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2 xperiments suggest the intermediacy of Ni(0)-ate complexes, leaving some doubt that a canonical catal
10 actors contributing to stability of a 10-X-2 ate-complex is removal of the formally cationic lithium
11 ructures and energies of a variety of 10-X-2 ate-complexes derived from reaction of alkyllithiums and
12 ations suggest that perfluoro dialkyl 10-X-2 ate-complexes should be experimentally observable specie
14 Among 4,116 children studied, 3,056 (74%) ate breakfast daily, 450 (11%) most days, 372 (9%) some
15 e)-2-[N-(4-methylthiazol-2-yl)carbamoyl]acet ate (YH439)]-treated and suspension cells, suggesting a
24 fin by a mechanism involving formation of an ate complex, 1,2-metalate rearrangement, and beta-elimin
27 e transgenic mice had 50% less adiposity and ate 15% less food but did not have altered energy expend
31 omen were maintained in a metabolic unit and ate a diet of conventional foods containing less than on
32 intensity; once food was picked up, animals ate for the remainder of the 60-s stimulation period.
33 ded by one-electron oxidation of an anionic "ate" cerium(III)-carbene precursor, thereby avoiding dec
34 ch day in 16.3 distinct bouts, rats with APX ate comparable amounts of food (28.6 g) in much fewer da
35 ly unencumbered homoleptic uranium (IV) aryl-ate species of the form [U(Ar)(6) ](2-) (Ar=Ph, p-tolyl,
37 cids reversibly bind catechol to form boron "ate" complexes (BACs) that alter the electron density on
38 f the formation of a chlorine radical-boron 'ate' complex that selectively cleaves sterically unhinde
39 nism with rapid initial formation of a boron-ate complex followed by slower migration of methyl from
42 DIO rats had briefer postmeal intervals, but ate smaller and briefer meals, resulting in normal intak
44 levels, HFD rats had lower VMH FA levels but ate less from 3 to 6 h of refeeding than did LFD rats.
45 ,7a-dihydro-4H-benzo[1,3]dioxole-3a-carboxyl ate by a Curtin-Hammett mechanism, has also been examine
51 he fast food restaurant, fast food consumers ate Western diets, which might have stronger association
54 y Catholic sisters who lived in one convent, ate from the same kitchen, and were highly comparable fo
58 tantial stability to both diaryl and dialkyl ate-complexes, and the calculations suggest that perfluo
59 able experimental data, indicate that diaryl ate-complexes are more stable than their dialkyl counter
63 ygous transgenic animals fed a high-fat diet ate 10% more and were 12% heavier at 13 weeks of age tha
64 n of diabetes, rats selecting their own diet ate and drank less, weighed more, and had more adipose t
67 mothers often used food to regulate emotions ate more cookies in the absence of hunger than did child
68 ating this reaction is two-fold: it enables "ate" complex formation and overcomes catalytic inhibitio
70 rom partitioning of the enzyme-bound enediol(ate) intermediate between hydron transfer to C-1 and C-2
71 ransfer of a proton to the TIM-bound enediol(ate) intermediate in D(2)O, but it strongly favors catal
72 s a better mimic of the proposed cis-enediol(ate) intermediate than 6-phospho-D-gluconate, which was
73 transfer between C2 and C1 of a cis-enediol(ate) intermediate to yield the open chain form of the pr
77 ate side chain of Glu-165 in the TIM-enediol(ate) complex is not in chemical equilibrium with those o
78 by nonstereospecific ketonization of an enol(ate) species is indicated by the observation that COMC-6
79 C derivative to give a glutathionylated enol(ate), which undergoes nonstereospecific ketonization, ei
81 ase chemistry for the generation of the enol(ate) intermediate of acetyl-coenzyme A, while main-chain
82 lly, we demonstrate that vinyl boronic ester ate complexes, prepared by combining organoboronates and
83 ly, despite their obesity, Kiss1r KO females ate less than WT females; however, Kiss1r KO females dis
86 ween 1200 h and 2000 h, whereas the CD group ate regularly from breakfast until the end of the day.
88 ts not yet eating table foods, the HCF group ate significantly more savory-, bitter-, and sour-tastin
93 Africa, demonstrates that this early hominid ate not only fruits and leaves but also large quantities
95 ant conditions tend to yield the homoleptic "ate" complex [Fe(mes)3 ](-) (mes=mesityl) rather than ad
96 on of the tetrakis(triphenysiloxide) Pr(III) ate complex, [KPr(OSiPh(3))(4)(THF)(3)], 1-Pr(Ph), with
97 dation of the tetrakis(siloxide)terbium(III) ate complex, [KTb(OSi(O (t)Bu)(3))(4)], 1-Tb, with the t
98 e of uremic symptoms or chemical imbalances, ate at least three meals daily which were unrestricted i
103 ous reactions of the (c-Hex)(2)B and Ti(IV) "ate" enolates of enantiopure (+)-1a (R = MOM) with (+/-)
105 acting protected iodofulvenes with magnesium ate complexes at low temperatures, followed by addition
107 Percent body fat was assessed after mice ate low-energy diet and again after the same mice ate hi
110 We found that male GAL(-/-)/NPY(-/-) mice ate significantly more and were much heavier (30%) than
112 cleaved to form the trimetallic, monouranyl "ate" complexes [(py)3LiOUO(mu-X)Ln(py)(L)] by the additi
113 ed significantly from baseline after mothers ate soy: in maternal urine (x +/- SEM) from 18.4 +/- 13.
117 bladder cancer compared with those who never ate bacon (multivariate RR = 1.59; 95% CI = 1.06, 2.37),
119 86; p(trend) < 0.001) than did men who never ate or who ate less than 1 unit per month (rare consumpt
121 l study results showed that cases more often ate in food establishments than did controls (OR 3.4 [95
122 state framework constructed from diphosph(on)ate ligands, a widespread investigation on the preparati
123 ylated analogues (1-3), 1,2-cyclic phosph(on)ate analogues (4-6), isosteric methylene phosphono analo
124 subsequently was converted to the phosph(on)ate and an aryl vinyl ketone by a beta-elimination react
126 crystal structures and provide Mn-phosph(on)ate bonding information not available from these studies
127 n (adjusted OR, 0.39; 95% CI: 0.16, 0.94) or ate liver (adjusted OR, 0.26; 95% CI: 0.12, 0.57) were l
128 mpared with those who never consumed fish or ate fish less than once per month, individuals with a hi
130 ic carbenes (NHCs) to create organometallic -ate complexes of Au(I) that serve both as WCAs and funct
135 ng a standardized diet for 3 d, participants ate ad libitum from a computer-operated vending machine
138 mation was provided, restrained participants ate more of the fat-free chips than the regular chips; h
141 t had examined food intake when participants ate alone or with strangers/acquaintances (Z = 1.32; P =
144 versible formation of a pentavalent peroxide ate complex, prior to rate-limiting aryl migration, has
145 children who selected larger food portions, ate faster, and consumed more energy (eating behavior x
146 children who selected smaller food portions, ate slower, and consumed less energy, but was positively
147 d by EEG), a constant semirecumbent posture, ate regular small meals, had constant interaction with e
148 y of vegetables, but not those fed potatoes, ate significantly more of the carrots after the exposure
149 en used food for emotion regulation purposes ate more chocolate in the experimental condition than in
151 k of preterm birth than did women who rarely ate fish (</= 1 time/wk); the adjusted RR of fish intake
159 ached nadirs by 30-40 min, and the same rats ate 60% faster and spent 84% more time eating during the
160 5% in the high-fat diet and because the rats ate less of the high-fat diet, we also compared the high
161 4v, alloxan injection, alloxan-treated rats ate only 30% and their blood glucose area under the curv
163 established rat MO model, female Wistar rats ate chow (controls (C)) or high energy, obesogenic diet
168 phosphide produces the mononuclear scandium ate complex [(PNP)Sc(mu(2)-P[DMP])(mu(2)-Br)Li] (3) (DMP
175 On average, lactating women in our study ate two-thirds of the recommended intake for choline (Ad
180 scheduling a recurring 28-h "day." Subjects ate 4 isocaloric meals each 28-h "day." For 8 days, plas
182 Thirty minutes after oral preloads, subjects ate and drank ad libitum, and amounts ingested and the t
184 10-day laboratory protocol, wherein subjects ate and slept at all phases of the circadian cycle-achie
187 protein (HiPro) compared with controls that ate 20% protein for 3 wk had higher urine excretion of e
191 bjects were randomly assigned to groups that ate specific diets for 4 weeks-a diet low in FODMAPs (n
193 FGF21 expression were observed in mice that ate a ketogenic diet and when fasting, which suggests th
194 er on a treadmill than did control rats that ate an isocaloric diet that was supplemented with either
198 e neutral complex [(WCA-NHC)Rh(CO)2] and the ate complex (NEt4)[(WCA-NHC)Rh(CO)2Cl] were prepared, wi
199 onformational complexity, especially for the ate complexes, and of the nature of the microscopic mode
200 nterconversion between the conformers of the ate complex and subsequent migration control the outcome
201 indered substituent, the conformation of the ate complex is the dominant factor whereas, in the case
202 ly cationic lithium from the vicinity of the ate-anion via coordination with a Lewis basic solvent.
203 formation of 2 but instead formation of the ate-complex [K(OEt(2))](2)[((tBu)pyrr(2)py)Fe](2) (4).
204 Me(4))(3)] could be obtained by reacting the ate complex [Li(3)ScMe(6)(thf)(1.2)] with AlMe(3) in the
207 y boat to the dive site, dove twice and then ate lunch at 12:30 on the diving boat (no nattou at lunc
212 ved that they would be more credible if they ate a healthy diet, were not Asian or white, or intended
213 their activity levels, everything that they ate or drank, and the environmental and psychological fa
215 st consumers did more MVPA on days when they ate breakfast [exponentiated beta coefficients (95% CIs)
216 e information about both where and when they ate throughout the day, evidence that this species has t
217 ulum, striatum and midbrain] or whether they ate chocolate despite being satiated (parahippocampal gy
218 bserved in the 20 min interval in which they ate the 8.1 kcal meal and remained for an additional 60
219 c anti-TB agents, in that the cysteine thiol(ate) or a hydride source at the active site of DprE1 may
220 he additional cysteine contains a free thiol(ate); it perturbs neither the overall structure of the p
223 re, that neither TruB nor RluA require thiol(ate) groups to effect catalysis, excluding their partici
224 of thymidylate synthase, in which the thiol(ate) group of a cysteine side chain serves as the nucleo
225 than adducts of the diamine, and it is this ate complex that accounts for the catalytic activity.
226 ,4,7,10-tetraazacycloDOdecane-4,7,10-triAcet ate) and GdNP-DO3AM (1-methlyene(p-NitroPhenol)-1,4,7,10
227 arbonylamino)-3'-deoxyadenosine-5'-triphosph ate (deac-aminoATP), to study the ATP hydrolysis mechani
229 a Ni-catalyzed cross-coupling of vinylboron "ate" complexes and acid chloride or acid anhydride elect
233 increased in 10 of 16 volunteers (62.5%) who ate three doses of potatoes; in 9 of 17 volunteers (52.9
234 potatoes; in 9 of 17 volunteers (52.9%) who ate two doses of transgenic potatoes; and in none of the
235 od trace-back investigations among cases who ate in food establishments identified eggs from Poland a
237 3-5 y were more likely to have children who ate more under conditions of negative emotion at ages 5-
238 ts of the consumption of foods; children who ate the foods more often expected them to deliver greate
242 Compared with men who ate 3 times/d, men who ate 1-2 times/d had a higher risk of T2D (RR: 1.25; 95%
245 ) < 0.001) than did men who never ate or who ate less than 1 unit per month (rare consumption) (1 uni
246 The relative risks for participants who ate eight or more servings of spinach per month compared
248 zard ratios for death among participants who ate nuts, as compared with those who did not, were 0.93
253 asional meat eaters, 34% lower in people who ate fish but not meat, 34% lower in lactoovovegetarians,
254 ausea, or vomiting occurring in a person who ate at the restaurant between December 20, 1998, and Jan
259 Typhimurium was isolated from 79 persons who ate fresh Mexican-style cheese from street vendors and f
261 r, most of the questionnaire respondents who ate untreated meals knew how to prevent Anisakis infecti
262 [relative risk (RR) = 2.31 for subjects who ate beef > or =3 times/wk compared with vegetarians], si
264 sexes (RR approximately 0.5 for subjects who ate nuts > or =5 times/wk compared with those who ate nu
267 did not eat breakfast relative to those who ate breakfast daily were adjusted for adiposity, the dif
268 f depression during follow-up than those who ate fish <2 times/week (adjusted relative risk = 0.75, 9
269 roke was significantly lower among those who ate fish 1 to 3 times per month (RR, 0.57; 95% confidenc
270 least once per month compared with those who ate fish less than once per month was 0.56 (95% CI, 0.38
272 r of household members (defined as those who ate from the same pot and slept in the same structure th
273 s concentrations were higher among those who ate infant rice cereal (9.53 microg/L) or rice snacks (4
274 men who did not eat late at night, those who ate late at night had a 55% higher CHD risk (relative ri
275 aring data between that group with those who ate less than 1 serving weekly, the mean difference for
277 uts > or =5 times/wk compared with those who ate nuts <1 time/wk), and reduced risk of IHD in subject
283 the RRs were 1.09 (0.84, 1.41) for women who ate 1-2 times/d, 1.13 (1.00, 1.27) for women who ate 4-5
284 ls were almost 4-fold higher among women who ate 3 or more servings of fish in the past 30 days compa
287 1-2 times/d, 1.13 (1.00, 1.27) for women who ate 4-5 times/d, and 0.99 (0.81, 1.21) for women who ate
290 ombotic infarction was found among women who ate fish 2 or more times per week (multivariate RR, 0.49
294 in the past 30 days compared with women who ate no fish in that period (1.94 microg/L vs 0.51 microg
296 ight youth, but not nonoverweight youth, who ate with an overweight partner (friend or unfamiliar pee
299 were smaller than wild-type littermates, yet ate significantly more and had greater stool frequency,