ライフサイエンスコーパス: condensed phase

1 ter-soluble organic compounds (WSOCg) to the condensed phase.

2 lecular reactions both in the gas and in the condensed phase.

3 at affect partitioning between the vapor and condensed phase.

4 imulations of Miller-like experiments in the condensed phase.

5 ample of siliconoid cluster expansion in the condensed phase.

6 e-time imaging of structural dynamics in the condensed phase.

7 the nandrops are comparable to those of the condensed phase.

8 r the investigation of hydrogen tunneling in condensed phase.

9 orientations of successive molecules in the condensed phase.

10 ist to perform density reconstruction in the condensed phase.

11 , familiar for high-spin d4 complexes in the condensed phase.

12 n recent claims of concerted transfer in the condensed phase.

13 ble preferences for either the disordered or condensed phase.

14 athway becomes kinetically more favorable in condensed phase.

15 of small molecule inhibitors of this type of condensed phase.

16 dominates the thermal initiation of the TATP condensed phase.

17 tion processes in both the gas phase and the condensed phase.

18 the gas phase, it is endergonic in the polar condensed phase.

19 rge method for generating O(3P) atoms in the condensed phase.

20 oclinic tilted chain lattice is found in the condensed phase.

21 ns and previous spectroscopic studies in the condensed phase.

22 istence between a liquid-expanded and liquid-condensed phase.

23 on models to study chemical reactions in the condensed phase.

24 ion reactions that proceed so readily in the condensed phase.

25 ionship between CI and beta-OH-RO(2)* in the condensed phase.

26 of cavity-modified chemical reactions in the condensed phase.

27 02, and condensation on the cold side of the condensed phase.

28 phase chemistry and sulfate formation in the condensed phase.

29 o-induced electron transfer processes in the condensed phase.

30 t ions for synthesizing new compounds in the condensed phase.

31 amped, with all added molecules entering the condensed phase.

32 much smaller than the cohesive energy in the condensed phase.

33 ation of complex molecular structures in the condensed phase.

34 high reactivity has eluded isolation in the condensed phase.

35 imilar systems that have been studied in the condensed phase.

36 -optical characterisation of substances in a condensed phase.

37 g description as a "free" boryl anion in the condensed phase.

38 re on CN(-), CO, and O2 bound globins in the condensed phase.

39 ly as a short-lived transient species in the condensed phase.

40 ries of radical bimolecular reactions in the condensed phase.

41 to low-temperature oxidation in gaseous and condensed phases.

42 experimental optical spectra of FTPE in both condensed phases.

43 avior of SOA species into aqueous or organic condensed phases.

44 and chemical properties of Tc(VII) oxides in condensed phases.

45 dynamics occurring at interfaces and within condensed phases.

46 f organic glasses and molecular diffusion in condensed phases.

47 ning of the salt between the aqueous and the condensed phases.

48 s that have been synthesized and analyzed in condensed phases.

49 ne and other residues, both before PS and in condensed phases.

50 eir molecular structures and interactions in condensed phases.

51 of engineered carbohydrate assemblies in the condensed phases.

52 alone can dictate the formation of distinct condensed phases.

53 their reactivity, and their organization in condensed phases.

54 tors that influence client partitioning into condensed phases.

55 difficult to observe in symmetric dimers or condensed phases.

56 lular protein from dilute to concentrated or condensed phases.

57 Transformation of the higher order condensed-phase 3-D PMF potential-energy surface, comput

58 gies in the gas phase (~62 kcal/mol) and the condensed phase (~35 kcal/mol) of TNT and identifies the

59 ger cross-sectional molecular areas than the condensed phases achieved by spreading at temperatures o

60 mplete picture of how dissolution within the condensed phase affects the client energy landscape.

61 it is exceeded, the mutant protein forms the condensed phase after a nucleation time of 10-20 min.

62 ) so that the phase state (viscosity) of the condensed-phase after heating is similar to how it would

63 s the SOZ yields, enhancing the formation of condensed-phase aldehydes and volatile C9 products.

64 s is extremely high speed, exceeding that of condensed-phase alternatives by orders of magnitude.

65 In this respect, it provides a condensed-phase analogy to gas-phase ("intrinsic") acidi

66 ixes into a two-phase system consisting of a condensed phase and a dilute phase of particular biomole

67 requires the materials to be employed in the condensed phase and display a high degree of Z to E swit

68 systems, such as DPPC/water monolayer in the condensed phase and DPPC/water bilayer in the gel phase.

69 kyl imines undergo photoisomerization in the condensed phase and exhibit isomer-dependent fluorescenc

70 40% of FUS RRM remains folded in the CAPRIN1 condensed phase and high-resolution [(1)H-(15)N]-HSQC sp

71 cantly impacts the coexistence of the liquid-condensed phase and liquid-expanded phase.

72 rst direct observation of metaphosphate in a condensed phase and may provide the structural basis for

73 ne adducts of gold(I) enone complexes in the condensed phase and that the existence of naked alpha-ox

74 nge with volume shows two stable phases: the condensed phase and the isolated micelle phase.

75 powerful tuning knob for the exploration of condensed phases and geophysical phenomena(1).

76 Because SVOCs are found in both gas and condensed phases and redistribute from their original so

77 del systems for unraveling the complexity of condensed-phase and biological structures, not to mentio

78 Both the packed form (the condensed-phase) and the dispersed form (the dilute-phas

79 d to the study of molecules in gas phase, in condensed phase, and at interfaces.

80 n elementary systems to model systems in the condensed phase, and on to biological structures.

81 electrostatic solvation energy: once for the condensed phase, and once for the solution phase.

82 degree of conformational homogeneity in the condensed phase, and represents a rare example where suc

83 roduced, with each being based on a distinct condensed-phase approach.

84 incomplete, and rules for the coexistence of condensed phases are lacking.

85 line tension between the fluid phase and the condensed phase as confirmed by the formation of "stripe

86 he coexistence of liquid-expanded and liquid-condensed phases as well as liquid-ordered and liquid-di

87 icant factor for its colocalization with the condensed phases, as similar trends are observed for oth

88 sts an order-to-disorder transition for this condensed phase at 480-490 K, with a sharp reduction in

89 polymers and that flexible polymers nucleate condensed phases at lower binding energies than their ri

90 undergo facile reversible photoswitching in condensed phases at room temperature, exhibiting unprece

91 the partitioning of selenium between gas and condensed phases at the scrubber inlet and outlet.

92 lied to explain the stability of families of condensed phase Au clusters.

93 LBID results are in excellent agreement with condensed phase behavior determined in other studies.

94 action, have been extensively studied in the condensed phase but have yielded only limited detailed i

95 ls enhanced interprotein interactions in the condensed phase but more favorable protein-solvent inter

96 parallel reactivity patterns observed in the condensed phase, but offer new insights into steric fact

97 ified industrial catalyst, ambient pressure, condensed phase, ca. 0.03 m monomer).

98 ncrease of the domain fraction of the liquid-condensed phase can be observed for the deposition of 20

99 inhibited by SOA coatings, and further that condensed phase chemical pathways and rates in organic p

100 The BQT allows for condensed phase chemical reactions to be initiated by co

101 echanisms and kinetic parameters for complex condensed-phase chemical processes that underlie importa

102 ification approach to reduce the reliance on condensed-phase chemistries and extensive separations fo

103 g) calculations enable to directly probe the condensed phase chemistry under extreme conditions of te

104 Condensed-phase chemistry plays a significant role in th

105 However, there exist examples in condensed-phase chemistry where increasing mass leads to

106 Such complexes are very rare in condensed-phase chemistry.

107 lateau along the force curves), typical of a condensed phase (compaction of a long DNA into a micron-

108 e approach apportions combined gas-phase and condensed-phase concentrations of individual compounds a

109 how the high macromolecule concentrations in condensed phases contribute "solvent" interactions that

110 atch closely with those observed from a TATP condensed-phase cookoff simulation, indicating that unim

111 of intermediates, some the same as in their condensed-phase counterparts.

112 Previous condensed phase data indicate a reactivity order of iodi

113 this variation, the gas-phase data parallel condensed phase data indicating that the substituent eff

114 dramatic suppression of activation energy in condensed phase decomposition of nitroaromatic explosive

115 area per molecule and compressibility of SM condensed phases depended upon the length of the saturat

116 soporous metal-organic framework NU-1000 via condensed-phase deposition where the MOF is simply subme

117 ion/ion strategy is presented that obviates condensed-phase derivatization and introduces a radical

118 Condensed-phase derivatization strategies, often used in

119 hat G(M1) and DPPC pack cooperatively in the condensed phase domain to form geometrically packed comp

120 This fluid phase forms a network, separating condensed-phase domains at coexistence.

121 We use this "optoDroplet" system to study condensed phases driven by the IDRs of various RNP body

122 ssociated biomolecular mobility within these condensed phase droplets, or condensates, are increasing

123 uced in measurements of the molecules in the condensed phase due to polarization effects in the solid

124 ver, this assumption is commonly violated in condensed phases due to mechanical instabilities.

125 lyzed noncovalent complex dissociated in the condensed phase during the spraying process.

126 cs of individual atoms or small molecules in condensed phases, e.g. lithium ions in electrolytes, wat

127 cular dynamics simulations are presented for condensed-phase electron transfer (ET) systems where the

128 eal how hydrogen bonding is reflected in the condensed phase electronic structure.

129 ctive MLIP for C, H, N and O elements in the condensed phase, enabling high-throughput in silico reac

130 products between m/z 300 and 350, the major condensed-phase end products were levulinic acid (LLA) a

131 xamples have emerged where the proteinaceous condensed phase environment protects clients from aggreg

132 y of this specific analyte and the analyte's condensed phase environment.

133 Incorporation of a condensed-phase environment by means of mixed quantum me

134 d building a full molecular-level picture of condensed-phase ET reactions.

135 order observed in the gas phase and in some condensed phase experiments.

136 e intermediates impossible to isolate in the condensed phase for decades, their actual characterizati

137 PPL domains that were similar to the liquid condensed phase for dipalmitoyl phosphatidylcholine (DPP

138 reveals that the network of forces governing condensed phase formation can differ from the network of

139 PCM solvation calculations used to calculate condensed-phase free energies are slightly less accurate

140 Ligands from recent examples of stable condensed-phase gold(II) complexes appear to meet at lea

141 NA-MD application to condensed phase has drawn tremendous attention recently

142 They were obtained by measuring the condensed-phase heat of reduction to the corresponding a

143 elucidate the nature of the transfer in the condensed phase, here we examine variation of solvent po

144 nt has been well-studied in both the gas and condensed phases; however, understanding this process in

145 rovide valuable data that can be compared to condensed-phase hydricity, to reveal the effects of solv

146 tmospheric liquid water volume, we show that condensed-phase hydrolysis of 1,2-IHN can account for th

147 regenerates the perfluorocarboxylic acid via condensed-phase hydrolysis.

148 commonly, MOFs have been metalated from the condensed phase (i.e., from solution).

149 essary but not sufficient for formation of a condensed phase in our system.

150 namic mass transport between the gaseous and condensed phases in a non-equilibrium system.

151 peptide, SP-B1-25, inhibit the formation of condensed phases in monolayers of palmitic acid, resulti

152 e and therefore partition between vapour and condensed phases in the atmosphere and both the vapour a

153 tum vibrational spectroscopy in solution and condensed phase, incorporating high-level and computatio

154 ffusion, and chemical reactions from the gas-condensed phase interface to the bulk.

155 r-scale variation in solvation forces across condensed-phase interfaces.

156 gle molecule (intramolecular) and inside the condensed phase (intermolecular).

157 ze biological macromolecules intact from the condensed phase into the gas phase for nanospray postion

158 chrome c and lysozyme are vaporized from the condensed phase into the gas phase intact when exposed t

159 is also pointed out that all reactions in a condensed phase involve correlated motions (both in enzy

160 Complex systems in condensed phases involve a multidimensional energy lands

161 s' diffusion theory of reaction rates in the condensed phase is considered as an alternative to the t

162 tal concentration of all tau variants in the condensed phase is constant.

163 age dipole moment of a water molecule in the condensed phase is enhanced by around 40 percent relativ

164 ng blocks for designing new compounds in the condensed phase is largely unexplored.

165 nding of the origin of volume changes in the condensed phase is needed to complement the experimental

166 t concentration of oxidation products in the condensed phase is predicted for a scenario assuming the

167 Diffusion in condensed phases is a ubiquitous but poorly understood p

168 l framework towards understanding biological condensed phases is emerging, derived from biological, b

169 different experimental regimes: molecules in condensed phases, isolated in supersonic jets and helium

170 atecholato)silane is tetrahedral, but in the condensed phase, it is metastable toward oligomerization

171 s, which are the least polar and polarizable condensed phases known.

172 us media are the least polar and polarizable condensed phases known.

173 ate simulations of water from the gas to the condensed phase, leads to a definitive molecular-level p

174 Alternatively, condensed-phase magic-number cluster theories may need t

175 on experiments at 75% relative humidity, and condensed-phase mass was measured in bulk thermogravimet

176 phidynamic crystals are an emergent class of condensed phase matter designed with a combination of la

177 Condensed-phase matter with anisotropic molecular order

178 To address these challenges, we present condensed phase membrane introduction mass spectrometry

179 We present condensed phase membrane introduction mass spectrometry

180 ategy addressing this significant impasse is condensed phase membrane introduction mass spectrometry

181 Condensed phase membrane introduction mass spectrometry

182 that could not be addressed by conventional condensed phase methods.

183 Traditional condensed-phase methods are of limited use for character

184 cal/mol, respectively, which are the highest condensed phase MO-H BDFEs to date and (ii) that the hig

185 Condensed-phase molecular dynamics simulations are appli

186 Ultrafast electron transfer in condensed-phase molecular systems is often strongly coup

187 thin films of zeolite and cement can act as condensed-phase nitrite reservoirs.

188 mulation is an appropriate condition for the condensed-phase NP(N)gammaT simulation.

189 cular dynamics (MD) simulation of the liquid condensed phase of a 1,2-dilignoceroylphosphatidylcholin

190 d lead to a chain collapse transition into a condensed phase of DNA tethered by divalent counterions.

191 mplex assembly by inducing a multi-component condensed phase of SVs, alpha-Syn and other components.

192 Interstellar dust (ISD) is the condensed phase of the interstellar medium.

193 f specific area corresponding to an untilted condensed phase of the the pure palmitic acid monolayer.

194 charge state on the energetic proton in the condensed phase of water results in the strongly suppres

195 the understanding of structural order within condensed phases of matter.

196 uctures at the interface; these appear to be condensed phases of small ion-extractant complexes.

197 ral techniques to investigate the dilute and condensed phases of the ELF3 PrLD with varying polyQ len

198 andard molar enthalpies of formation, in the condensed phase, of the three isomers were derived from

199 formation of chlorine oxides (ClxOy) in the condensed phase on Mars.

200 o the evolution of charge transfer states in condensed phase, one that is strongly coupled to the sur

201 ural properties, the phase state of the bulk condensed phase, or surface curvature.

202 The composition of condensed-phase organic compounds in SOA is measured usi

203 tal findings could be explained by secondary condensed-phase ozone chemistry, which competes with OH

204 In this study, condensed phase particles collected from around the deto

205 ular interactions drive the vast majority of condensed phase phenomena from molecular recognition to

206 This condensed-phase photochemical process may produce a few

207 These condensed-phase photochemical processes occur on atmosph

208 olet (lambda>300 nm) radiation, we find that condensed-phase photochemistry can induce significant ch

209 ark contrast to what is commonly observed in condensed phase photophysics.

210 We show that C4N2 ices undergo condensed-phase photopolymerization (tholin formation) a

211 ultimately led to an entirely new branch of condensed-phase physics and chemistry.

212 eatures of the packing process are rooted in condensed-phase polymer dynamics suggests that statistic

213 he morphology and chemical identity of these condensed phase postblast particles remains undetermined

214 e observe a slow-down in the dynamics of the condensed phase, potentially resulting in loss of functi

215 nuders show similar results, suggesting that condensed-phase processes dominate over heterogeneous re

216 In addition, a wide array of oxygenated, condensed-phase products has been observed.

217 oducts of squalene ozonolysis are known, the condensed-phase products have not been characterized.

218 companied by the formation of functionalized condensed-phase products including secondary ozonides (S

219 Previous work examining the condensed-phase products of squalene particle ozonolysis

220 We present an analysis of condensed-phase products resulting from an extensive oxi

221 t absorption spectrometer (IBBCEAS), whereby condensed-phase products, adsorbed nitrite and nitrate,

222 , the assembly of organic molecules into the condensed phase promotes a diverse set of lattice dynami

223 protein/nucleic acid-ligand interactions or condensed phase properties by force field-based methods

224 rately predicting a wide variety of gas- and condensed-phase properties of molecular systems.

225 PC/water monolayer shows that various liquid condensed-phase properties of the monolayer have been we

226 force field parameter set developed based on condensed-phase quantum mechanical calculations and a Ge

227 ditional secondary structure elements in the condensed phase; rather, it maintains conformational het

228 Unlike the corresponding condensed-phase reaction, where catalytic proton exchang

229 Our results further illustrate how condensed phase reactions can be predicted using quantum

230 the importance of accounting for the role of condensed phase reactions in altering the composition of

231 siders transitions between continuum states, condensed-phase reactions involve transitions between bo

232 y insufficient to reveal the extent to which condensed-phase reactions occur in conjunction with the

233 rene-derived epoxydiols (IEPOX) by enhancing condensed-phase reactions within sulfate-containing subm

234 LIP (ANI-1xnr) through automated sampling of condensed-phase reactions.

235 and as such, they have been used to create a condensed phase reactivity profile for O((3)P).

236 lecular driving forces and the nature of the condensed phases remain poorly understood.

237 on events, enhanced gas-phase emissions from condensed-phase reservoirs partitioned to airborne parti

238 n-usage was inferred to deposit siloxanes in condensed-phase reservoirs throughout the house, leading

239 ions through interactions with surface-laden condensed-phase reservoirs.

240 e present a comprehensive strategy combining condensed-phase sample preparation, electrospray ionizat

241 ectrostatic charge induction in the proximal condensed-phase sample, resulting in the liberation of f

242 e for the measurement of infrared spectra of condensed phase samples.

243 issue) is applied to the direct analysis of condensed-phase samples.

244 ration speeds exceeding that of conventional condensed-phase separations by orders of magnitude.

245 to preserve the key PTM connectivity, which condensed-phase separations failed to achieve.

246 ral orders of magnitude greater than that of condensed-phase separations.

247 demonstrate that acceleration occurs in the condensed phase showing that enhanced sulfate formation

248 ide and trifluoroacetate are reversed in the condensed phase so this reactivity pattern does reflect

249 The condensed-phase SOA photodegradation processes could the

250 votal in identifying these species, although condensed-phase spectroscopy remains essential for full

251 provides a quantitative determination of the condensed-phase spectrum.

252 In fact, tau in the condensed phase state does not reveal any immediate chan

253 lvation is consistent with results from many condensed-phase studies, and contrasts with results for

254 the application of gas-phase measurements to condensed-phase studies.

255 e its significance, however, hypervalency in condensed phases, such as amorphous solids, remains larg

256 hese effects have also been observed in less condensed phases, such as self-assembled monolayers; how

257 ational energy redistribution in the gas and condensed phases suggest that other gas-surface reaction

258 and thermodynamic properties in the gas and condensed phases suggests that the polarizable models pr

259 ion to atmospheric aerosols by reacting with condensed phase sulfuric acid, forming low-volatility or

260 tion, and the thermodynamic stability of the condensed phases surrounding such sites, in turn, implie

261 This distinctive condensed-phase system is ideally suited to spectroscopi

262 rformed at instantaneous configurations of a condensed-phase system, leading to modes with negative e

263 ng of electronically-coupled chromophores in condensed phase systems, tightening the inferred relatio

264 rafast snapshots of biological molecules and condensed-phase systems undergoing structural changes.

265 e thermodynamics, structure, and dynamics of condensed-phase systems, but often present significant c

266 In complex condensed-phase systems, however, it is difficult to des

267 itions between the eigenstates occur-such as condensed-phase systems-must be studied.

268 tions demonstrate that thermal initiation of condensed-phase TATP is entropy-driven (rather than enth

269 roducing secondary electrons is lower in the condensed phase than in the gas phase.

270 terions are significantly more mobile in the condensed phase than in the uncondensed phase because el

271 ol and more flexibility for the detection of condensed phases than with other chemical ionization met

272 association of the P23T mutant to form a new condensed phase that contains clusters of the mutant pro

273 cause syntheses are largely performed in the condensed phase, the present computational investigation

274 to E switching in both the solution and the condensed phase to a higher completeness of switching th

275 The average transfer free energy from the condensed phase to the solution phase was found to predi

276 alculating the transfer free energy from the condensed phase to the solution phase.

277 hromophores such as bacteriochlorophyll a in condensed phases to measure both high-resolution coheren

278 s have been prepared, and their structure in condensed phases unambiguously assigned using (1)H, (13)

279 cular forms in which HOMs are present in the condensed phase upon gas-particle partitioning remain un

280 itions but might be expected to occur in the condensed phase upon heating or with further lowering of

281 ate and detect diazirinone (1) in either the condensed phase (using matrix isolation spectroscopy) or

282 and as mixtures in the gaseous, solution, or condensed phases, using He, Ar, N2, or ambient air as th

283 hase of condensed material and the effective condensed phase vapor pressures of the SVOCs.

284 an proceed with much smaller barriers in the condensed phase via many-body mechanisms involving ionic

285 The condensed phase was modeled as an implicit solvent, with

286 all-metal cluster-like fragments isolated in condensed phase was previously shown to be mainly ascrib

287 Density functional simulations of condensed phase water are typically inaccurate, due to t

288 py (XAS) experiments on liquid water, that a condensed-phase water molecule's asymmetric electron den

289 resolved infrared (TRIR) spectroscopy in the condensed phase, we have conducted a detailed kinetic an

290 disproven claims of HAsAsH formation in the condensed phase, we report the isolation and structural

291 comparison of the IR-spectra in the gas and condensed phases, we propose putative assignments for th

292 n-carbon double bonds were identified in the condensed phase which survived ozonolysis during new par

293 lectronic effects acting on molecules in the condensed phase, which in this case are greater than the

294 ng rates are limited by diffusion within the condensed phase, which is thought to be "glassy." Here,

295 unity photoluminescence quantum yield in the condensed phase, which is unprecedented for aluminium co

296 RNA can nevertheless enable recruitment to a condensed phase, which reveals that the network of force

297 electron dynamics in matter from gas to the condensed phase with attosecond temporal resolution.

298 talyst deactivation have been studied in the condensed phase with both classical and quantum methods

299 the properties of water from the gas to the condensed phase with unprecedented accuracy, thus openin

300 higher propensity to phase separate and form condensed phases with higher concentrations.