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1 iamino-2,3-dicyano-1,4-bis[2-aminophenylthio]butadiene).
2 drosilylation of conjugated dienes including butadiene.
3 ion of terminal alkenes and 2,3-dimethyl-1,3-butadiene.
4 tigated for the conversion of ethanol to 1,3-butadiene.
5 e of a radical trap such as 2,3-dimethyl-1,3-butadiene.
6 tive ultimate carcinogenic metabolite of 1,3-butadiene.
7 , trapped in 80% yield with 2,3-dimethyl-1,3-butadiene.
8 anhydride with 1-(tert-butyldimethylsiloxy)-butadiene.
9 he cycloaddition of oxidopyrylium ylides and butadiene.
10 xposed to a model DNA-damaging chemical, 1,3-butadiene.
11 ical or via cyano radicals reacting with 1,3-butadiene.
12 h classical double bonds of a 2,3-disila-1,3-butadiene.
13 %) with no ene product from 2,3-dimethyl-1,3-butadiene.
14 Dehydrohalogenation gives 2-alkyl-1,3-butadienes.
15 ved with 1-substituted and 1,2-disubstituted butadienes.
16 to afford predominantly (E,E)-1,4-diaryl-1,3-butadienes.
17 ization barriers between some cis- and trans-butadienes.
18 is was developed to generate (E)-1-cyano-1,3-butadiene (1) (10:1 E/Z) via tandem S(N)2 and E2' reacti
19 Diels-Alder cycloaddition of s-trans-1,3-butadiene (1) should yield trans-cyclohexene (7), just a
20 eactions leading to (E)- and (Z)-1-cyano-1,3-butadiene (1) were analyzed by density functional theory
21 radical, benzylallenyl radical, 1-phenyl-1,3-butadiene, 1,2-dihydronaphthalene, and naphthalene), wit
25 adducts of p-methoxycarbonylbenzyl trans-1,3-butadiene-1-carbamate and N,N-dimethylacrylamide have be
26 iamino-2,3-dicyano-1,4-bis[2-aminophenylthio]butadiene (10 microm), also prevented the induction of t
27 sized from (Z,Z)-1,4-bis(tert-butylthio)-1,3-butadiene (2) to evaluate the effects of electron-withdr
29 y-tert-butyldimethylsilane, (E)-1-phenyl-1,3-butadiene, 2,3-dihydrofuran, and 2,5-dihydrofuran) probe
31 d of a hydrogen atom to 1-butyne (3) and 1,2-butadiene (4) to form the 1-buten-2-yl carbocation and r
33 lead directly to 3 was prepared (1-amino-2,3-butadiene, 4) and was found to be an even more potent in
34 yloxy-3Z,5E-hexadienoyl)- 1-aza-2-ethoxy-1,3-butadiene (40) undergoes cycloaddition to produce as the
35 uch as 1-methoxybutadiene (6g) and alkyl 1,3-butadienes (6a, 6j), the diamination is first-order in d
36 nerated polymer-bound 2-(phenylsulfonyl)-1,3-butadiene (9) in situ which underwent Diels--Alder cyclo
37 iamino-2,3-dicyano-1,4-bis(2-aminophenylthio)butadiene], a mitogen-activated protein kinase kinase in
38 ere prepared, including adducts derived from butadiene, acrolein, crotonaldehyde, and styrene, and ex
40 -diazines; and 1,3,4-oxadiazoles), 1-aza-1,3-butadienes, alpha-pyrones, and cyclopropenone ketals.
42 omass-generated) syngas, can be converted to butadiene, although there is no large commercial activit
44 2 equiv of (E,E)-1,4-bis(4-bromophenyl)-1,3-butadiene and 1,4-benzoquinone led to the formation of a
45 ally deuterated counterparts (1,1,4,4-D4-1,3-butadiene and 2,3-D2-1,3-butadiene) at two collision ene
46 e, reacts readily with the conjugated dienes butadiene and 2,3-dimethylbutadiene to afford the corres
47 o-2,3-dicyano-1,4-bis(o-aminophenylmercapto) butadiene and 2-(2-amino-3-methoxyphenyl)-4H-1-benzopyra
49 rosoformaldehyde (CHONO) as dienophiles with butadiene and a series of 1- and 2-substituted dienes.
50 romotes asymmetric hydrohydroxyalkylation of butadiene and affords enantioenriched alpha-methyl homoa
52 a new reaction between 2-nitroperchloro-1,3-butadiene and electron-deficient anilines producing the
53 xample, in the classic Diels-Alder reaction, butadiene and ethylene combine to produce cyclohexene.
56 ydrazine, starting from 2-nitroperchloro-1,3-butadiene and para-nitro aniline, and generated the pote
59 reactions of 1-methoxy-4-trimethylsiloxy-1,3-butadiene and the corresponding o-xylylene with acryloni
60 plexes 9 and 10/11 that contain the isomeric butadiene and trimethylenemethane (TMM) C(4) fragments,
61 a(3)Pi(u) state have been conducted with 1,3-butadiene and two partially deuterated counterparts (1,1
63 der (DA) reactions of phosphaethene with 1,3-butadiene and with isoprene reveal asynchronous transiti
64 rsion of Fe(CO)(4)-cyclobutenes to Fe(CO)(3)-butadienes and CO is thought to proceed through a mechan
65 .e. freely rotating sigma,pi-acyclic carbo-n-butadienes and flexible sigma-cyclic, pi-acyclic carbo-c
66 hat were obtained from 2,3-disubstituted 1,3-butadienes and naphthoquinone followed by dehydrogenatio
71 ymer systems considered here comprise ether, butadiene, and siloxane backbones with grafted imidazole
73 ins acrolein; acrylamide; acrylonitrile; 1,3-butadiene; and ethylene oxide) than combustible cigarett
74 no-2,3-dicyano-1,4-bis(o-aminophenylmercapto)butadiene] and the phosphatidylinositol 3-kinase/Akt inh
75 no-2,3-dicyano-1,4-bis(o-aminophenylmercapto)butadiene] and was abolished by the phosphotidinositol 3
77 es, the 1-(2-oxazolidinon-3-yl)-3-siloxy-1,3-butadienes are still very reactive in Diels-Alder reacti
79 enes (ethylene, propylene, 1-butene, and 1,3-butadiene) are investigated by experiments and density f
81 yl cyanide, 1-octene, and trans-1-phenyl-1,3-butadiene at low temperatures and pressures with passive
82 rts (1,1,4,4-D4-1,3-butadiene and 2,3-D2-1,3-butadiene) at two collision energies of 12.7 and 33.7 kJ
84 rticles (JNPs), made from polystyrene-b-poly(butadiene)-b-poly(methylmethacrylate), PS-PB-PMMA, tribl
88 efficiently to 1,3-cyclohexadiene (CHD), 1,3-butadiene (BD), and (C2H4)Pt(PPh3)2 to form P2(CHD)2 (>9
90 were cast directly from solution using poly(butadiene-block-2-(dimethylamino)ethyl methacrylate) (PB
91 amino-2,3-dicyano-1,4-bis[2-amino-phenylthio]butadiene) blocked ERK phosphorylation, and also blocked
92 ft), closure to trialene (bicyclo[1.1.0]-1,3-butadiene), bond-shift isomerization to exchange C-2 and
93 s of DEB are produced metabolically from 1,3-butadiene, but S,S-DEB is the most cytotoxic and genotox
94 of label scrambling between maleic acid and butadiene, butadiene is unlikely to be the primary react
95 tercepted by acyclic, 2-silyloxy-substituted butadienes by highly regioselective (4 + 3) cycloadditio
96 rgic reaction of the ethynyl radical and 1,3-butadiene, C(2)H + H(2)CCHCHCH(2) --> C(6)H(6) + H, unde
97 -bearing radical, silylidyne (SiH), with 1,3-butadiene (C4 H6 ) in the gas phase under single-collisi
98 ,6-dialkylphenyl)-1,4-diaza-2,3-dimethyl-1,3-butadiene) carrying nearly unperturbed nitric oxide radi
99 lododecatriene by selective trimerization of butadiene catalyzed by TiCl(4) and ethylaluminum sesquic
102 polymers (S = poly(styrene) and B = poly(1,4-butadiene)) comprised of a broad polydispersity B block
105 amino-2,3-dicyano-1,4-bis[2-amino-phenylthio]butadiene), demonstrating that signaling pathways downst
107 ar and atom-efficient synthesis of 2-aza-1,3-butadiene derivatives has been developed via nickel-cata
108 -allylic substrates lead to amido 2-sulfinyl butadiene derivatives in excellent yields, with total ch
110 of selected dilithium derivatives of the 1,3-butadiene dianion including cis-dilithio-1,4-bis(TMS)-2-
111 corporation of a poly(ethylene oxide)-b-poly(butadiene) diblock copolymer, we show that membrane prot
112 A alkylation of nearest-neighbor adenines by butadiene diepoxide (BDO(2)) was determined in the oligo
113 ase eta does not bypass the (R,R)- and (S,S)-butadiene diolepoxide N(2)-guanine-N(2)-guanine intra- s
115 isolated as pure compounds: (E)-1-cyano-1,3-butadiene (E-1), (Z)-1-cyano-1,3-butadiene (Z-1), 4-cyan
117 onal equilibria of 10 methyl-substituted 1,3-butadienes [(E)- and (Z)-1,3-pentadiene; 2-methyl-1,3-bu
118 s [(E)- and (Z)-1,3-pentadiene; 2-methyl-1,3-butadiene; (E)-2-methyl-1,3-pentadiene; 2,3-dimethyl-1,3
119 E)-2-methyl-1,3-pentadiene; 2,3-dimethyl-1,3-butadiene; (E,E)-, (E,Z)-, and (Z,Z)-2,4-hexadiene; 2,5-
120 n byproducts, formed in the trimerization of butadiene: eleven tricyclic C(12)H(20) and one tetracycl
121 arising from the alkylation of adenine N1 by butadiene epoxide (BDO), followed by deamination to deox
123 obutane, propylene, 2-methylpropene, and 1,3-butadiene even xenon are coencapsulated with other guest
126 different feedstock possibilities to produce butadiene, followed by a comprehensive summary of the cu
127 n mice treated with 3, 62.5, or 1250 ppm 1,3-butadiene for 10 days and rats exposed to 3 or 62.5 ppm
128 0 days and rats exposed to 3 or 62.5 ppm 1,3-butadiene for 10 days, or to 1000 ppm 1,3-butadiene for
129 ,3-butadiene for 10 days, or to 1000 ppm 1,3-butadiene for 90 days, using a newly developed immunoaff
131 ontrast, Y-DeAlBEA was highly active for 1,3-butadiene formation but exhibited no activity for ethano
132 -C(7)H(11)) ligand (<Zr-C> = 2.56(6) A), the butadiene fragment (<Zr-C> = 2.43(5) A), and the amide n
135 n this context, on-purpose production of 1,3-butadiene from biomass-derived feedstock is an interesti
136 FTO process, (ii) the catalytic synthesis of butadiene from ethanol, butanol and butanediols, and (ii
139 ethyl ester with 2,3-bis(phenylsulfonyl)-1,3-butadiene gives rise to a 7-oxa-1-azanorbornane cycloadd
143 alization of unactivated 1,3-dienes, such as butadiene, has been achieved by employing different comm
144 to exhibit high activity and selectivity for butadiene hydrogenation to butenes under mild conditions
145 nd a TADDOL-derived phosphoric acid promotes butadiene hydrohydroxyalkylation to form enantiomericall
148 tic conversion of ethanol and butanediols to butadiene, including thermodynamics and kinetic aspects
149 d; experiments with partially deuterated 1,3-butadiene indicate the formation of the thermodynamicall
150 a strain that acquired higher levels of 1,3-butadiene-induced DNA damage, around the same genes, ult
151 EiJ mice, which acquired relatively less 1,3-butadiene-induced DNA damage, we observed increased tran
152 an industrially available bulk chemical, 1,2-butadiene, into dimethyl adipate, which is a valuable fe
153 3-formyl-4-(2-formylaryl)-1-sulfinyl-(1Z,3E)-butadiene iron tricarbonyl complex also underwent diaste
157 oselective carboboration of 1,1-bisboryl-1,3-butadiene is developed to generate enantioenriched 3,6'-
158 tive cyclization of one s-cis to one s-trans butadiene is facile and exergonic, leading to the observ
159 The dehydration of crotyl alcohol to 1,3-butadiene is facile and occurs over the mildly Bronsted
164 crambling between maleic acid and butadiene, butadiene is unlikely to be the primary reaction interme
166 The same step with two s-cis or s-trans butadienes is either kinetically or thermodynamically un
167 Diels-Alder reaction of N-sulfonyl-1-aza-1,3-butadienes is reported enlisting a series of 19 enol eth
168 c spectroscopy of benzylallene (4-phenyl-1,2-butadiene) is presented along with a detailed analysis o
169 es to purify commodity chemicals such as 1,3-butadiene, isobutene, and 1-butene, but the very similar
171 ) Sigmag (+) , a(3) Piu ), with 2-methyl-1,3-butadiene (isoprene; C5 H8 ; X(1) A') accessing the trip
172 , commercially available acyclic 1,3-dienes, butadiene, isoprene, and 2,3-dimethylbutadiene, couple t
173 rbene 3-butenylidene rearranges primarily to butadiene, its perfluoro counterpart is predicted to be
174 valent to a sigma(2), pi-coordination of the butadiene ligand to the element atom as it is typical fo
175 es and alkanolamines are separated on a poly(butadiene)-maleic acid on silica stationary phase using
176 incorporation of a bioadhesive coating, poly(butadiene-maleic anhydride-co-L-DOPA) (PBMAD), to non-bi
178 analyses of several adducts derived from 1,3-butadiene metabolites provided new insight into species
180 norbornene, acrylonitrile, methyl acrylate, butadiene, methyl(vinyl)silanediamine, methyl crotonate,
181 /ethylene, propyne/propylene, and butyne/1,3-butadiene mixtures, with unprecedented dynamic separatio
182 C bond path with each of the pentadienyl and butadiene moieties, contrary to the usually depicted glo
186 benzene circuit results in a flexible 'carbo-butadiene' molecule that has a conductance 40 times lowe
189 d amino acids (FAAs) 1 skeleton from racemic butadiene monoepoxide as a starting material and its app
190 ase inhibitor, was carried out starting from butadiene monoepoxide through a synthetic sequence invol
193 ansformations that entail the combination of butadiene or isoprene (common feedstock), an enoate (pre
194 transition states (TSs) for the phosphethene-butadiene or isoprene DA reactions are earlier than the
195 hrough reaction of pyridyl radicals with 1,3-butadiene or sequentially with two acetylene molecules,
196 both the direct conversion of ethanol to 1,3-butadiene or the formation of this product by the reacti
197 ratio (OR) = 2.30; 95% CI: 1.44, 3.67], 1,3-butadiene (OR = 2.23; 95% CI: 1.28, 3.88), benzene, and
198 benzene (OR = 3.27; 95% CI: 1.17, 9.14), 1,3-butadiene (OR = 3.15; 95% CI: 1.57, 6.32), and benzene.
199 b-PMOXA, and poly(ethylene oxide)-block-poly(butadiene) (PEO-b-PB)) were reacted with externally adde
200 itoring data, concentrations of benzene, 1,3-butadiene, perchloroethylene, and hexavalent chromium de
201 veral different hydrophobic blocks: poly(1,4-butadiene), poly(-caprolactone), and poly(methyl methacr
202 actide) that relies on self-assembly of poly(butadiene)-poly(lactide) (PB-PLA) diblock copolymers fol
203 which internally crosslinked poly(styrene-co-butadiene) polymer nanoparticles self-assembled to form
204 Large (200 nm) poly(ethylene oxide)-b-poly(butadiene) polymer vesicles fuse into giant (>1 mum) ves
205 nds have been investigated as initiators for butadiene polymerization and ethylene oligomerization.
206 Another probe is based on the diphenyl-1,4-butadiene possessing the boronic acid group in the 4' po
207 iamino-2,3-dicyano-1,4-bis[2-aminophenylthio]butadiene), prevented BDNF's suppressive effects on coca
208 propargyl epoxides leads to 1,2-diborylated butadienes probably via en allenylboronate intermediate.
209 ]octa-2,5-diene, and benzobarrelene with 1,3-butadienes proceed in excellent yields using cobalt-base
210 the (E) and (Z) isomers of the resulting 1,3-butadiene radical cations depends largely on steric effe
211 re much lower than that of the parent ethene-butadiene reaction, 28 kcal/mol, even though the exother
212 les (C(2)) with C(4)H(6) isomers such as 1,3-butadiene represent a potential, but hitherto unnoticed,
213 zed hydrogen transfer from 4-aminobutanol to butadiene results in the pairwise generation of 3,4-dihy
214 ion, the main constituents of tires, styrene butadiene rubber (SBR) and polyisoprene (IR), has been i
215 2) cofeed impact on the pyrolysis of styrene butadiene rubber (SBR) was investigated using thermograv
216 d by black foams (66%, identified as styrene-butadiene rubber) and to a lesser extent fibers/lines (2
217 eused scrap tires (main constituent, styrene butadiene rubber, SBR), which might be harmful to the en
218 ere employed during 1943-1984 in two styrene-butadiene rubber-manufacturing plants in the United Stat
220 ith cyclohexa-1,3-diene and 2,3-dimethyl-1,3-butadiene (several cycloadducts characterized by X-ray c
221 iamino-2,3-dicyano-1,4-bis(2-aminophynylthio)butadiene]-specific inhibitors of mitogen-activated prot
223 ice was printed in transparent acrylonitrile butadiene styrene (ABS) and contained a 400 mum wide str
224 ely 180 mug/min), styrene from acrylonitrile butadiene styrene (ABS) and high-impact polystyrene (HIP
225 ed for in situ analysis during acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA) 3D pri
227 structure made from commercial Acrylonitrile Butadiene Styrene (ABS) modules, known as LEGO(R) blocks
229 microparticles in the polymer acrylonitrile butadiene styrene (ABS), which may be used with a commer
231 nd sludge, and polystyrene and acrylonitrile butadiene styrene were the most common polymers quantifi
232 electrode were fabricated from acrylonitrile-butadiene-styrene (ABS) and conductive graphene polylact
233 vapor bath was used to smooth acrylonitrile-butadiene-styrene (ABS) surfaces and facilitate bonding
234 of carbon nanotubes (CNTs) and acrylonitrile-butadiene-styrene (ABS) was analyzed with respect to its
239 entafluorophenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; TFA = trifluoroacetate] has been reported to
240 entafluorophenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; TFA is trifluoroacetate] converts benzene, et
241 n to one of the terminal carbon atoms of 1,3-butadiene, the collision complex undergoes trans-cis iso
242 on VPO catalysts to produce maleic acid and butadiene, the isotopic labels were observed in both the
243 on, which undergoes thermal rearrangement to butadiene, the perfluoro compound will yield hexafluoroc
245 the reaction of 1,1-difluoroallene with 1,3-butadiene, the results of which indicate that the use of
247 with thiophene to give eta(5)-thiophene and butadiene-thiolate complexes, (eta(5)-C(4)H(4)S)Mo(PMe(3
248 To specifically examine metabolism of 1,3-butadiene to 1,2;3,4-diepoxybutane, the formation of the
249 4-addition across the commodity chemical 1,3-butadiene to afford skipped polyene products is reported
250 ination of H2C horizontal lineNH and cis-1,3-butadiene to form a six-membered ring was examined by qu
251 oceed efficiently from 1 to 2,3-dimethyl-1,3-butadiene to form Diels-Alder product 3 with a zero-orde
252 gered carbon-carbon coupling of alcohols and butadiene to form products of carbonyl crotylation with
255 ed dienes are copolymerized efficiently with butadiene to stereoregular copolymers by [(mesitylene)Ni
256 of 1,4-, 1,3-, and 2,3-bis(2-nitroaryl)-1,3-butadienes to afford 2,2'-, 2,3'-, and 3,3'-biindoles, r
257 s of many plants emit isoprene (2-methyl-1,3-butadiene) to the atmosphere, a process which has import
258 fting materials [such as 1,1,4,4 Tetraphenyl Butadiene (TPB)] have several disadvantages and are unre
260 , 1,4-diamino-2,3-dicyano-1,4-bis(methylthio)butadiene (U0126) and 2'-amino-3'-methoxyflavone (PD9805
262 eatment with 1,4-diamino-2,3-dicyano-1,4-bis butadiene (U0126) could significantly inhibit mouse brai
263 y 1,4-diamino-2,3-dicyano-1,4-bis(methylthio)butadiene (U0126) of an HGF downstream kinase mitogen-ac
264 diamino-2,3-dicyano-1,4-bis(2-aminophynyltio)butadiene (U0126), and ER antagonist ICI-182780 failed t
266 amino-2,3-dicyano-1,4-bis(2-aminophenylthio)-butadiene (U0126), attenuated insulin action, indicating
267 diamino-2,3-dicyano-1,4-bis(2-aminophynyltio)butadiene (U0126), or Rho kinase signaling with R-(+)-tr
268 r 1,4-diamino-2,3-dicyano-1,4-bis(methylthio)butadiene (U0126), two ERK kinase MAP inhibitors, wherea
269 y 1,4-diamino-2,3-dicyano-1,4-bis(methylthio)butadiene (U0126), which blocks the phosphorylation of E
270 1,4-diamino-2,3-dicyano-1,4-bis(methylthio) butadiene (U0126)], and therefore cAMP-dependent target
271 [1,4-diamino-2,3-dicyano-1,4-bis(methylthio)butadiene (U0126)], whereas PAR2 effects were only block
272 mprises initial isomerizations of allenes to butadienes under N2 and subsequent oxidations of N-hydro
273 no-2, 3-dicyano-1, 4-bis (2-aminophenylthio) butadiene (UO126; for ERK1/2), trans-1-(4-hydroxyclycloh
274 benzenes were prepared from 2,3-dimethyl-1,3-butadiene using Diels-Alder cycloadditions and Pd(0)-cat
276 ydes and ketones, furans, acrylonitrile, 1,3-butadiene, vinyl chloride, and nitromethane) in the micr
277 es RCH=CH(2) (R = SiMe(3), CH(3)CH(2)CH(2)), butadiene, vinylarenes ArCH=CH(2) (Ar = phenyl, 4-methyl
278 enteen SBS triblock copolymers with poly(1,4-butadiene) volume fractions 0.27 </= f(B) </= 0.82, we d
281 reactions of substituted cyclopropenes with butadiene were explored with M06-2X density functional t
285 chiral 1-(2-oxazolidinon-3-yl)-3-siloxy-1,3-butadienes were prepared from readily available starting
286 similar in mice exposed to 3 or 62.5 ppm 1,3-butadiene, whereas 2-hydroxy-3-butenyl-valine was 3-fold
287 )(-), each with two pi bonds, are similar to butadiene, while H(2)B(10)(2-), H(2)B(11)(-), and H(2)B(
288 ctive, while 1-methoxy-4-trimethylsiloxy-1,3-butadiene will give a small preference ( approximately 5
289 solution in the presence of 2,3-dimethyl-1,3-butadiene with a quantum efficiency of approximately 38%
291 tensive efforts to cooligomerize isoprene or butadiene with alkynes in a controlled fashion by zerova
293 tepwise reactions of tetrafluoroethylene and butadiene with density functional theory, DFT (B3LYP and
295 ding the parent Diels-Alder cycloaddition of butadiene with ethylene, electrocyclic ring-opening of c
296 solid catalyst for the polymerization of 1,3-butadiene with high stereoselectivity (>99% 1,4-cis).
297 the treatment of a 1-aminoethyl-substituted butadiene with maleic anhydride at 0 degrees C to room t
298 volatile hydrocarbon isoprene (2-methyl-1,3-butadiene), with subsequent analysis of isoprene by head
299 cylaniline and the volatile 2,3-dimethyl-1,3-butadiene, with an outlier being operationally defined a
300 1-cyano-1,3-butadiene (E-1), (Z)-1-cyano-1,3-butadiene (Z-1), 4-cyano-1,2-butadiene (2), and 2-cyano-