ライフサイエンスコーパス: catalysis

1 to the burgeoning domain of stereodivergent catalysis.

2 being a critical residue for F6P binding and catalysis.

3 ton energy into redox equivalents for enzyme catalysis.

4 or cooperative small-molecule activation and catalysis.

5 led supramolecular materials in the field of catalysis.

6 an important model system to understand RNA catalysis.

7 c acids by means of visible-light photoredox catalysis.

8 tion of an 'in-line' attack conformation for catalysis.

9 under mild conditions without activation or catalysis.

10 oducts from CH(4) in gas-phase heterogeneous catalysis.

11 he key role of MLC in facilitating effective catalysis.

12 of the POM, the catalyst, and the MOF after catalysis.

13 mary amines through visible light photoredox catalysis.

14 avor a closed conformation not conducive for catalysis.

15 special dimer-dimer interaction required for catalysis.

16 ent effects for organic substrates in chiral catalysis.

17 rstanding a broad range of systems including catalysis.

18 ne Esco2 active site cleft, are critical for catalysis.

19 N- and C-terminal CD73 domains necessary for catalysis.

20 e enzyme to the membrane, and the subsequent catalysis.

21 cale is a critical challenge in bifunctional catalysis.

22 se of their important applications including catalysis.

23 tion of 1H-N-(benzoyloxy)indazoles using CuH catalysis.

24 icals, and are used as ligands in asymmetric catalysis.

25 ons but maintains sufficient flexibility for catalysis.

26 tonated anionic forms, or under nucleophilic catalysis.

27 efforts in applying supramolecular hosts in catalysis.

28 oach relative to electrolysis and photoredox catalysis.

29 le, illustrates the biomimetic nature of the catalysis.

30 stly expanding the use of abundant metals in catalysis.

31 -catalysed hydrogen atom transfer and copper catalysis.

32 ces in the cage framework affect binding and catalysis.

33 ing consequences in stereoselective ion pair catalysis.

34 ddress outstanding challenges in sustainable catalysis.

35 was developed, using chiral phosphoric acid catalysis.

36 le of internal diffusion barriers in zeolite catalysis.

37 ght into the evolutionary divergence of Usb1 catalysis.

38 domain organization tightly associated with catalysis.

39 cent advances in computational heterogeneous catalysis.

40 triads, suggesting important implications in catalysis.

41 ility of lanthanide complexes in homogeneous catalysis.

42 catalysis, photocatalysis, and heterogeneous catalysis.

43 ultinuclear NMR spectroscopy observed during catalysis.

44 ate preference and the mechanistic basis for catalysis.

45 es which align the nucleophile for efficient catalysis.

46 s for applications in sensing, medicine, and catalysis.

47 effects in routinely used oxidative addition catalysis.

48 pe CPs without the need for transition-metal catalysis.

49 ed palladium/norbornene (Pd/NBE) cooperative catalysis.

50 s by the merger of photocatalysis and enzyme catalysis.

51 ructures-important features in heterogeneous catalysis.

52 rmation involves two cycles of Fe/2OG enzyme catalysis.

53 relieve all inhibitory constraints on enzyme catalysis.

54 complementary to late transition metal-based catalysis.

55 yzed visible-light-mediated light photoredox catalysis.

56 aryl diols is investigated using isothiourea catalysis.

57 range of amines and thiols under Lewis acid catalysis.

58 e catalytic Lys may act as a proton donor in catalysis.

59 mote N(2) reactivity(1), which has prevented catalysis.

60 e elements involved in substrate binding and catalysis.

61 roton-electron transfer (MS-PCET) and nickel catalysis.

62 enzymatic domain's substrate recognition and catalysis.

63 various fields as an alternative to chemical catalysis.

64 ane to methanol has long been challenging in catalysis.

65 N-heterocyclic carbene (NHC) and photoredox catalysis.

66 -CO is kinetically favored, facilitating the catalysis.

67 nventional high-temperature (>943 K) thermal catalysis.

68 d important topic in materials chemistry and catalysis.

69 which has enormous potential in sensing and catalysis.

70 ould otherwise prohibit efficient asymmetric catalysis.

71 earrangement that allows for ATP binding and catalysis.

72 able attention in the field of heterogeneous catalysis.

73 all, and usage of two glutamate residues for catalysis.

74 1,5-O...Ch interactions in enantioselective catalysis.

75 plished using dual organic photoredox/cobalt catalysis.

76 s in energy conversion, optoelectronics, and catalysis.

77 d on-DNA C-H selenylation under rhodium(III) catalysis.

78 nto the role of TMEDA in achieving effective catalysis.

79 one of the popular topics in supramolecular catalysis.

80 on is not a completely essential step in its catalysis.

81 chemical glycosylation and enantioselective catalysis.

82 1,1-carboboration and wider B(C(6) F(5) )(3) catalysis.

83 e energy landscape of transfer hydrogenation catalysis.

84 te and relative configurations in asymmetric catalysis.

85 rsatile reactant when coupled with palladium catalysis.

86 ructure-function correlation in the field of catalysis.

87 , including photosynthesis, respiration, and catalysis.

88 tures for donor and acceptor recognition and catalysis.

89 remained, hitherto, elusive under thermal Ni catalysis.

90 tein that we assign to roles in assembly and catalysis.

91 f in PKAc regulate its thermal stability and catalysis.

92 these helices offers a basis for asymmetric catalysis.

93 rfaces for the optimization of heterogeneous catalysis.

94 articularly useful as ligands for asymmetric catalysis.

95 ed by Rh/Ir-catalyzed system; in the Rh(III) catalysis, 3-alkenyl-1H-isochromen-1-one and 3,4-dialkyl

96 However, so far photoinduced enzymatic catalysis(6) has not been used for the cross-coupling of

97 tallographic structure resolving the site of catalysis, a protein-bound Mn(4)CaO(x) complex, which pa

98 estigated the role of the Mg(2+) cofactor in catalysis, analyzing the first crystal structure of the

99 s has made substantial impact in noble metal catalysis and also started to gain popularity in iron ca

100 significant role in the field of single-site catalysis and are typically composed of catalytically ac

101 the regulatory subunit regulates activation, catalysis and autoinhibition through the a-loop.

102 ences of DNMT3A mutations on DNA methylation catalysis and binding interactions and summarize their e

103 de clear insights into substrate binding and catalysis and clearly elucidate why previous structures

104 ts potential significance in both asymmetric catalysis and convenient build-up of libraries of molecu

105 larly, the merger of Earth-abundant 3d metal catalysis and electrooxidation has recently been recogni

106 e broad implications in the renewable energy catalysis and electrosynthesis of valuable products.

107 rials essential for applications in sensing, catalysis and energy conversion and storage.

108 unifies a body of observations on biological catalysis and energy conversion, and the scheme provides

109 nd points to the competing factors of enzyme catalysis and ET efficiency that may arise when complex

110 ve provided information about DNA polymerase catalysis and fidelity.

111 The molecular mechanisms underlying enzyme catalysis and inhibition for SRD5A2 and other eukaryotic

112 the quaternary Pol mu complex is poised for catalysis and nucleotide incoporation proceeds in crysta

113 The compatibility of bioorthogonal catalysis and physical hydrogels opens up new opportunit

114 o interfaces involved in light-driven enzyme catalysis and points to the competing factors of enzyme

115 ay important roles in molecular recognition, catalysis and self-assembly.

116 tions, making them ideal for shape selective catalysis and separation.

117 oductive ACP-AT interactions is required for catalysis and specificity within primary and secondary F

118 icle will compare the aspects of single atom catalysis and surface organometallic catalysis by consid

119 he modes of activation and control in enzyme catalysis and the realization that this can be achieved

120 renders them useful for applications such as catalysis and the sequestration of precious materials.

121 c systems can be carried out under mild acid catalysis and thus under far milder conditions than know

122 of an ICE TA toxin that influences substrate catalysis and toxin function which may be relevant to sp

123 n)binding of this transient third ion during catalysis and whether this ion has a catalytic function.

124 structural inhomogeneity in zeolites during catalysis and will assist the future design of zeolites

125 to alkenes have been a longstanding goal of catalysis, and anti-Markovnikov addition of arenes to al

126 ions in areas including storage, separation, catalysis, and biomedicine since it is essential to guar

127 orage/conversion, gas adsorption/separation, catalysis, and chemo-photothermal therapy.

128 e fields including gas storage, separations, catalysis, and drug delivery.

129 tments that accumulate ribozymes and enhance catalysis, and offering a mechanism for functional prebi

130 , dye sensitization, spintronics, photoredox catalysis, and organic light emitting diodes (OLEDs).

131 f beyond 2D TMD crystals in optoelectronics, catalysis, and quantum information science.

132 c modeling in homogeneous catalysis, electro-catalysis, and transient reaction kinetics.

133 This chelated Pd(II) catalysis appears to be different from the Pd(0) pathway

134 Deep insights into photo-thermo catalysis are achieved via the catalytic oxidation of pr

135 New challenges in asymmetric catalysis are arising in the field of deuterium labellin

136 individual protease-on-protease binding and catalysis are determined, proteolytic network dynamics c

137 in the application of MOFs in heterogeneous catalysis are discussed.

138 earch and development activities in titanium catalysis are highlighted.

139 play between photoredox and transition metal catalysis are included.

140 in the binding of NADP(+) and L-AHG and the catalysis are revealed.

141 hnology, biology, medicine, geology, optics, catalysis, art conservation and other fields are also di

142 olefins by dual palladium and copper hydride catalysis as a convenient and general approach to access

143 recently demonstrated asymmetric ion pairing catalysis as an effective approach to achieve stereosele

144 d of modern chemistry which impacts areas of catalysis as well as biological and materials chemistry.

145 mixed-valent compounds, and implications for catalysis as well as electronic communication are discus

146 nction relationship in molecular homogeneous catalysis as well as to summarize the main approaches pr

147 Heterotetramerization is required for catalysis, as heterodimeric ENZ-PRO mutants lack binding

148 nhibitory element that must re-orient during catalysis, as supported by molecular dynamics simulation

149 n and storage, manipulation of biomolecules, catalysis, as well as materials design and assembly.

150 tent with the proposed mechanism of in trans catalysis, as well as with conventional catalysis in cis

151 to 4CL1-knockout appear to have enabled 4CL5 catalysis at a level sufficient to sustain lignification

152 Innovative electrocatalysis, i.e., catalysis at the interface between the electrode and ele

153 that are relevant for application in (photo)catalysis, bioinorganic chemistry and materials science.

154 the fabrications and applications of PAs in catalysis but also anticipates future research efforts i

155 kets alters the energetics of adsorption and catalysis, but a mechanistic understanding of how nonaqu

156 are exploited by numerous metalloenzymes for catalysis, but it is not common to utilize a metal clust

157 tom iron catalyst is a landmark discovery in catalysis, but the proposed gas-phase reaction mechanism

158 metals, are frequently used in heterogeneous catalysis, but they are expensive, rare and the ability

159 sis by a carboxylate coupled to general acid catalysis by a carboxyl is not operative.

160 ey mechanistic information: (a) General base catalysis by a carboxylate coupled to general acid catal

161 We report a dual function asymmetric catalysis by a chiral phosphoric acid catalyst that cont

162 nosylmethionine cofactor, revealing possible catalysis by an S-adenosylmethionine-dependent carboxyli

163 n of modern-day respiratory complexes and of catalysis by biological iron-sulfur clusters.

164 e discovery that chiral anion phase transfer catalysis by C(2)-symmetric phosphoric acids allows cata

165 Catalysis by canonical radical S-adenosyl-l-methionine (

166 rmin D P1'-P4' region into pro-IL18 enhanced catalysis by caspase-11 to levels comparable with that o

167 le atom catalysis and surface organometallic catalysis by considering several specific catalytic reac

168 VvAHGD performs catalysis by controlling the consecutive connection and

169 out the structure, substrate recognition, or catalysis by family members.

170 ' position suggest a clear role for 2'-OH in catalysis by providing an indispensable hydrogen bond; p

171 e Rh -> In interaction is proposed to enable catalysis by stabilizing the reactive Rh(-I) species, wh

172 trates under reaction conditions amenable to catalysis by the hairpin ribozyme.

173 ular dynamics, we identify the origin of the catalysis by the supramolecular capsule Ga(4)L(6)(12-) o

174 ucture thus provides important insights into catalysis by this enigmatic respiratory machine.

175 The impairment of catalysis by Tyr68Ala can be understood in the context o

176 hermodynamic parameters with the kinetics of catalysis can provide new understanding and guide predic

177 fied a 1400-fold rate enhancement under BIMP catalysis, compared to the prior state-of-the-art cataly

178 ribution upon E(4)(H(2),2H) formation during catalysis, complementing these results with correspondin

179 eria utilize a common ping-pong mechanism of catalysis consisting of two subsequent nucleophilic subs

180 polymers could be extended to fields such as catalysis, cosmetics, life sciences, and food packaging,

181 electrochemistry to determine how efficient catalysis depends on the long-range coupling of electron

182 tions and allylations under transition metal catalysis, dimerization of acetylenes, bromination of be

183 ution single-particle tracking, we show that catalysis does not increase the diffusion of alkaline ph

184 tion of microkinetic modeling in homogeneous catalysis, electro-catalysis, and transient reaction kin

185 Photoredox catalysis employing ruthenium- and iridium-based chromop

186 Analogous photoredox catalysis enables C-H activation and H/D exchange in a n

187 or water filtration, chemical adsorption and catalysis, energy and resource recovery, as well as ener

188 and experiments to verify the strain-induced catalysis enhancement of the oxygen reduction reaction (

189 (PF-TMPPCo), thereby achieving a homogeneous catalysis environment inside ion-flow channels, with gre

190 Bifunctional hydrogen bond donor (HBD) catalysis exemplifies this in which a broad collection o

191 up to 300 degrees C, whereas electrochemical catalysis facilitates the reaction at room temperature.

192 valent and successful additives used in iron catalysis, finding application in reactions as diverse a

193 A predictive model for methane activation catalysis follows, which suggests that strongly electron

194 will have applications beyond supramolecular catalysis for copper-catalyzed cycloaddition reactions.

195 hodium(II) dimer in visible light photoredox catalysis for the aerobic oxidation of arylboronic acids

196 Applications of TEMPO(.) catalysis for the development of redox-neutral transform

197 d pyridine systems allows a disconnection of catalysis from autocatalysis, providing insights into th

198 Moreover, its potential in photooxidation catalysis has also been demonstrated by successful appli

199 Gold catalysis has become one of the fastest growing fields i

200 n for monosubstituted arenes and that the Rh catalysis has better tolerance of halogen groups.

201 In this regard, homogeneous gold catalysis has emerged as a powerful tool to construct th

202 nt years, research in the area of photoredox catalysis has enabled the use of PET for the catalytic g

203 Over the last two decades, iridium catalysis has evolved as a valuable tool enabling the st

204 Metallaphotoredox catalysis has evolved into an enabling platform to const

205 s and 2-oxo-3-butenoates under Bronsted acid catalysis, has been developed.

206 Using only proline catalysis, heteroaryl-substituted acetaldehydes are fluo

207 During catalysis, homolytic cleavage of the Fe-C5' bond liberat

208 cerevisiae was proposed to perform in trans catalysis, i.e. while localized in the ER, Opi3 would me

209 rans catalysis, as well as with conventional catalysis in cis.

210 Catalysis in confined spaces, such as those provided by

211 amples point to a poor understanding of cage catalysis in general, limiting the ability to design new

212 n scheme has been proposed for nitroprusside catalysis in indophenol reaction.

213 tanding of how nonaqueous solvents influence catalysis in microporous voids remains unclear.

214 90-100 % H(2) O(2) from electrochemical ORR catalysis in neutral pH water, whereas the Co-TPP monome

215 and also started to gain popularity in iron catalysis in recent years.

216 ad sizable impact on the field of asymmetric catalysis in recent years.

217 s under mild conditions, enabled by micellar catalysis in recyclable water as the reaction medium.

218 By defining single-atom catalysis in the broadest sense, we explore the full ele

219 w do external electric fields (EEFs) lead to catalysis in the presence of a (polar or nonpolar) solve

220 iated TET2 mutations on the kinetics of TET2 catalysis in vivo, and allows time-resolved monitoring o

221 etics employing cooperative palladium/copper catalysis in water is developed.

222 ing also enables homogeneous CO(2) reduction catalysis in water without compromising selectivity or r

223 This is a key feature of acid catalysis in zeolite solvents, which lack the isotropy o

224 Bifunctional catalysis in zeolites possessing both Bronsted and Lewis

225 xamples that employ complex Fe-S clusters in catalysis include the Fe-Mo cofactor (FeMoco) of nitroge

226 l the residues essential for specificity and catalysis including the catalytic nucleophile (Glu-297)

227 nventional system, further demonstrating its catalysis-independent nature.

228 he dynamic changes at the active site during catalysis is a fundamental challenge that promises to im

229 Reversible catalysis is a hallmark of energy-efficient chemical tra

230 of nanomaterials science, and their role in catalysis is becoming central.

231 veries provide compelling evidence that PRC1 catalysis is central to Polycomb system function and gen

232 ed carbon pai-systems under homogeneous gold catalysis is extremely rich and varied.

233 literature of three major research areas in catalysis is integrated as a step toward establishing th

234 with palladium catalysis showed that rhodium catalysis is more selective for meta-functionalization f

235 As expected, we observed that catalysis is mostly accomplished by a small set of resid

236 ding inhomogeneous active regions during the catalysis is not yet observed by conventional analytical

237 nd electrons, also known as "electrochemical catalysis", is a little explored approach that has the p

238 ferential effects on k (cat) and K (0.5) for catalysis, K (0.5) for substrate binding, and the Hill c

239 ulation, heterogeneous catalysis, photoredox catalysis, light emittance, sensing, energy storage, bio

240 sly employed to identify spatially resolved, catalysis-linked dynamical regions of enzymes.

241 w-temperature equilibrium regimes of thermal catalysis, mechanism underlining potential interplay bet

242 manipulation offers the promise of targeting catalysis-mediated signaling without grossly disrupting

243 h the bridging glutamate E205 and subsequent catalysis occurs only in the presence of carnitine.

244 TART domain and allosterically enhance Them1 catalysis of acyl-CoA, whereas 18:1 LPC destabilizes and

245 Catalysis of cis/trans isomerization of prolines is impo

246 fundamental kinetics of MOF-based molecular catalysis of electrochemical reactions is of crucial imp

247 1 (CAF1) proteins are important enzymes for catalysis of mRNA deadenylation in eukaryotes.

248 The major parts are catalysis of organic and molecular reactions, electrocat

249 Acid-based catalysis of procyanidin B2 and B3 produced four compoun

250 The STR catalysis of reactions of small aldehydes gives an unexp

251 ted to play a role in proton transfer during catalysis of the antibiotics.

252 tudies, provide the basis for a model of the catalysis of triacylglycerol synthesis by DGAT.

253 substrate, which is present in excess during catalysis, on the structure of transient Rh(2) nitrenoid

254 the reaction rate in relation to crown ether catalysis only.

255 the importance of the main group elements in catalysis, opening new avenues in synthetic chemistry.

256 te MOFs under realistic synthesis as well as catalysis (or sorption) conditions.

257 surface mass transport such as heterogeneous catalysis, oxidation, corrosion and carburization.

258 eterocyclic styrenes by the action of nickel catalysis paired with an unconventional bromothiophene o

259 adsorption and encapsulation, heterogeneous catalysis, photoredox catalysis, light emittance, sensin

260 Computational studies reveal that catalysis proceeds through hydrogen atom abstraction fol

261 eroatom nucleophiles via a metallaphotoredox catalysis protocol.

262 provide key insights into their mechanism of catalysis, relevant as a guide for the development of ef

263 cale regulation of such active sites for NRR catalysis remains challenging because of the large dista

264 The use of organic photoredox catalysis renders this method operationally simple under

265 This precise molecular mechanism for SAMHD1 catalysis, reveals how SAMHD1 down-regulates cellular dN

266 new applications, including optoelectronic, catalysis, sensing, and data encryption.

267 which may be useful in many areas, including catalysis, sensing, and photonics.

268 us scientific and industrial fields, such as catalysis, sensing, and renewable energy.

269 These data on the molecular basis of CCD catalysis shed light on the origins of the varied cataly

270 Comparison with palladium catalysis showed that rhodium catalysis is more selectiv

271 ontrast, under photochemical conditions, the catalysis smoothly proceeds at the 1((II/I)) redox poten

272 ent examples covering main-group homogeneous catalysis, stoichiometric organic synthesis, low-valent

273 Enantioselectivity in heterogeneous catalysis strongly depends on the chirality transfer bet

274 t reactions in electro-, photo-, and thermal catalysis studies.

275 ites are important in relevant heterogeneous catalysis suffering from mass transfer limitations and w

276 The unique structure of the homogeneous catalysis system comprising interconnected nanoreactors

277 tage for aqueous electron transfer and redox catalysis that takes place proximate to a solid interfac

278 to the sulfur via the S-C5' bond, but during catalysis thermally induced conformational changes that

279 the different inositide phosphate groups to catalysis, these structures provide new insights in the

280 gh this is unlike the biomimetic scenario of catalysis through direct host-guest interactions, the el

281 e documented constellation of di-iron enzyme catalysis to include a dioxygenase reactivity in which a

282 are useful for applications that range from catalysis to soft electronics.

283 strate scope and the application of titanium catalysis to the synthesis of complex organic small mole

284 provides a basis for enhancing hydrogenation catalysis under mild conditions via electrical polarizat

285 couplings is reported that relies on nickel catalysis under mild conditions, enabled by micellar cat

286 missense mutations (Y793C, R800C, Y849C) on catalysis, unveiling the molecular mechanisms underlying

287 ms of its operational simplicity, metal-free catalysis, use of water as a solvent, ambient reaction c

288 potential of isonitriles as ligands in metal catalysis utilizing both commercially available but also

289 Surprisingly, PGD catalysis was constitutively elevated without activating

290 enals promoted by cooperative (terpy)Pd/NHC catalysis was developed that generates various bioactive

291 ambiguity surrounding class A beta-lactamase catalysis, we have used ultrahigh-resolution X-ray cryst

292 Key residues for sugar binding and catalysis were identified by alanine scanning, D36 being

293 For tandem catalysis, where adjacent catalytic interfaces in a sing

294 versal strategy based on light-driven cobalt catalysis, which enables the generation of nucleophilic

295 Photo-thermo catalysis, which integrates photocatalysis on semiconduc

296 f [((tBu)POCOP)Re(CO)(2)H](-) present during catalysis, which is further impacted by changing the sol

297 By combining photoredox catalysis with oxoammonium cations in the presence of so

298 The combination of photoredox catalysis with the Wolff-Kishner (WK) reaction allows th

299 h applications of gold(III) in synthesis and catalysis, with emphasis on the mechanistic insight gain

300 e, advantages and pitfalls of using internal catalysis within different DCC applications, ranging fro