ライフサイエンスコーパス: borohydride

1 educed to the corresponding amines by sodium borohydride.

2 ying the promising, high-energy density fuel borohydride.

3 laminodiboranate, a new kind of multidentate borohydride.

4 H and by reduction of glycated peptides with borohydride.

5 d to active MCRred1 by treatment with sodium borohydride.

6 ample with a gold nanorod solution in sodium borohydride.

7 uced and stabilized by treatment with sodium borohydride.

8 using 300 microL of sample and 100 microL of borohydride.

9 idation and subsequent reduction with sodium borohydride.

10 on of an alpha-nitro ester by TiCl(3)/sodium borohydride.

11 es (96% ee) and diminished the effect of the borohydride.

12 kyl halide followed by reduction with sodium borohydride.

13 form can be trapped by reduction with sodium borohydride.

14 tein-DNA complexes in the presence of sodium borohydride.

15 s were carried out in the presence of sodium borohydride.

16 ty in the same pot by the addition of sodium borohydride.

17 termediates trapped by reduction with sodium borohydride.

18 e, which can be stabilized by reduction with borohydride.

19 plex can be trapped by reduction with sodium borohydride.

20 e wild-type enzyme in the presence of sodium borohydride.

21 equently be trapped by reduction with sodium borohydride.

22 butyl-3-methylimidazolium bromide and sodium borohydride.

23 Complex 3 is the first reported thallium borohydride.

24 either acetylation or reduction with sodium borohydride.

25 (3-oxoindolin-2-yl)acetonitriles with sodium borohydride.

26 of methylene blue in the presence of sodium borohydride.

27 al treatment with iodosylbenzene then sodium borohydride.

28 ionation and chemical reduction using sodium borohydride.

29 ring can be opened by reduction with lithium borohydride.

30 reducing agents such as hydrazine or sodium borohydride.

31 ocene and the condensation of pyrazoles with borohydride.

32 s electrochemical oxidation of the resulting borohydride.

33 o 2-amino-1,3-diols by reduction with sodium borohydride.

34 of p-nitrophenol to p-aminophenol by sodium borohydride.

35 sample after complete reduction with sodium borohydride.

36 u electrochemical oxidation of the resulting borohydride.

37 y reduction of the adsorbed salt with sodium borohydride.

38 s of 10a,b and 11 by tailoring the amount of borohydride.

39 responding alcohols by reduction with sodium borohydride.

40 harging' the borane functional group back to borohydride.

41 reased 8-fold when lysates were treated with borohydride; 2) the reagent caused 4-8 glutamic acid res

42 duction of mitomycin C (40 microm) by sodium borohydride (200 microm) in 20 mm Tris-HCl, 1 mm EDTA at

43 st borane 7, which is generated in situ from borohydride 6, constitutes a convenient and preparativel

44 +/- 2.5% inhibition of CO photoproduction by borohydride, a dilemma since only borohydride affects mo

45 e-DNA intermediate in the presence of sodium borohydride, a new finding that supports the grouping of

46 The CPG-modified flavin can be reduced with borohydride, a reaction that blocks conversion to unmodi

47 ation of MutY-DNA adducts in the presence of borohydride, a series of site-directed mutant forms of M

48 dducts with substrate DNA in the presence of borohydride, a trait otherwise known to be associated on

49 e among the decomposition products of stable borohydrides, a topic of critical importance for the rev

50 duction by borohydride, a dilemma since only borohydride affects most ketones.

51 e, incorporating derivatization using sodium borohydride, allowed the development of a sensitive meth

52 Borohydride also decreased CDOM absorption much more tha

53 The parent compounds of ammonium borohydride, ammonia borane, and diammoniate of diborane

54 potential utilisation of ligands containing borohydride and borane functionalities as reversible hyd

55 fer reactions and the transformation between borohydride and borane moieties.

56 wn lactones by one-pot reduction with sodium borohydride and boron trifluoride etherate.

57 Borohydride and catalytic photoreduction give the same s

58 cal reduction using sodium amalgam or sodium borohydride and enzymatic generation from porphobilinoge

59 potential, as illustrated through studies of borohydride and hydrazine electro-oxidation.

60 omo substituent was accomplished with sodium borohydride and palladium chloride.

61 (3) SgcC4 is strongly inhibited by sodium borohydride and potassium cyanide, but preincubation wit

62 H(4) )(3) ][Li(THF)(4) ] (3), where use of a borohydride and preformed C(4) -unit circumvents difficu

63 the ring-D dienone successively with sodium borohydride and singlet oxygen.

64 ation under alkaline conditions using sodium borohydride and sodium hydroxide.

65 ve materials that upon reduction with sodium borohydride and subsequent hydrolysis decarboxylation ge

66 onyls were derivatized with tritiated sodium borohydride and the tritiated proteins were separated on

67 were stereospecifically reduced using sodium borohydride and then deprotected to give allo- and epi-i

68 ing from simple binary metal-halide salts to borohydrides and "designer reagents" such as alkyl and o

69 lase was resistant to reduction by arsenite, borohydride, and dithiothreitol, suggesting that sulfhyd

70 f their reaction with sodium cyanide, sodium borohydride, and methoxylamine and by the mass spectra d

71 ral data supported the tris(trifluoroacetoxy)borohydride anion (16) as the active reducing agent.

72 nion-substituted compounds where the complex borohydride anion, BH4(-), is replaced by another anion,

73 pair of electrons on sulfur and the incoming borohydride anion.

74 xyuridine, followed by reduction with sodium borohydride as a limiting reagent, produces dTHU and lim

75 itions in the presence of tetrabutylammonium borohydride as a reducing agent.

76 enylenehexacarbonitrile [HAT(CN)(6) ] sodium borohydride as the starting materials.

77 The reducibility of DOM by sodium borohydride (as judged by relative removal of initial ab

78 Sodium borohydride-based hydride generation was automated by us

79 This is in contrast to other borohydride-based syntheses of thiolate monolayer protec

80 The catalytic currents with borohydride begin at the potential of GR-bound FAD, show

81 oranes are quantitatively converted to their borohydrides by replacing electronegative groups (e.g.,

82 teric and solvation requirements in HCN- and borohydride-CDOM reactions.

83 played mannan by acid treatment of periodate-borohydride cells exposes glucan.

84 tivated with a hydride source such as sodium borohydride, cleanly and selectively dehalogenates dibro

85 The first stable copper borohydride complex [(CAAC)CuBH4] [CAAC = cyclic(alkyl)(

86 (2)BH(3))(6), the first example of a Pu(III) borohydride complex authenticated by XRD and NMR spectro

87 de complexes over 80 years ago, no plutonium borohydride complexes have been structurally validated u

88 Despite the discovery of actinide borohydride complexes over 80 years ago, no plutonium bo

89 enzene, ortho-to-fluorine cobalt(I)-aryl and borohydride complexes were identified as resting states

90 s of sugar-aldehyde reduction and the sodium borohydride concentration dependence of the rate of form

91 -ketoacyl triketide intermediate with sodium borohydride confirmed that in each case the triketide in

92 dent resistance can be overcome by periodate-borohydride conversion of mannose polysaccharides to pol

93 of metal-boron distances suggest that metal-borohydride covalency in M(2)(H(3)BP(t)Bu(2)BH(3))(6) co

94 ract and BER intermediate as bait for sodium borohydride crosslinking.

95 Borohydride-dependent cross-linking using an OG-containi

96 Borohydride-dependent enzyme-DNA cross-linking, which is

97 SA) in vitro; (ii) to determine, by a sodium borohydride-dependent mass peptide mapping method, the g

98 Two major classes of metal borohydride derivatives have also been discovered: anion

99 d not stimulate and hydroxylamine and sodium borohydride did not inhibit the enzyme activity, indicat

100 )-ones 21a-d, which were converted by sodium borohydride directly into optically active 3-substituted

101 m an inorganic salt was seen for a magnesium borohydride electrolyte.

102 cin 1140 was chemically modified with sodium borohydride followed by ethanethiol, allowing the differ

103 tion and chromophore trapping by isopropanol/borohydride, followed by exhaustive protein digestion, c

104 les calculations, we investigate a magnesium borohydride framework that has small pores and a partial

105 er of hydrophobic QDs to aqueous media under borohydride-free conditions.

106 products with O(2) in the presence of sodium borohydride furnished 72, which was readily separated fr

107 rignard reagents, sodium cyanide, and sodium borohydride gave 1,2,3,4-tetrahydropyrrolo[1,2-a]pyrazin

108 Addition of sodium borohydride generates a hydroquinone derivative that is

109 f dissolved organic matter (DOM) with sodium borohydride has been used to understand the geographic o

110 1-yl)oxyl (TEMPO), ascorbic acid, and sodium borohydride) have been investigated to eliminate these r

111 oexcitation of CdSe NCs in the presence of a borohydride hole quencher, Li[Et3BH], yields colloidal n

112 Using a series of substituted borohydride hole quenchers, we show that it is possible

113 For borohydrides, HRR potentiometry reveals that effective h

114 ides are quite stable to triphenylphosphine, borohydrides, hydrazine, alkyllithiums, Grignard reagent

115 determined by chemical reactions with sodium borohydride, hydrogen peroxide, alpha-methoxy-alpha-(tri

116 band 3 with Woodward's reagent K plus sodium borohydride (i.e., the modification process) exposes a c

117 The binary hydride, diisobutylaluminum borohydride [(iBu)(2)AlBH(4)], synthesized from diisobut

118 that are capable of being reduced by sodium borohydride in an aqueous medium.

119 enol ester that cannot be reduced by sodium borohydride in an aqueous solution, while other nucleoph

120 tly to the dianion was achieved using sodium borohydride in ethanol.

121 FMNH(2) failed to substitute for potassium borohydride in in vitro assays for corrinoid adenosylati

122 ere synthesized by reduction of AgNO(3) with borohydride in water with ATP as a capping ligand.

123 urium enzyme by phosphonoacetaldehyde-sodium borohydride-induced inactivation and by site-directed mu

124 o polyalcohols; cells treated with periodate-borohydride initiate the alternative pathway without the

125 relative stability of, magnesium hydride and borohydride intermediates during the course of the catal

126 2-ones 17a-c, which were converted by sodium borohydride into (3S,7aR)-3-substituted-1-(4-nitrophenyl

127 It is shown that the borohydride ion, a known reducing agent for GR, is catal

128 glass-forming trihexyltetradecylphosphonium borohydride ionic liquid that shows no tendency to cryst

129 e and the reduction by borane, diborane, and borohydride ions were also examined.

130 nol and (ii) hexacyanoferrate (iii), both by borohydride ions.

131 e cobalt-hydride dimer, [((iPr)ACNC)CoH](2), borohydride ((iPr)ACNC)CoH(2)BPin, or diboryl hydride, (

132 e, and treatment of such adducts with sodium borohydride irreversibly inactivated the enzyme.

133 ars that the extent of absorbance removal by borohydride is largely driven by the origin of the humic

134 s for hydrogen generation from hydrolysis of borohydride is one of the most desirable pathways for fu

135 itu reduction of InCl(3) using lithium amino borohydride (LAB) were explored, generation of HInCl(2)

136 duction of the HemA-PLP complex using sodium borohydride led to > 90% inactivation of the enzyme.

137 he presence of a catalytic amount of lithium borohydride (LiBH(4)) reduces a large variety of aliphat

138 Metal borohydrides [LiBH(4), Mg(BH(4))(2), Ca(BH(4))(2)] are a

139 The divalent lanthanide borohydrides [Ln(BH(4))(2)(THF)(2)] (Ln = Eu, Yb) have b

140 A wide variety of metal borohydrides, MBH4, have been discovered and characteriz

141 On the other hand, zinc borohydride-mediated chelation-controlled reduction of a

142 This sodium borohydride-mediated reduction process resulted in signi

143 The key development is the use of a molten borohydride (MEt3BH, M = Na, K) as both the reducing age

144 followed by sequential treatment with sodium borohydride, methanesulfonyl chloride, and morpholine af

145 anion, i.e. a halide or amide ion; and metal borohydrides modified with neutral molecules, such as NH

146 The carbene-stabilized beryllium borohydride monomer L:Be(BH(4))(2)2 is prepared by the r

147 action cartridge packed with solid supported borohydride (MP-borohydride), which can be attached to a

148 by WR-K and then reduced by tritiated sodium borohydride (NaB[3H]4) showed the presence of a prominen

149 re obtained in very good yields using sodium borohydride (NaBH(4)) as a reducing agent and a catalyti

150 major tRNA modifications, followed by sodium borohydride (NaBH(4)) reduction of m(7)G sites and subse

151 l(2) from the reduction of InCl(3) by sodium borohydride (NaBH(4)) was also re-evaluated for comparis

152 nitrophenol (4-NP) in the presence of sodium borohydride (NaBH(4)).

153 he chemical precipitation method with sodium borohydride (NaBH4) as the reductant in the presence of

154 microparticle motors in a solution of sodium borohydride (NaBH4) fuel.

155 AgNPs onto silica using a chitosan + sodium borohydride (NaBH4) method results in higher silver load

156 Specifically, we use a sodium borohydride (NaBH4) treatment process to thoroughly remo

157 ich is obtained by reducing F430 with sodium borohydride (NaBH4).

158 h varying amounts of reductant, i.e., sodium borohydride (NaBH4).

159 n alkylating agent (usually MeI), and sodium borohydride (NaBH4).

160 improve the CO(2) uptake properties in metal borohydride nanomaterials.

161 e., metals as synthetic precursors, halides, borohydrides, nitrogen donors, oxygen donors, triflates,

162 re performed using dissolving metals, sodium borohydride or hydrogen transfer conditions under solven

163 ipid fraction derived from oxLDL with sodium borohydride or potassium iodide completely abrogated apo

164 ldehydes to alcohols employing excess sodium borohydride produced pronounced and largely, but not com

165 line hydride generation with acid and sodium borohydride produces AsH3 and H2, which are separated fr

166 ed by electrocyclization and subsequent acid/borohydride-promoted reduction.

167 al of the chiral auxiliary in 5 using sodium borohydride, protection of the gamma-cyano alcohol 6 as

168 -enhanced stain was used; it utilizes sodium borohydride, proteinase K, Triton X-100 and xylenes to i

169 Herein, we studied the kinetics of DOM-borohydride reactions by recording absorbance and fluore

170 f two electron-withdrawing nitrile groups, a borohydride reacts with a base to give a carbene-stabili

171 e by lithium aluminum hydride and by a bulky borohydride reagent were investigated computationally an

172 While borohydride reagents are generally used as reducing agen

173 on of ((i)PrPDI)FeCl(2) with alkali metal or borohydride reagents results in sequential electron tran

174 ted the effects of different solid supported borohydride reagents, cartridge size, starting radioacti

175 Metal borohydrides receive increasing interest within the ener

176 ence emission with pH for both untreated and borohydride reduced samples suggest that a pH-dependent

177 s were initially converted to stable, sodium borohydride-reduced 3-aminopyridine conjugates, while FA

178 The borohydride-reduced CPG-modified enzyme exhibits a mass

179 The borohydride-reduced enzymes retain full catalytic activi

180 d both for a variety of untreated as well as borohydride-reduced HS and C(18) extracts from the Delaw

181 Alkaline borohydride-reduced keratan sulfate chains were isolated

182 protectable peptide from [3H]PLP-inactivated borohydride-reduced mevalonate kinase allow assignment o

183 ioxygen concentration for both untreated and borohydride-reduced samples.

184 egions of the sample matrix where the sodium borohydride-reduced silver colloidal particles are prese

185 ated photochemically from both untreated and borohydride-reduced Suwanee River fulvic and humic acids

186 ctra acquired by ESI FT-ICR MS of untreated, borohydride-reduced, and borodeuteride-reduced samples o

187 n which (1)O(2) sensitizing chromophores are borohydride reducible groups in DOM, such as aromatic ke

188 with sodium metaperiodate followed by sodium borohydride reduction (PerT-GUS) eliminated uptake by ma

189 in adjacent collagen molecules that resisted borohydride reduction and after acid hydrolysis produced

190 Au-Cu nanoparticle aggregates synthesized by borohydride reduction are collected by centrifugation an

191 standard heparin by periodate oxidation and borohydride reduction enhanced its ability to inhibit pl

192 ed by treatment with sodium azide and sodium borohydride reduction gave 5-azido-5-hydroxylmethyl subs

193 The free amine emerges from a borohydride reduction of an iminium ion (protonated imin

194 Borohydride reduction of AuCl(4)(-) in the presence of h

195 e origins of pai-facial selectivities in the borohydride reduction of endocyclic iminium ions have be

196 Hence, the sodium borohydride reduction of hemiacetals 2a,b can be control

197 histidinohydroxymerodesmosine is produced by borohydride reduction of N-telopeptide allysine aldol di

198 Borohydride reduction of several samples in both D(2)O a

199 r colloid, was prepared in situ, on-chip, by borohydride reduction of silver nitrate.

200 Borohydride reduction of the aldimine promotes an accomp

201 Borohydride reduction of the enzyme DXP imine followed b

202 l inhibition of the enhanced RH2O2 following borohydride reduction of the HS, as well as the dependen

203 saccharides were released by alkaline sodium borohydride reduction of the jelly coating from the Sout

204 Borohydride reduction of the native enzymic aldimines di

205 Borohydride reduction of the Schiff base results in the

206 possible to correctly predict the effects of borohydride reduction on DOM absorbance spectra with a r

207 ionally, by predicting the effects of sodium borohydride reduction on the model compounds and then ca

208 The combined effects of pH and borohydride reduction on the optical properties of a ser

209 Sodium borohydride reduction operates from the beta-face of C-1

210 ers advantages over the traditional methods (borohydride reduction or catalytic hydrogenation) in ter

211 Borohydride reduction resulted in increased fluorescence

212 Using this technique (Borohydride Reduction sequencing [BoRed-seq]) alongside

213 Borohydride reduction significantly reduced TMP loss, su

214 NA selection, AlkB demethylation, and sodium borohydride reduction steps to achieve specific and effi

215 Borohydride reduction substantially attenuated the broad

216 Although borohydride reduction substantially reduced light absorp

217 e inhibition of the enhanced RH2O2 following borohydride reduction suggests that there may remain ano

218 s dihydroxylation of dienoate ester and zinc borohydride reduction to establish the C-8-C-11 stereoch

219 nstrate that decreasing molecular weight and borohydride reduction work in opposition regarding quant

220 e incomplete loss of sensitization following borohydride reduction, as well as the inverse dependence

221 lowed by a standard Fukuyama reduction and a borohydride reduction, furnishes alpha,alpha'-quaternize

222 c residues by periodate oxidation and sodium borohydride reduction, indicating a requirement for the

223 equence is followed by recrystallization and borohydride reduction, resulting in rapid synthesis of (

224 thylcytosine and, in combination with sodium borohydride reduction, single 5-formylcytosine nucleobas

225 release to promote lactonization, and sodium borohydride reduction, that were both optimized to impro

226 Enhancement was completely reversed by borohydride reduction, yielding a strength of interactio

227 entanone 8 was effected by (S)-CBS-catalyzed borohydride reduction.

228 phosphate-containing DNA substrate by sodium borohydride reduction.

229 nked to the 8-oxoG oligonucleotide by sodium borohydride reduction.

230 and captured under catalytic conditions via borohydride reduction.

231 ehydes using hypervalent iodine reagents and borohydride reduction.

232 hanged by molecular-weight fractionation and borohydride reduction.

233 breaking point, both with and without sodium borohydride reduction.

234 ies have been explored in lanthanide-bearing borohydrides related to solid state phosphors and magnet

235 kinetics and ultimate reducibility of DOM by borohydride remain poorly characterized.

236 f MSOX or MTOX with a small excess of sodium borohydride results in immediate flavin reduction to a s

237 , physical and chemical properties for metal borohydrides, revealing a number of new trends correlati

238 Reduction of the bimetallic dicarbonyl with borohydride salts afforded impure, thermally stable hydr

239 SO(4).5H(2)O in the presence of 2.5 mol % of borohydride salts in 10 min at room temperature in air.

240 available alkyl halide precursors and simple borohydride salts, alkyl radicals can be generated in aq

241 Upon treatment of [H1(NCMe)](+) with borohydride salts, the MeCN ligand is displaced to affor

242 In this study, treatment of CBS with sodium borohydride selectively reduced the Schiff base but did

243 ng COS cells lysed in the presence of sodium borohydride showed that: 1) phosphate recovered on proth

244 the enzyme-inhibitor complex with sodium [3H]borohydride shows that 1.2 mol of the affinity label/mol

245 original state after treatment with a sodium borohydride solution, demonstrating the reversible, redo

246 eral relative rate experiments showed that a borohydride species in BTHF catalyzed the nonselective b

247 Protonation of Li2[1] leads to the cyclic borohydride species Li[1H] featuring a B-H-B two-electro

248 ulfides with glutathione (protein-SSG) after borohydride splitting of the disulfide bond.

249 Treatment of galactated HSA with sodium borohydride stabilized the condensed sugars on the prote

250 On the basis of the crystal structure of the borohydride-stabilized adduct, we conclude that the labi

251 d a cyclic moiety, and reduction with sodium borohydride suggested two reducible oxygen-containing gr

252 upon exposure to pyridoxal phosphate/sodium borohydride, suggesting a reactive lysine residue.

253 Reduction of pyrazinium salt 11 with lithium borohydride/TFA provided anti-2 unaccompanied by its syn

254 modes of the coordinated and free states of borohydride, TFSI(-), and polyether COC groups.

255 on pair composed of a silyliminium ion and a borohydride that subsequently reacts to yield an N-silyl

256 tures were quantitatively converted to their borohydrides through their reaction with activated KH (K

257 yclohexadienyliron(1+) complexes with sodium borohydride to access the endo series also gave a novel

258 reduced by either triethyl silane or sodium borohydride to form the corresponding beta- and gamma-am

259 cinnamaldehyde derivatives, acetic acid, and borohydride to give secondary amines which were subseque

260 and could be selectively reduced with sodium borohydride to give unstable benziphlorins.

261 cal reduction of the silver ions with sodium borohydride to produce silver particles.

262 ene rings, followed by treatment with sodium borohydride to reduce the nitro-groups to primary amines

263 BASH MaP utilizes potassium borohydride to reveal the chemical accessibility of the

264 base intermediate that can react with sodium borohydride to trap the DNA-enzyme complex.

265 3,4-dihydroflavin with a second molecule of borohydride to yield an air-sensitive tetrahydroflavin i

266 ced to a similar extent with reductants from borohydrides to H(2) and are reoxidized back essentially

267 These ICOFs use borohydrides to irreversibly deprotonate the alcohol mon

268 onin as a DNA glycosylase/AP lyase using the borohydride trapping assay revealed that gelonin was sim

269 Sodium borohydride trapping of wild-type Fpg and its E3Q and E1

270 e matrices was accounted for by using sodium borohydride-treated blanks.

271 ed) among the O-glycans released by alkaline borohydride treatment from glycoproteins of the nervous

272 rain glycopeptides after release by alkaline borohydride treatment have been subjected to mass spectr

273 released from Ser/Thr residues by mild base/borohydride treatment of purified glycoproteins, and gly

274 pted by increased temperature because sodium borohydride treatment of the enzyme at either 15 or 60 d

275 Sodium borohydride treatment reduces M(1)GdR to the 5,6-dihydro

276 ex and reactivity to decreased pH and sodium borohydride treatment were suggestive of a structure inv

277 )H(12) and MgB(12)H(12) phases, while for Ca borohydride two competing reaction pathways (into CaB(6)

278 (2)[LCoH](2) (2), depending on the amount of borohydride used.

279 bioreductants, exogenous thiols, and sodium borohydride were studied.

280 packed with solid supported borohydride (MP-borohydride), which can be attached to a second cartridg

281 re of 6 M guanidine hydrochloride and sodium borohydride, which stopped the reaction and reductively

282 arried out using aqueous solutions of sodium borohydride, which yielded a refractive index sensitivit

283 hese imine bonds after reduction with sodium borohydride while under tension and found that their lev

284 mixtures are converted to the corresponding borohydrides whose (11)B NMR spectra normally exhibit re

285 unlikely since prior scavenging of residual borohydride with excess formaldehyde had no effect on th

286 ute to the design and discovery of new metal borohydrides with tailored properties towards the ration

287 Reduction of thiocolchiocone with sodium borohydride yielded the racemic alcohol 9, the structure