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1 energy and chemistry, involve the making or breaking of a bond between carbon, nitrogen and oxygen.
2 r different catalytic motifs to catalyze the breaking of a carbon-carbon bond in a nonnatural substra
3 response to a local perturbation such as the breaking of a chemical bond or the absorption of a photo
4 chemical and physical processes such as the breaking of a chemical bond or the vibrational motion of
5 ndeed, in contrast to the discrete case, the breaking of a continuous symmetry leads to the emergence
9 tners either (i) through thermally activated breaking of a hydrogen bond that creates a dangling hydr
10 r chiral inversion that does not require the breaking of a metal-sulfur bond at the metal-ligand inte
14 orque generation facilitates chiral symmetry breaking of actomyosin flows and drives organismal left-
15 s involving hydrocarbons (homolytic C-C bond breaking of alkanes, progressive insertions of triplet m
16 ence of the plastic phase which involved the breaking of all hydrogen bonds, and modeling of small cl
19 transitions that the compounds induced: (i) breaking of an interaction between Tyr-223 and Arg-187 i
20 We find that the barrier crossing involves breaking of an interhelical hydrogen bond between helix5
22 single walker, which require the making and breaking of As-S bonds, and occur in aqueous solution at
23 rane-associated polarity crescent defined by BREAKING OF ASYMMETRY IN THE STOMATAL LINEAGE (BASL) and
28 vior of a tissue cell polarity protein BASL (BREAKING OF ASYMMETRY IN THE STOMATAL LINEAGE) in the si
29 pic expression of the stomatal protein BASL (BREAKING OF ASYMMETRY IN THE STOMATAL LINEAGE) reveals a
31 he transformation are proposed which require breaking of at least one in six of the covalent bonds th
35 ich could have important implications on the breaking of B cell central tolerance in autoimmunity.
36 the patient-oncologist encounter during the breaking of bad news, comprising essential aspects of th
38 computational model tracks the formation and breaking of bonds between platelets and treats the throm
39 and electronics on the gradual weakening and breaking of bonds was studied by investigating bridgehea
40 etal complexes that result in the making and breaking of C-N, C-O and C-S bonds via fundamental organ
41 agnetic moments from the c-axis leads to the breaking of C3 rotation symmetry, and thus, a small band
44 imately 0.25 eV and intra-unit cell symmetry breaking of charge distribution in individual alpha-RuCl
45 allows us to observe with clear evidence the breaking of chemical bonds between the ligands and the C
47 atic and twist-bend nematic with spontaneous breaking of chiral symmetry is crucially dependent on th
48 emerging as a result of spontaneous symmetry breaking of clock/counterclockwise rotation of self-asse
54 out external concentrations necessitates the breaking of detailed balance and consumption of energy,
56 robes to quantify entropy production and the breaking of detailed balance, little is known about the
61 oscopic split-phase interface (MSPI) by dual breaking of electron cloud and space structure symmetry
62 ress has been made in understanding both the breaking of embryonic L-R symmetry and how the Nodal-Pit
64 emonstrated a strong capability for C-C bond breaking of ethanol than pure Pt and intermetallic Pt/Sn
65 rupture propagation could be promoted by the breaking of fault asperities in a cascading sequence.
66 est that the imaged subevents are due to the breaking of fault asperities-stronger spots or pins on t
67 weak antilocalization signatures as well as breaking of fourfold spin-valley symmetry, consistent wi
68 actor exceeds alpha(C), spontaneous symmetry breaking of fraction of cooperators presents itself betw
71 paradigmatic system in which the making and breaking of H-bonds in a highly anharmonic potential ene
72 sufficient to observe repeated formation and breaking of helical structure, which we found to occur o
73 on, in an SW-defective (5,5) BNNT results in breaking of hydrogen bonding with neighboring water mole
74 in forced unfolding in TI I27 is largely the breaking of hydrogen bonds and hydrophobic interactions
76 consistent with the view that formation and breaking of hydrogen bonds in such water chains is a lim
77 water molecule clusters and the weakening or breaking of hydrogen bonds within clusters is introduced
78 ich is characterized by first stretching and breaking of hydrogen bonds, followed by deformation of c
81 of perpendicular magnetization requires the breaking of in-plane symmetry, which can be artificially
83 thelial NF-kappaB activation orchestrate the breaking of inhalational tolerance and allergic antigen
84 ore, our data suggest that the formation and breaking of inter- and intradomain salt bridges control
85 g of FN-III(10) A and B-strands and precedes breaking of inter-strand hydrogen bonds between F and G-
87 and global climate, largely results from the breaking of internal gravity waves--disturbances propaga
88 A primary driver of deep-ocean mixing is breaking of internal tides generated via interactions of
92 ch necessarily involves the energy intensive breaking of intramolecular hydrogen bonds, provides a ph
93 ey to lattice instability, which governs the breaking of inversion symmetry and induces ferroelectric
96 rmolecular ion hopping through formation and breaking of ion-associations involving four polymerized
98 tivistic electrons are generated through the breaking of large-amplitude relativistic plasma waves cr
102 , a photon Devil's staircase, induced by the breaking of long-range translation symmetry, can emerge.
105 gh-resistance domain walls, arising from the breaking of magnetic point group symmetry strongly coupl
106 criterion identifies a new kind of symmetry breaking--of magnetic translations--where nonvanishing c
107 ation of sulfur from the thiol complexes via breaking of mercury-sulfur bonds as in an alkylation rea
108 and acetyl species indeed helps the C-O bond breaking of methoxy species and therefore the direct eth
109 ifically of tau proteins leads to mechanical breaking of microtubules at high strain rates, whereas e
110 nodules to bands may result from a symmetry breaking of mineral dissolution and precipitation trigge
111 edge that pivots to enforce rapid making and breaking of miRNA:target base pairs in the 3' half of th
112 twisting energy, resulting in a spontaneous breaking of mirror symmetry; the chiral twisted state pe
114 Ammonia oxidation requires not only the breaking of multiple strong N-H bonds but also controlle
115 rmalities of the myelin sheaths included the breaking of myelin at several locations, a splitting and
116 ation of unfolding of disordered domains and breaking of native cross-links at different stages of st
117 only by promoting the formation but also the breaking of Nepsilon-(gamma-glutamyl)lysine isopeptides.
118 ecifically, we demonstrate that the symmetry breaking of network connectivity constitutes a timescale
119 resolution permits direct observation of the breaking of nuclear spin degeneracy for the 1S0 and 3P0
121 oses the catalytic loop concertedly with the breaking of one of the two C-O bonds of CO2 and with pro
122 ting that mate change by pair members and/or breaking of pair bonds by unmated individuals is more fr
123 T phases is characterized by the spontaneous breaking of parity symmetry and the disappearance of per
127 iated killing of endothelial cells indicated breaking of peripheral immune tolerance against this sel
128 single IV dose up to 15 mg/kg, resulting in breaking of peripheral immune tolerance to self-tissues
131 lated electron-hole pair diagrams illustrate breaking of pi-conjugation in three-arm dendrimers due t
132 larization control, the spontaneous symmetry breaking of polarization states could be used for polari
133 tes and catalyzes hydride transfer, enabling breaking of polyethylene C-C bonds and forming C-C bonds
135 he ligand is undocked from the binding site, breaking of protein-disaccharide H-bonds takes place in
137 r mechanisms governing the establishment and breaking of radial symmetry at the gynoecium apex (style
139 DCvC relies on the reversible formation and breaking of rather strong covalent bonding within molecu
140 which relies on the reversible formation and breaking of rather strong covalent bonds within molecule
141 essive numbers illustrate why the making and breaking of RBCs is at the heart of iron physiology, pro
143 representing intra-unit-cell nematicity: the breaking of rotational symmetry by the electronic struct
151 h parameters that typically lead to symmetry breaking of signalling states between neighbouring cells
152 d that this barrier is due to the concurrent breaking of six interstrand hydrogen bonds (H-bonds) bet
153 field, which is below the threshold for bond breaking of solvent molecules, leads to significant orde
155 Proteases are enzymes that catalyse the breaking of specific peptide bonds in proteins and polyp
156 d radiative transfer, which reveals that the breaking of spherical symmetry is a critical factor in d
159 mays) causes significant yield losses due to breaking of stalk tissue below the ear node before harve
162 e propose that the origin of this gap is the breaking of sublattice symmetry owing to the graphene-su
163 nother class of metamaterials that shows the breaking of 'supersymmetry'(23,24) causing only antisoli
164 is underscores the importance of spontaneous breaking of symmetries, Fermi surface reconstruction, an
165 ctricity in any material through appropriate breaking of symmetry at surfaces and artificial nanostru
168 nvolves cilia as essential components in the breaking of symmetry, an asymmetric signaling cascade, a
170 ly narrow pH range; they exhibit spontaneous breaking of symmetry; and homochirality emerges through
171 ass starch of degradation processes also the breaking of the 1-6 glycosidic bonds, limiting oxidation
176 ucture and dynamics that take place with the breaking of the Asp-His hydrogen bond in the catalytic t
181 tion, in the absence of enzyme, involves the breaking of the C O bond facilitated by intramolecular p
183 of 1.04 +/- 0.01 was measured, showing that breaking of the C-S bond in the substrate Me-S-CoM is th
185 Unlike in C60, in doped fullerenes, the breaking of the cage spherical symmetry makes super atom
186 ayer atomic registry results in both a local breaking of the carbon sublattice symmetry and a long-ra
188 a subtle quantum phenomenon that denotes the breaking of the classical chiral symmetry by quantum flu
190 f Rho primarily proceeds through spontaneous breaking of the covalent linkage between opsin and 11-ci
193 glutamate is due to two motions: Spontaneous breaking of the D1 dimer interface and hyperextension of
194 nsistent with the outward rotation of H6 and breaking of the dark-state Glu134(3.49)-Arg135(3.50)-Glu
195 ation to the In(III) center, and concomitant breaking of the dimer into monomeric porphyrin species,
200 n state, the rate-determining step, involves breaking of the exocyclic P-O bond where a metal-ligated
201 embrane and axoneme alterations, followed by breaking of the flagellar membrane connected to the tryp
204 es trans-cis isomerization, which results in breaking of the H-bond between Glu46 and the chromophore
206 that such mutations result in the transient breaking of the helix at the site of mutation but with n
208 rovides a potential molecular mechanism: the breaking of the hydrogen bond between the side chains of
209 ogresses, we find a sequential weakening and breaking of the hydrogen bonds between the ATP molecule
211 During vertebrate embryo development, the breaking of the initial bilateral symmetry is translated
212 ental confirmation of such a BCD induced via breaking of the interfacial symmetry remains elusive.
213 CB2 binding pocket is sufficient to trigger breaking of the intracellular TMH3/6 ionic lock and the
214 ucial step for the complex formation was the breaking of the intramolecular hydrogen bond in urea der
215 rmational switches in beta(2)AR, namely, the breaking of the ionic lock between R131(3.50) at the int
216 odopsin and other class A GPCRs, namely, the breaking of the ionic lock between R135(3.50) at the int
217 typal model, rhodopsin, such as the apparent breaking of the ionic lock that stabilizes the inactive
218 idized state, which results in the transient breaking of the iron-methionine-sulfur bond and sufficie
219 morphological changes are caused by symmetry breaking of the irreducible building blocks, with the fo
221 Here we present a study of local symmetry breaking of the lattice structure on the picosecond time
222 ing-dependent three-fold rotational-symmetry breaking of the local density of states in TBG, with the
223 ectedly large flexoelectric response exhibit breaking of the macroscopic centric symmetry through inh
224 rt effect is mainly governed by the symmetry breaking of the material systems and is gaining extensiv
225 tice scattering are intertwined resulting in breaking of the Matthiessen's rule with increasing EES.
227 p (>C=NH), most likely to MnB, is coupled to breaking of the MnB-(mu-H2O) bond, forming a terminal aq
229 simulations reveal the spontaneous symmetry breaking of the Ni coordination environment after Li ext
230 reaction coordinates of the reaction are the breaking of the O-O bond of H2O2 and the formation of th
231 y acids or H(2) O(2) : reactions that entail breaking of the O-O bond to form a Fe(V) =O fragment.
232 rocenyl units and the imine pai system since breaking of the orbital symmetry results in allowed tran
234 r equilibrated SMO complex exhibits complete breaking of the pi-cation interaction between R451(6.32)
237 Higgs mechanism, i.e., spontaneous symmetry breaking of the quantum vacuum, is a cross-disciplinary
238 -entry pathway, which involves formation and breaking of the salt bridge between side chains of Arg(8
239 is that this large dipole moment drives the breaking of the salt bridges between the two monomer sub
241 onal Theory simulations trace changes in the breaking of the scaling relationship for the Tafel HER m
242 ation of a trigonal intermediate and then by breaking of the scissile bond between the beta- and gamm
244 opening at the Fermi level and an additional breaking of the six-fold rotational symmetry, which pers
245 duced by C(2) symmetry and z-mirror symmetry breaking of the slanted nanograting, STOV is generated t
246 r(2)O(7)/Dy(2)Ti(2)O(7) heterostructure, the breaking of the spin-ice rule in insulating Dy(2)Ti(2)O(
248 I copper species that appears results from a breaking of the strong antiferromagnetic coupling of the
249 place as the arrival of MPT(+) triggers the breaking of the strong Fe-H(delta-)...H(delta+)-O dihydr
250 es is "anticorrelated" in the sense that the breaking of the T252-G248 hydrogen bond is concurrent wi
253 hus a macroscopic witness of the progressive breaking of the tetrahedral hydrogen bond network that m
255 changes and cannot be fully accounted for by breaking of the top contact, we argue that the cause is
256 tilted outward at the tip end, leading to a breaking of the trimerous symmetry and distortion at a r
257 -dependent DFT calculations predict that the breaking of the two strong Ru-O bonds and the formation
260 r role except in the case of gold, for which breaking of the weak Au-S bond that tethers the monolaye
263 Conversely, the corresponding sequential breaking of these bonds is driven by rotation of the sha
265 ies and the intrinsic orientational symmetry-breaking of these materials gives rise to a host of intr
266 e failure of conscious access results in the breaking of this chain and a subsequent slow decay of th
269 ransient (a)cyclic oxocarbenium cations, the breaking of three single C(sp(3))-O bonds, and the forma
273 es, the Kelvin and Yanai modes, owing to the breaking of time-reversal symmetry by Earth's rotation.
275 rength of the deformations, temperature, and breaking of time-reversal symmetry were also investigate
279 ses are linked and what role RV plays in the breaking of tolerance in regulatory T (Treg) cells is un
282 To understand the role of T cells in the breaking of tolerance, an anti-DNA site-specific transge
284 Using the analogy of crystals in space, the breaking of translational symmetry in time and the emerg
285 h states were intimately associated with the breaking of translational symmetry(1,2), resulting in th
289 e but small relative yield that involves the breaking of two molecular bonds and the formation of a n
290 t imaging of charge state-dependent symmetry breaking of two prototypical atomic quantum emitters in
291 eta-strands A' and G that is preceded by the breaking of two to three hydrogen bonds between strands
292 s, the main transition was identified as the breaking of van der Waals interactions between the acyl
293 ion (SFG) spectroscopy to probe the symmetry-breaking of water molecules at a charged silica surface
294 ket in a step-wise process involving (i) the breaking of water-mediated hydrogen bonds and van der Wa
295 tailed analysis of DNA stretching shows that breaking of Watson-Crick bonds is not necessary for the
297 metastable configurations that form from the breaking of weak bonds between metals and underlying hig