ライフサイエンスコーパス: allylic alcohol

1 ed Ti-alkyne complex and a pyrone-containing allylic alcohol.

2 lenoxide to effect a 1,3-transposition of an allylic alcohol.

3 in exclusive formation of a single tricyclic allylic alcohol.

4 ighly enantioselective dihydroxylation of an allylic alcohol.

5 hydroxylation at the primary C26 to form an allylic alcohol.

6 f a 1,1-dichloroalkene to a chiral secondary allylic alcohol.

7 ious alpha-branched aldehydes with different allylic alcohols.

8 rmolecular Heck-Matsuda arylation of acyclic allylic alcohols.

9 for alpha-nitro alkyl enoates or beta-nitro allylic alcohols.

10 on of quaternary stereocenters directly from allylic alcohols.

11 ows the direct coupling of readily available allylic alcohols.

12 hesis of (Z)-alpha,alpha,beta-trisubstituted allylic alcohols.

13 ehydes to produce racemic (Z)-trisubstituted allylic alcohols.

14 l Ru catalysts and enantiomerically enriched allylic alcohols.

15 tive allylation of hypophosphorous acid with allylic alcohols.

16 and other nucleophiles delivered (2Z)-2-iodo allylic alcohols.

17 nriched chiral allylic amines from prochiral allylic alcohols.

18 ved from (-)-MIB generates (Z)-disubstituted allylic alcohols.

19 ntioselectivities to generate trisubstituted allylic alcohols.

20 d by an enantioselective Rh isomerization of allylic alcohols.

21 nylzinc reagents to aldehydes to give chiral allylic alcohols.

22 nylzinc reagents to aldehydes to give chiral allylic alcohols.

23 c methyl groups were monooxygenated to yield allylic alcohols.

24 internal nucleophiles and electrophiles, and allylic alcohols.

25 an iron-catalyzed transfer hydrogenation of allylic alcohols.

26 ne of these privileged structural motifs are allylic alcohols.

27 ust and highly selective synthesis of chiral allylic alcohols.

28 various a-branched aldehydes with different allylic alcohols.

29 alladium-catalyzed isomerization reaction of allylic alcohols.

30 of tethered silanoxyiodination reactions of allylic alcohols.

31 on of variously substituted allenamides with allylic alcohols.

32 ma-disubstituted or beta,gamma-disubstituted allylic alcohols.

33 itrosobenzene to furnish nonracemic tertiary allylic alcohols.

34 -metathesis of alkyl acrylates and 2 degrees allylic alcohols.

35 electrophilic traps in the transposition of allylic alcohols.

36 The alcohol 9 was converted into the allylic alcohol 12 and then to the ester 14.

37 as not affected by Ph(3)PCl(2) conversion of allylic alcohols 13-16 into corresponding chlorides 17-2

38 tion of the enantioenriched ketone 8 to form allylic alcohol 14 was achieved by a Stille palladium-ca

39 have been completed, starting from the known allylic alcohol (+)-14, which can be prepared in large q

40 -nitrobenzoic acid, allyl acetate couples to allylic alcohols 1a-c, aliphatic alcohols 1d-l, and benz

41 ndrost-15-en-17-one 3, via the corresponding allylic alcohol 2.

42 zed asymmetric allylic amination of unmasked allylic alcohols (27 examples, up to 99% ee).

43 ylic and aliphatic alcohols 1a-1l to furnish allylic alcohols 2a-2l, constituting a direct C-H vinyla

44 couple efficiently to aldehyde 4b to provide allylic alcohols 2m-2o as single regioisomers.

45 bstrate afforded, in addition to the acyclic allylic alcohols (2Z,6E)-farnesol (6.7%) and nerolidol (

46 of the product 9 of the rearrangement of the allylic alcohol 3 under very mild conditions, probably p

47 beta-elimination of acetate from resin-bound allylic alcohol 3, underwent regioselective 1,3-dipolar

48 tive oxidation of 2-methyl-2-butene into the allylic alcohol, 3-methyl-2-buten-1-ol, at 90% selectivi

49 a-2m and 2-butyne 1a are converted to chiral allylic alcohols 3a-3m with excellent levels of absolute

50 tions of alkyne 9 and aldehyde 10, affording allylic alcohols 42 or 11-epi-42 in a 3:1 ratio (or 1:3

51 of 15-acetates of the pure diastereoisomeric allylic alcohols 4a and 4b with PBr(3) occurred with sig

52 ate followed by acetylation of the resulting allylic alcohols (4a-b) and S(N)2'-type amination of the

53 e hydroxyl-directed epoxidation of tricyclic allylic alcohol 57 followed by regioselective reductive

54 ved by differential elaboration of tricyclic allylic alcohol 57.

55 desilylation with allylic transposition, the allylic alcohol 6g via protodesilylation with allylic tr

56 ogue 6, and the subsequent conversion of the allylic alcohol 7 to the chloride 8 via Ph(3)PCl(2) foll

57 elective Sharpless asymmetric epoxidation of allylic alcohol 81 (98% yield); intramolecular acetylide

58 nt intramolecular coupling to deliver cyclic allylic alcohol 8a.

59 CBS reduction to generate an enantioenriched allylic alcohol (97% ee), followed by an orthoester John

60 nd of oxidation to convert oleate to a trans allylic alcohol acid.

61 nyl intermediates undergo ene reactions with allylic alcohols, affording regioisomeric adducts in fai

62 It begins with a coupling reaction involving allylic alcohol, aldehyde, and LiHMDS to produce stereod

63 roach for the transformation of benzylic and allylic alcohols, aldehydes, and ketones into boronic es

64 t contain a carboxylic acid, an aldehyde, an allylic alcohol, an aryl olefin, an alpha substituent, o

65 ative allylation", the coupling partners, an allylic alcohol and a ketone pronucleophile, undergo in

66 Specifically, CM of allylic alcohol and enone components provides gamma-hydr

67 Next, we have shown that this mixture of allylic alcohol and I(2) could be beneficial for the iod

68 e light-mediated photoredox reaction from an allylic alcohol and iodoacetic acid.

69 The switchable roles of allylic alcohol and molecular iodine as reagents and cat

70 Both isomerization of allylic alcohol and oxidation of methanol occurred throu

71 nism of neocannabinoid synthesis from cyclic allylic alcohol and substituted resorcinol reaction part

72 atalyzed isomerization of highly substituted allylic alcohols and alkenyl alcohols by means of a sing

73 -catalyzed strategy for the isomerization of allylic alcohols and allylic ethers has been developed.

74 irect metal-catalyzed [1,3]-transposition of allylic alcohols and allylic silyl ethers is a synthetic

75 The oxidation of a range of cyclic allylic alcohols and amides with OsO4/TMEDA is presented

76 s to deliver a range of synthetically useful allylic alcohols and amines in high enantiopurity.

77 anes, or ureas (derived from isocyanates and allylic alcohols and amines) as substrates.

78 alculations on the acidities of a variety of allylic alcohols and carboxylic acids support the specia

79 formation of Ru(IV) allyl intermediates from allylic alcohols and chain growth by selective nucleophi

80 hothiolate complex and afford trisubstituted allylic alcohols and ethers in up to 81% yield and >98%

81 y promoted allylic substitution reactions of allylic alcohols and ethers with diethylphosphorothioic

82 gy relies on direct use of branched, racemic allylic alcohols and furnishes a diverse and unique set

83 e also described leading to the synthesis of allylic alcohols and gamma-lactones.

84 yze the concomitant isomerization of primary allylic alcohols and homoallylboronates into (chiral) al

85 he direct reaction between branched, racemic allylic alcohols and potassium alkenyltrifluoroborates p

86 on of this one-step protocol between various allylic alcohols and resorcinol derivatives are discusse

87 loped regioselective [1,3]-transpositions of allylic alcohols and silyl ethers and their applications

88 zed cross-coupling between branched, racemic allylic alcohols and simple olefins is described.

89 l variations have been performed on both the allylic alcohols and the homoallylboronates.

90 provides a streamlined process for accessing allylic alcohols and their derivatives; however, it repr

91 strate-controlled epoxidation of the C12-C13 allylic alcohol, and (iii) a late-stage Julia-Kocienski

92 ls the facial selectivity of addition to the allylic alcohol, and a subsequent anti-selective beta-hy

93 ved by hydroxyl directed hydrogenation of an allylic alcohol, and the A-ring of the natural product w

94 A broad scope of phenols, various allylic alcohols, and an alkyl hydroperoxide are viable

95 The allylboronates may be oxidized to the allylic alcohols, and can be used in stereoselective ald

96 yrenes, secondary allylic alcohols, tertiary allylic alcohols, and olefins with alpha-quaternary cent

97 ve transformations with an alpha-substituted allylic alcohol are shown to afford congested Z alkenes

98 Allylic alcohols are a privileged motif in polyketide-ba

99 Aryl allylic alcohols are converted to halogenated unsaturate

100 substrates are employed, (Z)-trisubstituted allylic alcohols are isolated with high dr (>20:1 in man

101 of thiophiles, the sulfenate is trapped, and allylic alcohols are obtained under mild conditions.

102 Allylic alcohols are shown to be highly reactive olefin

103 hen HFIP is employed as solvent and aromatic allylic alcohols are the substrates.

104 The resulting allylic alcohols are then transformed into the correspon

105 (Z)-trisubstituted allylic alcohols are widespread structural motifs in nat

106 Stille cross-coupling leads to a nonracemic allylic alcohol as a prerequisite for the introduction o

107 erived from Katsuki-Sharpless epoxidation of allylic alcohols as initiating groups for cationic cycli

108 -propanol (HFIP), polyene cyclizations using allylic alcohols as initiators gave the desired cyclized

109 for C-H allylation of aryl oxazolines using allylic alcohols as the coupling partner.

110 asymmetric cyclopropanation of (E)- and (Z)-allylic alcohols as the key step.

111 lization, owing to the utility of enones and allylic alcohols as versatile intermediates, and their p

112 nnamyl alcohols (benzylic C-H amination) and allylic alcohols (aziridination) using ion-paired Rh (II

113 regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been dev

114 Thus, enantioenriched tertiary allylic alcohols bearing a variety of functional groups

115 Allylic alcohols bearing a Z-iodoalkenyl tether can be s

116 even tertiary alkylboronic esters, providing allylic alcohols bearing almost any alkyl group availabl

117 precise construction of all stereoisomers of allylic alcohols bearing analogous substituents and the

118 e involves a desilylation of a TBS-protected allylic alcohol, borylation, and addition of an allyl gr

119 a novel, formal oxyalkylation reaction of an allylic alcohol by [3 + 2] cycloaddition; a tandem lacto

120 stic studies indicate that the activation of allylic alcohol by molecular iodine took place probably

121 d which was readily converted to the derived allylic alcohol by oxidative workup.

122 itized cycloaddition of alkenylboronates and allylic alcohols by a temporary coordination is presente

123 Asymmetric V-catalyzed epoxidation of allylic alcohols can be carried out in water with chiral

124 Allylic alcohols can be directly ionized in the presence

125 thyl and alpha-cyclohexyl (Z)-trisubstituted allylic alcohols can now be synthesized with excellent l

126 lar coupling of ortho-(alkynyl)styrenes with allylic alcohols catalyzed by PdCl(2).

127 shed that the isomerization of epoxides into allylic alcohols catalyzed by supported Au nanoparticles

128 ion of readily available starting materials (allylic alcohols, chlorophosphites, and organic azides),

129 Overman rearrangement of the resulting allylic alcohols, concurrent alkene hydrogenation and tr

130 utyl hydroperoxide and tin(IV) chloride upon allylic alcohols containing a lactam ring leads mainly t

131 terminal alkynes and allyl vinyl ethers into allylic alcohols containing up to three contiguous asymm

132 s were found in which secondary and tertiary allylic alcohols could be formed with high levels of ena

133 1,2-disubstituted alkenes, including simple allylic alcohols, deliver syn-dichlorides with exquisite

134 reducing reagent gave a very functionalized allylic alcohol derivative in 86% yield.

135 hydes and allenes, providing silyl-protected allylic alcohol derivatives possessing a terminal methyl

136 Using this method, a number of allylic alcohol derivatives were efficiently obtained wi

137 ium-catalyzed allylic alkylation of tertiary allylic alcohol derivatives with a cyanohydrin pronucleo

138 ing groups have been limited to reactions of allylic alcohol derivatives with Grignard reagents.

139 The development of an enantioselective allylic alcohol dichlorination catalyzed by dimeric cinc

140 A variety of allylic alcohols, each consisting of a 1:1:1:1 mixture o

141 antioselective bromochlorination reaction of allylic alcohols, employing readily available halogen so

142 r delta-chiral amines from readily available allylic alcohols, esters and ethers using a reductive re

143 free preparation of carbon-carbon bonds from allylic alcohols/ethers and Grignard reagents is describ

144 ective Markovnikov addition of carbamates to allylic alcohols for the construction of alpha-tertiary

145 This included the coupling of allylic alcohols for the first time in a Pd-catalyzed co

146 oss-coupling reactions of acyclic and cyclic allylic alcohols for the stereoselective introduction of

147 ed formal anti-Markovnikov hydroamination of allylic alcohols for the synthesis of chiral gamma-amino

148 For instance, (E)- and (Z)-allylic alcohols furnish the corresponding aldehydes wit

149 ogical precursor, redox isomerization of the allylic alcohol gave an epimeric mixture of aldehydes, w

150 g-chain fatty acid alkene that also bears an allylic alcohol group.

151 The asymmetric hydroalkylation of racemic allylic alcohols has been developed for the synthesis of

152 isomerization-methylenation of a variety of allylic alcohols has been established for the first time

153 Although [1,3]-transposition of allylic alcohols has been known since the late 1960s, th

154 a(3)-allyl)palladium complexes directly from allylic alcohols has been studied.

155 eOSiPh(3), 1) catalyzed 1,3-isomerization of allylic alcohols has been thoroughly explored.

156 ective coupling reactions between imines and allylic alcohols have been developed.

157 strate classes, including 4-pentenoic acids, allylic alcohols, homoallyl amines, and bis-homoallylami

158 imidazoheterocycles employing the mixture of allylic alcohol-I(2).

159 selective synthetic methods: (1) Ti-mediated allylic alcohol-imine reductive cross-coupling and (2) i

160 ent the first application of a TBS-protected allylic alcohol in a palladium-catalyzed borylation/ally

161 the allylation of imidazoheterocycles using allylic alcohol in an aqueous medium.

162 e direct allylic substitution reaction using allylic alcohols in 1,1,1,3,3,3-hexafluoroisopropanol (H

163 orkup allows isolation of B(pin)-substituted allylic alcohols in 70-95% yield.

164 reactions to provide densely functionalized allylic alcohols in good to excellent yields.

165 e a range of optically active functionalized allylic alcohols in good yields and high ee's.

166 Direct activation of allylic alcohols in the presence of transition metal cat

167 formation unravels the unusual reactivity of allylic alcohols in the synthesis of 4-methyleneisochrom

168 ation of Rh(III), and, collectively with the allylic alcohol, in directing cyclopropanation to contro

169 ne 2 gives primarily cyclopentanone and some allylic alcohol, in similar amounts as the known cyclohe

170 sformations that directly generate acyclic Z allylic alcohols, including products that contain a hind

171 zed diastereoselective [2+1] annulation onto allylic alcohols initiated by alkenyl C-H activation of

172 the route's initial steps to reach a common allylic alcohol intermediate employs a highly stereosele

173 Conversion of the product allylic alcohol into the allylic phosphate affords excel

174 s described for the isomerization of acyclic allylic alcohols into B-functionalized ketones via 1,3-a

175 complexes can catalyze the isomerization of allylic alcohols into saturated carbonyl derivatives und

176 wo-step synthesis of carbonyl compounds from allylic alcohols involving an oxidation-reduction sequen

177 (eta(2)-Allylic alcohol)iridium(I) and (eta(3)-allyl)iridium(III

178 The starting allylic alcohol is converted to its trichloroacetimidate

179 dy the rearrangement finding that a terminal allylic alcohol is determinant to achieve complete regio

180 This allylic alcohol is then utilized in a Claisen rearrangem

181 molecular hydrofunctionalization of tertiary allylic alcohols is described.

182 ic enantioselective dichlorination of simple allylic alcohols is described.

183 mino aldehydes from allylic amines or linear allylic alcohols is described.

184 Under these conditions, deoxyfluorination of allylic alcohols is effected with high chemoselectivity

185 aration of enantioenriched (Z)-disubstituted allylic alcohols is introduced.

186 ective Ir-catalyzed isomerization of primary allylic alcohols is reported.

187 stereochemical information contained in the allylic alcohols is transferred to the ketone products.

188 sfer process in concert with a base-promoted allylic alcohol isomerization.

189 oprene to 1-nonanol, 65% isolated yield) and allylic alcohols (isoprene to geraniol, 75% isolated yie

190 Not unexpectedly, applying the method to allylic alcohols leads to fragmentation rather than a di

191 -hydroxy esters bearing both propargylic and allylic alcohol moieties were obtained from beta-formyla

192 rtant role in preferential engagement of the allylic alcohol motif and provides a new basis for selec

193 was also achieved by utilizing the unreacted allylic alcohol obtained during the Sharpless kinetic re

194 These reactions provide either allylic alcohol or homoallylic alcohol derivatives selec

195 lylboronate can be oxidized to stereodefined allylic alcohols or can be used in stereoselective carbo

196 kylation products derived from 2-substituted allylic alcohols or their corresponding iodides can then

197 with hydrogen peroxide to provide secondary allylic alcohols or with nitrosobenzene to furnish nonra

198 basis for the increased facility with which allylic alcohols participate in olefin metathesis proces

199 A range of allylic alcohols participates in the diastereoselective

200 ar to that obtained from 3, yields primarily allylic alcohol rather than ketone; neither ring size no

201 The B(pin)-substituted allylic alcohols react with NBS to afford (E)-alpha,beta

202 s enable the synthesis of either (Z)- or (E)-allylic alcohols regarding the order of introducing coup

203 molecular strategy can overcome the inherent allylic alcohol selectivity of the free catalyst, achiev

204 By this system the formation of the allylic alcohol side product and the racemization of the

205 3]-rearrangements, the stereochemistry in an allylic alcohol starting material is transferred with fi

206 of the products is a complex function of the allylic alcohol structure and is consistent with a mecha

207 The effects of allylic alcohol structure, type of vinylating agent, and

208 n-coupled electron transfer activation of an allylic alcohol substrate affords an alkoxy radical inte

209 fer (PCET) activation of the O-H bond in the allylic alcohol substrate, followed by C-C B-scission of

210 rearrangement was observed with a secondary allylic alcohol substrate.

211 A variety of allylic alcohol substrates bearing alkyl and acyl migrat

212 for a wide variety of secondary and tertiary allylic alcohol substrates bearing aryl, alkyl, and cyan

213 The racemic allylic alcohol substrates can be converted to the enant

214 al beta-alkynyl carbonyl compounds employing allylic alcohol substrates in contrast to more tradition

215 reodivergent S(N)2 and S(N)1 cyclizations of allylic alcohol substrates.

216 e enzymes catalyze the oxidation of aromatic allylic alcohols, such as coumaryl, sinapyl, and conifer

217 his is a reliable and predictable method for allylic alcohol synthesis.

218 tuted and functionalized styrenes, secondary allylic alcohols, tertiary allylic alcohols, and olefins

219 d catalytic vinylation of aldehydes leads to allylic alcohols that are then transformed to the allyli

220 ped a convergent method for the synthesis of allylic alcohols that involves a reductive coupling of t

221 noallylation step of amines with substituted allylic alcohols that proceeds to yield the monoallylate

222 ized by anti-dichlorination of the precursor allylic alcohols; their stereochemistry was elucidated b

223 ld be converted to enantiomerically enriched allylic alcohols through a catalyst-controlled asymmetri

224 x migration strategy to access stereodefined allylic alcohols through vinylic C-H activation with ald

225 nce of CuCN, and conversion of the resultant allylic alcohol to the acetate affords good syn:anti pro

226 actions is the temporary coordination of the allylic alcohol to the Bpin unit.

227 nslate the stereochemical information of the allylic alcohol to the homoallylic amine or to control d

228 stereoselective method for the conversion of allylic alcohols to (Z)-trisubstituted alkenes is presen

229 enantioselective isomerization of secondary allylic alcohols to access ketones with a alpha-tertiary

230 nted that catalytically oxidize benzylic and allylic alcohols to aldehydes with O2 under mild conditi

231 ve catalyst for asymmetric isomerizations of allylic alcohols to aldehydes, furnishing improved yield

232 ion between beta-iodoenamide derivatives and allylic alcohols to generate beta-allyloxyenamide deriva

233 A ferrocenium boronic acid salt activates allylic alcohols to generate transient carbocations that

234 olecular coupling of oxygen nucleophiles and allylic alcohols to give beta-aryloxycarbonyl compounds

235 cess, the catalysis allows racemic secondary allylic alcohols to react with various amines, affording

236 lly challenging substrate class of protected allylic alcohols to the corresponding acyloin products.

237 c investigation reveals the isomerization of allylic alcohols to the corresponding ketone, which ulti

238 e carboxylic acid and the sensitivity of the allylic alcohol toward elimination.

239 L/D280K) that converts stearoyl-ACP into the allylic alcohol trans-isomer (E)-10-18:1-9-OH via a cis

240 The sequence of allylic alcohol transposition, carbonyl group trapping,

241 idge as well as a challenging late-stage 1,3-allylic alcohol transposition.

242 Importantly, primary benzylic and allylic alcohols-typically a challenging class of alcoho

243 An enantioselective fluorination of allylic alcohols under chiral anion phase-transfer condi

244 ere, we report that carbamate-functionalized allylic alcohols undergo highly enantioselective aziridi

245 A diverse range of allylic alcohols undergo transfer hydrogenation to form

246 Allylic alcohols undergo transposition reactions in the

247 Primary and secondary allylic alcohols underwent a regioselective Mitsunobu re

248 was used to provide the C(2)(-)C(3)(-)C(12) allylic alcohol unit characteristic of the lycorine alka

249 transfer from a delta-hydroxyl group in the allylic alcohol unit.

250 The synthesis of beta-unsubstituted, anti-allylic alcohols using a catalytic Evans aldol reaction

251 nantioselective dehydrative lactonization of allylic alcohols using a novel Pd(II) -catalyst containi

252 onvergent 1,3-rearrangement/hydrogenation of allylic alcohols using an Ir-N,P catalyst.

253 al phosphoric acid catalyzed fluorination of allylic alcohols using aryl boronic acids as transient d

254 technology for arriving at valued nonracemic allylic alcohols using asymmetric ligand-accelerated cat

255 ctive arylative semipinacol rearrangement of allylic alcohols using diaryliodonium salts is reported.

256 the Simmons-Smith fluorocyclopropanation of allylic alcohols using difluoroiodomethane and ethylzinc

257 eadily available ketone pronucleophiles with allylic alcohols using facile retro-Claisen cleavage to

258 Directed reduction of the chiral allylic alcohols using Red-Al gives exclusively the 1,2-

259 hed products furnishes secondary or tertiary allylic alcohols, valuable small molecules that cannot b

260 hyl-2-butene oxide affords the corresponding allylic alcohol via a monosolvated monomer in THF and a

261 imary C26 of the isoprenoid side chain to an allylic alcohol via a phosphorylated intermediate in a f

262 e a valuable alternative to the synthesis of allylic alcohols via 1,2-metallate rearrangement.

263 ralins from readily available alkyne-derived allylic alcohols via consecutive multibond-forming tande

264 selective synthesis of functionalized cyclic allylic alcohols via dynamic kinetic resolution has been

265 ne-3(2H)-furanones from skipped diynones and allylic alcohols via nucleophilic addition/Claisen rearr

266 ydes can be obtained directly from protected allylic alcohols via palladium-catalyzed autotandem reac

267 dium-mediated deoxygenation of the resulting allylic alcohol was followed by adjustment of protecting

268 productive CM coupling, the sphingosine head allylic alcohol was protected with a cyclic carbonate mo

269 thesis of allylic silanes and boronates from allylic alcohols was investigated.

270 By using this aqueous protocol, a range of allylic alcohols were epoxidized with up to 94% ee.

271 In this fashion, (Z)-disubstituted allylic alcohols were obtained with up to 98% ee.

272 It was found that the resulting allylic alcohols were racemic, most likely due to a rapi

273 The obtained allylic alcohols were transformed into conjugated alkeny

274 e from the substrate in the isomerization of allylic alcohols, whereas it disengages during the isome

275 or redundant chirality at the alpha-position allylic alcohol, while simultaneously producing a termin

276 cross-metathesis to unite a sphingosine head allylic alcohol with a long-chain fatty acid alkene that

277 Cross-coupling of an allylic alcohol with a vinylsilane or styrene derivative

278 -disubstituted furan directly; (ii) CM of an allylic alcohol with an enone to provide an isolated gam

279 ion of dieneoxide ester (E)-7 to the 1 alpha-allylic alcohol with an exocyclic double bond (E)-8.

280 reduction of a prochiral enone to afford an allylic alcohol with high enantioselectivity.

281 are generated from the reaction of a second allylic alcohol with high selectivity in moderate to goo

282 identified several that deliver the desired allylic alcohol with nearly perfect facial selectivity a

283 metallacycle-mediated union of the resulting allylic alcohol with preformed trimethylsilane-imines (g

284 Arylations of enals generated allylic alcohols with 81-90% ee.

285 lection in the coupling reactions of achiral allylic alcohols with chiral imines.

286 atalyzed direct dehydrative coupling between allylic alcohols with electron-deficient amines has been

287 ct iridium-catalyzed substitution of racemic allylic alcohols with enamines generated in situ.

288 o catalyze the formation of 10 different (E)-allylic alcohols with enantioselectivities ranging from

289 o catalyze the formation of 15 different (E)-allylic alcohols with enantioselectivities that ranged f

290 The new method affords allylic alcohols with excellent regioselectivity (anti-M

291 and were found to provide the desired chiral allylic alcohols with good regioselectivity and ee in ma

292 Treatment of crude gamma,gamma-disubstituted allylic alcohols with NaOH, followed by acidification, a

293 Geometrically defined allylic alcohols with SE, SZ, RE and RZ stereoisomers se

294 o the reactions of the analogous carbocyclic allylic alcohols with tert-butyl hydroperoxide-VO(acac)2

295 n allylic substitutions of branched, racemic allylic alcohols with various nucleophiles.