ライフサイエンスコーパス: chiral

1 es and two macrocycles that are "inherently" chiral.

2 Chiral 1,2-bimetallic reagents are useful motifs in synt

3 y enabling the stereoselective transfer of a chiral 1-carboxyethyl group to the substrate.

4 bstituted carbon centers in the synthesis of chiral 2,2-disubstituted benzomorpholines.

5 logy has been developed for the synthesis of chiral 2-aryl-ferroceneamides from chiral 2-iodo-N,N-dii

6 hydrogen bond donors and acceptors but is a chiral 2-arylbutyrate and potentially prone to racemizat

7 thesis of chiral 2-aryl-ferroceneamides from chiral 2-iodo-N,N-diisopropylferrocencarboxamide, iodoar

8 The chiral 3,4-dihydro-2H-naphtho-1,4-oxazinones have been a

9 od has been developed for the preparation of chiral 3,4-dihydro-2H-naphtho[1,2-b][1,4]oxazin-2-ones b

10 These chiral AAO membranes successfully demonstrated enantiose

11 di(1H-tetrazol-5-yl)benzene] (H(2)L(1)) with chiral acceptors (R,R)M and (S,S)M yielded enantiopure h

12 Previously, Bode's chiral acylated hydroxamic acids were used to determine

13 Reported here is a strategy to prepare chiral AgNP arrays templated by two constitutionally iso

14 ure affect the plasmonic properties of these chiral AgNP/APA hybrids.

15 to the beta-carbon, thus favoring the linear chiral aldehyde over the achiral branched alternative.

16 es, stereospecific synthesis of useful alpha-chiral alkyl amines, and rapid construction of different

17 nts, takes advantage of an in situ generated chiral alkyl Ni(III)-intermediate to ensure a stereodefi

18 Further, multiple transformations of the chiral amides obtained in this process showcase the pote

19 he remote substituents of the D(2)-symmetric chiral amidoporphyrin ligand.

20 The chiral amine (the inductor) forces a change in the struc

21 The use of simple chiral amines and easily prepared achiral or racemic pho

22 Biocatalytic strategies for the synthesis of chiral amines are increasingly attractive and include en

23 amic self-assembly of commercially available chiral amines, 2-formylphenylboronic acid, and chiral di

24 xtures of enantiomers of 1,2- and 1,3-diols, chiral amines, amino alcohols, and amino-acid esters.

25 ions allow an efficient access to nonracemic chiral amines.

26 reaction of benzoxepine-4-carboxylates with chiral amino acid ethyl esters for the first time.

27 ion of l- or d-enantiomeric excesses (ee) of chiral amino acids and sugars could be a powerful indica

28 ent alternative to electrochemically produce chiral amino acids for biotechnology applications.

29 ersion from chemically inert nitrogen gas to chiral amino acids, powered by H(2) oxidation.

30 es, providing fast access to enantioenriched chiral amino alcohols, important building blocks for med

31 symmetry breaking as well as the subsequent chiral amplification process are discussed.

32 ontrolled supramolecular copolymerization of chiral and achiral biphenyl tetracarboxamides in alkanes

33 interaction (DMI) is responsible for exotic chiral and topological magnetic states such as spin spir

34 oxides and identify paths toward engineering chiral and topological states in centrosymmetric oxides

35 are accessible following the discovery that chiral anion phase transfer catalysis by C(2)-symmetric

36 A surface-enhanced Raman scattering-chiral anisotropy (SERS-ChA) effect is reported that com

37 50% and confirms the prediction based on the chiral anomaly in quantum chromodynamics.

38 es, in which discrete NPs are assembled into chiral architectures, represent an exciting and growing

39 tructural and optical properties of designed chiral architectures.

40 The chiral aspect of inorganic crystals that crystallize in

41 assemblies, chiral plasmonic nanostructures, chiral assemblies of interacting plasmonic nanoparticles

42 iological processes, complicating the use of chiral asymmetry by itself as a definitive biosignature.

43 ral inducer, polydiacetylene (PDA) with high chiral asymmetry was obtained from achiral diacetylene m

44 ophilic aromatic substitution catalyzed by a chiral-at-metal rhodium Lewis acid.

45 The first enantiopure chiral-at-rhenium complexes of the form fac-ReX(CO)(3) (

46 ve phenol containing a lactate moiety as the chiral auxiliary.

47 stortion, which is largely influenced by the chiral backbone and adamantyl groups on the salicylaldeh

48 nto its enantiomers, and all four inherently chiral bambusuril pairs (two Pr(4)Me(4)BU[4] and two Bn(

49 adical C-H amination enabled broad access to chiral beta-amino alcohols from a variety of alcohols co

50 Chiral beta-aminoalkylboronates generate growing interes

51 atalytic system to prepare the corresponding chiral beta-hydroxy nitriles.

52 mines, leading to the efficient formation of chiral beta-lactam derivatives.

53 Specifically, we prepared the chiral biaryl bisphosphine ligand (TMG-SYNPHOS) containi

54 ng from restricted rotation about an axially chiral biaryl bond.

55 e energy required for breaking symmetry with chiral bias is compared for this near-equilibrium AED pr

56 polarized, while the other two show that the chiral bias provided by the electron helicity can drive

57 plification refers to the ability of a small chiral bias to fully control the main chain helicity of

58 hirality in a system containing a very small chiral bias.

59 mines (cyclopropylmethylamines) enabled by a chiral bidentate thioether ligand.

60 f imprinting surface optical structures onto chiral biomaterials facilitates a range of prospective p

61 ncoding, chiral polarizers, and colorimetric chiral biosensing.

62 enantioselective ring opening with CsF and a chiral bis-urea catalyst.

63 An (l)-(+)-isoleucine chiral bisoxazoline ligand and the presence of coordinat

64 ng ethylbenzylamine or phenylglycine-derived chiral BP synthons incorporating a photolabile protectin

65 In the same flask, a chiral Bronsted acid is added next to engage the isomeri

66 Chiral Bronsted acid-catalyzed asymmetric aldehyde addit

67 observed enantio- and stereoselectivities of chiral Bronsted acid-catalyzed asymmetric allylation.

68 hodology for the straightforward assembly of chiral building blocks such as primary and secondary ami

69 mary structure is clockwise/counterclockwise chiral cap and core molecules.

70 We report that a readily accessible chiral carboxylic acid catalyst exerts control over asym

71 onfinement effects for organic substrates in chiral catalysis.

72 the C-H...pai and pai...pai NCIs between the chiral catalyst and alpha-methylstyrene render the si-fa

73 tractive non-covalent interactions between a chiral catalyst and the substrate are leveraged to exert

74 lyst Rh(2) (S-NTTL)(4) is the most effective chiral catalyst for triazole-derived carbene transformat

75 In the presence of a chiral catalyst, both the central and axial chirality of

76 rate that the use of two mutually compatible chiral catalysts in one-pot conditions can help realize

77 iven by the reagents' interaction with bulky chiral catalysts.

78 Chiral cations have been used extensively as organocatal

79 nvestigating the enantiopurity of inherently chiral cavitands, which complements and augments the con

80 Introduction of the second chiral center and subsequent chiral separations provided

81 oup in the unsymmetric pyrazoles generated a chiral center to extend the scope of this method.

82 ecursors with a phenyl group attached at the chiral center were asymmetrically synthesized using a pe

83 mediated Barbier allylation to set the third chiral center with high substrate control.

84 of a phenyl group positioned remote from the chiral center.

85 ed by chemical bond polarization involving a chiral center.

86 ivation, shares the same scaffold with three chiral centers as the aforementioned compounds.

87 es, with six fused rings and four contiguous chiral centers, is reported.

88 iolane ring leading to up to four contiguous chiral centers.

89 complex substrates possessing more rings and chiral centers.

90 compounds bearing deuterium ((2)H) atoms at chiral centres are becoming increasingly desirable targe

91 istries, geometries, and properties found in chiral ceramic nanostructures are summarized.

92 investigation of 2D transport anisotropy and chiral charge transport as a result of broken symmetry.

93 Through strategic chemical derivatization, chiral chromatographic separation, and multistage tandem

94 single-molecule scale can be advanced, using chiral chromatography as an example case.

95 eractions, i.e., relative retention times on chiral columns) did not predict the atropselective parti

96 Chiral compounds have become of great interest to the ph

97 to perform ultrafast separations and screen chiral compounds in supercritical fluid chromatography (

98 n be potentially applied to diverse types of chiral compounds, several benchmark amino acids were use

99 ce is discussed considering both achiral and chiral contributions.

100 fficulty in separating (sub)micrometer-scale chiral crystal enantiomers.

101 Here, we show that the chiral crystal palladium gallium (PdGa) displays multifo

102 s, which demonstrates that the handedness of chiral crystals can be used to control the sign of their

103 FA are expected at the surface when forming chiral crystals in the space group of P2(1) 3 (#198).

104 As HER catalysts, PtAl and PtGa chiral crystals show turnover frequencies as high as 5.6

105 e was applied to the asymmetric synthesis of chiral cyclohexanones via a catalytic [4+2] cycloadditio

106 Chiral cyclooctadienes are a frequently occurring scaffo

107 reductive desymmetrization process to access chiral cyclopentane bearing multiple stereocenters with

108 f the flat band is directly confirmed by the chiral d-orbital texture of the corresponding real-space

109 nes (AAO) were prepared by coating protected chiral D/L aspartic acid appended polyfluorene in the po

110 zimidazolylbenzoic acid (TBBA) was used as a chiral derivatization agent for the assignment of the ab

111 ed chromatography system was used for inline chiral derivatization with (S)-naproxen chloride and sub

112 Because chiral dialkyl carbinols, as well as their derived ester

113 Chiral diamines are particularly useful as ligands for a

114 iral amines, 2-formylphenylboronic acid, and chiral diols in acetonitrile to form fluorescent diaster

115 yldiazoacetates in the presence of the bulky chiral dirhodium tetracarboxylate catalyst, Rh(2) (R-p-P

116 (SERS-ChA) effect is reported that combines chiral discrimination and surface Raman scattering enhan

117 Chiral discrimination is a key problem in analytical che

118 The reliability and chiral discrimination sensitivity of the method can be f

119 and pore adaptability collectively determine chiral discrimination.

120 is synthetic pursuit is to study whether the chiral dyes can impart a chiral-induced spin selectivity

121 Hall effect (QAHE) causes a dissipationless chiral edge current at the sample boundary(1,2).

122 matter featuring a finite Chern number C and chiral edge states(2,3).

123 -volatile magnetic-domain structures hosting chiral edge states, with applications ranging from recon

124 In the present study, we show how chiral editing can be a powerful tool to trap and stabil

125 d here can be applied to realize and control chiral electronic phases in other quantum materials(4,16

126 t the collected serine octamer has undergone chiral enrichment relative to the starting solid used in

127 cemic switch with enantiomers in presence of chiral environment for human beings.

128 erstructures or supramolecular assemblies in chiral environments.

129 The quasiparticles form a chiral field, which breaks the time-reversal symmetry on

130 , so it has been unclear whether one or both chiral forms are active.

131 s to cyclopentenoyl enamines and imines, or (chiral) gamma-lactams through two geminal C-C bond or tw

132 Herein, chiral GSH-anchored selenium nanoparticles (G@SeNPs) are

133 Surprisingly, the presence of R-BINOL as a chiral guest in the above self-assembly induced selectiv

134 Encapsulation of chiral guest molecules such as [(R/S)-1,1'-binaphthalene

135 Enantioselective binding of chiral guests, with energetic differences DeltaDeltaG(29

136 hese limitations, a generic and fast achiral-chiral heart-cutting two-dimensional (2D)-LC method has

137 ches for the synthesis of three-dimensional, chiral heterocyclic systems, important synthetic buildin

138 Chiral Pr(4)Me(4)BU[4], 4b, was resolved by chiral high-performance liquid chromatography (HPLC) int

139 broad substrate scope and delivers complex, chiral homopropargyl amines; useful building blocks on t

140 antiomeric guest from a racemic mixture by a chiral host is well-known, present observation of "rever

141 ve samples of enantioenriched sulfoxides for chiral HPLC to enable reproducible results is clear.

142 work shows the tremendous potential of these chiral hybrid semiconductors for controlling both spin a

143 o study whether the chiral dyes can impart a chiral-induced spin selectivity (CISS) spin-filtering ef

144 nanoparticles modified with cysteine as the chiral inducer, polydiacetylene (PDA) with high chiral a

145 ty to achieve chirality-selective synthesis (chiral induction) is of great importance in stereochemis

146 ation of H with right handedness by means of chiral induction.

147 sically chiral nanocrystals (NCs) of several chiral inorganic compounds with significant enantiomeric

148 c systems with broken inversion symmetry and chiral interactions, such as Dzyaloshinskii-Moriya inter

149 em, hence highlighting the huge potential of chiral intermetallic compounds for enantioselective synt

150 cyclization reactions with in situ generated chiral iodine(III)-catalysts.

151 selective functionalizations of C-H bonds by chiral iridium complexes with emphasis on the mechanisms

152 By combining a tailored chiral iridium phosphoramidite catalyst, which controls

153 specifically convert distinct diastereomeric chiral isoflavonoid precursors to the chiral pterocarpan

154 ly stereocontrolled aldol reactions of three chiral ketone building blocks, an efficient first total

155 e dual activation of both reaction partners, chiral Lewis-base activation of the electrophile and lig

156 opment of iridium-based systems with various chiral ligand classes, as well as studies of their react

157 in the presence of an appropriate ancillary chiral ligand, the opposite regiochemistry can be observ

158 ace-mediated transfer of optical spin from a chiral light beam to produce an electronic torque that r

159 an OAM-tunable vortex microlaser, providing chiral light states of variable topological charges at a

160 account on the state of the art of emerging chiral liquid crystalline nanostructured materials and t

161 thermodynamic phases of superconductors and chiral liquid crystals.

162 In the E isomer form, the chiral m-BTA monomers intercalate into stacks of a-BTA a

163 magnetic response of Weyl semimetals such as chiral magnetic effect has been observed and presented b

164 rovide critical insights into the origins of chiral magnetism in low-damping magnetic oxides and iden

165 t-matter interaction that can be observed in chiral magnetized systems.

166 cular magnetic sponges, luminescent magnets, chiral magnets and photomagnets, SHG-active magnetic mat

167 many fascinating physical phenomena, such as chiral magnon and skyrmion glass states.

168 uctance plateau is unlikely to be induced by chiral Majorana fermions in samples with a highly transp

169 s-wave superconductor is predicted to harbor chiral Majorana modes.

170 ly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molec

171 -large optical asymmetry on a wider scope of chiral materials.

172 The incorporation of chiral MBA cations leads to circularly polarized absorpt

173 ory insertion, and norbornene as a transient chiral mediator in relay chemistry, provide new insights

174 eractions between an organic substrate and a chiral mediator, we have developed a transient-directing

175 Out of the chiral medicines, 1,591 (74%) and 559 (26%) were racemat

176 tic Weyl points by using a three-dimensional chiral metacrystal of sound waves.

177 of interacting plasmonic nanoparticles, and chiral metal metasurfaces and metamaterials.

178 The chiral MHP can thus be melt-quenched into a stable glass

179 ll, using aromatic oligoamide foldamers as a chiral model, we demonstrate the capabilities of HRS as

180 e triarylmethanol, para-substituted with the chiral moiety, shows a propensity for a solid-state sort

181 , ideally suited for the analysis of various chiral molecular and supramolecular systems in solution.

182 This is achieved through the use of chiral molecular ligands, which bind to the atomic/ionic

183 These chiral molecular switches induce photoresponsive helical

184 l chiroptical features of optically emissive chiral molecular systems.

185 trates the enantioselective association of a chiral molecule with an achiral self-assembled monolayer

186 -H bonds for stereoselective construction of chiral molecules bearing quaternary stereocenters.

187 aneous enantiospecific detection of multiple chiral molecules in a mixture represents a major challen

188 l enabling the stereocontrolled synthesis of chiral molecules via C-H activation.

189 By enchaining a small fraction of chiral monomer units, the helical sense of a dynamic pol

190 alized tripeptides consisting of homo/hetero chiral monomeric all-cis 5-arylpyrrolidine-2,4-dicarboxy

191 xional into configurationally stable axially chiral N-arylpyrroles was achieved with a highly atropos

192 n of a new strategy that involves the use of chiral N-protonated alkenyl oxazaborolidines as dieneoph

193 e viewed as building blocks for more complex chiral nanocarbons.

194 iscoveries and technological translations of chiral nanoceramics have received substantially smaller

195 rs, the colloidal synthesis of intrinsically chiral nanocrystals (NCs) of several chiral inorganic co

196 ual advances that helped define the field of chiral nanomaterials is provided, and some of the major

197 Chiral nanoparticle (NP) superstructures, in which discr

198 and surface Raman scattering enhancement on chiral nanostructured Au films (CNAFs) equipped in the n

199 The development of applications for chiral nanostructures is rising rapidly.

200 Thus, chiral nanosystems may have the potential to provide a n

201 Here we have proven that newly synthesized chiral naphthalene diimide (NDI) derivatives are excelle

202 Future perspectives on chiral NCs are also proposed.

203 lies on the specific interaction between the chiral NDI receptor and the thalidomide enantiomer of th

204 als (CNCs) are known to self-assemble into a chiral nematic liquid crystalline phase, leading to soli

205 Preliminary investigations using chiral NHCs demonstrate that enantioselectivity can be a

206 Here, we report a chiral nickel catalyst that couples racemic electrophile

207 Chiral nitriles and their derivatives are prevalent in p

208 insertion of an arylpalladium species into a chiral norbornene derivative.

209 lded a complex mixture of stereoisomers of a chiral octahedral cage.

210 terials that can be created by combining two chiral oligomeric components (e.g., proteins) in precise

211 se transition, and signatures of topological chiral one-way edge currents, completely in synthetic di

212 thod toward the fabrication of NPs with high chiral optical activity.

213 a clear need to design and develop sensitive chiral optical probes that can function within a biologi

214 owever, the structural interplay between the chiral organic molecules and the inorganic sublattice, a

215 r the accumulation of DNA writhe and for the chiral organization of the genome.

216 A proper chiral packing of the building block at several molecula

217 Chiral pai-conjugated molecules provide new materials wi

218 we will overview the existing literature on chiral pai-conjugated systems whose thin films have been

219 known how much PCB enters the cells and, for chiral PCBs, if the partitioning is atropselective.

220 hod to fabricate programmable 2D patterns of chiral PDA with tailored chirality distributions, such a

221 Axially chiral phenols are attractive targets in organic synthes

222 r, scalable, and stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides are

223 The use of expensive chiral phosphines is more scattered, but the most common

224 Chiral phosphoric acid based organocatalysis and visible

225 or the Minisci reaction was developed, using chiral phosphoric acid catalysis.

226 he alkyl groups of the diol on boron and the chiral phosphoric acid catalyst influence the orientatio

227 rt a dual function asymmetric catalysis by a chiral phosphoric acid catalyst that controls both enant

228 gold(I) complex of a phosphine displaying a chiral phosphoric acid function.

229 tween the neutral sulfonamidyl radical and a chiral phosphoric acid generated in the PCET event are h

230 atalyzed by a combination of palladium and a chiral phosphoric acid was investigated by a combined ex

231 ts to induce an enantioselective 3CR using a chiral phosphoric acid were unsuccessful.

232 of this reaction is accessible by employing chiral phosphorous ligands was obtained.

233 pplication to the preparation of a potential chiral phosphorus organocatalyst is also reported.

234 ionalities, such as enhanced iridescence and chiral photoluminescence.

235 Sharp chiral wrinkles lead to chiral plasmon modes with high dissymmetry factors (~0.2

236 etic dipoles associated with enantiomers and chiral plasmonic modes of CNAFs.

237 s, including molecular-plasmonic assemblies, chiral plasmonic nanostructures, chiral assemblies of in

238 uggest modes of binding in the (DHQD)(2)PHAL chiral pocket that explain the system's remarkable contr

239 tereoscopic displays, polarization encoding, chiral polarizers, and colorimetric chiral biosensing.

240 plementary nucleobases on opposite arms of a chiral polyhydroxypyrrolidine while also ensuring that t

241 This disruptive mechanistic insight into chiral polymer thin films will offer new approaches towa

242 makes effective use of (-)-quinic acid as a chiral pool starting material and substrate stereocontro

243 er from the aqueous racemic mixture into the chiral pores of the AAO membrane leaving the filtrate en

244 Chiral Pr(4)Me(4)BU[4], 4b, was resolved by chiral high-

245 gnment of the absolute configuration of beta-chiral primary alcohols.

246 peptide catalyst to afford stable, helically chiral products in up to >99:1 er.

247 ve been proposed to demonstrate scatter-free chiral propagation, but their experimental realization t

248 omeric chiral isoflavonoid precursors to the chiral pterocarpans, (-)- and (+)-medicarpin, respective

249 to the octamer, which displays a much higher chiral purity than the monomer.

250 A chiral pyrenylpyrrolidino-squaramide catalyzed enantiose

251 The synthetic protocol to form chiral pyrrolidines was further applied to the asymmetri

252 re in depth the SOMO-HOMO inversion (SHI) in chiral radical molecular systems and provide new insight

253 Our findings demonstrate strong chiral recognition and a significant ensemble effect in

254 A novel approach to chiral recognition of small molecules using the classica

255 well-known, present observation of "reverse chiral recognition" where the guest molecule determines

256 these results, we describe here its use for chiral recognition.

257 arcely studied chirality of these ubiquitous chiral scaffolds.

258 THFA is presented using a recently proposed chiral self-tag approach.

259 Trigonal tellurium (Te) is a chiral semiconductor that lacks both mirror and inversio

260 helices as switchable asymmetric catalysts, chiral sensors, and circularly polarized light emitters

261 on(s) with achiral microporous materials for chiral separation purposes.

262 efficient asymmetric photolysis, a method of chiral separation that has conventionally been impeded b

263 n of the second chiral center and subsequent chiral separations provided all four stereoisomers, wher

264 ral monomers strategically positioned within chiral sequences may reinforce the degree of peptoid hel

265 helicity, although with a reduced content of chiral side chains.

266 tion and characterization of the Si-centered chiral silyl cation intermediates, finally allowed to pr

267 ically detected using NMR spectroscopy and a chiral solvating agent.

268 spectroscopy with the aid of (R)-BINOL as a chiral solvating agent.

269 ct of inorganic crystals that crystallize in chiral space groups has been largely ignored until recen

270 These findings led us to separate the two chiral species and test their effectiveness as chemoattr

271 ecular catalyst operating with ppm levels of chiral species.

272 e for DHP drugs, but the molecular basis for chiral specificity remained elusive.

273 search for layered structures that stabilize chiral spin textures such as topologically protected sky

274 A precisely designed chiral squaramide derivative is shown to promote the hig

275 e triplet pairing in UTe(2), the presence of chiral states suggests that UTe(2) is a strong candidate

276 lexes were isolated by preparative HPLC on a chiral stationary phase in good yields and excellent opt

277 al ligands around the metal center affords a chiral structure with two geometrically different helica

278 % and |g(lum) | up to 0.240) by introducing chiral substituents onto the macrocyclic scaffolds.

279 esolutions and asymmetric transformations of chiral substrates are presented.

280 Chiral sugar derivatives are potential cyclitol surrogat

281 Chiral sulfinyl compounds, sulfoxides, sulfoximines, sul

282 The self-assembly of chiral supramolecular polymers is an intricate process t

283 Studies of both the concept of chiral symmetry breaking as well as the subsequent chira

284 cted chemists' perspective of autocatalysis, chiral symmetry breaking, absolute asymmetric synthesis

285 lation reaction of aliphatic ketones using a chiral TDG.

286 nstrated as a unique broadband source of the chiral terahertz wave.

287 ntioselective synthesis of alpha-fluorinated chiral tertiary alcohols from (hetero)aryl methyl ketone

288 A practical synthesis of a D1 potentiator chiral tetrahydroisoquinoline has been accomplished empl

289 he electronic properties of the prototypical chiral topological semimetal PdGa.

290 set of optical and transport experiments in chiral topological semimetals.

291 Axially chiral trifluoromethylbenzimidazolylbenzoic acid (TBBA)

292 ggests that UTe(2) is a strong candidate for chiral-triplet topological superconductivity.

293 A chiral trisubstituted cyclobutane was efficiently synthe

294 In this study, an achiral-chiral two-dimensional liquid chromatographic method for

295 the evolution, development, and genetics of chiral variation in snails, and place it in context with

296 suitable intermediates for the synthesis of chiral vicinal diamines as has been verified for a repre

297 dical change of the band velocities when the chiral Weyl fermions are excited during selective optica

298 ystalline electronic system is geometrically chiral when it lacks mirror planes, space-inversion cent

299 When subjected to an electrical current, the chiral winding of the spin texture leads to a deflection

300 Sharp chiral wrinkles lead to chiral plasmon modes with high d