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1 ctivity, geometry, topology, and dynamics of bonding.
2 van der Waals gap and soft intralayer In-Se bonding.
3 ouble-halide perovskite material via halogen bonding.
4 eric effect, including pai-conjugation and H-bonding.
5 harge transfer (LMCT) induces the aurophilic bonding.
6 e distance typically observed for aurophilic bonding.
7 nce (or resonance) as the origin of chemical bonding.
8 cal intermolecular and transannular hydrogen bonding.
9 dentifies characteristic features of halogen bonding.
10 rther reveals the important roles of surface bonding.
11 ion (RIR) via intra- and interlayer hydrogen bonding.
12 posing effect on metal-ligand sigma- and pai-bonding.
13 ly with respect to the nature of thiol-metal bonding.
14 in fibrous network structure and interfiber bonding.
15 is significantly reduced in networks with H-bonding.
16 for the excited-state turn-on of aurophilic bonding.
17 s excited states with significant aurophilic bonding.
18 rials due to the strong interatomic metallic bonding.
19 rganocatalysis, anion transport, and halogen bonding.
20 idues that have a high capacity for hydrogen bonding.
21 lar structure stabilized by intermolecular H-bonding.
22 substrates by van der Waals liquid capillary bonding.
23 , highly interconnected in-plane 2D hydrogen bonding (2D-HB) network at the ionic interface, reminisc
25 plays a central role in the understanding of bonding across a range of biological, chemical and physi
28 rt to their similar capacity toward hydrogen bonding and ability to reliably engender defined conform
29 ies that form robust intermolecular hydrogen bonding and are tethered to naphthalic anhydride with th
30 tion energy for halogen rather than hydrogen bonding and by an electron density topology analysis tha
33 T studies have been used to help explain the bonding and electronic structure in these unique diiron-
34 clic aromatics and quantitatively assess the bonding and electronic structure of acene hydrocarbons.
37 o hundred-fold, in comparison to the halogen bonding and hydrogen bonding heteroditopic receptor anal
38 bly of Abeta oligomers is driven by hydrogen bonding and hydrophobic packing of the residues from the
39 self-assembly in water by a combination of H-bonding and hydrophobicity and to impart specific respon
41 standing of the correlation between chemical bonding and lattice dynamics in intrinsically low therma
42 ion (including disruption of strong hydrogen bonding and novel conformer formation) and any associate
43 nide CaO(3) crystal that exhibits intriguing bonding and oxidation states with profound geological im
44 High pressure can drastically alter chemical bonding and produce exotic compounds that defy conventio
47 These examples suggest that both hydrogen-bonding and stacking interactions can result in increase
48 balance of water-water versus water-surface bonding and the ease with which hydrogen-bond exchange c
50 We demonstrate how the unique directional bonding and varying basicity of the decaniobate ([Nb(10)
51 ic combination of a chemical force (hydrogen bonding) and magnetic dipole coupling to assemble polyme
52 and/or hydrophobic), sp(2)O-sp(2)N (hydrogen bonding) and sp(3)C-sp(2)C (CH-pai and/or hydrophobic).
54 ew intramolecular or intermolecular hydrogen bonding, and improve the thermal behavior and crystallin
56 its sensitivity to the protonation state, H-bonding, and the conformation of different groups in pro
57 fastening, conventional welding and adhesive bonding are examples of techniques currently used for th
58 cause of the exotic nature of their chemical bonding as they contain both metal-metal and metal-main
60 cientific interest in chemical structure and bonding, as nitrogen is uniquely situated in the periodi
62 vex side due to a difference in metal-carbon bonding at the curved surfaces as confirmed by density f
64 mechanism is due to intermolecular hydrogen bonding between ADD and AA, which was confirmed by Densi
65 Current cell-wall models assume no covalent bonding between cellulose and hemicelluloses such as xyl
67 ay of experimental techniques to propose the bonding between inorganic and MOF domains, and show that
71 =Co(III) canonical form with significant pai-bonding between the cobalt centers and the nitride atom.
75 ilization effects of intermolecular hydrogen bonding between the side-chain functionalities and TBD i
76 that charge-charge interactions and hydrogen bonding between the suramin sulfonated groups and Arg/Ly
80 addition of ancillary groups (e.g., hydrogen bonding, Bronsted acid/base) near the active site of met
81 ons demonstrate that intramolecular hydrogen bonding can stabilize Boat, whereas electron repulsive i
83 nal 3,6-cycoladdition, the enhanced hydrogen bonding capability of HFIP uniquely results in promotion
84 son to control structures that lack hydrogen bonding capability, resulting in lower surface area and
85 ion spectroscopy evinces ultrafast chalcogen-bonding cascade switching in the excited state in soluti
86 erocyclic azadiene cycloaddition by hydrogen bonding catalysis but also the first to alter the mode (
87 rticular, the detection of protonation and H-bonding changes in a time-resolved manner, not easily ob
88 ct states in the band gap retaining the anti-bonding character of the valence band maximum which is b
89 Nitride materials feature strong chemical bonding character that leads to unique crystal structure
90 dynamic reversible covalent and non-covalent bonding chemistries for self-healing polymers, an ultima
91 n involves incorporation of "triple hydrogen bonding clusters" (THBCs) as side groups into the hydrog
93 ts reveal generic backbone-backbone hydrogen bonding constraints as a determining factor in governing
96 instead, our results indicate that these two bonding contributions generally interplay in more subtle
97 is study, the intra-atomic (antibonding) and bonding contributions to the total molecular energy of t
98 F(3), respectively) and its influence on the bonding, crystal packing as well as the excited state en
100 e(105) for a serine, located within hydrogen-bonding distance to Asp(22), would change the microenvir
101 monogamous prairie voles, we found that pair bonding does not elicit differences in overall nucleus a
102 at organic molecules' low number of hydrogen-bonding donors and small topological polar surface area
103 eworks (ZIFs), i.e., reversible metal-linker bonding, driven by specific vibrational modes, can be ob
107 h its unique capability of sampling chemical bonding element-specifically ((1/2)H, (13)C, (14/15)N, (
108 -1,110 cm(-1)) and C-OH (1,239-1,030 cm(-1)) bonding endows the selective emissivity of 78% in 8-13 m
109 te entities because of the difference in the bonding environment and are often investigated separatel
110 troscopy to study the distribution and local bonding environment of Y and Nd, as proxies for heavy an
111 ry is characterized by C-N double and triple bonding environments distinct from what is usually found
116 d-to-side" delta and "side-to-side" phi back-bonding, found in complexes of metallacyclopropenes and
119 eters, including primary sequence, disulfide bonding, glycosylation patterns, biotransformation, and
121 , highly active catalysts or highly reactive bonding groups, as is done in classical DCC, is often no
124 and iodide halide anions, with the chalcogen bonding heteroditopic receptor notably displaying the la
125 dynamics associated with the local chemical bonding hierarchy in Zintl compound TlInTe(2) , which ca
127 FeO(2) and XeFe(3)O(6) with significant Xe-O bonding in a wide range of pressure-temperature conditio
129 sults suggest that gold-ion-induced hydrogen bonding in an actual solvent environment may be feasible
132 cations, in which 3-center-2-electron sigma bonding in Ge(2) Zn or Ge(2) Cd triangles plays a vital
133 more, the dynamic nature of the coordination bonding in M/COF-DB allows for the easy replacement of m
135 e demonstrated covalent cellulose-xyloglucan bonding in plant cell walls and showed that CXE and MXE
136 in the molecular mechanisms underlying pair-bonding in prairie voles and paves the way to further ou
138 al angles accompanying transannular hydrogen bonding in the [3.3]paracyclophane and (b) monomer entro
139 the structure models, the nature of chemical bonding in the molybdates is explained by molecular orbi
140 evidenced a role for K14-dependent disulfide bonding in the organization and dynamics of keratin IFs
141 ations create a generalized paradigm for M-M bonding in the transition-elements periods, and Pauli re
143 alization of the nature of metal-metal (M-M) bonding in transition-metal (TM) complexes across the pe
147 ation (occurring by intramolecular chalcogen bonding) in determining the conformation, equilibrium po
149 n, a unified picture of metal-ligand surface bonding-induced chirality for the nanoclusters is propos
150 cceptors (-F, -Cl, -Br, -OR) establish the H-bonding interaction strength for the -CF(2)H group (~3 k
151 site, Asn(255) engages in a unique hydrogen-bonding interaction with the target histidine of actin t
153 (II) ions are held together, within range of bonding interaction, by the hexa-amide, hexaphenolate ma
154 f interfacial water, as well as the hydrogen-bonding interactions and conformational motions of inter
155 Substituting Ge for Sn weakens the {Ge,Sn}-S bonding interactions and increases the charge density as
156 g analyses suggest the formation of hydrogen-bonding interactions between the flavin and Arg65 in the
157 f the mu-OH(-) ligands and the presence of H-bonding interactions between the mu-OH(-) bridging ligan
159 (32), as well as the possibility of hydrogen-bonding interactions between Y(32) and E(13), through st
161 ational flexibility of Y731 and the hydrogen-bonding interactions of both Y731 and Y356 with interfac
163 pocket" stitches the gelators through weak H-bonding interactions to facilitate the formation of an o
164 nical binding motif, but with fewer hydrogen-bonding interactions to the protein than is observed in
166 )ethylammonium and their asymmetric hydrogen-bonding interactions with lead bromide-based layers caus
167 10-phenanthroline provides highly directed H-bonding interactions with Pd-coordinated substrates.
169 widely recognized, its influence on chemical-bonding interactions, and on consequent material propert
170 number of OH functions and their inherent H bonding interactions, but also the wide range of polyol
171 predominantly limited to exploiting hydrogen-bonding interactions, while the relevant atomic-level bi
176 eased the enzyme-mediated degradation of the bonding interface by inhibiting collagenolytic activity.
177 sile bond strength (uTBS), characterized the bonding interface with an atomic force microscope, condu
179 eases the stiffness of the mat; however, the bonding is more effective at stiffening when the porosit
180 uring incorporation, this base pair hydrogen bonding is not sufficient to hold an ATP substrate in th
181 Additionally, a limiting case of hydrogen bonding is observed when the benzamide derivatives are r
184 ruptions of D2 loop intramolecular disulfide bonding lead to haploinsufficiency-related RP, but rathe
186 ectral studies revealed that the anion-anion bonding led to the formation of crystals comprising 2D l
187 ions including slow adhesion formation, weak bonding, low biocompatibility, poor mechanical match wit
188 t high loading rates, giving rise to a catch bonding mechanism that manifests under force ramp protoc
189 intermolecular interactions such as hydrogen bonding, metal-ligand coordination, and the hydrophobic
190 ing (e.g., guest-host interactions, hydrogen bonding, metal-ligand coordination, grafted biopolymers)
191 om or less, even in the presence of hydrogen bonding, metal-metal bonding, and electrostatic interact
192 mal zerovalent germanium core and a peculiar bonding mode of sp(2)-Ge@(PdPPh(3))(3) trigonal planar s
193 transitions), we present a unifying dynamic bonding model for LnB(6) that explains simultaneously Eu
195 sists of a trimerization via an unidentified bonding motif of prochiral 9-ethynylphenanthrene (9-EP)
197 e phases, but also the very similar chemical-bonding nature between crystalline PCMs and one of the b
198 The accessibility, relative energetics, and bonding nature of the states involved dictate the proper
199 in, we highlight that non-classical hydrogen bonding (NCHB), likely resulting from hyperconjugation,
201 )Se while reducing the dimensionality of the bonding network connecting the Bi(2)O(2)Se units to allo
204 ly of compounds is endowed with an extensive bonding network in the protein active site, including th
205 ve additional changes in a delicate hydrogen-bonding network that further stabilized S1-S3 sites.
206 en uses an arginine/lysine-mediated hydrogen-bonding network to reposition the asparagine in the McrB
208 eratures, transient tetrahedral domains of H-bonding networks are evidenced and the observation of th
209 R spectroscopy to study how alkanol hydrogen-bonding networks confined within hydrophobic and hydroph
212 aking place at an atomic level and colloidal bonding occurring at the length scale two orders of magn
213 n reaction is severely hampered by the tight-bonding of active centers with hydroxyl group intermedia
215 cidate thermodynamic behaviors, non-covalent bonding of coacervates, and microstructure of coacervate
216 ed enamines promoted by the solvent hydrogen bonding of hexafluoroisopropanol (HFIP) that is conducte
217 ion as 2-Tb but with both side-on and end-on bonding of the N(2) unit in the same crystal, [K(crypt)]
219 ibrational and photoemission spectroscopies, bonding of the two peptides to TiO(2) surfaces (either n
221 e acid treatment is capable of weakening the bonding of zigzag octahedral chains in anatase TiO(2) ,
223 other evolved faculties, evolved for social bonding, or evolved to signal mate quality - are incompl
224 onal fiSAPT energy decomposition and natural bonding orbital analyses correlated with experimental da
227 gaments/cartilages and bones, we report that bonding ordered nanocrystalline domains of synthetic hyd
228 motor for recognition of different hydrogen-bonding organocatalysts a greater than 10-fold modulatio
229 yields rather unusual U-O(ArO) and U-N(tacn) bonding parameters for the metal-tris(aryloxide) interac
232 adhesives that achieved equivalent/enhanced bonding performance suggest great potentials in developi
234 ss, which highlights the ability of hydrogen bonding phase-transfer catalysts to couple two ionic rea
235 w 5hmC-specificity that mirrors the hydrogen bonding potential of the side chain (C-H < S-H < O-H).
236 OXTR in male and female titi monkeys, a pair-bonding primate species that exhibits biparental care of
237 networks, and pathways involved in the pair-bonding process in the nucleus accumbens, our work illus
239 ities to design novel materials, where the H-bonding properties of peripheral NH hydrogens could serv
240 Furthermore, it could be shown that the bonding properties of the (i)Pr group are similar to tho
242 Formula: see text] and Co[Formula: see text] bonding quantified by exploiting the known exposed surfa
244 xxxS(44)xxxG(48)) together with a patch of H-bonding residues (T(51), T(54), N(55)) sideways along TM
245 ural behavior follows directly from hydrogen-bonding restrictions and suggests that the protein secon
247 ovalent interactions like H-bonding, solvent bonding, S-H...pai, C-H...pai, pai-pai stacking, charge-
249 n stabilized in L->C(2)<-L compounds but the bonding situation of the central C(2) in this motif diff
250 al interaction mechanisms of Ti-O-C covalent bonding, sliding of MXene nanosheets, and pai-pai bridgi
252 zes multiple noncovalent interactions like H-bonding, solvent bonding, S-H...pai, C-H...pai, pai-pai
253 In particular, moderate-strength hydrogen bonding stabilizes a cobalt(III)-superoxo species formed
254 to molecular excitation to a repulsive anti-bonding state, in which recoil of the dissociation produ
255 nB(6) family, also easily access alternative bonding states through the electron-phonon coupling.
256 trongly on the secondary structure (hydrogen bonding status) of the oligonucleotides, but neither on
261 es of polyacrylate networks with differing H-bonding strength were undertaken; it was found that the
262 ter in hydrophobic pores alters its hydrogen bonding structure and related properties such as dielect
263 ation on exact proton locations and hydrogen bonding structures in a bona fide metalloenzyme proton p
264 ture between crystalline PCMs and one of the bonding subgroups (with the same bond length) found in a
265 -1,4-benzodioxanes bearing a small, hydrogen-bonding substituent at the 7-, 6-, or 5-position of benz
267 dispersed throughout the catalyst via alloy bonding; such catalysts combine the traditional advantag
268 ing mechanisms involving reversible covalent bonding, supramolecular chemistry, or polymers with phas
269 Our work bridges the gap between covalent bonding taking place at an atomic level and colloidal bo
271 ellulose, including the key role of hydrogen bonding, the dependence of structural interfaces on the
272 dW interactions do not allow H(2)O-diester H-bonding, thus forcing nBA side groups to adapt L-shape c
273 second water molecule stabilized by hydrogen bonding to a Gln side chain in the active site, offering
274 amic covalent polymer that facilitates tight bonding to itself and other surfaces, as a soft, elastic
275 iose binding, suggesting additional hydrogen bonding to terminal GalNAc of Gb4 and the urea group.
276 water decorates the metal channels, hydrogen bonding to the exposed O ligands that bind bitartrate to
277 e regeneration at nonosseous sites, and bone bonding to the implant was demonstrated at the ultrastru
282 reaction revealed that nonclassical hydrogen bonding was involved in the stabilization of the Michael
284 hat the footprint reflects SASA and hydrogen bonding, whereas one drawback is the labeling is reversi
285 rucial roles of charge capacity and hydrogen bonding, which can help elucidate the mechanisms of othe
286 to their inherently strong covalent or ionic bonding, which usually leads to material crazing and bri
287 rganization converts reactants' to products' bonding, will accelerate reactions, control regioselecti
292 h potency, likely because of strong hydrogen bonding with the RNA backbone of C2469, as suggested by
293 uoride, within 3, occurs through NH...F(-) H-bonding with the six NH residues of the tris-urea ligand
294 e charge capacity (of the site) and hydrogen bonding (with the intermediates), which were neglected/o
295 y arguing that CSBs are a distinct family of bonding, with a potential to bring about a Renaissance i
297 tructural features, such as steric fit and H-bonding within the active site for proper alignment with
298 effect has been proposed, whereby changes in bonding within the solid-electrolyte host framework modi
300 ient binding of guest molecules, but dynamic bonding would explain important MOF phenomena in catalys