greatly facilitates C-O formation.

276 at undergo diene insertion to generate Co-pi-allyl species.

277 Ring-opening polymerization (ROP) of an allyl-substituted caprolactone monomer was carried out u

278 eta-substituted ketones with monosubstituted allyl substrates, simply by using N-heterocyclic carbene

279 o first characterize the effect of thiol and allyl sulfide crosslink structures on degradation kineti

280 Allyl sulfide hydrogels are used to support the formatio

281 Here, an allyl sulfide photodegradable hydrogel is presented, ach

282 oncurrent thiol-ene-based polymerization and allyl sulfide-based addition-fragmentation chain transfe

283 Surprisingly, when an allyl-sulfide-containing azide monomer (AS-N(3) ) is use

284 Hydrogels crosslinked by allyl-sulfide-containing molecules are presented.

285 Allyl sulfides are bioactive phytochemicals found in gar

286 A variety of electron deficient allyl sulfone systems could be used as delta-carbon radi

287 azo sulfones and their ensuing reaction with allyl sulfones.

288 c amines based on Pd-catalyzed conversion of allyl surrogates readily obtained from cyclic vinyl carb

289 A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction a

290 the propyne derivatives containing either a allyl(tert-butyl)amine or a 1,2,3,6-tetrahydropyridine u

291 ronic nature, and conformational properties, allyl(tert-butyl)amine was found to be the best hydride

292 ewis pair was prepared by hydroboration of N-allyl-tetramethylpiperidine with Piers' borane [HB(C6F5)

293 Lewis acid organocatalysts: i.e., binaphthyl-allyl-tetrasulfone (BALT) and imidodiphosphorimidate (ID

294 An efficient synthesis of S-allyl thioimidate hydrobromide salts via coupling of thi

295 tulated to be the first reported examples of allyl-to-allyl 1,4-Rh(III) migration.

296 ation cycloaddition through a sequence of Pd-allyl transfer and ring closure.

297 yl monosulfide is inert with respect to this allyl transfer reaction.

298 omplexed boronic acid (DABO boronate) as the allyl transfer reagent and promotes conjugate addition o

299 losing metathesis (RCM) involving tyrosine(O-allyl) (Tyr(All)), but desallyl products limited the yie

300 y reactions with alkyl-, aryl-, heteroaryl-, allyl-, vinyl-, alkynyl-, or propargyl-metal reagents.