ライフサイエンスコーパス: carboxylate

1 atei on crotonate, benzoate or cyclohexane-1-carboxylate.

2 m), in turn synthesized from cyclopent-3-ene carboxylate.

3 e easily converted into 2-diazo-2H-pyrrole-4-carboxylates.

4 ules represents a sustainable way to prepare carboxylates.

5 ly more easily oxidized by Cr(V)/Cr(IV) than carboxylates.

6 r longer times revealed the presence of lead carboxylates.

7 y of metabolic enzymes converts aldehydes to carboxylates.

8 tion-5-hydroxy-6-oxo-4-aryl-6H-1,2-oxazine-3-carboxylates.

9 quantify precursors that form perfluoroalkyl carboxylates.

10 e separation and detection of the respective carboxylates.

11 amples that is capable of oxidizing aromatic carboxylates.

12 studies of their complexes with short-chain carboxylates.

13 vity of oximes, specifically 2-isoxazoline-3-carboxylates.

14 ternative to the regioselective synthesis of carboxylated 1,4-disubstituted 1,2,3-triazoles (1,4-cDTs

15 acetyl)-3-((diethylamino)methyl)piperazine-1-carboxylate ((11)C-EKAP) and its comparison with (11)C-G

16 ures and can be catalyzed by a few dirhodium carboxylates (5 mol %) under a balloon pressure of oxyge

17 droxymethylated (5hmC), formylated (5fC), or carboxylated (5caC) forms.

18 determine the concentration of deprotonated carboxylates, a sample is acidified with HCl, and the qu

19 screen also identified 1-AMINOCYCLOPROPANE-1-CARBOXYLATE (ACC) SYNTHASE7, an ACC synthase homolog inv

20 s immediate precursor, 1-aminocyclopropane-1-carboxylate (ACC), in the rhizosphere.

21 ca1pase resulted in lower initial and total carboxylating activities measured in flag leaves at the

22 oton transfer, enhancing the basicity of the carboxylate also decreases the equilibrium proton donor-

23 -3-(4-bromophenyl)-3,6-dihydropyridine-1(2H)-carboxylate, an intermediate in the synthesis of the ant

24 erized by an amino acid backbone with a free carboxylate, an N-linked aromatic or heteroaromatic subs

25 R analyses pointed to the formation of metal carboxylates, an indicator that the organic binder is no

26 However, PFOA, which is the carboxylate analog of PFOS, revealed a very close K(A) v

27 ma membranes, in contrast to Laurdan and its carboxylate analogue C-Laurdan.

28 Oxoborane carbamate and carboxylate analogues result from the in situ trapping o

29 e nucleophilic substitution reaction between carboxylate and alkoxyphosphonium ions, to reform the ph

30 phically degrades benzoate and cyclohexane-1-carboxylate and catalyses the novel synthesis of benzoat

31 terial benzyl (S)-2-methyl-4-oxopiperidine-1-carboxylate and employs an Overman rearrangement to cont

32 plays promiscuity toward different beta-keto carboxylate and esters.

33 OO(-)], where Ca(2+) ions are bridged by the carboxylate and hydroxyl groups of lactate and the carbo

34 lladacycle formation with substrates bearing carboxylate and pyridine directing groups exhibit a 50-1

35 nation of the lithium atom to the oxygens of carboxylate and sulfinyl units was proposed, being in ag

36 ion of a twisted peptide bond involving this carboxylate and the following tyrosine residue.

37 likely metabolites such as n:3-fluorotelomer carboxylates and n:2-fluorotelomer sulfonamides.

38 alysts, must have mediated the activation of carboxylates and phosphates for condensation reactions.

39 Simultaneous activation of carboxylates and phosphates provides multiple pathways f

40 sistently >50% for long-chain perfluoroalkyl carboxylates and sulfonates (>/=C8 and >/= C6, respectiv

41 ters solvolyze faster than the corresponding carboxylates and that the enhancement of aromatic carbon

42 of 6,6'-binicotinates and 2,2'-bipyridine-5-carboxylates and the homoleptic Cu(I) complex were synth

43 actions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the cor

44 tion of a beta-lactam antibiotic (carbapenem carboxylate) and a linear tripyrrole red antibiotic, pro

45 thiazolidine-4-carboxylate, l-thiazolidine-2-carboxylate, and N-formyl l-proline (NFLP).

46 rg(245) is crucial for binding the substrate carboxylate, and R245E/L mutations severely compromise a

47 etones, affording pyrrolo[1,2-a]pyrimidine-7-carboxylates, and are easily converted into 2-diazo-2H-p

48 y its enzymatic oxidation, activation of the carboxylate anion by acyl-CoA synthetase(s), and re-este

49 e software that harmonizes the abundances of carboxylate anion fragments originating from fatty acid

50 enting the nondissociated acid form, and the carboxylate anion group, representing the dissociated fo

51 therto unrecognized inhibitory effect by the carboxylate anion on the catalytic cycle, whereas 2-ethy

52 ass-selected GPL anions generates fatty acyl carboxylate anions via fragmentation of ester bonds link

53 Recognition of the cephalosporin carboxylate appears to be the key trigger for formation

54 In addition, alpha-hydroxyl carboxylates are probably more easily oxidized by Cr(V)/

55 The gradients of zinc carboxylates are unrelated to the Al-stearate distributi

56 available ethyl 3-alkyl-(2,2'-bithiophene)-5-carboxylate as a convenient substrate.

57 developed employing methyl 5-methyloxazole-4-carboxylate as a single starting material to provide hin

58 ts in the formation of 1,2-dihydropyrazine-2-carboxylates as the main products, which can be converte

59 e generation of radicals from sulfinates and carboxylates, as related to their role in radical cross-

60 Computational studies on carboxylate-assisted C-H activation and functionalizatio

61 of catalytic C-H functionalization based on carboxylate-assisted C-H activation.

62 These reagents promote an unusually mild carboxylate-assisted oxidative addition to alkylamine-de

63 An efficient weak carboxylate-assisted oxidative cross-dehydrogenative C-H

64 ive [2-5C1(2)](10-), via interactions of the carboxylates at the rims with ammoniums on the guest.

65 ce of extra phenyl rings, bearing one or two carboxylates, at the C2 position of the indole ring of e

66 nonanuclear [RE9(mu3-OH)12(mu3-O)2(O2C-)12] carboxylate-based cluster, points of extension matching

67 RE(9)(mu(3)-O)(2)(mu(3)-OH)(12)(O(2)C-)(12)] carboxylate-based clusters with purposely chosen organic

68 re that a sulfone-functionalized tetrahedral carboxylate-based ligand is capable of directing the for

69 Through comprehensive analysis of carboxylate-based metal-organic frameworks (MOFs), we pr

70 gzag ligands and other elements, focusing on carboxylate-based MOFs combined with common inorganic cl

71 enolic porphyrins, instead of commonly known carboxylate-based types.

72 ater sensitivity of the rate constant to the carboxylate basicity than to the redox potential of the

73 ate constants are much more sensitive to the carboxylate basicity than to the redox potential of the

74 ar cyclization of trisubstitued cyclopentane carboxylates bearing a leaving group (at the C-4 positio

75 impregnating oxidized activated carbon with carboxylated benzotriazoles, and that metal removal effi

76 0G predicts spatial shifts in the SCRIB PDZ4 carboxylate binding loop dictate alpha(1D)-AR binding sp

77 esent near the gold surface, indicating that carboxylate binding occurs as a 2e(-) L-type interaction

78 o acid substitutions, into which the pro-(S) carboxylate binds.

79 us electrolyte, an increase in the amount of carboxylate bonds at the interface, as a result of hydro

80 the decrease in the bite angles between the carboxylate building blocks.

81 nverted by a one-pot procedure to pyrazine-2-carboxylates by heating with catalytic amounts of TsOH.

82 ylate-calcium ion complexes prevented direct carboxylate-calcite interactions, thus lowering the AFM

83 and provided new insights for the competing carboxylate/calcite/calcium ion interactions.

84 that in calcium ion rich fluids, the strong carboxylate-calcium ion complexes prevented direct carbo

85 Without oleic acid impurities, cadmium carboxylate can be completely displaced from the surface

86 otentials between internal versus C-terminal carboxylates can be exploited towards obtaining C-termin

87 observed for (13)C-labeled l-alanine at the carboxylate carbon site, which was confirmed by macrosco

88 Dirhodium(II) carboxylates catalyze an Si-H insertion using carbenes d

89 (1)H(alpha)-(13)C(alpha) dipolar tensor and carboxylate chemical shift anisotropy tensor of aspartat

90 of ATRP initiators via the phosphate-Zr(4+)-carboxylate chemistry.

91 prototype TPR ligands that mimic key native 'carboxylate clamp' interactions between Hsp90 and its TP

92 OFs (CTGU-10a1-d1) based on trinuclear metal carboxylate clusters and a hexadentate carboxylate ligan

93 Ts), and CNT type (i.e., greater uptake with carboxylated CNTs composites).

94 ty, Iowa, optimal ENM-CNTs (PAN with 20 wt % carboxylated CNTs) yielded atrazine concentrations in su

95 g on the SP3 approach with nonfunctionalized carboxylate coated magnetic beads without affinity ligan

96 geneous agglomerates of Al-stearate and a Zn-carboxylate complex with Zn-stearate nano-aggregates in

97 is largely derived from stabilization of the carboxylate conjugate base through intramolecular anion-

98 nd exchange than amine-containing chemicals, carboxylate-containing chemicals, and inorganic salts du

99 Elucidating the binding mode of carboxylate-containing ligands to gold nanoparticles (Au

100 The titratable acidity, alkalinity, and carboxylate content are fundamental properties required

101 drinks, the alkalinity of tap water, and the carboxylate content of nanocellulose dispersions.

102 The reactivity of the (hetero)aryl carboxylate correlates qualitatively to the field effect

103 information: (a) General base catalysis by a carboxylate coupled to general acid catalysis by a carbo

104 lecular gears, formed with four 9-triptycene carboxylates cyclically arranged around a dirhodium core

105 eted liposomes were developed to deliver the carboxylated derivative, 5(6)-carboxy-DCFH2, to hepatocy

106 Benzo[4,5]thiazolo[3, 2-a]pyrimidine-3-carboxylate derivatives (4a-i) containing electron-donor

107 aliphatic photocoupling between redox-active carboxylate derivatives and electron-poor olefins, displ

108 A set of carboxylate derivatives demonstrated markedly improved i

109 ew class of initiators, (pai-allyl)palladium carboxylate dimers, which polymerize ethyl diazoacetate,

110 high Fsp(3) attached-ring junctures and the carboxylate directing group can be removed after couplin

111 Various carboxylate-directing groups including acetate, acrylate

112 Carboxylate directivity prevents over-arylation of the n

113 e into crotonate, benzoate and cyclohexane-1-carboxylate during growth on these different substrates

114 less-activated phenol derivatives, from aryl carboxylates (e.g., pivalates, acetates, etc.), aryl car

115 mide nitrogen by a carboxyl, while the other carboxylate engages in nucleophilic attack upon the amid

116 able, often lower than the KM of the primary carboxylating enzyme Rubisco, and in order to photosynth

117 One of the most efficient classes of carboxylating enzymes are enoyl-CoA carboxylases/reducta

118 ooctane sulfonate (PFOS), and perfluoroalkyl carboxylates (EPFCAs) in all three subpopulations.

119 oryanodane congeners that lack the pyrrole-2-carboxylate ester-such as perseanol-may have selective a

120 Seven silicon(IV) phthalocyanine carboxylate esters (SiPcs, 1-7) with non-, partially- an

121 e manner with various indanone and tetralone carboxylate esters.

122 eceptors strongly bind anions, in particular carboxylates, even in a highly competitive solvent mixtu

123 e proximal histidine (His134) of the 2-His-1-carboxylate facial triad, instead of assuming the offlin

124 1) integrin supported the notion that ligand carboxylate fixing to the metal ion-dependent adhesion s

125 t the reaction operates via oxidation of the carboxylate followed by rapid decarboxylation and oxidat

126 -methoxyisoxazol-4-yl)prop-1-ynyl)pyridine-3-carboxylates, followed by a transformation of the propar

127 tional, secreted, vitamin K-dependent, gamma-carboxylated form of periostin by macrophages and, to a

128 Of the three carboxylating forms of RubisCO, forms I and II participa

129 phospholipids are typically quantified using carboxylate fragments of their fatty acid moieties produ

130 ovel synthesis of benzoate and cyclohexane-1-carboxylate from crotonate.

131 ted by two Tyr side-chain phenolates and one carboxylate from Glu.

132 The synthesis of methyl 5-aminopyrrole-3-carboxylates from 4-methyleneisoxazol-5-ones via "cyanid

133 al 6,6'-binicotinates, and 2,2'-bipyridine-5-carboxylates, from 4-propargylisoxazoles.

134 The introduction of ester and carboxylate functionalities at the bay region of the ace

135 r pharmaceutical waste, some of which have a carboxylate functionality at the neutral pH range typica

136 -Universitetet i Oslo) to the basal-plane of carboxylate functionalized graphene (graphene acid = GA)

137 Special attention was given to the carboxylate-functionalized AFM tips because of their pro

138 Phthalocyanine-dyed and QDs-encapsulated carboxylate-functionalized polystyrene nanospheres with

139 n this work, ten different zinc(II) Pcs with carboxylate functions or quaternary nitrogens (hydrophil

140 We found that strong binding carboxylates (geometrical matching) is not enough for th

141 Additionally, the labile carboxylate group allows water to bind early in the cata

142 riven by ground-state destabilization of the carboxylate group being cleaved by the enzyme.

143 The relative position ( meta, para) of the carboxylate group in relation to the pyridinium nitrogen

144 ntial cleavage of the pro-(R) to the pro-(S) carboxylate group in the CLG-IPL variant of AMDase for a

145 pting an online-binding mode in which the C1 carboxylate group of 2OG is trans to the proximal histid

146 ylate and hydroxyl groups of lactate and the carboxylate group of acetate to give a three-dimensional

147 259 H-bonds and forms a salt bridge with the carboxylate group of glucuronic acid.

148 g site on the indicator cross-linker and the carboxylate group of the analyte was still operative upo

149 (PhNadA) in complex with IA and show that a carboxylate group of the molecule is ligated to Fe(a) of

150 acid rearrangement involving migration of a carboxylate group to form 2-carboxy-l-lyxonolactone; the

151 ssuming the offline-binding mode with the C1 carboxylate group trans to the distal histidine (His211)

152 iarylation of an alkene directed by a native carboxylate group.

153 setting the negative charge of the anchoring carboxylate group.

154 s the oxide relay functionality of a pendant carboxylate group.

155 enase enzymes, a subset of NSAIDs containing carboxylate groups also has been reported to competitive

156 y (XPS) confirmed the role of phosphates and carboxylate groups from the cell envelope in the bioasso

157 Carboxylate groups have diverse functionalities in ligan

158 steric stabilizer chains comprising anionic carboxylate groups lead to superior occlusion performanc

159 se the oxygen atoms with sulfur atoms in the carboxylate groups of sodium terephthalate which improve

160 hieved by the coupling of negatively charged carboxylate groups present at the surface of nanoplastic

161 4 owing to the joint presence of carboxy and carboxylate groups.

162 n-like (HX) domain, with a group of four Asp carboxylate groups.

163 While the presence of the terminal carboxylates has a modest effect on the thermodynamic st

164 ontaining ( S)- or ( R)-imidazolidin-2-one-4-carboxylate (Imi) have been obtained by the expedient in

165 onstrate that Glu179 serves as the catalytic carboxylate in bacteriophage lambda terminase and probe

166 scopy to determine the distribution of metal carboxylates in a 23-year old oil paint of known formula

167 h2(OAc)4 catalysis provides 4-aminopyrrole-3-carboxylates in good yields.

168 r intramolecular ones to furnish carbazole-4-carboxylates in mostly good to excellent yields.

169 C)-2-oxoindolin-1-yl)-[1,4'-bipiperidine]-1'-carboxylate) in nonhuman primates.

170 a suite of guest ligands (thiolates, amines, carboxylates, inorganic ions, and proteins), the guest l

171 and the calcite surfaces were mainly through carboxylate interactions with the calcium ions on calcit

172 The formation of a carboxylate ionic bond at the interface is characterized

173 The formation of hydrogen bonds and carboxylate ionic bonds at the interface are observed.

174 echanisms responsible for the trafficking of carboxylate ions across cell membranes are becoming clea

175 st {Mn31} cluster (1) has been prepared from carboxylate ions and the chelating/bridging ligand alpha

176 Product anions, including fatty acyl carboxylate ions, were then derivatized in the mass spec

177 fatty acid phosphate, sulfate, chloride, and carboxylate ions.

178 rystallization chaperone showed how well the carboxylate is poised to attack the phosphoramidate, hel

179 ow that one agent in particular (6-C pendant carboxylate) is an extremely effective MR reporter for t

180 Moreover, dihydrokaempferol dimer and carboxylated kaempferol diglucoside were identified for

181 d, cyclopentanecarboxylate, l-thiazolidine-4-carboxylate, l-thiazolidine-2-carboxylate, and N-formyl

182 metal carboxylate clusters and a hexadentate carboxylate ligand with a (6,6)-connected nia net.

183 We incorporated a pendant coordinating carboxylate ligand with a 2, 4, 6, or 8 carbon linker to

184 m via a reversible cleavage of the porphyrin carboxylate ligands under an applied voltage.

185 consistent with the loss of iron-complexing carboxylate ligands were observed, including decreases i

186 ation of stable adsorption sites between the carboxylate ligands, to allow hydration of O-Cu ligands

187 been based on paddlewheel building units and carboxylate ligands.

188 particle and which are likely coordinated by carboxylate ligands.

189 where the active palladium catalysts contain carboxylate ligands.

190 ization proceeds via intermediates that have carboxylate ligation in common, and a secondary cycle in

191 eezer bearing pyridyl moieties and the tetra-carboxylated linker.

192 esidue that directly precedes the N-terminal carboxylate metal ligand is conserved as a glycine withi

193 found that the motion of negatively charged, carboxylated microspheres in mucus from pregnant patient

194 As an alternative, we employed carboxylate-modified magnetic nanoparticles (MNPs) for i

195 Only carboxylate-modified or glycosylated lignin phenolics ar

196 ined using nano- to microsized (0.1-4.2 mum) carboxylate-modified polystyrene latex microspheres that

197 cific vibrational modes, can be observed for carboxylate MOFs by monitoring the red-shifts of carboxy

198 ese findings, we investigate a wide class of carboxylate MOFs that includes iconic examples with dive

199 in ZIF melting but heretofore unobserved for carboxylate MOFs, these metal-linker dynamics resemble t

200 ) and Ca(2+) were bound to the phosphate and carboxylate moieties on PS via contact ion pairing, dehy

201 hyperconjugation and pi-resonance within the carboxylate moiety is operative in TS.

202 a-aryl secondary alkylamines and renders the carboxylate motif a traceless directing group.

203 idinyl-N-oxyl) immobilized on the surface of carboxylated multi-walled carbon nanotubes (MWCNT-COOH),

204 engineer this immunosensor, uniform layer of carboxylated multiwall carbon nanotubes (MWCNT) was depo

205 yloyloxy)-3-formylphenyl)-4-methylthiazole-5-carboxylate (NL-AC) was designed and synthesized as a co

206 R', R' = n-butyl, n-hexyl, n-octyl) (</=0.01 carboxylates nm(-2)).

207 comprehensive kinetic examination of a model carboxylate O-arylation, comparing a state-of-the-art ho

208 tion of the chiral p-methoxybenzyl azetine-2-carboxylates occurs with both hydrogen addition to the C

209 Thr235 residue, which interacts with the C3 carboxylate of carbapenems, also contributes strongly to

210 concomitant formation of a bond between the carboxylate of Glu6 of the core peptide and the nascent

211 ble electrostatic contacts between the omega-carboxylate of ODDA-PTX and positively charged amino aci

212 -hexahydro-4-((E)-pent-2-enyl)-2H-chromene-6-carboxylate of polyketide origin, with activity against

213 sed to directly phosphorylate the C-terminal carboxylate of TglA.

214 o unknown chemical class, dihydroxymagnesium carboxylates [(OH)2MgO2CR](-), in meteoritic soluble org

215 (b) Nucleophilic attack by a carboxylate on the amide carbonyl coupled to general aci

216 able packing of oleates compared to branched carboxylates on the (100) facets of CdSe quantum dots.

217 alkene and the functional group, including a carboxylate, on the other substituent.

218 attributed to localized negative charges on carboxylate or amide group of deprotonated quinolone or

219 chemical stability still remains limited to carboxylate or azolate groups.

220 no cell death was seen after exposure to the carboxylated or PEG-modified Au-NPs.

221 rimary amines are selectively transformed to carboxylates or ketones in good to high yields.

222 p (ie, catechol, hydroxamate, alpha-hydroxyl-carboxylate, or mixed types).

223 , i.e., alkyl ammonium bromide, alkyl sodium carboxylate, or poly(ethylene glycol) (PEG)-terminated A

224 xylate stretches coupled to anharmonic metal-carboxylate oscillators.

225 1 binds and stabilizes 1-aminocyclopropane-1-carboxylate oxidase 4 (ACO4), which may in part explain

226 , glycosyltransferase, 1-aminocyclopropane-1-carboxylate oxidase homologs, receptor-like protein kina

227 A storage reduces ACC (1-aminocyclopropane-1-carboxylate) oxidase activity, ethylene production and r

228 n which the C-H bond is weak, while stepwise carboxylate oxidation and hydrogen atom transfer likely

229 This is directly bonded to a glutamine carboxylate oxygen atom, and its remaining inner-sphere

230 Importantly, two water molecules contact a carboxylate oxygen of caC and are poised to facilitate a

231 with 11 different Lewis bases (halide ions, carboxylates, p-nitrophenolate, amines, and tris(p-anisy

232 oline cycle by reducing Delta(1)-pyrroline-5-carboxylate (P5C) to proline through the oxidation of NA

233 oadipic semialdehyde (a-AASA), piperideine-6-carboxylate (P6C), pipecolic acid (PA) and alpha-aminoad

234 rly effective at sequestering sulfonates and carboxylate PFAS compounds and is less effective at conc

235 Long-chained perfluoroalkyl carboxylates (PFCAs) in arctic foxes decreased with avai

236 branes ( K(MW)) for series of perfluorinated carboxylates (PFCAs), perfluorinated sulfonates (PFSAs),

237 The PFASs studied include perfluoroalkyl carboxylates (PFCAs), perfluoroalkane sulfonates (PFSAs)

238 d included C(4) through C(14) perfluorinated carboxylates (PFCAs); C(4) through C(10) and C(12) perfl

239 ed galactopyranoside scaffold that locks the carboxylate pharmacophore in either the axial or equator

240 a condensation step in which the substrate's carboxylated phenyl group makes a nucleophilic attack to

241 hich is one of the promising products of the carboxylate platform.

242 Food and Drug Administration-approved 500nm carboxylated-poly(lactic-co-glycolic) acid, were infused

243 ed of interdigitated microelectrodes (IMEs), carboxylated polypyrrole nanotubes (CPNTs) and DA-specif

244 ing different sizes (20, 100, and 200 nm) of carboxylated polystyrene NPs, we examined how NP diffusi

245 difluoro-4-azaspiro[2.4]hepta-1,4,6-triene-1-carboxylate, presumably via the corresponding ketenimine

246 s and heteroarenes to synthesize the desired carboxylated product in moderate-to-good yields.

247 5-cyanopicolinate (picCN), 3-aminopyrazine-2-carboxylate (przNH(2)), and 1,2-dimethyl-3-hydroxy-4(1 H

248 This would, in theory, generate aminyl and carboxylate radicals, with the latter undergoing decarbo

249 3) and reacts with CO(2) to form a supported carboxylate (RCO(2)M); and (2) methylation, in which RCO

250 5-Amino-1H-pyrrolo-3-carboxylates react with 1,3-diketones, affording pyrrolo

251 Pyrroline-5-carboxylate reductase 1 (PYCR1) catalyzes the biosynthet

252 mitochondria and interacts with pyrroline-5-carboxylate reductase 1 (PYCR1), a key enzyme for prolin

253 anslocation and interaction with pyrroline-5-carboxylate reductase 1 (PYCR1), resulting in inhibition

254 panel of methylmalonyl-CoA analogs with the carboxylate represented by a sulfonate or nitro and the

255 esign proteins displaying arrays of up to 54 carboxylate residues geometrically matched to the potass

256 The mini-sensor is formed by six tandem carboxylate residues within the transmembrane (TM)5-6 lo

257 carboxylase-oxygenase oxygenates rather than carboxylates ribulose-1,5-bisphosphate.

258 rugs with additional ester promoiety(ies) on carboxylate(s) were examined for their ability to delive

259 iments revealed bis(phosphine)cobalt(II) bis(carboxylate)s were generated in catalytic reactions and

260 he originally characterized material was its carboxylate salt form not its free acid.

261 olyl 5-chloro-2-[ethylsulfonyl] pyrimidine-4-carboxylate [SBI-115]), and (3) a combination of SBI-115

262 By introducing two sulfur atoms to a single carboxylate scaffold, the molecular solid reaches a reve

263 active site, a conformational change of the carboxylate side chain metal ligand to allow for hydroge

264 am amounts of homogeneous UCNPs covered with carboxylated silica, biotin, or streptavidin with recove

265 The formation of Pb, Zn, and Cu carboxylates (soaps) has caused visible deterioration in

266 able properties, but can react to form metal carboxylates (soaps) that may damage artworks over time.

267 We design a series of metal carboxylate solutions that anchor on the perovskite surf

268 peroxide serves as both the oxidant and the carboxylate source, allowing not only the functionalizat

269 % Cu facilitates the formation of surface carboxylate species from CO(2), resulting in a 300-500%

270 lated by 5beta-reduced steroids, sulfated or carboxylated steroids, and beta-estradiol, whereas many

271 oxylate MOFs by monitoring the red-shifts of carboxylate stretches coupled to anharmonic metal-carbox

272 ands belonging to alpha-hydroxyl or carbonyl carboxylates, such as tartrate, malate, lactate, pyruvat

273 ressing Lolium perenne L. delta1-pyrroline 5-carboxylate synthase (LpP5CS) in group I (TG4 and TG6 li

274 dation versus for benzoate and cyclohexane-1-carboxylate synthesis.

275 nducing the activity of Delta(1)-pyrroline-5-carboxylate synthetase (P5CS) and decreasing proline deh

276 bis(pyridinium)-xylylene derivatives bearing carboxylate terminal groups were investigated as guests

277 B motifs that bind Mg2+-ATP and a catalytic carboxylate that activates water for hydrolysis.

278 t distinct from ruthenium(II) and nickel(II) carboxylates that operate by heterolytic H(2) cleavage p

279 ent a conceptually different function of the carboxylates: the oxide relay.

280 s alkyl 4-alkoxy-5-amino-3-methylthiophene-2-carboxylates through the one-pot sequential reaction of

281 ogenotrophic methanogens, homoacetogens, and carboxylate-to-alcohol reducing bacteria.

282 variants: the "phosphate tweezer" CLR01, a "carboxylate tweezer" CLR05, and a "phosphate clip" PC.

283 n the KTG motif to contact the cephalosporin carboxylate, twisting of the beta3 strand to form the ox

284 yl-5-methoxyisoxazoles give methyl oxazole-4-carboxylates under the same reaction conditions.

285 and 2-hydroxy-3-oxo-2,3-dihydrobenzofuran-2-carboxylates using rose bengal as a triplet photosensiti

286 nt mixtures) on chiral recognition of chiral carboxylates, using the titration method under (1)H NMR

287 Here, we searched for fast-carboxylating variants by systematically mining genomic

288 3,4,5-tetrahydropyrrolo[4,3,2-de]quinoline-4-carboxylate via a conjugate addition/intramolecular Ullm

289 ers of different end-terminal functionality (carboxylated vs. pyrrolidonated) by two phenotypically d

290 Glycosyl isoquinoline-1-carboxylate was developed as a novel benchtop stable and

291 one such complex, N,N-dimethylimidazolium 2-carboxylate, was remarkably sensitive to solvent polarit

292 Ten chloroperfluoropolyether carboxylates were tentatively identified, with at least

293 force depends mainly on the basicity of the carboxylate, which is influenced by the substituent on t

294 e known to be prone to the formation of zinc carboxylates, which can cause protrusions and mechanical

295 -dihydrobenzo[4,5]imidazo[1,2-a]pyrimidine-3-carboxylates, which contain 18 different pentagonal hete

296 gen atom is found to stabilize the phosphine carboxylate while also allowing solubility in organic so

297 agonists such as compound 1 by replacing the carboxylate with a sulfonamide as in 50.

298 azin-2-ones by the reaction of benzoxepine-4-carboxylates with chiral amino acid ethyl esters for the

299 carboxylative cross-coupling of (hetero)aryl carboxylates with iodoarenes in the presence of a gold c

300 r, methyl-5-chloroisoxazolo[4,5-b]pyrazine-3-carboxylate, with an overall radiochemical yield of 15-2