ライフサイエンスコーパス: chemisorption

1 with chemisorbed oxygen are required for DME chemisorption.

2 tle change in molecular structure outside of chemisorption.

3 es, molecular physisorption and dissociative chemisorption.

4 the adsorption process is governed mostly by chemisorption.

5 arm poly(ethylene glycol)-thiol (PEG-SH) via chemisorption.

6 measured for the likelihood of dissociative chemisorption.

7 heir supporting role in aqueous Nb-POM CO(2) chemisorption.

8 hindrance of the AAIL anions governing CO(2) chemisorption.

9 n and electronic interactions in the case of chemisorption.

10 mate and carbamic acid during carbon dioxide chemisorption.

11 way from the surface or undergo dissociative chemisorption.

12 on the 100 facet of Pd and its effect on CO chemisorption.

13 ide capture by the oxides is via monolayered chemisorption.

14 eneity and that GO retention was governed by chemisorption.

15 ructural changes of the sand surfaces due to chemisorption.

16 ex and Metsorb binding layers occurs through chemisorption.

17 ugation, via strategies of physisorption and chemisorption.

18 ids also show unusual examples of reversible chemisorption.

19 sized Au(n)(-) clusters: superoxo and peroxo chemisorption.

20 ctive of the regeneration temperature due to chemisorption.

21 than that of the monomers because of strong chemisorption.

22 pacities than those predicted based on CO(2) chemisorption alone.

23 n Pd and adsorbed N(2) , leading to enhanced chemisorption and activated protonation of N(2) , and su

24 n Pd and adsorbed N(2) , leading to enhanced chemisorption and activated protonation of N(2) , and su

25 cond-order and Elovich equations, suggesting chemisorption and diffusion processes.

26 The influence of surface structure on NO chemisorption and dissociation on Pt[100]-(1x1), Pt[211]

27 d for RCC and specifically address the CO(2) chemisorption and electroreduction mechanisms.

28 of quasi-two-dimensional structures that CO chemisorption and infrared experiments probe.

29 anol-H(2) equilibration is mediated by their chemisorption and interconversion at surfaces via C-H an

30 e, we apply the well established theories of chemisorption and interfacial electron transfer as conce

31 elate well with those obtained from CO pulse chemisorption and Mossbauer spectroscopy.

32 vectorially oriented peptide hbAP0 via both chemisorption and physisorption onto suitably alkylated

33 the material, followed by tandem cooperative chemisorption and physisorption.

34 Data suggest that size-dependent CO surface chemisorption and reversible Ni-carbonyl formation are k

35 ically) accurate calculation of dissociative chemisorption and scattering probabilities.

36 show that diamine degradation inhibits CO(2) chemisorption and that the degradation rate is significa

37 via the oxidation of Hg(0) which facilitated chemisorption and the subsequent physisorption onto chem

38 nanosheets, which significantly enhances N2 chemisorption and thereby promotes NH3 formation.

39 A combination of XRD, EXAFS, TEM, and CO chemisorption and TPD revealed the formation of CuPd bim

40 2-methylbenzo[d]thiazole which modulates the chemisorptions and hydrophobicity being designated as SQ

41 erally include both chemical bond formation (chemisorption) and nonbonding interactions (physisorptio

42 o sol-gel silica glass and by physisorption, chemisorption, and covalent attachment to silica gel.

43 temperature Mossbauer spectroscopy, CO pulse chemisorption, and electrochemical reductive stripping o

44 e was reconstructed by combining microscopy, chemisorption, and extended X-ray absorption fine struct

45 ed by the sorption mechanism: physisorption, chemisorption, and moisture-swing sorption.

46 th properties of high conductivity, hydrogen chemisorption, and plasmonic activity, are characterized

47 th other processes such as defect formation, chemisorption, and surface reconstruction and may play a

48 d the phase transition from physisorption to chemisorption, and we show that it predicts domain forma

49 The use of CO2 chemisorption as an alternative coagulating process has

50 icating heterogeneous surface adsorption and chemisorption as the dominant mechanisms.

51 Trace NH(3) capture typically relies on chemisorption at Lewis acid sites or physisorption on po

52 ies have directly interrogated mechanisms of chemisorption at open metal sites within porous framewor

53 +), demonstrate high efficiency of carbonate chemisorption at the interface, but SAXS and Raman of th

54 unambiguously differentiate between stronger chemisorption (Au-SR) and weaker physisorption (Au-SRR')

55 The O(2) chemisorption behavior is attributed to the greater elec

56 e characteristics such as molecular packing, chemisorption behavior, and hydrophilicity are found to

57 dsorption shows enthalpy values in line with chemisorption behavior.

58 Once atomic O binds to TiC(001), the chemisorption bond is so strong that temperatures well a

59 steps on Pt[211] strengthens the NO-surface chemisorption bond, but the barrier for NO dissociation

60 ourier transform infrared spectroscopy of CO chemisorption by mapping the gradual atomic-scale evolut

61 in situ infrared spectroscopy and volumetric chemisorption can quantify reversible H(2) adsorption on

62 involves energy-intensive processes such as chemisorption (CO(2) removal), catalytic hydrogenation (

63 can elucidate PYP's conformational steps and chemisorption configuration on Ag using the SERS selecti

64 skyrmions at room temperature, via hydrogen chemisorption/desorption on the surface of Ni and Co fil

65 Chemisorption, electrocatalytic, and computational studi

66 Estimating trends in surface chemisorption energies from in situ electrochemical CO/F

67 derived with two fundamental properties, the chemisorption energies of C and O (DeltaHC and DeltaHO,

68 ular dynamic simulations and calculations of chemisorption energies of radicals detected from our mas

69 CO-Pt-O complex is formed that equals the CO chemisorption energy at terraces and steps, leading to t

70 Chemisorption experiments including H(2) temperature-pro

71 sites into MFU-4l, enabling non-dissociative chemisorption for CH(3)I at 150 degrees C.

72 Interestingly, Al doping strengthened chemisorption for PMS (from -2.615 eV to -2.623 eV) and

73 s with the well-established d-band theory of chemisorption for reactivity prediction of transition-me

74 y over MIL-101(Cr)-supported TEPA and strong chemisorption (formation of carbamate) occurring over ga

75 the two supported amine materials, with weak chemisorption (formation of carbamic acid) being the dom

76 ic studies by X-ray absorption spectroscopy, chemisorption FTIR, operando UV/Vis and (1) H-(13) C HSQ

77 The As(OH)3 molecule displayed a variety of chemisorption geometries on the water-FeS(011) and water

78 electronic excitation upon highly exothermic chemisorption has been observed, and indirect evidence s

79 This extraordinary example of chemisorption has enormous implications for catalysis, s

80 Sensor response to thiolated DNA probe chemisorption, hsa-let-7a hybridization, labeled-DNA hyb

81 mino groups are mainly responsible for CO(2) chemisorption in amino acid-based capture media, the nat

82 Here, we demonstrate that CO(2) chemisorption in gamma-cylodextrin-based metal-organic f

83 lts underscore the crucial role of molecular chemisorption in shaping interfacial magnetic properties

84 The CO(2) chemisorption in state-of-the-art sorbents based on oxid

85 There is a kinetic energy threshold for chemisorption, indicating that it is an activated proces

86 d polycrystalline Cu foils via simple oxygen chemisorption-induced reconstruction, enabling fast grow

87 This chemisorption interaction is the strongest reported to d

88 analyses lead to decisive information about chemisorption interactions between CO and a model Au clu

89 ees C, which is consistent with dissociative chemisorption into NO and atomic O accompanied by surfac

90 ng of O(2) onto Au(8)(-), while the superoxo chemisorption is a slightly higher energy isomer.

91 In addition, the possibility of chemisorption is clearly ruled out.

92 same ionic liquid or in ionic liquids where chemisorption is impossible (such as [P66614][NTf2]) und

93 The results reveal that enantioselective chemisorption is only found when 2-butanol is present on

94 he TiO(2) surface, only one adsorption mode, chemisorption, is observed for acetic acid.

95 ined by elemental analysis (ICP-MS) and H(2) chemisorption isotherms, respectively.

96 ption and reduction and solely relies on the chemisorption kinetics of Au ions in the heterogeneous G

97 However, the thiol/Au chemisorption linking AEF-peptide to gold electrodes is

98 This enables chemisorption measurements in air at room temperature, w

99 has been shown to occur predominantly via a chemisorption mechanism involving CO(2) insertion at the

100 at can uptake CO2 at low pressures through a chemisorption mechanism.

101 vibrational spectroscopy techniques and (iv) chemisorption methods.

102 -Cp tantalum hydrocarbyl 2* follows the same chemisorption mode as 1*.

103 n of a material with SMM characteristics via chemisorption of (Cp(ttt))(2)DyCl ((Cp(ttt))(-) = 1,2,4-

104 The enantioselective chemisorption of (S)- and (R)-propylene oxide is measure

105 es of fluorescent products due to the strong chemisorption of 1-butanol onto the Bronsted acid sites.

106 self-assembled monolayers were performed by chemisorption of 11-mercaptoundecanoic acid on gold surf

107 In contrast, chemisorption of 2 on dehydroxylated alumina (DA) yields

108 e species, as evidenced by the inhibition of chemisorption of a disulfide reagent to the overcoated g

109 r identification and quantification that the chemisorption of acetone can convert the classical Brons

110 The EPFRs were produced by the chemisorption of adsorbates on the supported metal oxide

111 ardiac troponin I than those prepared by the chemisorption of alkane thiolated compounds.

112 A systematic study reveals chemisorption of ammonia and hydrocarbon gases and chemi

113 olution calorimetry, we clearly identify the chemisorption of an unusually strong iodine charge-trans

114 ape and intensity of the "white-line" due to chemisorption of atomic hydrogen (H(ad)) at low potentia

115 perature range studied, whereas dissociative chemisorption of both cyclohexane and cyclooctane occurs

116 e prompt addition of atoms to the seed; (ii) chemisorption of bromide on the seed to promote the form

117 Chemisorption of carbon dioxide by 1-ethyl-3-methylimida

118 culations reveal that dissociation of water, chemisorption of CO(2) and cleavage of the C-O bond-the

119 dynamic role of interfaces in modulating the chemisorption of CO(2) from air into solutions.

120 34) are suitably described the monolayer and chemisorption of CTX adsorption.

121 On the Ir(111) surface, the dissociative chemisorption of cyclobutane, cyclopentane, and cyclohex

122 On the Ru(001) surface, dissociative chemisorption of cyclopentane occurs via initial C-C bon

123 zed coupling agent, which is prepared by the chemisorption of dithiobis(succinimidyl undecanoate) on

124 Here, we show that nondissociative chemisorption of H(2) at the trigonal pyramidal Cu(+) si

125 alized with amino-propyl groups which led to chemisorption of H(2)CO; removing it permanently from ai

126 We propose 'Microbially Enhanced Chemisorption of Heavy Metals' (MECHM) to describe this

127 or beta phase PdH formation is dissociative chemisorption of hydrogen for each palladium alloy film.

128 ur results pave the way to investigating the chemisorption of ions in 2D materials at high electric f

129 y surface (Rh/Cu(111)) upon the dissociative chemisorption of methane (CH(4)), using molecular dynami

130 This was achieved by chemisorption of molecules of 4-azido-2,2,6,6-tetramethy

131 identified as a combination of site-specific chemisorption of MTFP and multiple non-covalent attracti

132 The kinetic energy threshold for chemisorption of N(2) on Al(100)(+) has been measured as

133 Cross sections for chemisorption of N2 onto Al44(+/-) cluster ions have bee

134 sm may be broadly applicable to dissociative chemisorption of NH3 on other metal oxide surfaces encou

135 Chemisorption of Ni(COD)(2) (COD, 1,5-cyclooctadiene) on

136 Ni alloying enables the chemisorption of nitrogen and the lower free-energy chan

137 Ni alloying enables the chemisorption of nitrogen and the lower free-energy chan

138 on, in comparison to ZIF-8, results from the chemisorption of NO molecules, which also causes a gate-

139 mineral (phosphate) precipitation or via the chemisorption of organic- and carbonate-Nd complexes ont

140 (3)N(4)) is a nontraditional support for the chemisorption of organometallic complexes with the poten

141 tion of the modification of Ti6Al4V alloy by chemisorption of osseoinductive alendronate using a simp

142 y changes of the carbon peak show continuous chemisorption of oxygen intermediates on the carbon cath

143 mong various nonradiative pathways, sidewall chemisorption of oxygen provides a known defect for exci

144 Chemisorption of oxygen to the Te-terminated surfaces pr

145 phenylene units formed from the dissociative chemisorption of p-diiodobenzene.

146 ed the initial probabilities of dissociative chemisorption of perhydrido and perdeutero cycloalkane i

147 l theory (DFT) calculations: (1) nonreactive chemisorption of PFOA in a perpendicular orientation on

148 Self-limiting chemisorption of precursors onto substrates is studied u

149 The chemisorption of prochiral molecules, such as adenine, o

150 The enantioselective chemisorption of R- and S-propylene oxide has been measu

151 ium diethylene complexes were synthesized by chemisorption of Rh(C(2)H(4))(2)(acac) (acac = CH(3)COCH

152 ratures remained almost unchanged indicating chemisorption of some of these compounds onto the BAC.

153 tent free radicals (EPFRs) are formed by the chemisorption of substituted aromatics on metal oxide su

154 lS/TaNp(x) (1) (Np=neopentyl) is prepared by chemisorption of the alkylidene Np(3) Ta=CH(t) Bu onto h

155 Chemisorption of the aromatic ligand leads to a shift in

156 (FePc) molecules is mediated via the strong chemisorption of the central Fe atom to the sp(3) -like

157 metallic state, initiates the catalysis via chemisorption of the hydrocarbon, adjacent B centers rea

158 The interfacial scattering from chemisorption of the Lewis base HDT on the atom-scale ju

159 solution and sensor chips were fabricated by chemisorption of these nanoparticles on amine-functional

160 s a way to tailor and control the subsequent chemisorption of transition metal coordination complexes

161 The chemisorption of two types of peptides, one containing t

162 which can be attributed to the dissociative chemisorption of water at specific surface sites.

163 Chemisorption of water onto anhydrous nanophase manganes

164 Despite the "weak chemisorption" of PYP on silver that only allows the sin

165 as a function of coverage: strongest initial chemisorption on active sites on fresh calcite surfaces,

166 nd Zr(CH(2)Ph)(4) (5) (Cp = eta(5)-C(5)H(5)) chemisorption on AlS are 5/AlS > or = 4/AlS > or = 3/AlS

167 CO chemisorption on Au(6) is observed to be highly unusual.

168 ng energies of Au(m)(CO)(n)(-) complexes, CO chemisorption on Au(6) is observed to have very little e

169 ts indicate that the mercury was captured by chemisorption on both the commercial and biomass ash sor

170 d to study the structure and energetics of H chemisorption on graphite zigzag edges.

171 Thus CO chemisorption on the apex sites (outer triangle) has lit

172 lamine, and trimethylamine undergo molecular chemisorption on the Ge(100)-2 x 1 surface through the f

173 -base chemistry at the interface rather than chemisorption on the oxide surface, a finding that can h

174 transfer to surface Lewis acid sites, while chemisorption onto dehydroxylated silica yields a mu-oxo

175 omagnetic field on the substrate by means of chemisorption or drop-casting and subsequent evaporation

176 The energy released in low-energy chemisorption or physisorption of molecules on metal sur

177 FLU adsorption's chemisorption performance on DP was involved in followin

178 The observed chemisorption phenomena exhibit adsorption energies betw

179 a straightforward visualization of the rich chemisorption phenomenology at steps and terraces.

180 ultimechanistic scavenging process involving chemisorption, physisorption, and redox reactions.

181 he gold atoms within the cluster bind to the chemisorption probe 2-naphthalenethiol.

182 of the thiol-ligated nanocrystals shows this chemisorption proceeds without displacement of the octad

183 The sequential chemisorption process allowed the simultaneous tailoring

184 The chemisorption process exhibits a characteristic nodal sy

185 p' = eta(5)-(CH(3))(5)C(5)) reveals that the chemisorption process involves M[bond]C sigma-bond proto

186 inding in these materials is mainly due to a chemisorption process, although a small amount of physis

187 ent carbon-oxygen bond, associated with this chemisorption process, releases CO2 at low activation en

188 attention as ideal candidates for the CO(2) chemisorption process.

189 ich and Langmuir and revealed a satisfactory chemisorption process.

190 elop a Bayesian learning approach to probing chemisorption processes at atomically tailored metal sit

191 s yield crystal structures to understand the chemisorption processes, K(+) counter cations enable hig

192 and high collision energies the Al44N2(+/-) chemisorption product dissociates through several channe

193 observe using solid state NMR that the major chemisorption product for this material is carbamic acid

194 Multiple chemisorption products are found from the interaction of

195 Elucidating the chemisorption properties of CO on gold clusters is essen

196 e local compressive strain, which alters the chemisorption properties of the surface.

197 ith more than half of the N retained through chemisorption rather than physisorption.

198 ry, and tertiary amines, leading to multiple chemisorption reaction outcomes, including carbamate (Rn

199 Features include providing basic oxygens for chemisorption reactions, direct binding of carbonate, an

200 nd selectivity, as well as steric effects in chemisorption reactions.

201 relative adsorption energies, in the strong chemisorption regime.

202 theory in the problematic van der Waals/weak chemisorption regime.

203 avities formed a monolayer formation through chemisorption resulting in an adsorption capacity of 429

204 While CO cryo-chemisorption revealed a twice lower site density of M-N

205 in) of NO2 at ambient temperatures, isolated chemisorption sites on the CuPc metal centers are observ

206 Non-dissociative chemisorption solid-state storage of hydrogen molecules

207 rgetic molecular beam, was into a metastable chemisorption state.

208 tural information forms the basis for future chemisorption studies to unravel the catalytic effects o

209 that the Pt-SWNTs store hydrogen by means of chemisorption, that is, covalent C-H bond formation: mol

210 Mono-Cp tantalum hydrocarbyl 1* undergoes chemisorption to form Cp'Ta((13)CH(3))(3)O-Si mu-oxo spe

211 relative contributions of physisorption and chemisorption to Hg(0) uptake would change with Hg(0) co

212 trong and (at low temperatures) irreversible chemisorption to the catalyst's surface is in particular

213 ctional by design and contain disulfides for chemisorption to the nanoparticle surface and succinimid

214 t, we report that polymers exhibiting strong chemisorption toward specific gas molecules can counteri

215 ork shows that there is a superoxo to peroxo chemisorption transition of O(2) on gold clusters at Au(

216 ises the activation barrier for dissociative chemisorption via C-C bond cleavage, depending on whethe

217 rbs directly, it is temporarily trapped in a chemisorption well on a Pt(332) step site.

218 coordinated surface sites and their stronger chemisorption were linked to surging H2 and CO selectivi

219 to the open metal sites in this MOF (called chemisorption, where the adsorbent-adsorbate interaction

220 ced lattice dissociation and defect-mediated chemisorption, which are undesirable features observed a

221 echanisms are common in inorganic materials: chemisorption, which can lead to the modification of the

222 extract in 1.0 M HCl predominantly underwent chemisorption, while the bulk-sized extract in 1.0 M HCl

223 materials like activated carbon (AC) undergo chemisorption with O2 to give species with electron defi

224 all the results in this work: physisorption, chemisorption, XRD, XPS, SEM, TEM, TGA, ICP, and Raman a