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1 )))(4)] (where Et is ethyl and (t)Bu is tert-butyl).
2 titution product formed when (1s,3s)-3-(tert-butyl)-1-methylcyclobutyl methanesulfonate, 7, reacts in
3 ng 3,5-di-tert-butylcatechol and 3,5-di-tert-butyl-1,2-bezoquinone we demonstrate that gamma-terpinen
4 eudo)benzylic primary amines and 2,6-di-tert-butyl-1,4-benzoquinone, undergo efficient allylation to
8 of natural product ligustrazine, (Z)-N-tert-butyl-1-(3,5,6-trimethylpyrazin-2-yl)methanimine oxide (
9 lexes of Ge(II), Sn(II), and Pb(II) with a 1-butyl-1-methyl-piperidinium cation (Bmpip), featuring un
10 h the room temperature ionic liquid (RTIL) 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)
11 lease cycle is studied in the ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)
14 es of N-(3-hydroxy-4-(4-phenylpiperazin-1-yl)butyl)-1H-indole-2-carboxamide analogues as high affinit
15 r, features a one-step Michael addition of t-butyl 2-((diphenylmethylene)amino)acetate (24) to (E)-be
16 l failure/late recurrence as compared with n-butyl 2-cyanoacrylate (OR: 3.87, CI: 1.73 to 8.68, I(2)
18 C](+/-)-7-methoxy-3-(4-(4-(methylthio)phenyl)butyl)-2,3,4,5-tetrahydro-1H-benzo[d]azepin-1-ol ((11)C-
19 ,7-dimethoxy-3,4-dihydroisoquinolin-2(1H)-yl)butyl)-2-(2-(18)F-fluoroethoxy)-5-methylbenzamide ((18)F
20 n reaction performance between 4,4'-di- tert-butyl-2,2'-bipyridine (dtbpy)- and 2,2'-bipyridine (bpy)
22 as well as the free ligand 2-[[(3,5-di-tert-butyl-2-hydroxyphenyl)imino]methyl]-4,6-di-tert-butylphe
24 phiphilic poly[(2-methyl-2-oxazine)- grad-(2-butyl-2-oxazoline)] (PMeOzi- grad-PBuOx) as well as the
25 Mn((tbu)dhbpy)Cl, where 6,6'-di(3,5-di- tert-butyl-2-phenolate)-2,2'-bipyridine = [(tbu)dhbpy](2-), w
26 lex oxo(triphenylphosphine) (bis(3,5-di-tert-butyl-2-phenoxo)amido)rhenium(V), (ONO(Cat))ReO(PPh3), r
28 ctually forms the 3,5-dinitro isomer, 4-tert-butyl-3,5-dinitrobenzaldehyde, instead of the claimed 2,
29 l chloride for the synthesis of (-)-(S)-tert-butyl-3-(4-bromophenyl)-3,6-dihydropyridine-1(2H)-carbox
30 dr o-2H-6-pyranylbutanoic acid (2) and 3-((5-butyl-3-methyl-5,6-dihydro-2H-pyran-2-yl)-methyl)-4-meth
33 RMs) formed by the ionic liquid-surfactant 1-butyl-3-methylimidazolium 1,4-bis-2-ethylhexylsulfosucci
34 f the room-temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)im
35 tive layer and a blend of an ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)im
36 planar thin films of an ionic liquid (IL) 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)im
37 ium bromide (CTAB) into a 125muL volume of 1-butyl-3-methylimidazolium bis(trifluorosulfonyl)imide [C
38 from two inexpensive commercial reagents: 1-butyl-3-methylimidazolium bromide and sodium borohydride
41 ynthesized to contain different amounts of 1-butyl-3-methylimidazolium nitrate IL ([bmim][NO(3)]), re
42 study, an imidazolium ionic liquid (IL; 1- n-butyl-3-methylimidazolium tetrafluoroborate, BMI.BF4) wa
43 lying ion motion and diffusivities in poly(1-butyl-3-vinylimidazolium-hexafluorophosphate) polymerize
47 to differentially protected diester, 1-(tert-butyl) 4-methyl (1R,2S,4R)-2-methylcyclohexane-1,4-dicar
48 ntly found that (11)C-ER176 ((11)C-(R)-N-sec-butyl-4-(2-chlorophenyl)-N-methylquinazoline-2-carboxami
49 mended by Cramer, e.g., ethyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propanoate and benzenepropanoic a
52 e presence of 2,4,6-collidine or 2,6-di-tert-butyl-4-methyl-pyridine, the deprotonation of the initia
53 the occurrence of SPAs, such as 2,6-di-tert-butyl-4-methylphenol (BHT) and 2,4-di-tert-butyl-phenol
54 ected in the PCPs, of which only 2,6-di-tert-butyl-4-methylphenol (BHT, < method quantification limit
56 With NIS/TfOH as the promotor, 2,6-di-tert-butyl-4-methylpyridine as the base, and a dichloromethan
57 ultiwalled carbon nanotubes (f-MWCNTs) and 1-butyl-4-methylpyridinium hexafluorophosphate (ionic liqu
58 cation of the aryloxy radical to 2,6-di-tert-butyl-4-tritylphenoxyl radical, which contains a trityl
59 d was UR-DEBa242 (26, 1-[4-(1H-Imidazol-4-yl)butyl]-4-{(1E,3E)-4-[4-(dimethylamino)phenyl]buta-1,3-di
60 ridin-2-yl)benzo[d]thiazole (L3), 2-(4-(tert-butyl)-6-phenylpyridin-2-yl)benzo[d]thiazole (L4), 2,6-b
61 icacid (8.19%), 9,O-ctadecenoicacid (5.00%), butyl-6,9,12,15-octadecatetraenoate (4.03%), hexadecanoi
62 amido complex FI(2)ZrX(2) (FI = 2,4-di- tert-butyl-6-((isobutylimino)methyl)phenolate, X = NMe(2)) is
65 ived from Schiff bases: (2,4,8,10-tetra-tert-butyl-6-phenyldibenzo[d,h][1,3,6,2]dioxazaboronine (3) a
66 =4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diisopropylphenyl)
67 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) that features a strongly pol
68 =4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) towards mono- and disubstitu
69 4,5-bis(2,6-diiso-propylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) with CO(2) , PhNCO and N(2)
71 Bu) (3) (Cp = cyclopentadienyl, (t)Bu = tert-butyl), a strained 4-membered metallacycle bearing a fre
72 treatment with the radical scavenger N-tert-butyl-a-phenylnitrone (PBN) also reduced pericyte death,
73 ligands (THF, diethyl ether, MTBE, THP, tert-butyl acetate) are characterized using (1)H NMR and X-ra
74 osphere gave higher levels of key volatiles (butyl acetate, 2-methylbutyl acetate and hexyl acetate),
75 by copolymerizing traditional PSA monomers, butyl acrylate and acrylic acid, with mussel-inspired ly
79 ith poly(methyl methacrylate) (PMMA), poly(n-butyl acrylate) (PBMA), poly(2-dimethylamino)ethyl metha
81 acrylics (methyl acrylate, ethyl acrylate, n-butyl acrylate, and methyl methacrylate) in broad molecu
82 ino)ethyl methacrylate) (PDMAEMA) and poly(n-butyl acrylate-block-methyl methacrylate) (PBA-b-PMMA).
84 ting substrates, such as methyl, ethyl, tert-butyl acrylates, and substituted styrenes with 2-iodo-N,
85 igation of the catalytic dehydration of tert-butyl alcohol (TBA) used to probe the activities of OH g
86 ative studies using the probe compounds tert-butyl alcohol and nitrobenzene verified the bubble-water
90 ver, the state-of-the-art is limited to tert-butyl alk-3-ynoate substrates that possess requisite aci
91 an effect eliminated by ROS scavenger N-tert-butyl-alpha-phenylnitrone (PBN) and P2X7R antagonist A43
92 ease in the peak-to-peak amplitude of N-tert-butyl-alpha-phenylnitrone (PBN) ESR spectrum during stor
93 o monitor short-lived lipid-radicals, N-tert-butyl-alpha-phenylnitrone (PBN), a spin-trap, is commonl
94 ective Co(III)-catalysis, directed by N-tert-butyl amides, is achieved to avail mono- or dihydroaryla
95 e derivatives containing either a allyl(tert-butyl)amine or a 1,2,3,6-tetrahydropyridine unit in prop
96 e, and conformational properties, allyl(tert-butyl)amine was found to be the best hydride donor for t
98 n addition of diazabicyclooctane and tetra(n-butyl)ammonium iodide to halothane solutions, indicating
99 acrylate" group, a high viscosity blend of n-butyl and 2-octyl cyanoacrylate was applied until hemost
100 e the structural similarity between the tert-butyl and amyl moieties, potassium tert-amylate in tolue
102 y (azoxystrobin, fluazifop acid, fluazifop-p-butyl, and pirimiphos-methyl) displayed cross-ring fragm
103 kyl-substituted analogues, and notably the n-butyl-arylamides (22b and 22c), all showed improved affi
104 rted that azodicarboxylates, such as di-tert-butyl azodicarboxylate (DBAD), are effective redox-activ
106 h a stoichiometric amount of 1-azido-4-(tert-butyl)benzene N(3)(C(6)H(4)-p-(t)Bu) furnished the corre
107 derivative 15 and the (4-hydroxy-3,5-di-tert-butyl)benzoyl-analogue 21 which were effective in reduci
108 s of mono-n-butyl phthalate, a metabolite of butyl benzyl phthalate (BBP), were associated with an in
109 oddler over 24 h to diethyl phthalate (DEP), butyl benzyl phthalate (BBzP), and di-2-ethylhexyl phtha
110 n toxicity and adverse health effects (i.e., butyl benzyl phthalate [BBzP], dibutyl phthalate [DBP],
112 (N(2) -alkyl-dGTP) derivatives with methyl, butyl, benzyl, or 4-ethynylbenzyl substituents were prep
113 ith a sigma-bond of a strained bicyclo[1.1.0]butyl boronate complex to enable addition of the aryl pa
114 monstrate that highly strained bicyclo[1.1.0]butyl boronate complexes (strain energy ca. 65 kcal/mol)
115 repeatability (% RSD for hexyl butanoate and butyl butanoate of 16.5 and 5.9, respectively, from 9 de
116 g oxetanes, sugar moieties, azetidines, tert-butyl carbamates (Boc-group), cyclobutanes, and spirocyc
117 the new electron-accepting units and di(tert-butyl)carbazole (DTC) as the electron-donating units.
118 and DTCBPy, bearing two carbazolyl and 4-(t-butyl)carbazolyl groups, respectively, at the meta and o
120 vatives, 1-(10H-phenothiazin-2-yl)vinyl tert-butyl carbonate (2APT-D6) was selected for its high pote
122 atients, liver lymphatic embolization with n-butyl cyanoacrylate glue resulted in sustained improveme
123 p(ttt) )2 DyCl] (1Dy Cp(ttt) =1,2,4-tri(tert-butyl)cyclopentadienide) by the triethylsilylium cation
124 alkylesters (dimethyl DME, diethyl DEE, di-n-butyl DBE) were strategically designed to copolymerize w
126 inyl magnesium bromide with 2,2-dimethyl-6-t-butyl-dimethyl-silyoxy-methyl-1-cyclo-hexanone to give a
127 use of a glycosyl phosphate with 6- O- tert-butyl diphenyl silyl group and a d-glucuronic acid-conta
128 fold (tBu)L ((tBu)L = 5-mesityl-(1,9-di-tert-butyl)dipyrrin) facilitate intramolecular 1,3-dipolar cy
129 the blocking was observed with rhodamine 19 butyl ester (C4R1), whereas the octyl ester (C8R1) was o
130 luorophenacetyl)-l-alanyl]-S-phenylglycine t-butyl ester (DAPT) significantly rescued Tat-impaired NP
131 luorophenacetyl)-L-alanyl]-S-phenylglucine t-butyl ester (DAPT), a gamma-secretase inhibitor, which i
132 he acid nitrone 4 and its corresponding tert-butyl ester 3 was initiated by a Michael reaction to int
134 ion of pyrrole-1,2,5-tricarboxylic acid tert-butyl ester dimethyl ester with electrophiles such as me
135 fluorophenacetyl)-l-alanyl]-S-phenylglycinet-butyl ester negated the up-regulation of MCT1 by LiCl, d
137 structure of Boc-l-4-thiolphenylalanine tert-butyl ester revealed crystal organization centered on th
138 complexes of alkenylboranes bearing two tert-butyl ester substituents was studied by EPR spectroscopy
139 ers, in which the carbonyl group of the tert-butyl ester was oriented toward and away from the NHC ri
140 e we identify a minor contaminant (pepstatin butyl ester) as the active anti-parasitic principle.
142 orophenacetyl)-L-alanyl]-(S)-phenylglycine t-butyl ester; DAPT) was administered subcutaneously three
144 llowing for the selective conversion of tert-butyl esters to acid chlorides in the presence of other
145 um-catalyzed N-arylations of amino acid tert-butyl esters using 4-bromo-N,N-dimethylaniline as a coup
148 was used from the 1990s to 2007, methyl tert-butyl ether (MtBE) concentrations >/=0.2 mug/L were foun
150 normal mammary gland tissue with methyl-tert-butyl ether (MTBE) results in three phases: an upper non
153 fermenting organics (e.g., diethylene glycol butyl ether) in all AFFF formulations to hydrogen and ac
155 the more volatile contaminants (methyl-tert-butyl ether, acetone, pentanone, butanol, and hexanol) a
161 ation 8N by C-C sigma-interactions and the t-butyl group amounts to 10.8 kcal/mol in the gas phase.
165 branched alkoxy groups, such as the unique t-butyl group found in a variety of natural products, is s
167 rom the Lambda-configured catalyst, the tert-butyl group that shields the si face of the substrate pl
171 TBM-SEGPHOS, a ligand containing 3,5-di-tert-butyl groups and widely used for copper-catalyzed hydrof
173 ups replacing four methyl groups in the tert-butyl groups at the 3- and 6-positions of 1,3,6,8-tetra-
175 van der Waals interactions between the tert-butyl groups of 1c and the alkyl chain of the cationic a
177 ng with 9-(4-[(18)F]-fluoro-3-[hydroxymethyl]butyl)guanine ([(18)F]FHBG) of B7H3-sr39tk CAR T cells i
179 st, Cu(phen)Cl2, in conjunction with di-tert-butyl hydrazine dicarboxylate and an inorganic base prov
180 safe, and environmentally friendly tertiary butyl hydrogen peroxide (TBHP)-mediated rearrangement of
184 eteroatom substituted cyclic alkenes by tert-butyl hydroperoxide (70% TBHP in water) using catalytic
185 tive effect against oxidative stress in tert-butyl hydroperoxide (t-BHP)-challenged RAW264.7 macropha
186 are chosen for efficient co-delivery of tert-butyl hydroperoxide (TBHP) and iron pentacarbonyl (Fe(CO
187 gal as an organophotoredox-catalyst and tert-butyl hydroperoxide (TBHP) as an oxidant at ambient temp
188 of tetrazoles have been achieved using tert-butyl hydroperoxide (TBHP) as the methyl source, alkyl d
189 tions in dioxane as solvent and aqueous tert-butyl hydroperoxide (TBHP) as the terminal oxidant.
190 AMPK during oxidative stress induced by tert-butyl hydroperoxide (TBHP) in HEK293T cells and C. elega
193 ns of amino acids after incubation with tert-butyl hydroperoxide and hypochlorous acid in vitro, we i
195 ers has been accomplished in minutes using t-butyl hydroperoxide in the presence of tetrabutylammoniu
196 ve cleavage reactions of arylalkenes by tert-butyl hydroperoxide that occur by free radical processes
197 05 mM Ti(IV), 160 mM cyclohexene, 24 mM tert-butyl hydroperoxide) are 9 +/- 2 M(-2) s(-1); whereas wi
198 ophiles including hydrazines, methylamine, t-butyl hydroperoxide, N-hydroxylamine, alpha-chloroacetal
201 compounds protected HepG2 cells against tert-butyl hydroperoxide-induced oxidative cytotoxicity.
202 nsor was developed for determination of tert-butyl-hydroquinone (TBHQ) in edible vegetable oils, base
203 ion of the synthetic antioxidant 2,6-di-tert-butyl-hydroxytoluene (BHT) at 20 and 800ppm was tackled.
204 ly(acrylic acid)-block-poly(4-vinylbenzyl)-3-butyl imidazolium bis(trifluoromethylsulfonyl)imide, in
205 he size of the residue R from methyl to tert-butyl in several steps, we find that the dynamics drasti
206 n of photoexcited iso-propyl iodide and tert-butyl iodide molecules (i-C(3)H(7)I and t-C(4)H(9)I) thr
208 evealed that ethyl isothiocyanate (EITC) and butyl isothiocyanate (BITC), which might have been produ
210 along with 4-mercaptobutyl and 4-(methylthio)butyl isothiocyanate, associated with typical rocket and
214 y reacting boronic esters with bicyclo[1.1.0]butyl lithium, react with electrophiles to achieve the d
215 n with higher gestational exposure to mono-n-butyl (MBP) and mono-3-carboxypropyl (MCPP) concentratio
216 ymerized or copolymerized (50mol% each) with butyl methacrylate (BMA) from a reversible addition - fr
217 er based on dimethylaminoethyl methacrylate, butyl methacrylate and methyl methacrylate, E) to enhanc
218 methylamino)ethyl methacrylate)-block-poly(n-butyl methacrylate) (DB) and poly(ethylene glycol)-block
219 methylamino)ethyl methacrylate)-block-poly(n-butyl methacrylate) (ODB), self-assemble into micelles,
220 styrene, poly(methyl methacrylate), and poly(butyl methacrylate), poly(tert-butyl methacrylate).
223 ously in the urine of pregnant women: mono-n-butyl (MnBP, 200 nM), monobenzyl (MBzP, 3muM), mono-2-et
224 e, or an acetamide substituent on the N-tert-butyl moiety and para-substituted phenyl or naphthlyl mo
225 e surface using n-alkylamines (NH2R', R' = n-butyl, n-hexyl, n-octyl) (</=0.01 carboxylates nm(-2)).
226 romethylsulfonyl)imide ([C2mim][NTf2]) and N-butyl-N-methyl-pyrrolidinium bis(trifluoromethylsulfonyl
227 ompared against that in the widely studied N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)
228 n cells, where the alkyl groups are ethyl, n-butyl (nBu), and, for O (6)-alkyl-dG, pyridyloxobutyl.
229 hesized and characterized methyl (Me)- and n-butyl (nBu)-PTEs in two diastereomeric configurations (S
231 esis of isoxazolines in the presence of tert-butyl nitrite, quinoline, and the Sc(OTf)3 catalyst in D
234 iscovery from this study is that tetra( tert-butyl) octabenzo[8]circulene in the single crystals self
235 cient threading with respect to the exo-tert-butyl ones, leading to apparent association constants mo
236 P)Nb identical withCH(OAr) and NCR (R = tert-butyl or 1-adamantyl) results in formation of a neutral
239 The most prevalent compounds were 2,6-di-t-butyl-p-benzoquinone, diphenylamine, 4,4'-di-t-octyl dip
240 late (DEP), di-n-butyl phthalate (DnBP), and butyl paraben (BP) and diluted to make creams with conce
241 um benzoate (SB), potassium sorbate (PS) and Butyl paraben (BP) have been widely used in food and pha
242 emerging contaminants (viz., methyl paraben, butyl paraben, diclofenac, and triclosan) from exposed m
243 en urinary paraben biomarker concentrations (butyl paraben, ethyl paraben, methyl paraben [MP], and p
244 lic acids was achieved employing the di-tert-butyl peroxide as a source of free radicals and a dehydr
248 ol, we showed the in situ conversion of tert-butyl peroxy compounds into peresters with the aid of ex
249 t-butyl-4-methylphenol (BHT) and 2,4-di-tert-butyl-phenol (DBP), in humans (fat tissues, serum, urine
250 alcohol initiator and magnesium 2,6-di-tert-butyl phenoxide as a catalyst, was investigated in order
251 4-tert-butylphenyldiazonium and bis(4-(tert-butyl)phenyl)iodonium salts, as well as phenyl iodide, n
252 bly, pyraclostrobin, dibutyl phthalate, tert-butyl-phenyl diphenyl phosphate, and the isopropylated t
253 up to 2340 pg m(-3) were observed for Tri-n-butyl phosphate (TnBP) at a land-based sampling location
254 ro-2-propyl) phosphate (TCiPP), EHDPP, tri-n-butyl phosphate (TnBP), and triphenyl phosphate (TPhP).
255 dichloroisopropyl) phosphate (TDCIPP), tri-n-butyl phosphate (TNBP), triphenyl phosphate (TPHP), and
256 that di-isobutyl phthalate (DiBP) and di- n-butyl phthalate (DnBP) were the main PAEs released from
257 was mixed with diethyl phthalate (DEP), di-n-butyl phthalate (DnBP), and butyl paraben (BP) and dilut
259 xture of four phthalate monoesters (33% mono-butyl phthalate, 16% mono-benzyl phthalate, 21% mono-eth
260 NA maternal urinary concentrations of mono-n-butyl phthalate, a metabolite of butyl benzyl phthalate
262 anted mice were treated with vehicle or di-n-butyl-phthalate (DBP, a plasticising chemical known to i
264 e metal-free porphyrin derivative tetra(tert-butyl)porphyrazine as an ideal model system to elucidate
266 th bulkier lipophilic substitutions [4-(tert-butyl)-propofol and 4-(hydroxyl(phenyl)methyl)-propofol]
268 Cu(II)(OCH2CF3) (Tp(tBu) = hydro-tris(3-tert-butyl-pyrazolyl)borate) and investigated the influence o
269 ridin-2-yl)benzo[d]thiazole (L1), 2-(4-(tert-butyl)pyridin-2-yl)benzo[d]thiazole (L2), 2-(6-phenylpyr
270 ) ((tBu)pyrr(2)py(2-) = 2,6-bis((3,5-di-tert-butyl)pyrrol-2-yl)pyridine) with KC(8) yields the comple
272 nteiso positions, terminal isopropyl and sec-butyl, respectively, do not alter CACI-MS/MS diagnostic
273 1 with the zinc derivative of 2 to give tert-butyl (S)-2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-
274 he 4,6-benzylidene acetal with a 4,6-di-tert-butyl silylidene led to a slight increase in alpha-selec
275 en-1-yl)-N-(alpha-methylbenzyl)amide to tert-butyl sorbate was followed by ring-closing metathesis of
276 a butterfly-shape pyrene ligand with a tert-butyl substituent enables the formation of the disordere
279 aintained upon replacement of the bulky tert-butyl substituents on the ligands with methyl groups.
280 persion interactions between contacting tert-butyl substituents surrounding the central contact deliv
281 eparation of structurally diverse P-chiral t-butyl substituted secondary phosphine oxides (SPOs) and
283 ds is higher than that of the silyl and tert-butyl-substituted analogues because of attractive disper
285 a comprehensive experimental study of a di-t-butyl-substituted cyclooctatetraene-based molecular bala
288 xia, the free radical scavenger alpha-phenyl-butyl-tert-nitrone (alphaPBN), and the N-methyl-D-aspart
290 s explored for the {WTp(NO)(PBu(3))} (Bu = n-butyl; Tp = trispyrazoylborate) system as a function of
292 e caused a specific cleavage at the terminal butyl-trithiocarbonate group, which initiated a free rad
295 le cross-linker (containing a 1,3-bis-(4-oxo-butyl)-urea group, BuUrBu) generating characteristic dou
296 holyte in a non-aqueous redox flow cell with butyl viologen as the anolyte to yield a 2.0 V battery.
297 ion sets of wheels including one set of tert-butyl wheels and another set of larger adamantane wheels
298 ed combinations of structural features: tert-butyl wheels, short alkyne chassis, and combination sets
299 )][B(C(6)F(5))(4)] (M = Ni, Cu; (t)Bu = tert-butyl), which feature low-coordinate metal centers and d