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1 ts the first example of a light-controllable cyclization reaction.
2 , a tandem beta-fragmentation-intramolecular cyclization reaction.
3 ium complex with HFIP which may initiate the cyclization reaction.
4 the activated triple bond competes with the cyclization reaction.
5 ey substrate for study of the reductive Heck cyclization reaction.
6 result is retention of configuration in the cyclization reaction.
7 se peptide synthesis chemistry and a rhenium cyclization reaction.
8 new example of a dynamic kinetic asymmetric cyclization reaction.
9 ting the folding of the substrate during the cyclization reaction.
10 etermined to be large enough to dominate the cyclization reaction.
11 imics of the tetrahedral intermediate in the cyclization reaction.
12 idine were also used for the tandem coupling-cyclization reaction.
13 ered pi-bonds undergo a related acid-induced cyclization reaction.
14 is region is important for the corresponding cyclization reaction.
15 etal ion" hybrid mechanism to facilitate the cyclization reaction.
16 used was found to affect the outcome of the cyclization reaction.
17 way for either C- or D-ring formation in the cyclization reaction.
18 ntibody 4C6 efficiently catalyzes a cationic cyclization reaction.
19 cantly alter the pK(a) of the intramolecular cyclization reaction.
20 model for pilin-precursor processing and the cyclization reaction.
21 ide and tetraketide intermediates during the cyclization reaction.
22 )-Ynamides are converted to oxazolones via a cyclization reaction.
23 ormation of FAICAR with the highly favorable cyclization reaction.
24 c diphosphate ester function to initiate the cyclization reaction.
25 olefins could serve as intermediates of the cyclization reaction.
26 bridization during a single enzyme-catalyzed cyclization reaction.
27 MeHg(+) and hCy7 through a mercury-promoted cyclization reaction.
28 zo[b][1,6]naphthyridones via a base-mediated cyclization reaction.
29 a sequential Suzuki-Miyaura coupling/Petasis cyclization reaction.
30 ormation, and ESI-MS analyses of the ongoing cyclization reaction.
31 dinated diyne for the further intramolecular cyclization reaction.
32 ngement and Zn-ene-allene (or Zn-yne-allene) cyclization reaction.
33 es was achieved through a sequential Ugi-4CR/cyclization reaction.
34 for the diphosphate anion coproduct in this cyclization reaction.
35 f formylation that is attended by an unusual cyclization reaction.
36 tiated) and class II (protonation-initiated) cyclization reactions.
37 monophosphine Au-catalyzed monoallylic diol cyclization reactions.
38 n reactivity in many gold(I)-catalyzed enyne cyclization reactions.
39 ticipation of the lone pair electrons in the cyclization reactions.
40 fferent 1,5-epoxyalcohols and initiate their cyclization reactions.
41 te a new mechanism for racemization in Prins cyclization reactions.
42 l radicals are trapped by subsequent radical cyclization reactions.
43 is sequence, featuring two resin-bound macro-cyclization reactions.
44 catalyzes the oxidative deamination and the cyclization reactions.
45 ereoselective fragmentation and transannular cyclization reactions.
46 f catalytic Sm(II) 5- exo- trig ketyl olefin cyclization reactions.
47 dimerization observed in the intramolecular cyclization reactions.
48 important for controlling the hydrolysis and cyclization reactions.
49 n many important chemical processes, such as cyclization reactions.
50 enzamides and facilitated vinyl radical ipso-cyclization reactions.
51 tertiary alkynols are compatible with these cyclization reactions.
52 l as intermediates of prototypical 1,6-enyne cyclization reactions.
53 s/intermediates in asymmetric intramolecular cyclization reactions.
54 carbinyl fragmentation avoided the secondary cyclization reaction (25 or 43 --> 26 or 44), whereas us
56 ated enyne-allene 21 followed by a C(2)-C(6) cyclization reaction and an intramolecular radical-radic
58 reaction to probe the mechanism of the Prins cyclization reaction and the subsequent nucleophilic cap
59 of hongoquercins using gold-catalyzed enyne cyclization reactions and further derivatization are des
61 s of this work was the use of olefinic-ester cyclization reactions and the utilization of glycal epox
62 a derailment of the natural anti-Markovnikov cyclization reaction, and not simply the consequence of
70 rresponding cycloaddition product makes this cyclization reaction attractive for a synthetic route to
71 effects disfavor the thermal C1-C6 diradical cyclization reaction (Bergman) and electronic effects fa
72 Compound 1 is prepared via a tripod-tripod cyclization reaction between 1,3,5-tris-bromomethyl-benz
73 3]thiazine derivatives via the electrophilic cyclization reaction between 2-(methylthio)-1-(3-arylpro
74 eoside was accomplished by an intramolecular cyclization reaction between a radical at the 2'-positio
76 demonstrated employing a Pictet-Spengler bis-cyclization reaction between commercially available (R)-
77 metal-free, simultaneous triple C-C coupling cyclization reaction between phenacyl bromides and indol
78 F, II.Rh, effectively catalyzed Pauson-Khand cyclization reactions between 1,6-enynes and carbon mono
80 g and sulphur transfer steps are used in the cyclization reaction, but a 5'- H -phosphonate intermedi
81 ucial in the final stage of the head-to-tail cyclization reaction, but the enzyme(s) involved in the
84 four-step sequence featuring a condensation/cyclization reaction cascade between 4-(2-aminophenyl)py
85 ich serves as the substrate for a subsequent cyclization reaction catalyzed by a terpenoid cyclase, m
86 -linalyl diphosphate and preceding the final cyclization reaction catalyzed by the monoterpene syntha
87 suicide inhibition, cyclization, and reverse cyclization reactions catalyzed by a group I intron from
88 he asymmetric intramolecular indium-mediated cyclization reaction delivers chromanes with excellent d
90 hydrations of Ser and Thr residues and three cyclization reactions during the biosynthesis of the cyt
93 the products obtained have revealed that the cyclization reactions follow an initial 6-endo-dig proce
94 enantioselective hydroboration-homologation-cyclization reaction followed by a hydrolysis-lactonizat
95 ridine scaffold is developed via an addition-cyclization reaction followed by an Ullmann-type C-N cou
96 ndem cationic aza-Cope rearrangement/Mannich cyclization reaction for accessing the unprecedented bri
97 We report herein a reversible ring-opening-cyclization reaction for some of these spirooxindoles, w
98 The approach is based on a SmI(2)-mediated cyclization reaction for the construction of the oxacycl
99 e particularly interested in the use of this cyclization reaction for the synthesis of 6-azabicyclo[3
100 istry to the commonly employed electrophilic cyclization reaction for the synthesis of benzo[b]thioph
101 The DFT calculation of the iodine-mediated cyclization reactions for molecules containing methoxy,
103 ication of thiyl-radical-mediated 5-exo-trig cyclization reactions for the preparation of a series of
104 ay crystal structures shows clearly that the cyclization reaction forces the two naphthyl rings into
105 roof-of-principle experiment on the Hantzsch cyclization reaction forming 2-amino-4-phenyl thiazole f
106 by SmI2 results in an instantaneous [2 + 3] cyclization reaction, forming a bridged seven-membered r
107 ared to identify relevant amino acids of the cyclization reaction from alpha-terpineol to 1,8-cineole
108 ts efficient and stereoselective dehydrative cyclization reactions from monoallylic diols, with stere
109 to catalyze highly enantioselective Nazarov cyclization reactions, giving rise to cyclopentenoids in
111 aining pincer ligand to Pt catalyzed cascade cyclization reactions has allowed for the catalytic, dia
112 ergent hydroimination and iminohydroxylation cyclization reactions has been accomplished through the
117 iates, also referred to as N-acyliminium ion cyclization reactions, have been employed for the constr
118 ut the increase of the quantum yields of the cyclization reaction in a nonpolar hexane is observed on
119 om M. tuberculosis that catalyzes an unusual cyclization reaction in converting the known M. tubercul
120 3-dicarbonyl compounds followed by Conia-ene cyclization reaction in moderate to good yields catalyze
121 alyzes a highly stereoselective chlorination-cyclization reaction in napyradiomycin antibiotic biosyn
123 zes two sequential, mechanistically distinct cyclization reactions in the formation of a mixture of a
126 arbonyldiimidazole-mediated one-pot/two-step cyclization reaction involving amino acid unsymmetrical
127 or constructing metallabenzenes has emerged, cyclization reactions involving metal-thiocarbonyl, meta
128 ies grandis), and the olefin product of this cyclization reaction is considered to be the precursor i
129 sm, in which a thermodynamically unfavorable cyclization reaction is coupled to an electronic conjuga
134 e stereoselective nature in the C-N coupling cyclization reaction is interpreted in terms of minimiza
135 shortcoming is particularly costly when the cyclization reaction is performed after a long sequence
137 ansient carbocation intermediates in terpene cyclization reactions is generally under kinetic rather
138 e substrate, which is the nucleophile in the cyclization reaction, is replaced with a hydroxyl group
140 rona discharge, solvent-free Borsche-Drecsel cyclization reaction, Katritzky chemistry, and Paal-Knor
141 ry centres induce large rate enhancements in cyclization reactions-known as the Thorpe-Ingold effect-
143 toxy)hexanes have been synthesized and their cyclization reactions leading to di- and trisubstituted
144 iterpenoid oxidation activities, including a cyclization reaction, leading to a triterpenoid lactone.
145 ormation of amide bonds and their effects on cyclization reactions led us to alkylate the amide bond.
147 detailed computational investigation of the cyclization reaction mechanism suggests facile C-N bond
150 thylhex-4-ene-1-thiol via (3,5)-thionium-ene cyclization reaction mediated by boron trifluoride ether
151 ynthesized from thioacrylates via thia-Prins cyclization reaction mediated by trimethylsilyltrifluoro
152 wo diastereochemically complementary radical cyclization reactions mediated by Ti(III) and Mn(III), r
153 as sufficient to "short circuit" the complex cyclization reaction normally catalyzed by ent-kaurene s
154 n the presence of oxygen, a radical addition/cyclization reaction occurred which resulted in the form
155 these alcohols to thionyl chloride, cascade cyclization reactions occurred to furnish polycyclic com
156 oacetonitrile, a subsequent condensation and cyclization reaction occurres to produced 4-amino-3,7-di
157 c phosphonamides have been synthesized via a cyclization reaction of (S,S)-aminobenzylnaphthols with
161 nium acetate assisted gold-catalyzed cascade cyclization reaction of 2-alkynylarylketones is describe
163 chieved by a tandem organocatalytic addition/cyclization reaction of 2-carbobenzyloxy-N-tosylbenzylid
164 ified isoflavonoids 1-11 are proposed, and a cyclization reaction of 9 was conducted to support one o
165 esized by lanosterol synthase (LSS) in a key cyclization reaction of a cholesterol synthesis pathway.
166 ss a pyran ring formed through a spontaneous cyclization reaction of a dithiolene side-chain hydroxyl
167 ighly robust one-pot, four-component cascade cyclization reaction of alpha-keto aldehydes, anilines,
172 beta-carbon atom by a Mannich-type addition/cyclization reaction of isocyanoacetate pronucleophiles
173 an operationally simple, palladium-catalyzed cyclization reaction of N-aryl imines, affording indoles
174 rate salt was employed for the electrophilic cyclization reaction of o-alkynyl thioanisoles for the s
175 using the same protocol, we carried out the cyclization reaction of relevant molecules, such as lapa
177 rs, and it relies on the fourfold oligomeric cyclization reaction of resorcinol with 2,3-dihydrofuran
178 nd high-yielding indium trichloride mediated cyclization reaction of silylated homoallylic alcohols,
179 lkyne 6, and the intramolecular Michael-type cyclization reaction of the phenolic naphthoquinone 20.
181 The efficiency of the redox-mediated Bergman cyclization reaction of this stable Pt(0) metalloenediyn
184 nism of the Dess-Martin periodinane-mediated cyclization reaction of unsaturated anilides discovered
185 d as a single regioisomer via a ring-opening cyclization reaction of unsaturated pyrrolinium ions in
188 ypothesis for the gem-dimethyl effect in the cyclization reactions of 2-chloroethoxide derivatives ha
189 demonstrate that at pH 7.5 the CHI-catalyzed cyclization reactions of 4,2',4',6'-tetrahydroxychalcone
190 e examined the spontaneous and CHI-catalyzed cyclization reactions of 4,2',4',6'-tetrahydroxychalcone
193 In this review a collection of examples of cyclization reactions of bis(allenes) is presented as we
195 ted lactams, prepared through group-transfer cyclization reactions of carbamoyl radicals, undergo a C
197 re is generated by periplasmic oxidation and cyclization reactions of d-tyrosine and l-diaminobutyric
198 eparation of chalcogenophene derivatives via cyclization reactions of diynols promoted by diorganyl d
201 transition metal-mediated cycloaddition and cyclization reactions of enyne and diyne substrates asse
202 his work, the mechanism of 10 representative cyclization reactions of hepta-1,2,4,6-tetraenes with di
203 This review aims to provide an overview of cyclization reactions of N-acyliminium ions derived from
208 mics the second step of splicing and reverse cyclization reactions of the self-splicing intron from T
209 nificant structural similarity, catalyze the cyclization reactions of the universal alicyclic precurs
210 tate analogues, catalyze disfavored endo-tet cyclization reactions of trans-epoxy alcohols, in formal
211 Highly diastereoselective metalloamination/cyclization reactions of zinc(II) hydrazides obtained th
212 radical-forming C2-C6 cyclization (Schmittel cyclization) reaction of the chlorinated benzoenyne-alle
219 f the adenylate nucleophile required for the cyclization reaction provides slow hydrolysis as the onl
220 tial palladium-catalyzed alpha-arylation and cyclization reactions provides a general approach to an
223 t efficiency by means of a sortase-catalyzed cyclization reaction, requiring only minimal modificatio
224 landin H(2) requires two oxygenation and two cyclization reactions, resulting in the formation of fiv
225 ow how antibody catalysis can guide cationic cyclization reactions selectively to form products (in h
226 uctural basis for this coupled isomerization-cyclization reaction sequence can be inferred by homolog
227 followed by a hitherto unprecedented cascade cyclization reaction sequence comprising a Cu-catalyzed
228 chanistic studies suggest that the oxidative cyclization reaction sequence is initiated by an electro
231 embered ring systems obtained by these novel cyclization reactions serve as useful and versatile inte
232 is was designed featuring two gold-catalyzed cyclization reactions, specifically, a dehydrative cycli
233 tional experiments are consistent with these cyclization reactions taking place by an anti-oxypallada
234 ta obtained by HPLC analysis support a rapid cyclization reaction that can be reversed upon acid dena
235 cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpi
236 ed through a stereocontrolled intramolecular cyclization reaction that has been evaluated both experi
237 is a thermodynamically controlled asymmetric cyclization reaction that produces two new stereogenic c
239 -oxindoles undergo a reversible ring-opening-cyclization reaction that, from a single compound in pro
240 strong solvent polarity effect, whereas the cyclization reactions that gave distonic radical cation
241 re model, the LctM-catalyzed dehydration and cyclization reactions that occur in two distinct active
242 Terpene synthases often catalyze complex cyclization reactions that typically represent the commi
243 tituted peptides and suggest that during the cyclization reaction the peptide substrate is preorganiz
244 addition to the generality and scope of this cyclization reaction, this article describes a number of
245 ted that, after future implementation of the cyclization reactions, this framework can be used to ide
246 described, which involves an intramolecular cyclization reaction through a nucleophilic substitution
247 mploy an optimized first-order bioorthogonal cyclization reaction to control the self-assembly of a f
248 to which is an adventurous samarium-mediated cyclization reaction to establish the tricyclic core and
250 or a two-step process involving a Schmittel cyclization reaction to form biradical 13 followed by an
251 follows: (a) a pinacol-terminated 1,6-enyne cyclization reaction to form the cis-hydrindanone core (
252 s the only reagent for the unusual and rapid cyclization reaction to furnish all new carbazole compou
253 -allene 12, which then underwent a Schmittel cyclization reaction to generate the benzofulvene biradi
254 ient and diastereoselective radical addition/cyclization reaction to give trisubstituted piperidines
256 ines participate in efficient intramolecular cyclization reactions to afford a variety of piperidine
258 ral alkynylindoles undergo gold(I)-catalyzed cyclization reactions to form a single isomer in each ca
259 donor (reverse addition), undergo efficient cyclization reactions to give N-heterocyclic furanosides
260 zation to give cyclic phosphonates and other cyclization reactions to give pi-rich P-heterocycles.
261 ndergo spontaneous intramolecular 5-exo-trig cyclization reactions to provide hydroxy-gamma-butyrolac
263 oxidation potential, contributes to a rapid cyclization reaction triggered by copper(II) ion in wate
265 s prepared and studied in the intramolecular cyclization reaction under acidic conditions in our seco
266 s effective in catalyzing the metalloradical cyclization reaction under neutral and mild conditions.
268 nes 4, where R(3) is aryl, undergo 5-exo-dig cyclization reactions under relatively mild conditions (
269 nones 8, 17, and 18 undergo 2-fold reductive cyclization reactions upon exposure to hydrogen in the p
273 on, heteroatom acylation, and a diversity of cyclization reactions using the title compound as a key
274 demonstrate a one-pot, tandem dihalogenation-cyclization reaction, using the same catalytic system tw
275 anthanide-mediated, intramolecular amination/cyclization reaction was determined for the formation of
276 with 2-bromophenols and a subsequent tandem cyclization reaction was developed for the one-pot synth
277 estigations, an interesting stereoconvergent cyclization reaction was discovered for the efficient as
280 by base-mediated intramolecular oxa-Michael cyclization reaction was investigated under steady-state
286 product of a Raney-cobalt mediated reductive cyclization reaction, was readily converted into the cis
291 ty of competitive pinacol rearrangements and cyclization reactions were overcome to develop a 7-step
292 ermediate, in contrast to other Au-catalyzed cyclization reactions where this intermediate severely r
293 anism is thought to be due to a head-to-tail cyclization reaction, where the N-terminal and C-termina
296 oach is exploited for multifold C-C coupling cyclization reactions with C-C cleavage using symmetrica
298 ollowed by a Pd-catalyzed intramolecular C-N cyclization reaction, with good to excellent yields is d
299 dramatic impact on the ratio of exo- to endo-cyclization reactions, with bicyclo[4.1.0] intermediates
300 covered and used three times in Pauson-Khand cyclization reactions without deterioration of yields or