ライフサイエンスコーパス: amine

1 -ketoacetals, tosyl hydrazide, and a primary amine.

2 nvolve hydrogen atom abstraction from the N2-amine.

3 nes in the presence of the Cinchona alkaloid amine.

4 nes, as well as cyclic and acyclic secondary amines.

5 eophilicity (N Mayr constants) of the tested amines.

6 alpha-allylation of (pseudo)benzylic primary amines.

7 ing a broad scope of enantioenriched primary amines.

8 larly for challenging alpha-tertiary primary amines.

9 approximately 20 min with these nucleophilic amines.

10 construction of different ureas and primary amines.

11 deamination of neurotransmitters and dietary amines.

12 s found to be critical for the extraction of amines.

13 ide derivatives from the corresponding alkyl amines.

14 ting from carbonyl compounds and alpha-silyl amines.

15 ding N-(pyridin-2-yl)imidazo[1,2-a]pyridin-3-amines.

16 gy-rich-alpha-amidonitriles to proteinogenic amines.

17 ctive ring-opening with primary or secondary amines.

18 pare and functionalize biologically relevant amines.

19 from the appropriately substituted tertiary amines.

20 ihydro-1H-benzimidazol-2-ones with secondary amines.

21 eloped for these reactions to access various amines.

22 the enantioselective C-H activation of free amines.

23 on more often with cysteine thiols or lysine amines.

24 conomical means to synthesize alpha-branched amines.

25 een applied for chirality sensing of primary amines.

26 lphosphino)butane, formaldehyde, and primary amines.

27 ate for sensitive quantification of biogenic amines.

28 ce area as occurs from primary to quaternary amines.

29 boxylic acids, sulfonates, phosphonates, and amines.

30 acetylated thermolysin, which lacks primary amines.

31 low an efficient access to nonracemic chiral amines.

32 nes to olefins, heterocycles, aldehydes, and amines.

33 -2-yl)-3-methyl-2-oxa-8-azaspiro[4.5]decan-4-amine (1), a highly potent, selective, orally efficaciou

34 is((1-methyl-1H-benzo[d]imidazol-2-yl)methyl)amine) (1) reacts with O(2) in the presence of base, gen

35 lf-assembly of commercially available chiral amines, 2-formylphenylboronic acid, and chiral diols in

36 3H-pyrazolo[4,3-f]isoquinolin-6-yl]pyridin-3-amine (28).

37 pplied to the Schiff base to yield secondary amine 3, which is also a highly effective hydrogelator a

38 plied to the arylation of one spiro-bicyclic amine, a class of substrates that has not been studied i

39 beta to nitrogen in an imine of an aliphatic amine, a process that occurs through a four-membered pal

40 y profiles can also be discovered within the amine-acid coupling system, as we show here via the late

41 ics approach to produce a map of conceivable amine-acid coupling transformations, which can be charte

42 he nitrile group can be readily converted to amines, acids, amides, or other heterocycles.

43 alkenes, the addition of the N-H bond of an amine across an alkene, is a fundamental, yet challengin

44 ur by the direct addition of the N-H bond of amines across unactivated internal alkenes(5-7), includi

45 strong or poorly soluble inorganic bases for amine activation nevertheless complicates the compatibil

46 (6)H(3)] with a commercially available alane amine adduct (H(3)Al.NMe(2)Et) in toluene resulted in th

47 Various amines, alcohols, thiols, and amino acid derivatives are

48 n of 1,4-dihydro-pyrrolo[3,2-b]pyrroles from amines, aldehydes, and diacetyl, we confirmed that iron

49 olving multifunctional aldehydes and primary amines, allow the formation of complex and sophisticated

50 isocyanobenzoates and a range of substituted amines, although the use of aromatic amines as nucleophi

51 abolomics not only confirmed the presence of amines, amino acids, carbohydrates, and organic acids in

52 of enantiomers of 1,2- and 1,3-diols, chiral amines, amino alcohols, and amino-acid esters.

53 al method of preparing ether, thioether, and amine analogues of galiellalactone was developed.

54 Derivatization conditions for 8 amines analysis were optimized using D-optimal and centr

55 llowed second-order kinetics, first order in amine and first order in electrophile.

56 C-H bonds has been developed, wherein a beta amine and gamma iodide are incorporated onto an aliphati

57 acts were purified through primary secondary amine and graphitized carbon black.

58 ignals indicated a chemical reaction between amine and hydrolyzed amide groups of nylon and MAH group

59 A proposed internal H-bond between the amine and neighboring benzenesulfonamide was stabilized

60 her, choosing from one type of aldehyde, one amine and one azide (from a possible family of two amine

61 trolled by carbonyl-trapping agents, such as amine and phenolic compounds.

62 ands decrease both the pK(a) of the Ni-bound amine and the barrier to reductive elimination from the

63 idins and methylxanthines, but also biogenic amines and alkaloids.

64 edented metal-free synthesis of a variety of amines and amides is reported via amination of C(sp(3))-

65 alkylation of primary and secondary aromatic amines and amides with primary, secondary, and tertiary

66 UHPLC-FD method, determining their biogenic amines and amino acids profile.

67 ate is an important source of free bioactive amines and amino acids which play important roles in hum

68 The efficacy of several secondary amines and aniline derivatives was evaluated in the coup

69 we synthesized a series of N-trifluoromethyl amines and azoles, determined their stability in aqueous

70 Condensation between amines and carbonyls, a process that frequently occurs i

71 iterative alkyl group transfer from tertiary amines and demonstrates a deaminative strategy for the c

72 d derivatives, 17 organic acids, 22 biogenic amines and derivatives, 40 acylcarnitines, 34 lipids, an

73 Except for those amines and diols which have a relatively high LOD, the L

74 The use of simple chiral amines and easily prepared achiral or racemic phosphoric

75 CxD7L2 binds biogenic amines and eicosanoids.

76 Low contents of biogenic amines and mycotoxins confirmed celery quality and fresh

77 The reaction, which yields amines and O(Bpin)(2), tolerates nitro, halide, and amin

78 uilding blocks such as primary and secondary amines and oxazolines, highlighting its synthetic utilit

79 Diverse protonation of the heterocyclic amines and oxime groups of the bis-oximes resulted in eq

80 Carbonylation reactions of amines and phenols are carried out via ligand-controlled

81 ion radical-mediated coupling of (arylmethyl)amines and photoelectrochemical activity in sunlight-dri

82 A wide range of secondary alkyl and aryl amines and primary and secondary alcohol-derived MTHPs a

83 DNA-compatible method for guanidinylation of amines and reduction of nitriles.

84 ouble bond isomerization of allyl ethers and amines and subsequent intramolecular reaction with nucle

85 sustainable production of different kinds of amines and their functionalization.

86 nemethyl)benzaldehyde reacts with a range of amines and thiols under Lewis acid catalysis.

87 en(py)(3) = tris(2-pyridyl-methylimino-ethyl)amine) and a series of benzoquinoid acceptors.

88 action to set the configuration of the axial amine, and an intramolecular alkoxycarbonylation to buil

89 ltivalent glycomimetics comprising aldehyde, amine, and isocyanide components related to isopropylide

90 onent reaction between pyruvate derivatives, amines, and aldehydes for the preparation of phosphorus

91 ing of ortho-hydroxybenzaldehydes, secondary amines, and alkynoic acids is performed under catalyst a

92 rious nucleophile classes, including azoles, amines, and carboxylic acids.

93 tumor development, the release of bioactive amines, and indolent growth of the tumors.

94 ternary 3,4-dihydroquinazolines from amides, amines, and ketones has been developed.

95 the transformation of nucleotides, biogenic amines, and microbiological changes affect the quality a

96 cific synthesis of useful alpha-chiral alkyl amines, and rapid construction of different ureas and pr

97 halide ions, carboxylates, p-nitrophenolate, amines, and tris(p-anisyl)phosphine) have been investiga

98 RNAseq reveals changes in amine- and G-protein coupled receptor pathways.

99 ophenyl)-N-(3,4,5-trimethoxyphenyl)pyrazin-2-amine (APA) treatment.

100 ophenyl)-N-(3,4,5-trimethoxyphenyl)pyrazin-2-amine, APA), and pointed to NAT2 loss being a therapeuti

101 While free primary aliphatic amines are common, versatile intermediates in synthesis,

102 It is noteworthy that the aromatic amines are generated in situ by the reaction of aryl hyd

103 lytic strategies for the synthesis of chiral amines are increasingly attractive and include enzymatic

104 Alkyl amines are intensively produced and use fine and bulk ch

105 We show that N-trifluoromethyl amines are prone to hydrolysis, whereas N-trifluoromethy

106 Aromatic amines are relevant aquatic organic contaminants whose p

107 A wide variety of primary amines are selectively transformed to carboxylates or ke

108 Biogenic amines are the important markers for food spoilage, thus

109 rast, by exploration of alpha-halo ketone in amine as a halide precursor, different shaped nanocrysta

110 tituted amines, although the use of aromatic amines as nucleophiles requires microwave heating.

111 ratories and industries for the synthesis of amines as well as pharmaceuticals, agrochemicals and bio

112 to determine the stereochemistry of primary amines, as well as cyclic and acyclic secondary amines.

113 esponses from odorant receptors (ORs), trace-amine associated receptors (TAARs), or both.

114 receptors but has agonist activity at trace amine-associated receptor 1 (TAAR1) and 5-hydroxytryptam

115 reaction between activated aryl halides and amines at low catalytic loading under metal-free conditi

116 o reversibility of the initial attack of the amines at the electrophiles followed by rate-determining

117 which allowed the rate of the attack of the amines at the electrophiles to be determined.

118 A new approach for biogenic amines (BA) determination in fermented beverages was dev

119 phenylethylamine and tryptamine are biogenic amines (BA) often found in foods.

120 istamine, one of the most important biogenic amines (BAs) is considered as food hazard and therefore

121 nm) irradiation in the presence of a soluble amine base without any additional photosensitizer, the r

122 In particular, functionalized homopropargyl amines bearing up to three contiguous stereocenters can

123 that four ethanol-solubilised complexes with amine bisphenol, aminoalcohol bisphenol or salan ligands

124 Selected examples of amine bond forming reactions include: (a) hydroamination

125 -diamines using readily available olefin and amine building blocks.

126 atom-economical method for the synthesis of amines, but reactions of unactivated alkenes remain inef

127 events: the in situ methylation of tertiary amines by PO(OMe)(3), Ni-catalyzed C-N bond cleavage, an

128 w method for the synthesis of alpha-branched amines by reductive functionalization of tertiary carbox

129 odified with diverse functional groups (i.e. amine, carboxylic acid, isocyanate, alkane and pyridine)

130 ron-deficient difluoro-substituted secondary amine catalyst and the intrinsic reactivity of methylene

131 o-5-nitrobenzofuroxan 1 with eight aliphatic amines (characterized by very different basicities/nucle

132 are attractive for identifying new bioactive amine chemical space.

133 nt work reports the use of an isothiocyanate-amine "click"-like reaction between isothiocyanate-conta

134 and yields in the arylation of small primary amines compared to previously reported YPhos ligands.

135 tion (GRR) between the Ga seeds and a copper-amine complex takes place.

136 idate intermediate, mainly influenced by the amine component.

137 nthesis, especially when using two different amine components.

138 cid profile of the wines, while the biogenic amine composition was not modified.

139 f these lipids when co-formulated with other amine containing lipid-like materials.

140 ts application for derivatization of several amine-containing drugs.

141 eir microbiological quality, TVB-N, biogenic amine content, fatty acid composition and TBARS.

142 wines just as on the amino acid and biogenic amine content.

143 fication of a family of alternative branched amine coreactants, which raises the analytical strength

144 ide range of cyclohexyl and linear aliphatic amines could be fluorinated selectively at the gamma-met

145 ng of (hetero)aryl halides with a variety of amine coupling partners through the use of a photoredox/

146 ith respect to both the alpha-ketoacetal and amine coupling partners, providing access to 4-, 1,4-, 1

147 00:1 rotaxane:axle selectivity, from primary amines, crown ethers and a range of C=O, C=S, S(=O)(2) a

148 sp(3))-H functionalization of free aliphatic amines (cyclopropylmethylamines) enabled by a chiral bid

149 in three rounds of directed evolution of an amine dehydrogenase biocatalyst via ultrahigh throughput

150 etrosynthetic disconnections for substituted amine derivatives in organic synthesis, and particularly

151 tforward preparation of diverse and valuable amine derivatives starting from simple compounds.

152 irines, or direct metalation of 4-azadiene-1-amine derivatives.

153 functional-group tolerance, alkyl and benzyl amine derived PDIs (incl. commercial dyes) were obtained

154 age, thus, an on-package sensor for biogenic amine detection is crucial for food quality control.

155 iverse aromatic carbocyclic and heterocyclic amines directly with carboxylic acids, by-passing their

156 Depending on the amine employed in the synthesis of the Ugi adducts, diff

157 ory study of the atmospheric autoxidation in amines exemplified by the atmospherically important trim

158 the Kochetkov amination, where reducing end amines exist solely as the beta-anomer.

159 We argue that the primary amine facilitates room-temperature decomposition of thio

160 a recognition element ending in a secondary amine followed by capping with different electrophiles.

161 moieties, enabling the use of protein-inert amines for selective protein modification.

162 or organic carbonate or nitriles) or into an amine (for instance, a nitro compound) in the presence o

163 rences in microbiological growth or biogenic amine formation were observed.

164 s between Maillard products and heterocyclic amines formation, as well as between volatile terpenes a

165 tion of N,N-Bis(2-hydroxyethyl) alkyl(C8-C18)amines from five different polypropylene capsules to Ten

166 that are able to construct complex aliphatic amines from simple, readily available feedstocks have be

167 Noteworthily, amine functionalities are present in a large number of p

168 In this work, the covalent attachment of an amine functionalized metal-organic framework (UiO-66-NH(

169 designed platform is based on the use of an amine-functionalized silica resin to facilitate the chem

170 Uniform-sized amine-functionalized tantalum oxide NPs (d ~ 5.7 nm) wer

171 However, by the incorporation of basic amine functions at controlled positions in the modifying

172 effect and enantiomeric excess of the parent amine gives potentiality for quantitative chirality sens

173 kage between carboxylic acid group of HA and amine group of dopamine.

174 The amine group of lysine can accept up to three methyl grou

175 These capsules were decorated with amine groups to present a positively charged outer coron

176 y the formation of the heterocyclic aromatic amine (HAA) 2-amino-3,4-dimethylimidazo(4,5-f)quinoline

177 Heterocyclic aromatic amines (HAAs) are neo-formed compounds generated during

178 the formation of other heterocyclic aromatic amines (HAAs) with the structure of quinoxaline is propo

179 The reactive amine handles, presented on their surface, allow "plug t

180 se reasons, deaminative functionalization of amines has emerged as an important area of research.

181 rmediates with nitrogen nucleophiles such as amines, hydrazines, and TMSN(3) afforded, in a one-pot t

182 f an aldehyde or a ketone with ammonia or an amine in the presence of a reducing agent and often a ca

183 intermediate that immediately coordinates an amine in the solvent cage, leading to B-pyridinium or B-

184 providing protected alkyl, alkenyl and aryl amines in high yields with gaseous N(2) and CO(2) as the

185 col was found to afford the N-formylation of amines in moderate-to-good yields.

186 organic chemistry owing to the key roles of amines in synthesis, drug discovery, and materials scien

187 =tris(3,5-dimethyl-4-methoxypyridyl-2-methyl)amine) in CH(3) CN with 4 equiv CAN and 200 equiv HClO(4

188 ades monoamine neurotransmitters and dietary amines, in stromal cells elevates production of reactive

189 and branched primary, secondary and tertiary amines including N-methylamines and molecules used in li

190 for 4-, 5-, and 6-membered cyclic secondary amines, including medicinally relevant compounds.

191 The amine-incorporated azo-PBIs (3 and 6) reduced chloroauri

192 s with the tetramic acid core and subsequent amine incorporation using either ammonium acetate or HMD

193 The histamine concentration and the biogenic amine index increased up to 45.2 +/- 1.62 mg kg(-1) and

194 failure generated a novel series of acyclic amine inhibitors displaying exceptional potency and PK p

195 rticospinal axons traced from biotin-dextran-amine injections in the left motor cortex were equally l

196 m simple alpha-1 degrees and alpha-2 degrees amines into alkylating reagents via Katritzky pyridinium

197 ubstituted homoallylic alpha-tertiary NH(2) -amines is introduced.

198 ctivated alkenes with simple secondary alkyl amines is preferentially achieved.

199 of ligand and substituent on the propargylic amine, leading to a stereodivergent process.

200 A sarcophagine cage amine ligand, MeCOSar (5-(8-methyl-3,6,10,13,16,19-hexaa

201 A broad range of primary and secondary amines may be inserted by this method, including enantio

202 ocatalyzed route to amides from alcohols and amines mediated by visible light is presented.

203 Here, we report the combination of in situ amine methylation and Ni-catalyzed benzalkyl C-N bond cl

204 ous suspension of either positively charged (amine-modified polystyrene; a-PS) or negatively charged

205 ncillary ligands (tpa = tris(2-pyridylmethyl)amine, n = 0-3 corresponds to methylation of the 6-posit

206 , leading to 3D spirocycles with a secondary amine (NH) in the spiro-ring.

207 Beginning with the nitro-NHC, we form an amine-NHC terminated surface, which further undergoes am

208 ation of gluten proteins using ethylamine as amine nucleophile, substantial amounts of glutamine resi

209 starting from widely available heterocyclic amine nucleophiles and carbonyl electrophiles.

210 were recalcitrant to reaction with thiol or amine nucleophiles under mild aqueous conditions.

211 sient Schiff base conjugate that the primary amine of taurine forms with retinaldehyde would readily

212 and levels of methylxanthines and bioactive amines of cocoa.

213 rases (NTMTs) methylate the alpha-N-terminal amines of proteins starting with the canonical X-P-K/R m

214 ds or directly via covalent coupling of free amines on the enzyme surface with the N-hydroxysuccinimi

215 ith methyl group substitution on the charged amine or with electron-donating or -withdrawing ring sub

216 mpounds (aldehydes or ketones) with ammonia, amines or nitro compounds in the presence of suitable ca

217 Secondary amines or primary alcohols as the third component of the

218 g upregulated pro-oxidative enzymes, such as amine oxidase 3/vascular adhesion protein 1 (AOC3/VAP1)

219 mportant to prevent confounding bovine serum amine oxidase-induced cytotoxicity in mechanistic studie

220 idized by the copper-containing bovine serum amine oxidase.

221 f favor the generation of the requisite mono(amine)-Pd(II) intermediate, thus enabling the enantiosel

222 beta-position, aminomethyl substituents with amine pK(a)'s > 7 accelerate, while those with pK(a)'s <

223 lic conformational control to achieve proper amine placement.

224 mall molecule 1H-pyrazolo[3,4-d]pyrimidine-4-amine (PP) compounds that are bulky ATP mimetics.

225 s a powerful tool to prepare enantioenriched amine precursors from abundant C-H bonds.

226 eses of complex ether, sulfone, and tertiary amine products, some of which would be difficult to acce

227 a broad scope of amines to form (hetero)aryl amine products.

228 eck reaction to give enantioenriched allylic amine products.

229 roxide, a phenol (4-methylumbelliferone), an amine (propargylamine and ethanolamine), fluoride, or a

230 ucts by virtue of changing the nature of the amine protecting group.

231 Photocatalytic alpha-functionalization of amines provides a mild and atom-economical means to synt

232 Transannular C-H heteroarylation of amines provides rapid access to complex scaffolds that a

233 cation/hydrogenation sequence on propargylic amines, providing fast access to enantioenriched chiral

234 er (poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine (PTAA)) is employed to partially replace polymer d

235 p and high yield by electron-donating cyclic amines (pyrrolidine (TPMA(PYR) ), piperidine (TPMA(PIP)

236 d quantitatively without the need for excess amine reactant or product purification.

237 erococcus viridans LOx (AvLOx) modified with amine-reactive phenazine ethosulfate (PES).

238 d functionalization of unprotected alicyclic amines remain rare.

239 All amines showed high bioaccessibility with slight influenc

240 re we describe the ability of a binary thiol-amine solvent mixture to dissolve the bulk bournonite mi

241 , a straightforward synthesis of azetidine-3-amines, starting from a bench stable, commercial materia

242 Besides aldehydes, ketones, or amines, starting materials have been used that can be co

243 hree distinct features: aglycon, glycan, and amine substitution pattern.

244 ytic mechanism involving the oxidation of an amine substrate through transfer of a hydride to the FAD

245 n between an aromatic residue and quaternary amine substrates allows us to delineate a subgroup of Ri

246 nd differences in the reactivity of tertiary amine substrates are discussed.

247 alytic turnover is promoted by electron rich amine substrates that enable catalytic turnover.

248 ommercially available alcohols and secondary amines, suggests broad applicability of the reaction in

249 agent and often a catalyst, is an important amine synthesis and has been intensively investigated in

250 Triangular, tris(4-aminophenyl)amine (TAA), and square, 1,3,6,8-tetrakis(p-formylphenyl

251 ed by strong electrostatic interactions with amine-terminated polystyrene dissolved in toluene at the

252 of the SPSs formed between H(4) TPPS(2-) and amine-terminated polystyrene.

253 The chiral amine (the inductor) forces a change in the structure of

254 In the presence of amines, the degradation of glutaconaldehyde in acidic me

255 a frequently invoked mechanism of concerted amine/thiol proton transfer and C-S bond formation and i

256 terically encumbered alpha-3 degrees primary amines through visible light photoredox catalysis.

257 ), and -(13)CH(3) groups into pharmaceutical amines thus has been demonstrated by tuning isotopic wat

258 the substrate scope of mTG beyond canonical amines thus substantially broadens the versatility of th

259 ign includes 2-amino-6-methylpyridine as the amine to enhance the rates of multiple steps within the

260 these results, we propose that ability of an amine to form multiple intermolecular interactions (i.e.

261 highlight the remarkable capacity for select amines to act as effective phase-transfer catalysts for

262 hetero)aromatic esters with a broad scope of amines to form (hetero)aryl amine products.

263 that ylidenemalononitriles (YMs) react with amines to form cyclic amidines and that the starting lin

264 e for the dehydrogenation of simple tertiary amines to give enamines than the previously reported di-

265 tion of several beta-functionalized tertiary amines to give the corresponding 1,2-difunctionalized ol

266 The conversion of amines to hydroperoxy amides may have important implicat

267 s-coupling partners (phenol esters and silyl amines) to preclude conventional reactivity that forms i

268 ubstituents in tris(4-chloro-2-pyridylmethyl)amine (TPMA(3Cl) ) were replaced in one step and high yi

269 onversions of the benzyl azide products into amine, triazole, tetrazole, and pyrrole functional group

270 and one azide (from a possible family of two amines, two aldehydes and four azides) with different vo

271 dynamic libraries (CDLs)-each containing two amines, two dialdehydes, and two metal salts-have been f

272 rate that a variety of homoallylic protected amines undergo an interrupted enantioselective relay Hec

273 e (formed from ortho-hydroxybenzaldehyde and amine) undergoes a concerted Eschweiler-Clarke type deca

274 e and delivers complex, chiral homopropargyl amines; useful building blocks on the way to biologicall

275 N-alkylation of aromatic and heteroaromatic amines using a diverse range of primary alcohols with ex

276 ylation and reductive N-functionalization of amines using CO(2) as the C(1) source.

277 ve condensation of o-nitrobenzaldehydes with amines utilizing iron pentacarbonyl as a reducing agent

278 controllable isotope-labeling in N-alkylated amines, we herein rationally design photocatalytic water

279 nomer architecture in which the catechol and amine were coupled together in a fixed orientation in th

280 u](2)-(mu-OH)}(4+) (L = tris(2-pyridylmethyl)amine), were measured.

281 fluorophenyl)methyl)sulfinyl)alkyl alicyclic amines, where the piperazine-2-propanol scaffold was mod

282 ogy in the preparation of different kinds of amines, which are of commercial, industrial and medicina

283 duce 1D ribbons, termed COF-76, bearing free amines, which are then used to link the ribbons into 2D

284 d to some specific analytes, e.g., diols and amines, which could have a high LOD and toxicity.

285 ses, especially for the syntheses of primary amines, which often are non-selective and suffer from ov

286 The coupling of an amine with a carboxylic acid to form an amide bond is th

287 nge of fused- and bridged-bicyclic secondary amines with a broad set of heteroarenes.

288 via the coupling of aldehydes and secondary amines with alkyl halides.

289 ng a core domain catalyzing the oxidation of amines with an auxiliary domain for substrate recognitio

290 ere realized upon replacing the ether-linked amines with carbon-linked morpholines, a modification mo

291 rogeneous photo-oxidation of various primary amines with conversion efficiency above 99% under visibl

292 By condensing alpha-3 degrees primary amines with electron-rich aryl aldehyde, we enable an ox

293 esentative examples of primary and secondary amines with pinacol allenylboronate is presented.

294 iet) are rich in polyamines, small aliphatic amines with potential cardioprotective effects.

295 ng 2'-alkynylbiaryl-2-carbaldehydes and aryl amines with tandem oxidation was performed using catalyt

296 wo abundant chemical feedstocks, alkenes and amines, with full atom economy(1-3).

297 a selective pathway to synthesize secondary amines without using a catalyst.

298 ee and modular transformation forms tertiary amines, without structural constraint, via the coupling

299 The direct coupling of olefins and amines would be an ideal approach to construct these mot

300 Reduction of these imine linkers to amines yields the more flexible cage Co-rPB-1(6).