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1 s to be nonplanar, thus making the molecules axially chiral.
2 lodextrin-based pseudo[3]rotaxane containing axially chiral 1,1'-binaphthyl and photoresponsive azobe
3 romophore by orthogonally tethering a single axially chiral 1,1'-binaphtyl moiety to it.
4 ol at -115 degrees C provided a range of new axially chiral 1,3-disubstituted alkoxyallenes in a dias
5                                              Axially chiral 1,8-bis(2,2'-diphenyl-4,4'-diquinolyl)nap
6             Despite severe steric hindrance, axially chiral 1,8-bis(3-(3',5'-dimethylphenyl)-9-acridy
7                  The syn and anti isomers of axially chiral 1,8-diquinolylnaphthalenes have been synt
8                                              Axially chiral 2-(2-(trifluoromethyl)-1H-benzo[d]imidazo
9                                    Nonbiaryl axially chiral 2-pyridones were synthesized and employed
10 N-aminocarbonyl directing group afforded C-N axially chiral acrylamides with the assistance of a race
11 this report, two classes of tetrasubstituted axially chiral acyclic olefins have been accessed in exc
12 light-mediated, enantioselective approach to axially chiral alkenes is described.
13 orus ylides to afford highly enantioenriched axially chiral alkenes.
14 ynes can produce a stereogenic center and an axially chiral allene simultaneously.
15 t the newly generated stereogenic center and axially chiral allene.
16 d to previously reported synthetic routes to axially chiral allenes (ACAs) from prochiral substrates,
17 ols, and 2-allenyl indoles that possessed an axially chiral allenyl moiety occurred with transfer of
18                                        These axially chiral alpha-oxoamides undergo enantiospecific p
19   Furthermore, asymmetric crotylborations of axially chiral amides were studied in detail.
20 roduce a novel design strategy to achieve an axially chiral and rigid perylene bisimide (PBI) dye by
21     Finally, the subsequent conversion to an axially chiral anilino alcohol is also reported.
22                                              Axially chiral atropisomers have energetic barriers to r
23  the N-phenyl moiety were found to be stable axially chiral atropisomers.
24             We report efficient syntheses of axially chiral biaryl amides in yields ranging from 80-9
25 barriers to enantiomerization of a series of axially chiral biaryl analogues of 4-(dimethylamino)pyri
26 ue arising from restricted rotation about an axially chiral biaryl bond.
27                               We report that axially chiral biaryl boronic esters can be generated wi
28                                              Axially chiral biaryl compounds are frequently encounter
29                                              Axially chiral biaryl compounds are ubiquitous scaffolds
30 Desymmetrization of prochiral diols provides axially chiral biaryl compounds with er up to 99:1.
31 kinetic resolution of secondary alcohols and axially chiral biaryl compounds with selectivity factors
32  aromatic substitution reaction which yields axially chiral biaryl derivatives in excellent yields wi
33 ers a direct route to highly enantioenriched axially chiral biaryl monophosphine oxides that are diff
34 d of any symmetry as they possess one or two axially chiral biaryl or N-arylindolyl bridges along wit
35 w approach for atropselective preparation of axially chiral biaryl was developed.
36  by atroposelective allylation to synthesize axially chiral biaryls from its racemic precursor.
37                          The racemization of axially chiral biaryls is a fundamental step toward tran
38                                              Axially chiral biaryls, as exemplified by 1,1'-bi-2-naph
39  asymmetric Suzuki-Miyaura cross-coupling to axially chiral biaryls, in particular for the most chall
40  to one single enzyme in the biosynthesis of axially chiral biaryls.
41 rch attention, with most studies focusing on axially chiral biaryls.
42                                          The axially chiral bicyclic thioketones 11 and 15 were prepa
43 systems are generated after formation of the axially chiral binaphthalene framework.
44                                     Using an axially chiral binaphthyl derivative and a borane photos
45                                              Axially chiral binaphthyl salts are shown to bind chiral
46                           Interestingly, the axially chiral biphenyl was found to be configurationall
47 ing (-)-sparteine-mediated annelation of the axially chiral bis(aryllithium) with electrophilic sulfu
48 phonates resulting in highly enantioenriched axially chiral bisphosphine oxides and bisphosphonates.
49            The experiments were done with an axially chiral borane that was introduced by us a few ye
50   A good turn: Three compounds that bear two axially chiral bridged binaphthyl units were developed a
51 he initially assigned stereochemistry of the axially chiral C6-C7 linkage may require revision.
52 inoids inspired by cannabidiol (CBD), termed axially chiral cannabidiols (axCBDs).
53           Finally, we provide an analysis of axially chiral cannabinoid (axCannabinoid) atropisomeris
54          We also introduce a second class of axially chiral cannabinoids inspired by cannabidiol (CBD
55                                              Axially chiral cannabinols (axCBNs) are unnatural cannab
56            However, enantiopure mechanically axially chiral catenanes in which the mechanical bond pr
57  reaction temperature and the ability of the axially chiral chromophore to form intramolecular and/or
58 tter having more complex architectures since axially chiral chromophores or multichromophore systems
59 is of both enantiomers (R/S) of 10 different axially chiral chromophores.
60 ances the field of biocatalytic synthesis of axially chiral compounds.
61 atalysts to deliver two important classes of axially chiral compounds: structurally diverse NOBIN ana
62 iamine ligands with pendant groups that have axially chiral conformations.
63 adily accessible, enantiomerically pure, and axially chiral contorting element, benzodinaptho[1,4]dio
64                                           An axially chiral, cyclic borane decorated with just one C6
65                                              Axially chiral cyclohexylidene oxime ethers exhibit uniq
66 atalytic enantioselective synthesis of novel axially chiral cyclohexylidene oximes has been developed
67 L(4) cages prepared from ligands based on an axially chiral diamino-[1,1'-biazulene] motif (serving a
68          A seven-step total synthesis of the axially chiral, dimeric tetrahydroxanthone natural produ
69    The general enantioselective synthesis of axially chiral disubstituted allenes from prochiral star
70 oyment of N-phenoxycarboxamide delivered C-C axially chiral enamides via migration of the oxidizing d
71  enantiopure cyclophanes by the insertion of axially chiral enantiomeric binaphthyl fluorophores into
72  deprotonation resulted in an (M)-configured axially chiral enolate.
73 ractical synthesis of structurally different axially chiral entities.
74                                              Axially chiral five-membered heterobiaryls synthesized b
75 nriched dihydrofuran precursors gave rise to axially chiral furans with high enantiopurities accounti
76 and 1,3-dicarbonyl compounds catalyzed by an axially chiral guanidine is investigated by density func
77 NAP as the ligand provides the corresponding axially chiral heterobiaryl amines with excellent yields
78          Our investigations demonstrate that axially chiral heterocyclic and biphenyl compounds can a
79  substituted phenyl ring is expected to form axially chiral hydroxylated metabolites (OH-PCBs); howev
80 lkyne addition to nitrones utilizing tunable axially chiral imidazole-based P,N-ligands.
81 ith a mild phosphine oxide reduction method, axially chiral imidazoles such as StackPhos and its deri
82 rization method that enables rapid access to axially chiral imidazoles with the basic nitrogen at the
83         To confirm the role of stereolabile, axially chiral intermediates in these reactions and to d
84 yde and an allyl alcohol, catalyzed by using axially chiral iridium phosphoramidites PR/S-Ir and cinc
85                Ruthenium complexes employing axially chiral ligands were found to be effective asymme
86 oiting the diastereoselective addition of an axially chiral lithiated alkoxyallene to an enantiopure
87                 This is because colchicine's axially chiral methoxytropone-trimethoxybenzene (called
88 e report a catalytic asymmetric synthesis of axially chiral methylenecyclopropanes by a [2 + 1]-cyclo
89          With methods to access mechanically axially chiral molecules in hand, their properties and a
90       In drug delivery, the incorporation of axially chiral molecules in systematic screening has als
91  However, there are less explored classes of axially chiral molecules that may also hold significant
92 rovide straightforward access to central and axially chiral molecules.
93 ess has been developed that allows access to axially chiral molecules.
94 ocatalysts' toolbox to construct challenging axially chiral molecules.
95 tructurally diverse NOBIN analogs as well as axially chiral N-aryl sulfonamides in excellent enantiop
96 n of fluxional into configurationally stable axially chiral N-arylpyrroles was achieved with a highly
97 enantiomer excess, ee) avenue to produce N-C axially chiral N-heterocycles, i.e., N-arylindoles from
98  of the process is the use of newly designed axially chiral N-heterocyclic carbene-gold catalysts.
99 l diimine ligands with backbones that become axially chiral on coordination to metal centers, achiral
100                                              Axially chiral open-chain olefins represent an underexpl
101                Despite the widespread use of axially chiral, or atropisomeric, biaryl ligands in mode
102                                              Axially chiral organic scaffolds, such as helicenes or t
103 ers are composed of diastereomerically pure, axially chiral (P or M) BODIPY monomers containing a pen
104              These findings demonstrate that axially chiral PCB metabolites are formed from axially p
105 on of a highly rigid and, simultaneously, an axially chiral perylene core.
106                                              Axially chiral phenols are attractive targets in organic
107 us centres to rapidly construct libraries of axially chiral phosphines through dynamic kinetic resolu
108      In the presence of catalytic amounts of axially chiral phosphoric acids, achiral N,N'-binaphthyl
109 out to afford the valuable P-stereogenic and axially chiral phosphorylated 1,2'-binaphthyl ring syste
110 hexanone with formation of the corresponding axially chiral R-configurated alcohols (up to 99% ee) wa
111 lective (70% ee) synthesis of a mechanically axially chiral rotaxane.
112 en azobenzene motif is directly linked to an axially chiral scaffold through a C-C bond.
113 g allenes, biaryls, arylamides and transient axially chiral short-lived species are discussed.
114 ficient and highly enantioselective route to axially chiral spirobiindanediones.
115 zide-derived 5,5'-bistriazoles possess rigid axially chiral structures with a broad distribution of d
116                                        These axially-chiral structures are much sought-after building
117  demonstrated the synthetic utility of these axially chiral styrenes.
118 e identified and applied in the synthesis of axially chiral styrenes.
119  of azobenzene derivatives decorated with an axially chiral substituent.
120                                A new type of axially chiral sulfonic acid was developed.
121 ation of propargylic difluorides to generate axially chiral, tetrasubstituted monofluoroallenes in bo
122   The isomer compositions of the synthesized axially chiral thiohydantoins have been determined throu
123                                   Nonracemic axially chiral thiohydantoins were synthesized atroposel
124                             A stereodynamic, axially chiral triaryl probe is locked into a single con
125                                              Axially chiral trifluoromethylbenzimidazolylbenzoic acid
126 for gamma-substituted allene ethers that are axially chiral, very high enantiomeric excesses of cyclo
127                    The dimers, which all are axially chiral, were resolved into their enantiomers by
128               The challenges with the double axially chiral YanPhos, bearing an N-benzyl BINOL-phosph
129 ctron demand 1,3-dipolar cycloaddition of an axially chiral, yet configurationally unstable, intermed

 
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