ライフサイエンスコーパス: atom

1 g compounds (decomposition enthalpy <0.05 eV/atom).

2 ntained a sulfur atom attached to an arsenic atom.

3 stituted carbon atoms attached to a nitrogen atom.

4 ing from the difference of a single fluorine atom.

5 roach capable of designing materials atom-by-atom.

6 ation for ionization of helium atom and neon atom.

7 ic interplay between dislocations and solute atoms.

8 ges composed of alternating carbon and boron atoms.

9 rmation of quantum liquid droplets from cold atoms.

10 ess that results in the clustering of solute atoms.

11 the presence of the alloyed transition metal atoms.

12 ter can hydrogen bond to the cysteine sulfur atoms.

13 nd S-containing species with up to 18 oxygen atoms.

14 y engineering grain boundaries with hydrogen atoms.

15 tures from side chains down to water and ion atoms.

16 n rule for radiative transitions in isolated atoms.

17 reading out the positive charge over several atoms.

18 between molecular carbon and copper surface atoms.

19 with a tunable dispersion density of single atoms.

20 Heavy atom (13)C/(12)C kinetic isotope effects near unity also

21 pic superconducting circuits into artificial atoms(2), enabling some of the best-controlled qubits to

22 engineering based on structured ensembles of atoms(4,8,9) and paves the way towards controlling many-

23 lin states in synthetic systems of ultracold atoms(7,8) or photons(9-11).

24 halogenation sequence by sequential hydrogen atom abstraction (HAA) and radical capture.

25 otope effect (KIE = 31.9 +/- 1.0) suggests H-atom abstraction (HAA) is the rate-determining step, ind

26 capability of LCuF to perform both hydrogen atom abstraction and radical capture was leveraged to en

27 play, rather than classical Norrish hydrogen atom abstraction as initially conceived.

28 isotope effect (KIE) = 6, consistent with H-atom abstraction by S being the rate-determining step.

29 nd deuterium isotope effects on the hydrogen atom abstraction by the adenosyl radical were used to in

30 eal that catalysis proceeds through hydrogen atom abstraction followed by radical rebound, as observe

31 (N1-H)(.) via dG(N2-H)(.) following hydrogen atom abstraction from dG is unlikely to be a major pathw

32 (.) with dG was proposed to involve hydrogen atom abstraction from the N2-amine.

33 ate the kinetic significance of the hydrogen atom abstraction.

34 emote C-H functionalization via 1,5-hydrogen atom abstraction.

35 presence of nitrogen-coordinated, single Ni atom active sites.

36 t with these observations involving hydrogen atom addition to the ipso position of the phenyl ring co

37 gnment of adenosine radicals as N-7 hydrogen atom adducts.

38 creased reactivity of a nucleophile when the atom adjacent to the nucleophilic atom has high electron

39 Single-atom alloys (SAAs) play an increasingly significant role

40 urthermore, the introduction of single metal atoms anchored onto supports provided another effective

41 The Ru atom is coordinated by the P atom and a phenyl group.

42 a controlled manner to abstract a specific H atom and avoid unproductive reactions.

43 toms) or (*)OH (e.g., addition of one oxygen atom and decarboxylation) are observed and produce highl

44 chrodinger equation for ionization of helium atom and neon atom.

45 lowest fraction of KED on the transferred H-atom and the highest chance to follow rebound hydroxylat

46 It was determined that both the bromine atom and the phosphate group were successfully substitut

47 ead to a more efficient utilization of metal atoms and at the same time enhance catalytic performance

48 grids enables the detection of single metal atoms and atomic-resolution imaging of the iron core of

49 How atoms and electrons in a molecule move during a chemical

50 Interactions between atoms and light in optical cavities provide a means of i

51 -pair repulsion between neighboring nitrogen atoms and maximize the favorable hyperconjugative donati

52 encies indeed enable tracking of single gold atoms and molecules with 17-us time resolution, more tha

53 he lowest empty d-states on the dopant metal atoms and occupied p-states on S.

54 rs an interplay between the local network of atoms and the observed NMR signals.

55 nment, and electronic properties of isolated atoms and thus providing a platform for tailoring hetero

56 We find U atoms and UO molecules co-exist in ultrafast laser-produ

57 ning a linear array of more than three metal atoms, and coordination polymers with a heterometallic m

58 An atom- and step-economic synthesis of aryliminophosphoran

59 ent and simulation results show that when Li atoms are deposited on rGO, each layer of Li atoms grows

60 The four H atoms are found to bridge the eight uncoordinated Au ato

61 Atoms are the building blocks of matter that make up the

62 el that traces the fate of individual carbon atoms as they interact with their environment, undergoin

63 of Mo and Y/Sc and Kagome ordering of the Al atoms, as evident from X-ray diffraction and electron mi

64 c waves(4-10), probing the properties of the atom at only a single frequency.

65 educed to the elements belonging to a single atom at the site of isotopic substitution, reveals a rem

66 toms reveal that the segregation of hydrogen atoms at the grain boundaries, rather than the change of

67 e found to bridge the eight uncoordinated Au atoms at the interface.

68 f these unknown chemicals contained a sulfur atom attached to an arsenic atom.

69 two of which may be tetrasubstituted carbon atoms attached to a nitrogen atom.

70 interface, which causes migration of surface atoms away from the dendrite tips, thereby smoothening t

71 tions of "body" are considered, specifically atom-based vs molecule-based approaches.

72 e large majority of molecules (especially, O-atom bearing molecules) are solvent accessible.

73 al dipole orientations generated from the Gd atom being trapped at two different sites inside the C(8

74 l-ACP with five of the seven pimelate carbon atoms being derived from glutaryl-CoA, an intermediate i

75 t structures of human SQOR revealed a sulfur atom bridging the SQOR active site cysteines in a trisul

76 ternative architecture that realizes a giant atom by coupling small atoms to a waveguide at multiple,

77 onal approach capable of designing materials atom-by-atom.

78 also computes significance scores of pocket atoms, called BionoiScores, to provide meaningful insigh

79 proach to quantum information science, where atoms can be deterministically positioned in a quantum b

80 iB(2) O(-) [Bi=B-B=O](-) in which both boron atoms can be viewed as sp-hybridized and the [B-BO](-) f

81 Herein, we rationally design a new In single-atom catalyst containing exclusive isolated In(delta+) -

82 rk, for the first time we employ iron single-atom catalysts (Fe-N-C SACs) as an advanced co-reactant

83 The superior performances of single-atom catalysts (SACs) and the structural similarity with

84 Single-atom catalysts (SACs) have shown superior activity and/o

85 Recently, single atom catalysts have attracted extensive interests in ele

86 ng differences in activity of diverse single-atom catalysts is not straightforward.

87 Single-atom catalysts not only maximize metal atom efficiency,

88 t strategy to fabricate various metal single-atom catalysts on nitrogen-doped carbon (M(1)/CN, M = Pt

89 ene is one of the most representative single-atom catalysts, and it has a high activity and selectivi

90 t method to adjust the performance of single atom catalysts.

91 Herein, single-atom catalytic electrodes design for advanced battery sy

92 phobic Beta zeolites containing framework Sn atoms catalyze the transfer hydrogenation reaction of cy

93 The spatial isolation of Fe atoms centered in porphyrin linkers of MOF sets the firs

94 ments (SSEs), backbone structure, and Calpha atoms, combining the results of each to produce a comple

95 n features tended to have fewer Cl and/or Br atoms compared to traditional legacy contaminant feature

96 e phase is substantially metastable (>70 meV/atom) compared to the wurtzite-type ground state.

97 ly, the molecular switch with terminal bromo atoms confers reversible handedness inversion to the hel

98 to the key intermediates on Co and Ni single-atom configurations for the H(2) and CO evolution.

99 Herein, we report a novel atom-confinement and coordination (ACC) strategy to achi

100 d on biophysical properties derived from raw atom coordinates.

101 le consisting of a few hundred ytterbium-171 atoms, corresponding to a reduction of the averaging tim

102 engineering of C(3) N(4) layers with single-atom Cu bonded with compositional N (Cu N(x) ) is demons

103 d the development of highly efficient single-atom decorated 1T-MoS(2) electrocatalysts.

104 to evaluate the spatio-temporal evolution of atoms, diatoms, polyatomic molecules, and nanoparticles

105 ization, and excellent activity, single iron atoms dispersed on nitrogen-doped carbons (Fe-N-C) have

106 en atom transfer (cHAT), where each hydrogen atom donated to the alkene arrives from a different cata

107 -absorbing reagent and electron and hydrogen atom donor to promote the desulfonylation reaction.

108 al motif is common across a range of M and X atoms (e.g., NbSe(3), HfTe(3,)TaS(3)), but not all M and

109 d to heterocycles with two nitrogen or boron atoms, e.g., C(2)B(10)H(12) carboranes versus planar N(2

110 Notably, this high atom economic approach (-2H(2)O) allowed the generation

111 boasts a wide scope, and can be made highly atom economic, makes this new methodology a very appeali

112 H bond activation, providing straightforward atom-economic access to a wide variety of multisubstitut

113 ansformation is environmentally friendly and atom economical with water as the only byproduct.

114 New atom-economical alternatives to Wittig chemistry are nee

115 nvergent synthetic plan by the use of highly atom-economical and chemoselective transformations in wh

116 a rapid, environmentally friendly, and high atom-economical manner.

117 Here we report an atom-economical olefination of carbonyls via aldol-decar

118 benzylic oxidation is accomplished with high atom economy without the use of directing groups, achiev

119 sts are vital to unlock superior efficiency, atom economy, and environmental friendliness in chemical

120 under mild conditions and demonstrates good atom economy, requiring only a modest excess of the phos

121 e C-H borylation has long suffered from poor atom economy, resulting from both the inclusion of only

122 group in a fast and efficient way, with high atom economy.

123 From a step- and atom-economy perspective, transition metal-catalyzed oxi

124 ingle-atom catalysts not only maximize metal atom efficiency, they also display properties that are c

125 ovements in the agreement between CG and all-atom electrostatic fields.

126 A single nickel atom embedded in graphene is one of the most representat

127 alite structure (Type-VII clathrate) with La atoms encapsulated within truncated octahedral cages com

128 y the antibiotic kirromycin, we employed all-atom explicit-solvent molecular dynamics simulations of

129 A 6-atom-extracted Hessian reproduces perfectly the alpha-T(

130 ive catalyst comprised exclusively of single-atom Fe(1)(II)-N(4) sites via in-temperature X-ray absor

131 ctive graphene ripples, followed by adsorbed atoms flipping to the other side of the graphene sheet w

132 The substitution of paramagnetic chlorine atoms for IAEs proves the magnetic nature of quasi-atomi

133 ors" to precisely confine multiple Fe and Cu atoms for NRR electrocatalysis is reported.

134 ents to achieve both a global search and all-atom force calculations to determine the relative affini

135 nuclearity copper nanocluster with 81 copper atoms, formulated as [Cu(81)(PhS)(46)((t)BuNH(2))(10)(H)

136 the asymmetric unit containing eight silver atoms, four melamine and four cyanuric acid molecules, w

137 G-Py) to encapsulate a semiconducting, heavy-atom-free pyrrolopyrrolidone-tetraphenylethylene (DPPTPE

138 Here, the direct observation of palladium atoms from a nanoparticle passing through a defect in a

139 This strategy couples nitrogen atoms from N(2) with abundant hydrocarbons, and maps a r

140 atoms are deposited on rGO, each layer of Li atoms grows along (110) crystallographic plane of the Li

141 e when the atom adjacent to the nucleophilic atom has high electron density.

142 1,2), the use of quantum degenerate gases of atoms has enabled the quantum emulation of important sys

143 Additionally, heteroboranes with two carbon atoms have been compared to heterocycles with two nitrog

144 form endohedral metallofullerenes, few metal atoms have been observed to be part of the fullerene cag

145 y quantum-mechanical nature of electrons and atoms, have revealed exotic properties that arise from c

146 chanical tunneling (QMT) chemistry involving atoms heavier than hydrogen was considered unreasonable.

147 We created all-atom in silico systems of influenza neuraminidase with e

148 e spin-orbit coupling associated to Br heavy atoms in 1,3,5,8-tetrabromopyrene (TBP), and the photoin

149 s which often contain oxygen and/or nitrogen atoms in addition to halogens (hHNPs).

150 an ensemble of about a million strontium-88 atoms in an optical cavity to simulate a collective Lipk

151 deformation and/or the rotation of fluorine atoms in anionic sites, thereby enabling ZU-61 to effect

152 Such ensembles of atoms in cavities have been proposed for studying collec

153 characterize the resolvability of individual atoms in cryo-EM maps, the map Q-score.

154 Q-scores can be calculated for atoms in proteins, nucleic acids, water, ligands and oth

155 ufficient resolution to visualize individual atoms in proteins.

156 ity differences but to the location of the C atoms in the carborane structure.

157 ns reveal an intercalation-type doping of Fe atoms in the tunnels of the W(18) O(49) crystal structur

158 n) and an additional substituent (at the C-3 atom), in turn synthesized from cyclopent-3-ene carboxyl

159 wn to provide seven of the ten biotin carbon atoms including all those of the valeryl side chain.

160 ne unit of the adamantane group by an oxygen atom increases the solubility, permeability, and stabili

161 new theoretical model structure, with carbon atoms inserted into the boron icosahedra and 2b sites in

162 veral different reaction pathways for oxygen atom insertion were explored-each encompassing a unique

163 hyperconjugative donation from each nitrogen atom into neighboring electron-poor sigma bonds, with th

164 ctures demonstrate that introducing N and Mo atoms into C and Ru lattices, respectively, triggers ele

165 ng undertaking - coordination of Lewis basic atoms into metal centers often necessitate elevated temp

166 rly indistinguishable and tunable artificial atoms into phase-stable PICs marks a key step towards mu

167 Here, we show that newly introduced nitrogen atoms into the inhibitor scaffold can act as hydrogen bo

168 nreactive C-H bond, proximal to the nitrogen atom, into a versatile chemical entity would be a powerf

169 hich establishes a new limit for the heavier atom involved in a QMT reaction in cryogenic matrices.

170 ation/ionization of particles with minimized atom/ion cloud diffusion.

171 generation of selective membrane for sieving atoms, ions and molecules.

172 The Ru atom is coordinated by the P atom and a phenyl group.

173 gy for tuning molecular properties, yet this atom is rarely found in Nature and approaches to integra

174 guishing remote C-H bonds on adjacent carbon atoms is an extraordinary challenge due to the lack of e

175 ontaining internal chains of bonded nitrogen atoms, is of fundamental scientific interest in chemical

176 Earth-orbiting research laboratory, the Cold Atom Lab.

177 The replacement of the Al- by an Fe atom leads to a planar bicyclic frame with a terminal Al

178 Traditional methods use atom level information, which can be complicated by the

179 l properties are more affected at the single atom level than the electronic properties.

180 Our results indicate that a 2-C to 4-C atom linker enables its respective bisubstrate analogue

181 MT1, but the bisubstrate analogue with a 5-C atom linker only interacts with the substrate-binding si

182 A 4.5-mus all-atom MD simulation of apo-Pin1 suggests that the fluctua

183 Here, we perform multiple all-atom MD simulations of the homomeric 5-hydroxytryptamine

184 ular dynamics (MD) simulations of an 800 000 atom model of SPL C complex from yeast Saccharomyces cer

185 1T-MoS(2) and single-atom modified analogues represent a highly promising cla

186 eed atomic force microscopy (HS-AFM) and all-atom molecular dynamics (MD) simulations to study the be

187 Employing all-atom molecular dynamics (MD) simulations, we established

188 ilic bacterium Thermotoga maritima using all-atom molecular dynamics (MD) simulations.

189 Microsecond-long all-atom molecular dynamics simulations are then calculated

190 used a combination of coarse-grained and all-atom molecular dynamics simulations of a CRAF RBD-CRD co

191 All atom molecular dynamics simulations on EMB in its nucleo

192 coarse-grained structural modeling, and all-atom molecular dynamics simulations-based refinement, an

193 eta-ladder segment of NS1 with extensive all atom molecular dynamics.

194 Single-atom nanozymes (SANs) are one of the newest generations

195 tline the impressive progress made in single-atom nanozymes and we discuss their applications in sens

196 When species contain sparse fluorine atoms, NMR spectra of fluorine-containing spin systems c

197 paradigm that the NCs with continuous metal atom numbers are accessible and crystallizable when meti

198 ical character is detected at the bridging N atom of 1.

199 of dihydrogen are transferred to the same C atom of a triple bond while the other position transform

200 n acyclic iodide through which a pentavalent atom of phosphorus can be introduced via the Arbuzov rea

201 d distances for close contacts between the S atom of SAM and Tyr68 or between any of the H atoms of t

202 rs via the cis form when the terminal oxygen atom of the NOO moiety reacts with the ortho position of

203 (H)tBu led by the insertion of the central C atom of the P=C=C group into the alpha-C-H bond of an iP

204 ional groups directly bonded to the nitrogen atom of the ynamides.

205 ond distances between a broad range of metal atoms of different sizes.

206 mentally new transformation, in which both H atoms of dihydrogen are transferred to the same C atom o

207 Three different atoms of hGGT1 interact with the carboxyl oxygen of the

208 ut numerous examples exist in which isolated atoms of other elements play key catalytic roles.

209 emical analysis, suggest that the two carbon atoms of the L->C(2) complex both have carbene character

210 The contribution of atoms of the protein residues Met40, Tyr68, and Asp141 t

211 tom of SAM and Tyr68 or between any of the H atoms of the transferring methyl group and either Met40

212 es with superatomic nanoclusters rather than atoms offers the possibility of new hierarchical solids

213 mpound to confirm the impact of the selenium atom on EBS photochemical reactivity.

214 Secondary Mo atoms on the surface act as electron pumps that stabiliz

215 tivation, namely direct activation through H-atom or hydride transfer from the sigma-H(2) adducts.

216 eased by electronic relaxation of an excited atom or molecule leads to ionization of a neighboring on

217 nd O(3) (e.g., addition of one to two oxygen atoms) or (*)OH (e.g., addition of one oxygen atom and d

218 de new insights including surface accessible atoms, overall assemblage, and interactions among the mo

219 um iron requirements for these cells (~5,100 atoms per cell).

220 can sustain growth with less than 50 cobalt atoms per cell, ~100-fold lower than minimum iron requir

221 ory calculations support up to 0.48 hydrogen atoms per formula unit of ([Formula: see text])[Formula:

222 ating peptide conjugates with up to 80 boron atoms per molecule.

223 anched conjugates loaded with up to 80 boron atoms per peptide molecule exhibited a maintained recept

224 The intrinsic activity of in-plane chalcogen atoms plays a significant role in the catalytic performa

225 Atom probe tomography of these crystals revealed the pre

226 y, and chart the elemental composition using atom probe tomography.

227 positive charge developing on the C-O carbon atom progressing C-H abstraction.

228 in the field, including multimetallic SACs, atom proximity control, and possible applications for mu

229 Moreover, the heavy-atom QMT takes place with considerable displacement of t

230 ing evidence for a mechanism involving heavy-atom QMT through crossing triplet to singlet potential e

231 tudies with solid-state devices in the giant-atom regime have been limited to superconducting qubits

232 DBE related to aromaticity, number of carbon atoms related to alkylation, and sample.

233 DBO, ANT3310, which uniquely has a fluorine atom replacing the carboxamide and stands apart from the

234 e materials is challenging because the metal atoms reside on surfaces that are typically nonuniform i

235 support users in gaining insights on the key atoms/residues responsible for protein-ligand interactio

236 Here, we use a combination of atom-resolved scanning probe microscopy and density func

237 functionalization occurs at C3 and C2 carbon atoms, respectively, at the indole scaffold in the prese

238 zation and atomic-scale tracking of hydrogen atoms reveal that the segregation of hydrogen atoms at t

239 the potential of porous carbon nanotubes for atom sieving.

240 DR3 loop highly flexible, as observed in all-atom simulations.

241 quickly ejecting proteins, according to all-atom simulations.

242 anthanide polyoxometalates (LnPOMs) as heavy atoms source, which could be used alternatively to UA in

243 In doing so, we show that piecewise all-atom steered molecular dynamics simulations can provide

244 e, we developed a piecewise approach for all-atom steered molecular dynamics simulations to examine s

245 uired by the large water box of standard all-atom steered molecular dynamics simulations.

246 rming reaction opens a straightforward pot-, atom-, step-, and energy-economic access to syntheticall

247 Computationally efficient all-atom structure-based simulations, calibrated against exp

248 of perpetual free-fall, offers to lift cold-atom studies beyond such terrestrial limitations.

249 The iron atoms substitute molybdenum sites in MoS(2) crystals, as

250 er catalysts for a reducing equivalent (an H atom), such that a water-soluble "reactive oxygen specie

251 e synthesis of rare-earth single erbium (Er) atoms supported on carbon nitride nanotubes (Er(1) /CN-N

252 -phonon interaction, which is measured in an atom surface collision.

253 experiments and calculations reveal that Pd atoms tend to migrate into the surface vacancy-enriched

254 ique chemical shift that is attributed to Cs atoms terminating the surface of the particle and which

255 The Fe(1)(II)-O(4) releases a single Fe atom that diffuses into the N-doped carbon defect formin

256 With three basic nitrogen atoms that can be protonated, Hoechst can exist as catio

257 Atom-thin transition metal dichalcogenides (TMDs) have e

258 the active site is formed by an ensemble of atoms, thus introducing further complications in its ide

259 nt Mn(V)-oxo species which can transfer an O atom to a thioether substrate.

260 nantioselective substitution of one fluorine atom to form a stereogenic centre(5,6).

261 that realizes a giant atom by coupling small atoms to a waveguide at multiple, but well separated, di

262 While fullerenes are known to entrap metal atoms to form endohedral metallofullerenes, few metal at

263 radical hydrogenation: cooperative hydrogen atom transfer (cHAT), where each hydrogen atom donated t

264 e mechanism suggests intermolecular hydrogen atom transfer (HAT) chemistry is at play, rather than cl

265 y two types of reactions occur: (a) hydrogen-atom transfer (HAT) from a donor to the peroxyl radical;

266 n of the oxidizing ability of S via hydrogen atom transfer (HAT) from TEMPO-H (2,2,6,6-tetramethylpip

267 reaction is proposed to operate via hydrogen atom transfer (HAT) from the substrate to the photoexcit

268 single electron transfer (SET) and hydrogen atom transfer (HAT) reactions, thus covering all the phy

269 are detailed, enlisting late-stage, hydrogen atom transfer (HAT)-mediated free radical bond formation

270 Surprisingly, 3 is a stronger oxygen atom transfer (OAT) agent than 2-trans; 3 performs OAT t

271 ght-driven, decatungstate-catalysed hydrogen atom transfer and copper catalysis.

272 l radical reactions-cobalt-mediated hydrogen-atom transfer and copper-promoted radical cyanation-to a

273 The developed oxygen atom transfer approach allows the generation of 1,3-oxaz

274 limide-based oxidant and a chloride hydrogen atom transfer catalyst.

275 t that promotes H(2) activation and hydrogen-atom transfer is described.

276 ased redox chemistry in the enzymatic oxygen atom transfer reaction.

277 of 2,3-dichloropyridine N-oxide as an oxygen atom transfer reagent reverses the regioselectivity to g

278 serves as a competent precursor for hydrogen atom transfer to (t) Bu(3) ArO(.) .

279 ince the 1970s to proceed through a hydrogen atom transfer to NiOOH.

280 al generated upon chlorine-mediated hydrogen atom transfer.

281 x-catalyzed C-H arylation and intermolecular atom-transfer radical addition through oxidative quenchi

282 This vapor-phase single Fe atom transport mechanism is verified by synthesizing Fe(

283 to lower temperatures(1,2), gravity empties atom traps that are too weak.

284 s the rate-determining step, indicative of H-atom tunneling being operative.

285 ions have been reported on the role of heavy-atom tunneling in the area of pericyclic reactions, pai-

286 fit with statistical expectations from heavy-atom tunneling when a low-energy sensitizer is employed,

287 and the first example of excited-state heavy-atom tunneling.

288 leic acids, water, ligands and other solvent atoms, using models fitted to or derived from cryo-EM ma

289 Owing to their earth abundance, high atom utilization, and excellent activity, single iron at

290 lectronic and structural properties, maximum atom-utilization efficiency, and outstanding catalytic p

291 direct connection between real space, namely atoms, valence electrons, bonds, and orbitals, and recip

292 The sulfur atom was introduced in a specific benzylic position of t

293 xchanging every hydroxyl group by a fluorine atom, we developed a strategy combining chemical mapping

294 umvent spin-spin broadening, iron and nickel atoms were doped into nonmagnetic [ZnAl]-LDH materials a

295 bicyclic sultams with a bridgehead nitrogen atom) were outlined, and a number of these compounds (in

296 with considerable displacement of the oxygen atom, which establishes a new limit for the heavier atom

297 ining fluorine, chlorine, bromine and iodine atoms, which vary by length and level of halogen substit

298 a THF/c-hexane solution, but abstracts an H atom with formation of the diamagnetic BNB-doped 1H-phen

299 Co, which is hybridized with neighboring Rh atoms with a large spin-orbit interaction.

300 e favors the sequential adsorption of oxygen atoms with facile kinetics.

301 loalkyl group linked via a quaternary carbon atom, with up to 40-fold increased potency against human