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1 ture TpNi(III)(R)(R(1)) (Tp = tris(pyrazolyl)borate).
2 ment and inhibition by 2-aminoethoxydiphenyl borate).
3 e following order: phosphate > bicarbonate > borate.
4 cked by nifedipine and 2-aminoethoxydiphenyl borate.
5 arbonate, hydroxide, hydrogen phosphate, and borate.
6 erion, i.e. bromide vs tetrakis(1-imidazolyl)borate.
7 ted by PTx, La(3+), or 2-aminoethoxydiphenyl borate.
8 affeine, ryanodine, or 2-aminoethoxydiphenyl borate.
9 riphenylmethylium tetrakis(pentafluorophenyl)borate.
10 tly or after activation to the corresponding borate.
11 r gelation of water by guanosine and lithium borate.
12 idic aryl and alkyl boranes to various alkyl borates.
13 bond in 2-ammoniophenyl(aryl)- or -(alkenyl)borates.
14 e) = hydridotris(3,4,5-trimethylpyrazol-1-yl)borate].
15 he potassium salt of the monoanionic bis(NHC)borate 1 (NHC = N-Heterocyclic Carbene) enables the synt
16 osphate receptors with 2-aminoethoxydiphenyl borate (100 mum), depletion of intracellular Ca(2+) stor
18 to 1 afforded the alkali metal disilicon(0) borates 1M[BAr4] (M = Li, Ar = C6F5; M = Na, Ar = Ar(F))
22 d during application of 2-aminoethyldiphenyl borate (2-APB) to activate a nonselective cation conduct
23 permeation behavior of 2-aminoethoxydiphenyl borate (2-APB), a broad-spectrum modulator for a number
25 activation pathway as 2-aminoethoxydiphenyl borate (2-APB), a common agonist for these TRPV channels
26 e-independent manner by 2-aminoethyldiphenyl borate (2-APB), a small molecule with complex pharmacolo
28 native cells, including 2-aminoethyldiphenyl borate (2-APB), SKF96363, and removal of extracellular C
29 powerful SOC modifier, 2-aminoethoxydiphenyl borate (2-APB), the mechanism of which has eluded recent
30 zing the SOCE modifier 2-aminoethoxydiphenyl borate (2-APB), we demonstrate that 2-APB-activated stor
34 e of an IP3 R blocker (2-aminoethoxydiphenyl borate, 2-APB), or during block of IP3 production by the
35 zation, but La(3+) and 2-aminoethoxydiphenyl borate (a dual inhibitor of inositol 1,4,5-triphosphate
36 receptor blocker, and 2-aminoethoxydiphenyl borate, a nonselective storeoperated Ca(2+) entry channe
37 This assay was also used to evaluate serine-borate, a well-known inhibitor of GGT1, which was 8-fold
39 made from uniaxial birefringent alpha-barium borate (alpha-BBO) or calcite crystals that overcome the
40 ium were attenuated by 2-aminoethoxydiphenyl borate, an inhibitor of store inositol trisphosphate rec
43 ral Ni(IV) complex ligated by tris(pyrazolyl)borate and a cationic octahedral Ni(III) complex ligated
44 sium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate and calcium ionophore IV (ETH 5234) or calcium io
45 In this work, we demonstrate novel phenyl borate and carborane-based anions paired with a near-inf
46 ment, where Tp' = tris(3,5-dimethylpyrazolyl)borate and L = neopentyl isocyanide, is used to investig
47 agmas in the early Hadean eon, may have made borate and molydate species available to prebiotic chemi
49 plexes 1-15, where Tp is a N,N,N-tris(azolyl)borate and P is a tertiary phosphine, have been synthesi
50 ibonucleosides stabilized by borate mobilize borate and phosphate from luneburgite, and are then regi
52 is of potassium trifluoro(N-methylheteroaryl)borates and their use in cross-coupling reactions with v
53 (Tp(tBu) = hydro-tris(3-tert-butyl-pyrazolyl)borate) and investigated the influence of the trifluoroe
54 b = phenyltris(3-methyl-imidazolin-2-ylidene)borate) and triethylamine as well as N,N-dimethylaniline
55 = phenyltris(3- tert-butylimidazol-2-ylidene)borate), and [Fe(V)(O)(TAML)](-) (5, TAML(4-) = tetraami
56 PM7 blockers Gd(3+) or 2-aminoethoxydiphenyl borate, and by knockdown of TRPM7 channels with small in
57 ing three non-denaturing aqueous (phosphate, borate, and carbonate) buffers at various conditions of
58 of three non-denaturing aqueous (phosphate, borate, and carbonate) buffers at various ionic strength
60 he presence of aqueous potassium tetraphenyl borate, and its competence as an intermediate was demons
63 dium tetrakis[3,5-bis(perfluorohexyl) phenyl]borate, and one of four fluorophilic Ag(+)-selective ion
64 odium tetrakis[3,5-bis(perfluorohexyl)phenyl]borate, and one of four fluorophilic H(+)-selective iono
65 als are all involved in bonding in a Cf(III) borate, and that large crystal-field effects are present
66 Depending on conditions, pyro-borates, spiro-borates, and boroxinate species can be generated and the
68 er of frequency-doubling oxides, phosphates, borates, and fluoride-containing borates were found, no
69 ) self-decay and ferric chloride addition in borate- and phosphate-buffered waters showed that phosph
71 nts of HN(NO2 )2 afforded the di-substituted borate anion consisting of two isomers, one with both ni
73 that the reaction to form the chiral spiral borate anion is stereospecific, namely, only one of two
74 ng and lipophilic tetrakis(pentafluorophenyl)borate anion stable as a solid and soluble in low polari
76 th OECs are chemically similar, and that the borate anions do not play an apparent role in the cataly
80 e; [Bc(Me)](-) = dihydrobis(methylimidazolyl)borate) are synthesized and fully characterized to exami
81 rate that a variety of weak acids (silicate, borate, arsenite, cyanide, carbonate, and sulfide) canno
82 electrolyte, using lithium difluoro(oxalato)borate as an electrolyte additive, that has superior per
84 Using a mixture of phosphate, citrate, and borate as the buffering ions and using a CEM suppressor,
85 acid) (PAA) as the capping ligand and sodium borate as the salt, the borate hydrolyzes rapidly in res
87 is reaction employs nonsymmetric bis(alkenyl)borates as substrates and appears to occur by a mechanis
88 riphenylcarbenium tetrakis(pentafluorophenyl)borate at -20 degrees C formed the cationic gold (beta,b
90 resence of Na(+), K(+), Mg(2)(+), Li(+), and borate at soil concentrations lethal to Arabidopsis.
91 er SLC4A11 in corneal endothelium transports borate (B[OH](4)(-)), bicarbonate (HCO3(-)), or hydroxyl
93 th tetrakis-[3,5-bis(trifluoromethyl)phenyl]-borate (BArF) to enhance catalytic activity and control
94 f the triphenylsulfonium salt of a carbamato borate based on a carbazole function, its establishment
96 , U; [Bp(Me)](-) = dihydrobis(methypyrazolyl)borate; [Bc(Me)](-) = dihydrobis(methylimidazolyl)borate
100 es, material is expected to have passed from borate-bound pent(ul)oses to a branched heptulose, which
102 Purified (18)F-SFB was incubated with IL2 in borate buffer (pH 8.5) and ethanol at 50 degrees C for 1
108 re solubilized by heating at 95 degrees C in borate buffer containing detergent (5 min), then labeled
116 the voltammetric data for water oxidation in borate buffered solutions (pH 9.2) at electrodes functio
117 absorbed by a paper filter impregnated with borate-buffered (pH 9.0) hydroxoaquocobinamide (hereinaf
123 re we propose the end-of-life utilization of borated CFI as B fertilizer, to decrease societal B cons
125 le method for the functionalization of closo-borates [closo-B10 H10 ](2-) (1), [closo-1-CB9 H10 ](-)
127 arable to that of another OER cocatalyst, Co-borate (Co-Bi), in 1 M Na2CO3, reaching 10 mA/cm(2) at a
129 nd binuclear organoscandium complexes with a borate cocatalyst are active for ethylene + amino olefin
130 greater than any variation introduced by the borate complexation, which had a negligible effect on th
132 ive conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplis
133 would almost certainly have formed as stable borate complexes on the surface of an early Earth beneat
134 xploited for its ability to bind and release borate-containing therapeutics such as BTZ in a pH-depen
135 s of type 1 Cu sites based on tris(pyrazolyl)borate copper thiolates [Cu(II)]-SR to unravel the facto
136 w-temperature reaction of the tris(pyrazolyl)borate copper(II) hydroxide [(iPr2) TpCu]2 (mu-OH)2 with
140 ehyde halogenation proceeded most readily in borate cross-linked gels at high ammonium persulfate dos
142 the technique by measuring the silicate and borate depth profiles in the Pacific Ocean; the silicate
143 rompts reaction with H2 to give a borane-oxy-borate derivative, the product of C-O bond cleavage.
144 gment {WTp(NO)(PMe(3))} (Tp = tris(pyrazolyl)borate), derived from pyridine, are demonstrated to unde
145 treatment to hydrolyse rhamnogalacturonan II borate diester bonds neither affected chains length or b
146 ogalacturonan-II (RG-II) is cross-linked via borate diester bridges, which influence the expansion, t
147 structural model that involves formation of borate dimers and G4.K(+) quartets by G 1 and KB(OH)4.
148 ated as [Fe(14)], Tp(-), hydrotris(pyrazolyl)borate; DMSO, dimethyl sulfoxide), which has a fluctuati
149 stasis in plants is regulated in part by the borate efflux transporter Bor1, a member of the solute c
151 in film from Ni(aq)(2+) solutions containing borate electrolyte (Ni-B(i)) has been studied by in situ
154 Co(2+) in phosphate, methylphosphonate, and borate electrolytes effects the electrodeposition of an
157 pW(NO)(PMe(3))} (Tp = hydridotris(pyrazolyl)-borate) enhances the basicity of the arene ligand to the
164 The present study examines the structures of borate esters of BINOL that are produced with different
166 tetradodecylammonium tetrakis(4-chlorophenyl)borate (ETH-500) and a cation-sensitive membrane without
167 Tp(iPr) = hydrotris(3-isopropylpyrazol-1-yl)borate], exhibits a distorted octahedral geometry with M
168 ), when combined with 0.5 equiv of potassium borate, forms a strong, self-supporting hydrogel with el
171 eral acids, microwave digestion, and lithium borates fusion in combination with polyethylene glycol (
173 n yielded the expected imidazolethiones, the borates gave the first representatives of new zwitterion
177 orming (11)B NMR measurements on a soda lime borate glass that has been pressure-quenched at ~0.6 GPa
178 anges in macroscopic properties of soda lime borate glasses compressed up to ~0.6 GPa are not attribu
180 reference materials (SRMs) fused in lithium borate glasses: two sediments as well as a soil and a ro
181 4) = tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; H(3)TEB = 1,3,5-triethynylbenzene; m-H(2)DEB = 1
182 s been incorporated into G-quadruplex G4K(+) borate hydrogels by using borate ester linkages (Pt-G4K(
183 ng ligand and sodium borate as the salt, the borate hydrolyzes rapidly in response to moisture and pr
184 lumns AS16, AS18, and AS23 were studied with borate, hydroxide and carbonate as suppressible eluents.
185 ) (1) afforded the mixed-valent disilicon(I)-borates [(Idipp)(R)Si(II) horizontal lineSi(0)(Idipp)][B
186 e or hydrogen tetrakis(4-methyl-1-imidazolyl)borate in a concentrated ammonium hydroxide solution at
187 reatment with cold dilute HCl or with excess borate in vitro) enhanced the GIPCs' extractability.
189 t a 1,2-metalate rearrangement of the silver borate intermediate is the key step responsible for the
190 derivative which reacts further via an epoxy-borate intermediate to capture CO, affording a heterocyl
195 room temperature of the new (trinitromethyl)borate is in sharp contrast to the behavior of [BCl3 C(N
198 The electronic structure of the Ce(III) borate is similar to the Pu(III) complexes in that the C
201 ensional network structures where rare earth borate layers are joined together by BO(3) and/or BO(4)
202 olyl) supported by the anionic bis(phosphino)borate ligand [Ph(2)B(CH(2)P(t)Bu(2))(2)](-) has been is
204 ticular geological environment that contains borate, magnesium, sulfate, calcium, and phosphate in ev
206 he disruption of membrane components by high borate may account for the phytotoxicity of excess B.
208 tion to guiding carbohydrate pre-metabolism, borate minerals in evaporite geoorganic contexts offer a
210 , namely inhibition by 2-aminoethoxydiphenyl borate, ML-9, and low concentrations of lanthanides.
212 ent of a branched pentose that is central to borate-moderated cycles that fix carbon from formaldehyd
213 carbenes that contain a weakly coordinating borate moiety (WCA-NHC) was prepared in one step from fr
214 s of carbohydrate premetabolism, showing how borate, molybdate, and calcium minerals guide the format
217 dium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (NaTFPB), theoretical calculations, and single-cr
218 o Fe-containing Ni-based OECs, namely nickel borate (Ni(Fe)-B(i)) and nickel oxyhydroxide (Ni(Fe)OOH)
220 1 crystal structure demonstrates that serine-borate occupies the active site of the enzyme, resulting
221 O(3))(2)] and hydrogen tetrakis(1-imidazolyl)borate or hydrogen tetrakis(4-methyl-1-imidazolyl)borate
222 the 3,3'-position will not form either spiro-borates or boroxinate species and thus are not effective
224 sts (xestospongin D or 2-aminoethoxydiphenyl borate) or a phospholipase C inhibitor (U73122) attenuat
225 (x)H(y) ligands stabilized by tris(phosphine)borate ([PhB(CH(2)PR(2))(3)] = [PhBP(R)(3)]) ligands hav
226 capillary was used for the separation, and a borate-phosphate buffer containing 25 mM cetyltrimethyla
227 inates from Ln(3+) coordination alterations, borate polymerization diversity and soft ligand coordina
229 roxyl and carboxylate groups, the effects of borate preservation in (1)H NMR-spectroscopy-based metab
230 carboxylate functions, it is concluded that borate preservation is "fit-for-purpose" for (1)H NMR-ba
232 odium tetrakis[3,5-bis(perfluorohexyl)phenyl]borate providing for ionic sites, and bis[(perfluoroocty
233 n be amplified during the crystallization of borates, providing chemical recognition of specific lant
234 e; Tp(Me) = hydridotris(3-methylpyrazol-1-yl)borate; pzTp = tetrakis(pyrazol-1-yl)borate; Tp* = hydri
236 the catalysts' activation stage phosphonium borates [R3PH][HB(C6F5)3] (6, R = iPr a, Cy b) are forme
238 lexation with a neutral coated capillary and borate reversed polarity, led to a robust platform for t
245 Tp(R,R'-) = hydrotris(3-R,5-R'-pyrazol-1-yl)borate ("scorpionate") anion (R = tert-butyl, R' = H, Me
247 ments, reproduced here, show that Mg(2+) and borate sequester phosphate from calcium to form the mine
248 stry and sinter mineralogy were dominated by borates, sodium, thiosulfate, sulfate, sulfite, sulfide,
251 as chiral catalysts, and these include meso-borates, spiro-borates, and diborabicyclo-borate esters.
252 s the synthesis and isolation of the bis(NHC)borate-stabilized chlorogermyliumylidene precursor 2 in
253 (polypyrrole) and a dynamic network (polyol-borate), strong and flexible polymer films were develope
254 Moreover, supplementation experiments with borate suggest that the function of boron in plants migh
256 n of the carbohydrate cis-hydroxyl groups by borate suppresses the long-range hydration shell detecte
257 etrabutylammonium tetrakis(pentafluorophenyl)borate [TBATFAB]) was utilized to elucidate the diffusio
258 incorporates the tetrakis(pentafluorophenyl)borate (TFAB(-)) anion, which is also present as a lipop
259 The tetrakis[3,5-bis(triflouromethyl)phenyl]borate (TFPB(-)) membrane dopant in the polymer ISE was
260 the tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (TFPB(-)) weakly coordinating (or "superweak") an
261 TpIr(III) complex (Tp = hydrotris(pyrazolyl)borate) that also features a labile ligand (i.e., 2-THF)
263 etroses form extremely stable complexes with borate, they are not accessible by pathways plausible un
265 ([M + Na]+) analyte molecules with trimethyl borate (TMB) in a modified linear quadrupole ion trap ma
266 f protonated sulfone analytes with trimethyl borate (TMB) that yields a diagnostic product ion, adduc
269 bitors (citric acid, oxalic acid, and sodium borate) to aqueous extraction solutions to aid pigment r
270 ylcarbenium (trityl) tetra(pentafluorophenyl)borate totally inhibits the reaction, producing the corr
271 [Cu(MeCN)(6)](2+) and hydrotris(pyrazol-1-yl)borate (Tp(-)) affords the zigzag chain compound (Bu(4)N
272 silver complexes bearing hydrotris(pyrazolyl)borate (Tp(x)) ligands have been investigated from a mec
273 [where Tp(R) = Tp, hydridotris(pyrazol-1-yl)borate; Tp(Me) = hydridotris(3-methylpyrazol-1-yl)borate
274 ol-1-yl)borate; pzTp = tetrakis(pyrazol-1-yl)borate; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borat
275 ; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate; Tp*(Me) = hydridotris(3,4,5-trimethylpyrazol-1-y
276 tested for three such agents: novel enzymes, borate-transferring ligands and cationic 'chaperones' th
279 y reaction with alkyl orthosilicates or aryl borates, under aerobic conditions in the presence of sil
281 ch utilized the secondary equilibrium of the borate-vicinal diol complexation to enhance resolution.
284 sium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate was used as an ion exchanger in a poly(vinyl chlo
285 (sodium tetrakis[(3,5-trifluoromethyl)phenyl]borate) was found to catalyze reactions of (Phebox)Ir(II
286 ) (2) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate), was synthesized by salt metathesis from Tp*(2)U
287 phosphates, borates, and fluoride-containing borates were found, no transition-metal silicate with us
288 en atoms contrasting the Am(III) and Cm(III) borates, where a basal O 2p orbital delocalizes to the A
289 ) = hydrotris(3-tert-butyl-5-methylpyrazolyl)borate), whereas the analogous reaction with sulfur stop
290 2 (Tp(Me2) = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water and a
291 3)-N,N',N"-hydridotris(3,5-dimethylpyrazolyl)borate), which incorporate a ptSi atom in addition to tw
292 capping agents-such as tannate, citrate, and borate-which does not seem to have been done previously
293 Mo, W; Tp* = hydrotris(dimethylpyrazol-1-yl)borate], which are readily obtained via the successive t
294 d the channel blocker, 2-aminoethoxydiphenyl borate, widely used reagents for disruption of Ca(2+)-de
295 asible for very weak acids like silicate and borate with a dedicated element specific detector like a
296 )] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with primary phosphines PH2R (R = Ph, Cy) afford
297 (CH3)H (1a, Tp' = tris(3,5-dimethylpyrazolyl)borate) with substrates containing B-H, Si-H, C-F, and C
298 )4 = tetrakis[3,5-bis(trifluoromethyl)phenyl]borate) with the oxygen atom transfer (OAT) reagent 2-te
299 study has shown that the phosphonium hydrido borate zwitterion 10 is formed exergonically in solution