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1 oped for the synthesis of highly substituted allylsilanes.
2 used to access densely functionalized chiral allylsilanes.
3 hat normally observed with alkyl-substituted allylsilanes.
4                         Attaching a modified allylsilane 29a-c to C(2)OH of methyl mannoside 15 impro
5 Si(tBuN)]}2) precatalysts in the presence of allylsilane, 3-butenylsilane, 5-hexenylsilane, and 7-oct
6 It was then possible to convert acetal 28 to allylsilane 32 followed by cyclization to the alkaloid t
7 allylic transposition yielding the exocyclic allylsilane 3a with excellent diastereoselectivity.
8 lective Mukaiyama-type [3 + 2]-annulation of allylsilane 5 with the unsaturated aldehyde 9a to assemb
9 h other important organic molecules, such as allylsilanes, activated arenes, and indoles, leading to
10 done reduction followed by a stereoselective allylsilane addition to a N-sulfonyliminium ion.
11                                              Allylsilanes afforded tetrahydropyrans in 34-67% yields,
12 nship between Mn and [alkenylsilane](-1) for allylsilane and 3-butenylsilane, and a superlinear relat
13 including heteroaromatic/aromatic compounds, allylsilane and alkynylsilane.
14  annulation reaction between a C1-C8 hydroxy allylsilane and an aldehyde comprising C9-C13.
15  This pyran was transformed to a new hydroxy allylsilane and then coupled with a preformed C ring ald
16    The Prins cyclization of syn-beta-hydroxy allylsilanes and aldehydes gives cis-2,6-disubstituted 4
17 eta-(triethylsilyloxy)aldehydes with several allylsilanes and crotyldimethylphenylsilane is described
18 ions of cyclization reactions between chiral allylsilanes and N-acyliminium ions, it was discovered t
19 c substitutions of 3 with Grignard reagents, allylsilane, and triethyl phosphite gave N,N'-disubstitu
20                    Arylated alkenes, dienes, allylsilanes, and enynes are accessed using this procedu
21 luated and enhanced utilizing diastereomeric allylsilanes anti-5 and syn-5 to establish an efficient
22 er N-heterocyclic carbene (NHC) ligands, and allylsilanes are produced via palladium catalysis with s
23                   When the anti-beta-hydroxy allylsilanes are used, the Prins cyclization gives predo
24 ionalized compounds such as the alpha-ureido allylsilanes as well as carbamate derivatives.
25 reoselective fluoride-initiated additions of allylsilanes (aza-Sakurai reaction).
26 hesis, which opens a new entry into valuable allylsilane building blocks.
27 pyrans as mixtures of two diastereomers with allylsilane, but only a single diastereomer was observed
28 nolide K (1) based on asymmetric addition of allylsilane C1-C8 to enal C9-C22 is reported.
29              The divergent reactivity of the allylsilanes can be controlled to afford a range of nove
30                                              Allylsilanes can be regioselectively transformed into th
31 a suitably positioned benzyloxy group on the allylsilane component caused a reversal in the diastereo
32 osomi-Sakurai coupling of complex acetal and allylsilane coupling partners, followed by DDQ-promoted
33 fficient asymmetric synthesis of alpha-amino allylsilane derivatives is reported.
34 g., higher reaction temperature), opening of allylsilane-derived epoxides with this reagent occurs at
35 ith silyl enol ethers, silyl ketene acetals, allylsilanes, enamino esters, and diazomethanes have bee
36 asts a broad range of nucleophiles including allylsilanes, enol ethers, and aromatics in addition to
37 nd accounts for the observed selectivity for allylsilane formation.
38 atalyst, providing vastly improved yields of allylsilanes from simple alkene starting materials.
39                                              Allylsilanes generated through these processes are susce
40 ixtures of alkenyl ethers into stereodefined allylsilanes has been developed by merging Ni-catalyzed
41 annulation of spiro-aziridine oxindoles with allylsilanes have been demonstrated to deliver direct ac
42 thermal Claisen rearrangement to provide the allylsilanes in excellent yields and diastereoselectivit
43  alternatively, the reactivity of the cyclic allylsilane intermediate can be harnessed to introduce a
44                                           An allylsilane is also applicable in this transformation, p
45                           The synthesis of E allylsilanes is accomplished with palladium NHC catalyst
46 st catalytic asymmetric carboannulation with allylsilanes is presented.
47 e for crotylsilanes was longer than that for allylsilanes likely due to the increased steric hindranc
48                                          The allylsilane moiety in the product underwent a second all
49 ion to the alkaloid tricyclic core 33 via an allylsilane/N-sulfonyliminium ion cyclization.
50 and are subsequently trapped by a variety of allylsilane nucleophiles.
51 derstood by intramolecular allylation of the allylsilane on to the activated anomeric center, followe
52 1-yl)-1-substituted-pyrrolidin-2-ones 9 with allylsilanes, organozinc reagents, and phosphorus compou
53            Ring-closing alkene metathesis of allylsilanes provides intermediates that can be protodes
54 subsequent S(E)' electrophilic desilylation (allylsilane RCM/S(E)') to construct exo-methylidenecyclo
55 todesilylation of a stoichiometrically added allylsilane reagent.
56 electively converted into E-vinylsilanes and allylsilanes, respectively, at room temperature.
57  The development of a strategy consisting of allylsilane ring-closing metathesis and subsequent S(E)'
58 ate nucleophiles to carbon analogues such as allylsilane, silyl enol ether, and silyl ketene iminal b
59 in 8 with NaBH(4), NaCN, triethyl phosphite, allylsilanes, silyl enol ether and Grignard reagents aff
60 es 4a and 4b react with nucleophiles such as allylsilanes, silyl ethers, and organozinc reagents to a
61 ns 18 and 27 reacted with Grignard reagents, allylsilanes, silyl ethers, and triethyl phosphite to pr
62 ss of the aldehyde (R'') or syn-beta-hydroxy allylsilane substituent (R') used.
63 ocyclization of an N-acyliminium ion with an allylsilane to form the A/C rings as the key step.
64 g reaction between trifluoromethylarenes and allylsilanes to access allylated alpha,alpha-difluoroben
65 ddition reactions of allyl and 3-substituted allylsilanes to indolizidine and quinolizidine alpha,bet
66  to lie between that of an enol ether and an allylsilane trapping group.
67 y enol silanes, ketene acetals, alkenes, and allylsilanes using chiral transition metal-phosphine com
68 tert-butyl)phosphine, for the preparation of allylsilanes using the palladium-catalyzed silyl-Heck re
69                   The Sakurai reaction of an allylsilane with an azido-containing enone under Lewis a
70 trans-4-octene also exclusively produces the allylsilane with the silicon located at the terminus of
71 lefins to selectively form the corresponding allylsilanes with commercially relevant tertiary silanes