ライフサイエンスコーパス: coordination number

1 utes (e.g. pore-size distribution, porosity, coordination number).

2 ament length and connectivity (also known as Coordination Number).

3 the catalytic reaction via changes in water-coordination number.

4 spin equilibrium occurs without a change in coordination number.

5 11 that occurs on the Pt atom with the lower coordination number.

6 even with small changes to first-shell Pt-Pt coordination number.

7 the uranium center in complexes with higher coordination number.

8 esembles a type II Cu(II) site with a higher coordination number.

9 resulting in an increase in the Al and/or Si coordination number.

10 count for their differences in heme-nitrosyl coordination number.

11 table choice of a structural property, water coordination number.

12 high spin Mn(III) in low symmetry and lower coordination number.

13 h are specific surface, pore sphericity, and coordination number.

14 ic trends based on substrate, ligand(s), and coordination number.

15 curate control over shape, functionality and coordination number.

16 vary depending on the actor ligands and the coordination number.

17 , which is a direct consequence of its lower coordination number.

18 variance in the Fe-P bond as a function of P-coordination number.

19 tal size but strongly depended on the ligand coordination number.

20 ation that occurs from a change in the metal coordination number.

21 were observed, consistent with an increased coordination number.

22 g that catalytic activity may correlate with coordination number.

23 ing relaxed coordination structures with low coordination number.

24 ates into spatial regions having much higher coordination numbers.

25 and pore throat sizes and distributions and coordination numbers.

26 antly ionic Ln bonding regimes favoring high coordination numbers.

27 nger adsorption of CO at Au sites with lower coordination numbers.

28 their subtle differences in ionic radius and coordination number(1-3).

29 molecules are packed to form polyhedra with coordination numbers 12, 14, 15 or 16.

30 As a result, Pd has the highest coordination number (14) so far recorded.

31 rs condense to form extended solids with low coordination numbers, 4 or 6.

32 The flexibility of Zn(II) ion's coordination number (5 and 6) as well as the formation o

33 e-nitrosyl function and reactivity is the Fe coordination number (5 or 6).

34 Shannon-Prewitt "effective ionic radii" (for coordination number 6) with mean absolute deviation of 0

35 tiple cation sites, with variable volume and coordination number (6-9) and different polyhedral compr

36 and where at some stage the Ru metal attains coordination number 7.

37 are defined on amorphous lattices with fixed coordination number, a realistic feature of covalently b

38 d to specific surface sites, with varying Al coordination number, acidity, and basicity, depending on

39 tion stage with a minor decrease of the In-O coordination number and a partial reduction of In(2)O(3)

40 localization is the result of reductions in coordination number and a transition from over-constrain

41 exes the two metal atoms have formally a low coordination number and an also low electron count.

42 persistence length, tubule length, junction coordination number and angles of the network were quant

43 ndergo permanent densification with enhanced coordination number and connectivity.

44 ds are strongly tied to oxidation state, the coordination number and crystallographic orientation of

45 efine invariants are generalizable to higher coordination number and dimensions, opening a route towa

46 in the variants correlate with the preferred coordination number and geometry of the metal ion.

47 structure (XANES) was used to determine the coordination number and geometry of the Ni site in the v

48 ws that the Ni site undergoes changes in the coordination number and geometry that are consistent wit

49 interconvertible oxidation states, variable coordination number and geometry, and ability to form po

50 , chirality, porosity, etc. due to change in coordination number and geometry, dimensionality, interp

51 due to change in coordination number and geometry, dimensionality, interp

52 ion size variance, exhibited lower effective coordination number and greater bond distortion.

53 rticular, the red copper center has a higher coordination number and lacks the long Cu-S(Met) and sho

54 in ligands and one anion from the buffer, by coordination number and ligand selection.

55 ors and acceptors as well as investigate how coordination number and metal bonding affect the preferr

56 g the systematic evaluation of the effect of coordination number and metal identity on M-Cl bond leng

57 py and microanalysis, features a small Pd-Pd coordination number and more importantly a Pd-Bi spatial

58 binding of 15.1, is due to the nature of the coordination number and not the ligating group.

59 -crown-4)(2)][1], effectively replicates the coordination number and oxidation state of the proposed

60 tipods (bi-, tri-, and tetrapods) of varying coordination number and patch angle in aqueous solution.

61 These results suggest that the coordination number and polarity may tune the electrophi

62 The coordination number and reactivity of the SmI(2)-ammonia

63 quantifying the temperature-responsive mean coordination number and solvate species concentrations,

64 ng and Co(II)-substituted VanX have the same coordination number and that the metal ions are coordina

65 Furthermore, the coordination number and the arrangement of ligands obser

66 rature, the Cu(II)Cl complex favored a lower coordination number and the CuCl2 complex prevailed, whe

67 among strongly correlated parameters such as coordination number and the Debye-Waller factor.

68 h as a surprisingly large fluctuation in the coordination number and the detailed mechanism by which

69 After aging for two years, the coordination number and the distance to the first O shel

70 them arise from the variability of aluminium coordination numbers and degree of dehydroxylation.

71 Ca(2+) selectivity filters having different coordination numbers and different geometries at the ent

72 structures and properties owing to the high coordination numbers and distinct optical properties of

73 e cases the mechanical bond enforces unusual coordination numbers and distorted arrangements as a res

74 w the property can be predicted based on the coordination numbers and electronic structures of parama

75 exes in these subsets examines the trends in coordination numbers and first shell distances as well a

76 panel of 11 siderophores with different iron coordination numbers and geometries was synthesized in u

77 igands to access main group complexes in low-coordination numbers and highly reactive bonding modes i

78 , characterized by decreasing In-O and In-In coordination numbers and intensities of the In(2)O(3) Br

79 as proven to be highly efficient for several coordination numbers and ligand classes enabling access

80 e experimentally observed and simulated Ni-O coordination numbers and Ni-O, Ni...Ni, and Ni...Zr dist

81 chemistry for their ability to stabilise low coordination numbers and provide soluble, and even volat

82 s in proteins is challenging due to the high coordination numbers and the incorporation of charged li

83 stablish a correlation between isomer shift, coordination number, and N/O composition.

84 emarkably independent of molecular charge or coordination number, and trends in values of d(PC) and n

85 nvironments with corresponding bond lengths, coordination numbers, and Debye-Waller factors for each.

86 everal structures with reduced symmetry, low coordination numbers, and even semiconducting character

87 wide diversity of packing fractions, average coordination numbers, and order as measured by standard

88 h units consisting of Ni(II) complexes whose coordination numbers are determined by temperature and t

89 gle distributions, interatomic distances and coordination numbers are examined and lead to similar pr

90 Spin-crossover complexes with low coordination numbers are much rarer.

91 The O-Ca and O-Al coordination numbers are similar in the eutectic 64 mol

92 particles-which contain metal atoms with low coordination numbers-are more active in catalysing oxida

93 Increasing the coordination number around Na(+) only partially accounts

94 hese carbene complexes to an increase of the coordination number around ruthenium is the insertion of

95 rent spatial location of water molecules and coordination numbers around the two CO2(-) groups.

96 Results show that the saccharide coordination numbers, as well as the saccharides hydrati

97 ent: acute (SiO-Mo(O)(2)-OSi) angles and low coordination numbers at Mo lead to highly deshielded (95

98 This observation excludes low coordination number Au sites as being active alone in th

99 Descriptors such as the average coordination number between half-SBUs and fractal dimens

100 upation of well-coordinated Pt sites (>=8 Pt coordination number) by WO(x) and structural features go

101 ks with central elements exhibiting variable coordination number can have the flexibility needed to a

102 fs, can use different combinations of phase, coordination number, cavity size, and rigidity (constrai

103 (XAS) at the Fe K-edge further supports this coordination number change with the binding of both cosu

104 f the spin state to in situ variation of the coordination number (CISSS) is a promising and viable ap

105 PC across all compositions, but the Li(+)-PC coordination number (CN(Li-PC)) decreases from four to t

106 ence spectroscopy, we found that a high Au-S coordination number (CN) and a high surface coverage res

107 the outer shell for all ions and an average coordination number (CN) for Ba that is higher than that

108 It is known that the coordination number (CN) of atoms or ions in many materi

109 ydrogenation (DDH) activity with the average coordination number (CN) of Pt-Pt bond in Pt NP, Pt(3) c

110 Ligands with maximum coordination numbers (CN) >= 3 (EDTA, NTA, and citrate)

111 ted Rh(1)Co(x) clusters with different Rh-Co coordination numbers (CNs).

112 , and network-enforced restrictions on Li(+) coordination number compared to the bulk electrolyte, wh

113 glass results in parameters interpretable as coordination number, composition, volumetric strain, and

114 Above 50 GPa, the estimated coordination number continuously increases from 6 to 6.8

115 ys metal-binding selectivity based solely on coordination number control and not on the chemical iden

116 Cation coordination numbers decrease with cation radius.

117 dent on the size of the lanthanide ions: the coordination number decreases from Pr (CN = 14) to Sm (C

118 the sizes of nonpolar local domains and ion-coordination numbers deduced from wide-angle X-ray scatt

119 re determined by intrinsic anisotropy due to coordination-number-dependent atom removal rates and ext

120 olecules, thereby affecting observables like coordination number distributions of ions.

121 e we report a MOF platform (CPM-66) with low-coordination-number environment for rare-earth ions.

122 all, we find that electronics and changes in coordination number exert the greatest influence on the

123 cise structural parameters (bond lengths and coordination number) extracted from the in situ PDF data

124 most bent monomers condense to form the high coordination number fluorite and PbCl(2) structure types

125 The coordination number for non-bonded interactions for each

126 superoxide dismutase indicating a change in coordination number for the metal complex at low tempera

127 metadynamics simulations to be the dominant coordination number for the mutant, the calculated relat

128 le binding site that accommodates a range of coordination numbers for Ca(2+), which is essential to t

129 structures have natural analogs spanning all coordination numbers found in inorganic chemistry.

130 We show that the change in ligand coordination number from 2 for aqueous Cu(+) to 5 for aq

131 istance from 2.01 to 1.91 A and decreased Fe coordination number from 6.3 to 4.6 after firing, indica

132 bility of trans-O-Ru-O groups, the change in coordination number from CN6 to CN7 at Ru high oxidation

133 a short Ni-O bond accounts for the change in coordination number from five to four that accompanies f

134 w that SiO2 first undergoes a change in Si-O coordination number from fourfold to sixfold between 15

135 s on metalloregulatory proteins suggest that coordination number/geometry and metal ion availability

136 that a given metal ion can adopt a preferred coordination number/geometry.

137 ne sites, as measured by the two-shell water coordination number, governs the kinetics of the oxidati

138 the average local structures (bond angle and coordination numbers), gradually transforming the a-GST

139 consistent with greater Ti 3d occupancy and coordination numbers greater than four, and 20-fold lowe

140 d the binding sites is tuned to sustain high coordination numbers (>6) around K+ ions, which otherwis

141 , ancillary ligand sterics and metal complex coordination number have been identified as the primary

142 of the heme across multiple spin states and coordination number highlights the flexibility of the he

143 water, is attributed to protons with reduced coordination number in confinement based on Density Func

144 bond strength, determines the heme-nitrosyl coordination number in cytochromes c'.

145 mplexes indicated by a decrease in the Ir-Ir coordination number in ethene-rich feed.

146 The Zn(II) complexes change coordination number in response to the residue in positi

147 with NmtR uniquely capable of expanding its coordination number in the Ni(II) and Co(II) complexes b

148 hat we are capable of controlling the Cd(II) coordination number in these 2 sites solely by varying t

149 rings, thereby establishing a new record for coordination numbers in the two-dimensional realm.

150 ovided a combined approach that revealed the coordination numbers in these systems.

151 coordinated d6R (12-c) due to the subsequent coordination number increase in one node of the resultan

152 mation of tetrairidium clusters as the Ir-Ir coordination number increased again.

153 n excess of Br(-1) ion is added, the bromide coordination number increases and the number of water mo

154 quids to fragile liquids by pressure-induced coordination number increases is demonstrated.

155 n states in water to states having different coordination numbers incurs a free energy cost.

156 zing the first atomic neighbor distances and coordination numbers inside the nanoalloy particles and

157 gold atoms: (a) one central gold atom whose coordination number is 12 (12 bonds to gold atoms); (b)

158 The fragmentation patterns indicate that the coordination number is 4 for this system.

159 n icosahedron around the central atom, whose coordination number is 6 (five bonds to gold atoms and o

160 inition, presents a nonselective medium, the coordination number is allowed to relax to suit the ion.

161 A new record coordination number is established, as AcHe17(3+) , ThHe

162 With oxidation state III, the coordination number is halfway between the coordination

163 e, and (1)H NMR spectra suggest that the low coordination number is maintained in solution.

164 ew atom) nanoparticles for which the average coordination number is much smaller than that in the bul

165 where the contribution of the protein to the coordination number is roughly constant in all four bind

166 Concomitant with the change in coordination number is the change of the spin state from

167 cesium chloride (B2) structure, with higher coordination numbers, is assumed for KF, RbF, and CsF.

168 wiching a cobalt atom, which has the highest coordination number known heretofore in chemistry.

169 first isolable iron-hydride complexes with a coordination number less than 5.

170 ing, in WT and mutant proteins, the roles of coordination number, ligand selection, and residues in t

171 ) with local structure, including changes in coordination number, local geometry (bond distances and

172 t step toward identifying sites in which the coordination number may drop spontaneously in water, a p

173 Those of higher coordination numbers (mu-OH, mu3-OH) do not participate.

174 ors and the membrane normal and an isotropic coordination number (number of Mn neighbors to Sr) of 1

175 meters describing each particle, such as the coordination number, number of neighbors, and local pack

176 The pore size, pore throat size and coordination number obey normal distribution, and the av

177 The U-As coordination number of 1.6 implied that two uranyl arsen

178 mplexes, the photophysical properties with a coordination number of 4 were studied in detail, includi

179 The average Zn(II) coordination number of 4.5 in the resting enzyme appears

180 hydration of the adsorbed Hf complex up to a coordination number of 7, followed by the dissociation o

181 These results show that the low coordination number of a trigonal-planar geometry is imp

182 t at high Ca:Si and H(2)O ratios, the stable coordination number of aluminum is six.

183 aintain a nominal 2+ charge and a total Cr-O coordination number of approximately 2.

184 cture of cubic diamond silicon, although the coordination number of atoms of the SWSNTs is still four

185 of the binding site and limits the dominant coordination number of Ca(2+) to be seven, thereby leadi

186 titution sites on CeO(2) terrace with a Pt-O coordination number of ca. 4.

187 ated at the edge sites of CeO(2) with a Pt-O coordination number of ca. 5, while those prepared at 80

188 ith five N atoms, in contrast to the average coordination number of four as previously reported.

189 At the drop, nu ~ 0.4, the coordination number of glass and rubber networks is appr

190 that unambiguously determines the gas phase coordination number of hydroxide to be four.

191 Increasing the coordination number of iron from three to four through b

192 wing to lower symmetry and a decrease in the coordination number of iron.

193 we report dynamic measurements of the water-coordination number of lanthanide triflate-based catalys

194 me of Earth's mantle the mean silicon-oxygen coordination number of magnesium metasilicate liquid cha

195 Here we show that the coordination number of network-forming structural motifs

196 s affinity switching was used to control the coordination number of Ni(2+).

197 ounds reveals that, in almost all cases, the coordination number of Pb is actually 5, 6, or 8.

198 With a coordination number of seven for Ca(2+), which is shown

199 ions that can increase the dimensionality or coordination number of silver-based metal-organic chalco

200 ermochromic event corresponds to a change in coordination number of the active-site Mn(3+) ion from 6

201 n in the few known monomeric structures, the coordination number of the alkali metal is raised by bin

202 The increased coordination number of the antimony center in this anion

203 g values of 6.5, 4.2, and 2.0, and that the coordination number of the Co(II) is 5 or 6.

204 if equivalent constraints are imposed on the coordination number of the complex.

205 retaining the overall charge neutrality and coordination number of the Fe3+ center.

206 ount of water present for hydration, and the coordination number of the heme iron atom.

207 lectivity is not correlated with the overall coordination number of the ion entering the pore, but is

208 dation level, presence of alkali metals, and coordination number of the iron atoms are varied, to gai

209 ermore, the chelate mode is sensitive to the coordination number of the metal center; binding of a si

210 Significantly, reducing the coordination number of the metal centers appears to incr

211 hat the fracture strain is controlled by the coordination number of the network junctions, with less

212 body modes that depends only on the average coordination number of the origami's vertices.

213 ophenone, and nitrobenzene are involved, the coordination number of the proton (x) in [H(solvent)(x)(

214 rmine the effect of steric properties on the coordination number of the species that undergoes oxidat

215 uranate coordination environments where the coordination number of U is less than 8.

216 The coordination number of Zr is restricted to six in arylox

217 cate significant changes in the topology and coordination numbers of silicon and boron atoms in the a

218 graphic data, the ionic radii of Am(3+) with coordination numbers of six (0.975 angstrom), seven (1.0

219 arious sets of collective variables, such as coordination numbers of the glycosidic oxygen, yielded a

220 nical model and find that a direct effect of coordination number on rate is unlikely.

221 e probed the effects of ligand structure and coordination number on the coating affinity to the nanoc

222 n of the effects of electronics, sterics and coordination number on the rate.

223 sses, jammed solids and biopolymer gels have coordination numbers placing them at the edge of mechani

224 more brittle Cu46Zr54, where topological low coordination number polyhedra are still observed around

225 ropy was incorporated into the model using a coordination number ratio, and an algorithm that was dev

226 f shale were integrated into the model via a coordination number ratio.

227 evelop a defective MnO(2) catalyst through a coordination number reduction strategy to enhance the ae

228 errous site, while in 3His-G4DFsc(Mut3), the coordination number remains the same and the substrate l

229 Analysis of the coordination number renders values that are almost const

230 Furthermore, we predict that low coordination numbers result in nonclassical nucleation b

231 thin the network extends beyond its chemical coordination number, resulting in a hyperconnected netwo

232 of Eu(2+) in inorganic polyhedra with small coordination numbers results in broad-band red emission

233 to minuscule differences in ionic radius and coordination numbers, separation of the lanthanides is t

234 essful metalloprotein design that has a high coordination number (seven) metal-binding site construct

235 dicates the mutation does not alter the heme coordination number, spin state, or porphyrin deformatio

236 erogeneous catalysis of metal atoms with low coordination numbers, such as found at atomic steps and

237 he number of (N, O) ligands, with noninteger coordination numbers suggesting zinc site heterogeneity.

238 orner-shared cobalt tetrahedra, which have a coordination number switching between 3 and 4 during the

239 xisting DNA assemblies use monomers with low coordination numbers that present an effective kinetic b

240 structural property, average two-shell water coordination number, that correlates well with measured

241 Owing to the reduced coordination number, the (VIII)Cm(III)-OH(2) bond length

242 phase diagram predicting that, for the same coordination number, the density of monodisperse random

243 is when the alkylated Fe site has a suitable coordination number, thereby providing support for the i

244 oneycomb model to random lattices with fixed coordination number three.

245 the dynamic evolution of oxidation state and coordination number throughout the operation of the nano

246 "NbO6" connectivity by extending the oxygen coordination number to 7 and 8.

247 quirement for topologically constraining the coordination number to a specific value.

248 with transition metals by maintaining a low coordination number to restrict the magnitude of the d-o

249 e shown promise in stabilizing unusually low-coordination number transition-metal complexes in low fo

250 fferences in the reactivity depending on the coordination number: tricoordinate boron azides behave a

251 The different coordination numbers, types of coordinating residues, an

252 in-group and transition-metal elements) with coordination numbers up to ten are discussed herein.

253 nce Raman spectra did not reveal a change in coordination number upon binding of isoniazid to KatG.

254 s work sheds light on the relationship among coordination number, valence state, and catalytic perfor

255 ation of isolated noble metal sites with low coordination numbers via exsolution from the POM during

256 II)Cm(III)-OH(2) (where (VIII) refers to the coordination number) was compared to (VIII)Ln(III)-OH(2)

257 sing restraints that solely enforce specific coordination numbers, we find all models are K(+)-select

258 ty, pore size, pore throat distribution, and coordination number were used.

259 ligand field strength due to an increase in coordination number, whereas resonance Raman spectra ind

260 that the polyhedral shape defines the final coordination number, which is equal to the number of fac

261 ith the second site having a lower effective coordination number, which, along with other structural

262 involves an increase in the nearest-neighbor coordination number while the bond angle distributions b

263 These results demonstrate that coordination number, without dramatic changes within the

264 yer-Villiger insertions are favored by lower coordination numbers (x = 1 versus x = 2), earlier trans

265 We also conclude that the coordination number z have a partial influence on how fa

266 e find that softness-and even just the local coordination number Z-is essentially equally predictive

267 Their stability depends critically on their coordination number z.