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1 effective chain carriers in the lipid chain autoxidation.
2 that are generated enzymatically or through autoxidation.
3 open problem in the kinetics of liquid-phase autoxidation.
4 site that is known to bind O(2) and undergo autoxidation.
5 sis evidenced the advanced stages of the oil autoxidation.
6 nt toxic effects of RCS derived from glucose autoxidation.
7 the design of the PEGylated Hb with minimal autoxidation.
8 urnover is curtailed by the side reaction of autoxidation.
9 lammation, on nitrosation observed during NO autoxidation.
10 lar and electronic structure, and aspects of autoxidation.
11 ogenic NO(x) and localized biogenic SOA from autoxidation.
12 o dopamine neurons, possibly due to catechol-autoxidation.
13 ction, preventing the initiation of catechol autoxidation.
14 endogenous catecholamines are protected from autoxidation.
15 O(2) binding while simultaneously inhibiting autoxidation.
16 s any HOOH produced in the initial stages of autoxidation.
17 believed to be relevant to room-temperature autoxidation.
18 orresponding monocation radical, followed by autoxidation.
19 n stabilizing bound dioxygen with respect to autoxidation.
20 d to protect petroleum-derived products from autoxidation.
21 sis revealed two separate phases of liposome autoxidation.
22 can be initiated but they must compete with autoxidation.
23 o their ability to protect omega-3 oils from autoxidation.
24 n extensive conjugated system, vulnerable to autoxidation.
25 verdin were susceptible to light-accelerated autoxidation.
26 iprotein, was subjected to light-accelerated autoxidation.
27 adicals that play a key role in benzaldehyde autoxidation.
28 concentrations in benzaldehyde, inhibits the autoxidation.
29 compounds to the bilayer protects them from autoxidation.
30 or monitoring reaction progress in inhibited autoxidations.
31 ical under the typical settings of inhibited autoxidations.
32 dole with base followed by a silica-mediated autoxidation, a distinct cascade process occurred, gener
33 pproximately 1.2 microM H(2)O(2) min(-1) via autoxidation, a level sufficient to kill serially dilute
34 eroxide radical expected to be formed during autoxidation, an isotropic free radical is produced with
35 ears to result from a high susceptibility to autoxidation and a low capacity of the cell to reduce it
36 alphaV96W, betaN108K) is stabilized against autoxidation and azide-induced oxidation compared to the
37 These E11 mutations do not slow down the autoxidation and azide-induced oxidation rates of the re
38 alphaL29F) has equivalent or slower rates of autoxidation and azide-induced oxidation than does Hb A,
39 lently cross-linked network through the slow autoxidation and cross-linking of catechol moieties.
41 rophore formation involves an intramolecular autoxidation and does not require exogenous co-factors.
45 ng that they are likely to arise simply from autoxidation and not from reactions with O3 or (1)O2.
48 med using pyridoxamine which blocked glucose autoxidation and RCS production, thus protecting protein
50 eurons occurs through two distinct pathways: autoxidation and the D1 dopamine receptor-linked signali
51 ate electron transfer and to minimize flavin autoxidation and the generation of reactive oxygen speci
53 The ability of excess succinate to block autoxidation and the inhibitory effect of lowering the f
54 K-trait mice that are more susceptible to Hb autoxidation and to hypoxia-induced superoxide productio
55 differs significantly from those for organic autoxidations and for the recently reported examples of
57 rostatic stabilization of bound O2, promotes autoxidation, and enhances hemin dissociation by inhibit
58 tly increased the NADP+ release rate, flavin autoxidation, and NADPH oxidase activity, and caused hyp
59 ate constant for propagation of free radical autoxidation, and the carbon[bond]oxygen BDEs of peroxyl
60 chiff reaction during glycation, via glucose autoxidation, and via hexosamine metabolism under suprap
61 While carboxylic acids produced during the autoxidation are shown to deactivate these more basic RT
65 by the concerted process inhibit hexadecane autoxidations at 160 degrees C to the same extent as the
66 e chemistry is shown to occur in hydrocarbon autoxidations at elevated temperatures without added aci
70 the atmosphere changes to one in which RO(2) autoxidation becomes increasingly important, potentially
71 pherical oligomers that depended on dopamine autoxidation but not alpha-syn oxidation, because mutage
72 eroxide dismutase (SOD) may protect QH2 form autoxidation by acting either directly as a superoxide-s
73 allylic positions in cholesterol suppresses autoxidation by H-atom transfer (HAT) in favor of additi
74 in the hydration layer of Hb and enhance the autoxidation by promoting the nucleophilic attack of hem
79 t methyl hydroperoxide can be produced by an autoxidation chain reaction when ultrasonicating polar a
80 cals that result are highly persistent under autoxidation conditions and undergo very rapid dimerizat
81 ich forms lysine-based pyrroles that lead to autoxidation-dependent protein cross-linking, 3-TFMHD fo
82 examples of sonochemically initiated solvent autoxidation destabilizing single-walled carbon nanotube
86 This mechanism leads to unexpectedly rapid autoxidation even in the presence of water, implying tha
87 ns of oxidative nitrosylation rather than NO autoxidation, explaining why S-nitrosation can compete e
88 mental approaches to investigate the rate of autoxidation for organic peroxy radicals (RO2) produced
89 o coincide with enhanced rates of hemoglobin autoxidation for partially oxygenated intermediates.
90 n of the thiyl radical decreases the rate of autoxidation for the beta-chain and reduces heme degrada
91 e longstanding dogma that cholesterol (chol) autoxidation gives chol 7-hydroperoxide (7-OOH) as the s
94 t on NADP+ release, flavin reduction, flavin autoxidation, heme reduction, reductase activity, or NO
95 sition-state theory study of the atmospheric autoxidation in amines exemplified by the atmosphericall
96 d molecular mechanism, we show that although autoxidation in an archetypal biogenic VOC system become
98 esent study, we examined the role of glucose autoxidation in functional protein damage using lysozyme
100 cine at position 29 of myoglobin can inhibit autoxidation in myoglobin and at position 29 of the alph
103 ion of their kinetic parameters by inhibited autoxidations in the presence of a very strong H-bonding
104 n addition, the spatial propagation of lipid autoxidation increased with the degree of oil unsaturati
112 result of ongoing NO x emission reductions, autoxidation is now competing with bimolecular chemistry
114 rate coefficients greater than 0.1 s(-1) and autoxidation is thus an important atmospheric pathway fo
115 hat increased oxidative stress, due to BH(4) autoxidation, is responsible for the observed BH(4) effe
117 Additionally, GLB-6 exhibits rapid two-state autoxidation kinetics in the presence of physiological O
118 present within protein active sites, glucose autoxidation may be a common mechanism contributing to E
120 nolysis of alpha-cedrene was explained by an autoxidation mechanism initiated by ozone attack at the
121 saturated lipids, we present evidence for an autoxidation mechanism, initiated by hydroxyl radical (O
124 lavin potential indicate that all detectable autoxidation occurs from its FAD site, rather than from
126 id-containing phospholipids were produced by autoxidation of 1-palmitoyl-2-arachidonoyl-sn-glycero-3-
127 ty of this reaction, the copper(II)-mediated autoxidation of 4-tert-butylresorcinol and 4,6-di-tert-b
131 The precise mechanism for the liquid-phase autoxidation of anthrahydroquinone (AnH(2)Q) appears to
132 of ascorbate are hypothesized to involve the autoxidation of ascorbate leading to increased steady-st
135 ) (H(2) O)(40) , making use of the inhibited autoxidation of benzaldehyde in benzyl alcohol solutions
136 cs and regio-/stereochemical outcomes of the autoxidation of both polyunsaturated fatty acids and ste
137 eactive carbonyl compounds are formed during autoxidation of carbohydrates and peroxidation of lipids
139 ard and was implicated previously in aqueous autoxidation of catechols to give ultimately hydroxyquin
141 ic endoperoxides have been detected from the autoxidation of cholesteryl arachidonate by LC-MS and GC
144 coli these oxidants arise primarily from the autoxidation of components of its respiratory chain.
147 rivative spectroscopy to monitor kinetics of autoxidation of cytochromes P450 and applied it to study
154 may therefore underlie the increased rate of autoxidation of Hb S under aerobic conditions, the incre
158 ntity of this product that is generated upon autoxidation of linoleic acid and by decomposition of 13
159 nds were equally effective in inhibiting the autoxidation of linoleic acid in aqueous micelles, with
160 e induction temperature of linoleic acid and autoxidation of linoleic acid in Tween 20 micellar mediu
161 ere confirmed by HPLC to be generated in the autoxidation of linoleic acid promoted by Fe(II)/ascorbi
162 nt activity (radical scavenging activity and autoxidation of linoleic acid) was higher in JE than in
164 s more closely related to that found for the autoxidation of main group and early transition metal al
165 y differential oximetry during the inhibited autoxidation of model substrates: stripped sunflower oil
167 vity of nitrogen oxide species formed during autoxidation of nano- to micromolar levels of NO were ex
169 m the generation of nitrogen dioxide via the autoxidation of nitric oxide, a product of HU metabolism
172 analysis of the product mixture derived from autoxidation of optically pure Ch-15-HpETE by atmospheri
174 s tunnel is proposed to facilitate the rapid autoxidation of oxy-DcrH-Hr and suggests that sensing is
176 nge heme from methemoglobin (metHb) and that autoxidation of oxyhemoglobin to metHb must occur prior
179 that this H2O2 is primarily generated by the autoxidation of redox enzymes within the respiratory cha
186 However, as in the solution experiments, autoxidation of the Hb mutant crystals leads to electron
187 ty, enhanced Bohr effect, and slower rate of autoxidation of the heme iron atoms from the Fe(2+) to t
188 nity and high cooperativity and also ease of autoxidation of the heme iron atoms from the Fe2+ state
190 sion to Met and Asp enhanced the spontaneous autoxidation of the mutants relative to wild-type HbA an
191 ing in CYP3A4, we documented the kinetics of autoxidation of the oxy-ferrous intermediate of CYP3A4 a
192 ion of the PEGylated Hb, we have studied the autoxidation of the PEGylated Hb site-specifically modif
196 litate the analysis of degradation products, autoxidation of the three methine bridges in biliverdin
198 gene encoding NADH dehydrogenase II averted autoxidation of vesicles, and its overproduction acceler
200 roplate reader) in samples from 24 inhibited autoxidations of a lubricating oil, which were carried o
202 ed that the free-radical-mediated oxidation (autoxidation) of cholesterol yields a more complex mixtu
204 . L-1 . min-1) produced either by pyrogallol autoxidation or a hypoxanthine/xanthine oxidase system i
210 onditions (25 and 40 degrees C) to mimic the autoxidation process during real storage conditions.
211 e beta-93 cysteine residue in the hemoglobin autoxidation process has been delineated by electron par
213 ation products accumulated in VOO during the autoxidation process, thus they may be used as early eva
215 roved to be a more potent inhibitor of model autoxidation processes in a polar solvent (acetonitrile)
216 ow here that reaction of nitrite (NO2-), the autoxidation product of nitric oxide (.NO), with hypochl
217 undergo rapid autoxidation, suggesting that autoxidation product(s) acts directly or indirectly on A
218 f beta-carotene-5,6-epoxide, a ROS-catalyzed autoxidation product, and inhibiting accumulation of ant
220 mes were associated with increased levels of autoxidation products (octane, hexanal, C10 hydrocarbons
221 cumin, but it is not known how many and what autoxidation products are formed, nor their mechanism of
223 The resolution and quantification of all autoxidation products by LC-MS/MS was greatly enabled by
226 A1 may participate in the removal of harmful autoxidation products in these tissues, while providing
228 Q-deficient yeast are hypersensitive to the autoxidation products of linolenic acid and other polyun
231 ng [(14)C2]curcumin as a tracer, seven novel autoxidation products, including two reaction intermedia
235 s lipid bilayer radical clock gives relative autoxidation propagation rate constants of arachidonate
241 urbed the heme environment and increased the autoxidation rate of Hb, which is at a higher level than
244 nt technique and enabling measurement of the autoxidation rate over a wide range of temperatures, yie
248 vel presentation of the oxygen dependence of autoxidation rates that uses heme saturation, rather tha
249 n hemoglobin was also assessed by evaluating autoxidation rates using recombinant Hb tetramers contai
252 tep (alpha --> alpha3), followed by a slower autoxidation reaction that promotes the assembly of high
253 physiological pH and rapidly degrades in an autoxidation reaction to a major bicyclopentadione produ
254 Accordingly, by using LC-MS, we screened autoxidation reactions of 11-hydroperoxy-eicosatetraenoi
255 ified kinetic theory for both initiation and autoxidation reactions of Et3B and O2 is put forth, and
256 otopologues, the precursors to a sequence of autoxidation reactions that ultimately yield HOMs in the
261 e heme cavity of the extreme oxygen-avid and autoxidation-resistant oxy-myoglobin complex from the tr
262 nt forms a stable oxy adduct; instead, rapid autoxidation results in formation of the corresponding m
263 y, high cooperativity, and stability against autoxidation, rHb (beta N108Q) is considered a potential
265 and Fe(II)-MetAP enzymes are susceptible to autoxidation, so strict care must be taken to remove all
269 be linked to their tendency to undergo rapid autoxidation, suggesting that autoxidation product(s) ac
271 oignition and are implicated in tropospheric autoxidation that can form low-volatility, highly oxygen
274 ough NO(2) was not a component of aqueous NO autoxidation, the results suggest that the intermediacy
275 amounts of oleic acid will be more prone to autoxidation, thus potentially having greater impact on
276 ercepting reactive intermediates of aldehyde autoxidation to aerobically generate hypervalent iodine
277 e-buffered saline (PSB), HQ underwent a slow autoxidation to BQ, which was accelerated by Cu/Zn-SOD,
279 se and glucose have been reported to undergo autoxidation to generate reactive oxidative species (ROS
281 assembly of the I-ring; discovery of a novel autoxidation to introduce the C(22) tertiary hydroxyl gr
282 ration, either in vivo or in vitro, involves autoxidation to methemoglobin, followed by cofactor loss
284 albumin (BSA) (PBS/BSA), HQ did not undergo autoxidation to SQ-., and as such the presence of SOD wa
286 he nitrite-forming reaction (which may be NO autoxidation under these conditions) competes with react
289 e induced by radicals generated from sulfite autoxidation using cyclic voltammetry (CV) and electroch
294 ucing power, and inhibition of linoleic acid autoxidation were significantly enhanced after appropria
295 ilize the ferrous-O2 complex with respect to autoxidation, which should result in partial uncoupling
296 ced responses were lost when we inhibited Hb autoxidation with CO or nitrite, or when the H(2)O(2) in
298 dant load and ability to prevent lipid chain autoxidation, within the inner mitochondrial membrane of