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2 tachlorophenol (PCP), but rather by the less chlorinated 2,3,5,6-tetrachlorophenol (2,3,5,6-TeCP), on
4 ults show that while HOCl is the predominant chlorinating agent for the most reactive alkene, Cl(2) a
5 ide is used as a cheap and readily available chlorinating agent in combination with trioctylphosphane
6 ith amino acid and eventual formation of the chlorinating agent in the form of the hydrochloride salt
7 it is not possible to preclude H2OCl(+) as a chlorinating agent, we were able to model our low-pH dat
11 e pH, Cl(-) concentration, and the resulting chlorinating agents (e.g., Cl(2), HOCl, OCl(-), and Cl(2
15 remediation of groundwater contaminated with chlorinated aliphatic hydrocarbons such as perchloroethe
16 orm FeS, suggesting that, after oxidation by chlorinated aliphatics, FeS can be regenerated by additi
17 apid disinfection of the hospital WDS with a chlorinated, alkaline detergent and subsequent superchlo
19 ancomycin, exclusive conversion of vicinally chlorinated alkanes, and tolerance to short-term oxygen
21 ssion as a result of the hydrolysis of the N-chlorinated amidic N-C bond due to nucleophilic attack b
23 d dialdehyde 2-butene-1,4-dial (BDA) and its chlorinated analogue, chloro-2-butene-1,4-dial (Cl-BDA),
25 etrahydrofuran, and cyclohexane), as well as chlorinated and aromatic pollutants, including vinyl chl
26 the simultaneous determination of up to nine chlorinated and brominated acetic acids by HPLC-ICPMS/MS
27 ug Cl L(-1) and 0.8-1.5 mug Br L(-1) for the chlorinated and brominated acetic acids, respectively.
28 ncreased antimicrobial activity, we designed chlorinated and brominated analogues of a known peptoid
31 end=0.13; the ORs at the 95th percentile for chlorinated and brominated THMs were 1.77 (95% CI: 1.05,
32 omers, with complementary strategies to both chlorinated and brominated variants, formed with high di
33 xtracting nonvolatile and volatile DBPs from chlorinated and chloraminated drinking water to minimize
34 report elevated levels of gaseous inorganic chlorinated and nitrogenated compounds in indoor air whi
36 ransformations were intensively studied with chlorinated and simply structured compounds such as chlo
39 lationship between bladder cancer and total, chlorinated, and brominated trihalomethanes (THMs) throu
41 ss spectral patterns was applied to identify chlorinated- and brominated-containing substances with m
43 comparison and formation and degradation of chlorinated aromatic intermediates using the same non-ch
44 oPhenol catalyzed aza-Darzens reaction using chlorinated aromatic ketones as nucleophilic partners fo
45 uperfamily associated with dehalogenation of chlorinated aromatics and appears to represent a new sub
46 ) to have their drinking water automatically chlorinated at the point of collection by a solid tablet
47 pea (Pisum sativum) seeds, the level of the chlorinated auxin, 4-chloroindole-3-acetic acid (4-Cl-IA
49 ectronic and geometrical influences of ortho-chlorinated azobenzenes on their photophysical propertie
50 wo types of PCDD/F precursors, involving all chlorinated benzenes (CBz) and chlorinated phenols (CPh)
53 l) of two polychlorinated biphenyls and four chlorinated benzenes were below a factor of 2 in the pla
55 In this study, we describe the screening for chlorinated biomolecules by the use of mass isotope rati
58 ptor (AhR) agonist activities of a series of chlorinated, brominated, and mixed bromo/chlorocarbazole
64 lic indices and the experimental profiles of chlorinated carbazole, phenoxazine, and phenazine sugges
65 stigated the relationship between persistent chlorinated compounds and hypertension in residents livi
66 f the minimal formation of free chlorine and chlorinated compounds in photocatalytic degradation is d
74 types were dominated by PCB 28/31 and higher-chlorinated congeners in both groups reflecting rapid me
76 By the end of the experiment, all the lower chlorinated congeners were absent from the colorant whil
78 rs revolatilization is important, for higher-chlorinated congeners, the main processes are storage in
82 s of groundwater samples containing BTEX and chlorinated contaminants at microgram per liter concentr
84 to encode a new pathway to generate a novel chlorinated coumarin "non-natural" product in E. coli.
86 ure and contains novel high molecular weight chlorinated DBPs that are detected via high-resolution m
87 nt) after exposure to six brominated and two chlorinated DBPs: bromoacetic acid (BAA), bromoacetonitr
90 ater, chlorination leads to the formation of chlorinated derivatives of Bisphenol A (ClxBPA), that ha
93 the parent diacid was calculated for all 15 chlorinated diacids and shows a dramatic increase with s
96 hese applications include the measurement of chlorinated dioxins in soil samples, the identification
104 Cl(2) may enhance the formation kinetics of chlorinated disinfection byproducts (DBPs) and exacerbat
107 tion of methyltrioxorhenium (MTO) onto these chlorinated domains serves to activate it as a low tempe
108 ed water can increase taste acceptability of chlorinated drinking water while still reducing the risk
110 DCAM or, more broadly speaking, N-Cl-HAMs in chlorinated drinking waters is of significance because t
113 o a change in the ratio of electron donor to chlorinated electron acceptor in continuously stirred ta
117 We collected 95 groundwater samples across 6 chlorinated ethene-contaminated sites and searched for r
120 en in other hydrocarbon contaminants such as chlorinated ethenes and ethanes due to in situ degradati
122 nes in flowing groundwater, mass transfer of chlorinated ethenes between mobile groundwater and stati
123 The nonexistent chlorine isotope effects of chlorinated ethenes in all aqueous OS-SET experiments co
124 model applied here accounts for transport of chlorinated ethenes in flowing groundwater, mass transfe
125 and unsuccessful reductive dechlorination of chlorinated ethenes in groundwater under different flow
127 ment factors for microbial dehalogenation of chlorinated ethenes vary considerably we studied the pot
128 ta(13)C were from 2 to 60 mug/L (MTBE, BTEX, chlorinated ethenes, and benzenes) and 60-97 mug/L for d
137 al with known isotope composition, including chlorinated ethylene, chloromethane, hexachlorocyclohexa
139 able to effectively beta-brominate and beta-chlorinate for the first time cyclic enones with differe
140 igh catalytic activity to reduce alachlor, a chlorinated herbicide, in the aqueous medium at differen
141 chlorine isotope analysis (Cl-CSIA) of three chlorinated herbicides, atrazine, acetochlor, and metola
143 he lower ppt(v) range for different ketones, chlorinated hydrocarbons and methyl salicylate that form
144 eling study aims to reveal if degradation of chlorinated hydrocarbons in low permeability sediments c
145 on and CSIA profiles were determined for the chlorinated hydrocarbons that had diffused into the clay
146 s of free chlorine (hypochlorite, Cl(2)) and chlorinated hydrocarbons were formed in solution, while
147 by UV/FC and SS/FC and minimal formation of chlorinated intermediates and disinfection byproducts.
148 After all free chlorine was consumed, the chlorinated intermediates autodecomposed slowly with a f
149 s results in the accumulation of the harmful chlorinated intermediates dichloroethene (DCE) and vinyl
151 3 min(-1); when a reductant was added, these chlorinated intermediates were then reduced back to BMAA
153 ulfonates, and bromosultone sulfonates, with chlorinated/iodinated analogues formed to a lesser exten
155 n contrast to North American marine mammals, chlorinated MBPs and DMBPs were more abundant than their
156 ed metabolomics analysis revealed a group of chlorinated metabolites produced by the well-studied mod
157 purification led to the isolation of several chlorinated metabolites, including two new natural produ
160 xy-brominated diphenyl ethers (MeO-BDEs) and chlorinated methyl- and dimethyl bipyrroles (MBPs and DM
162 at catalytic system capable of detoxifying a chlorinated model compound with turnover numbers of up t
163 crin, the most common HNM, is synthesized by chlorinating nitromethane, suggesting that nitromethane
164 oom temperature conversion of brominated and chlorinated nucleobases or nucleobase precursors as star
166 bited a low or nondetectable toxicity, lower-chlorinated OH-PCBs significantly inhibited the germinat
168 ool/spa waters were 1.8x more mutagenic than chlorinated ones; spa waters were 1.7x more mutagenic th
169 The composition profiles were dominated by chlorinated OPEs at the urban and rural sites and by non
170 -OPEs (Cl-OPEs) concentrations exceeded Enon-chlorinated-OPEs (non-Cl-OPEs) with median concentration
171 dent tryptophan halogenases regioselectively chlorinate or brominate trypto-phan's indole moiety at C
172 pended to its carrier protein but can either chlorinate or hydroxylate C4 and (ii) two bifunctional e
173 studied for the reductive transformation of chlorinated or nitroaromatic compounds, no work exists e
175 ty-two-year record of in situ degradation of chlorinated organic compounds by a granular iron permeab
177 efore, utilizing enzymes in the synthesis of chlorinated organic compounds is important, and providin
191 Bs and OCPs biomagnified (TMF >1), while all chlorinated paraffins (CPs), PAHs, and phthalates underw
192 additional characterization of medium-chain chlorinated paraffins (MCCPs, C14-17) in oven-baked past
195 r simultaneous quantification of short-chain chlorinated paraffins (SCCPs, C10-13) and an additional
198 analyte signal of a polychlorinated alkanes (chlorinated paraffins) technical mixture that contains 7
205 ollowing initial hydroxylation of these less-chlorinated PCBs, metabolic sulfation to form PCB sulfat
206 oils were found to be a source of PAHs, high chlorinated PCBs, the majority of OCPs and PBDEs, and a
210 +, which is even better than the most-highly chlorinated PCP, and much better than its two other TeCP
211 ngest CL was produced not by the most-highly chlorinated pentachlorophenol (PCP), but rather by the l
213 ammals, including mercury (whole blood), sum chlorinated pesticides (comprised of approximately 95% D
214 (PCBs) congeners, congener groups and three chlorinated pesticides [dichlorodiphenyldichloroethylene
215 ersistent organic pollutants, such as highly chlorinated pesticides and polychlorinated biphenyls.
216 In general, the loss rates of vapor phase chlorinated pesticides have slowed by about a factor of
217 ted biphenyl (PCB) congener groups and three chlorinated pesticides in a Native American population.
218 lycyclic aromatic hydrocarbons (PAHs), three chlorinated pesticides, and five metals in Norwegian wat
219 zed C-O-selective Suzuki-Miyaura coupling of chlorinated phenol derivatives where the oxygen-containi
221 it is a general phenomenon for other highly chlorinated phenols (HCPs); and if so, what are the majo
224 or studies have focused on legacy persistent chlorinated pollutants (POPs), while the effects of poly
225 in the transformation and detoxification of chlorinated pollutants, including chlorinated ethenes.
226 coides mccartyi strain JNA detoxifies highly chlorinated polychlorinated biphenyl (PCB) mixtures via
229 dered to be associated with the formation of chlorinated potentially toxic compounds, such as chlorop
230 Subsequent diverse transformations of the chlorinated products demonstrate the versatility of meta
231 d through monitoring of formation of HMF and chlorinated products under pyrolytic conditions using gl
234 onditions, this compound outperforms typical chlorinating reagents for organic synthesis, facilitates
236 ntibiotic activity of the parent compound in chlorinated samples at 2.0, 3.0, and 4.0 mgCl(2)/L, resp
237 in line with the decrease of bioactivity in chlorinated samples, an increase of bioactivity after co
241 the transformation products of oxybenzone in chlorinated seawater swimming pools; especially that use
243 of the long term health effects of the lower-chlorinated, semi-volatile PCBs in the indoor environmen
245 lity, indicating strong interactions between chlorinated soft wheat flour (CSWF) components and solve
246 hloride in surface soils, and the ability to chlorinate soil organic matter (SOM) appears widespread
247 advantage of this approach is the use of non-chlorinated solvent and small amounts of organic solvent
251 tificially contaminated by a three component chlorinated solvent mixture (tetrachloroethene (PCE) 45
252 dation by bacterial pure cultures exposed to chlorinated solvent mixtures as well as in environmental
253 set of sites, there was little evidence that chlorinated solvent remedial efforts (e.g., chemical oxi
255 ous film-forming foams (AFFFs) to extinguish chlorinated solvent-fueled fires has led to the co-conta
256 g., 250 to 1000 mug/L) with co-occurrence of chlorinated solvents (e.g., 0.5 to 8 mg/L), underscoring
259 study investigated the impacts of individual chlorinated solvents and their mixtures on aerobic 1,4-d
261 ane bioremediation strategies at sites where chlorinated solvents are present as co-contaminants.
263 ion that abiotic natural attenuation (NA) of chlorinated solvents can be important has created demand
264 ng reactants for reductive dechlorination of chlorinated solvents due to high reaction rates and the
265 erovalent iron (Fe(0)) in the degradation of chlorinated solvents in subsurface environments is of in
267 es used for the bioremediation of co-mingled chlorinated solvents such as trichloroethene (TCE).
268 n occur in groundwater plumes comingled with chlorinated solvents such as trichloroethene (TCE).
269 ition of 1,4-dioxane biodegradation rates by chlorinated solvents was attributed to delayed ATP produ
272 are a common photoisomerization mechanism in chlorinated solvents with notable differences in kinetic
273 s 1-7 exhibit moderate-to-good solubility in chlorinated solvents, such as 1,2-dichlorobenzene and ch
281 ed stereodivergent synthesis of all possible chlorinated stereoisomers while also demonstrating diast
285 ed to a stronger interaction between MTO and chlorinated surface regions, as well as extensive deplet
287 o-beta-aminoketone intermediates featuring a chlorinated tetrasubstituted stereocenter can be isolate
288 ial of ERD, the exact microstructure of the (chlorinated) TFC membranes should be better understood.
290 ion of bioactive samples identified that the chlorinated TP296 (generated from the destruction of the
291 r, concerns about the potential formation of chlorinated transformation products require an understan
292 kidneys, levels of HOCl-derived oxidized and chlorinated tryptophan residues W(28) and W(192) are sig
295 atment aimed predominantly at remediation of chlorinated volatile organic compounds (cVOCs) and perfl
297 vated DBP formation during transportation of chlorinated waters in copper-containing distribution sys
298 ncluding BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albeit at generally lower concentrat