ライフサイエンスコーパス: cyclohexane

1 onsted acid sites and the formation rate for cyclohexane.

2 ver conjugate reduction to the corresponding cyclohexane.

3 ether is a 4-substituted 1-(methoxymethylene)cyclohexane.

4 some cyclic 2-nitroalkanones was studied in cyclohexane.

5 t with their DeltaG(tr) values from water to cyclohexane.

6 arent 1,2-BN cyclohexane, the BN-isostere of cyclohexane.

7 d the Phase I "plastic crystal" structure of cyclohexane.

8 acterized by UV-vis spectroscopy in MeCN and cyclohexane.

9 ly 2 x 10(12)-fold by transfer from water to cyclohexane.

10 um in this solvent relative to reaction with cyclohexane.

11 ydrogen and larger species such as argon and cyclohexane.

12 ethane, and halobenzene solvents relative to cyclohexane.

13 form VB is slower than spin equilibration in cyclohexane.

14 ime of 1BpCMe is the same in cyclohexene and cyclohexane.

15 cycle with two substrates, benzphetamine and cyclohexane.

16 imes of 1BpCMe and 1BpCMe-d3 are the same in cyclohexane.

17 me of 1BpCH is shortened relative to that in cyclohexane.

18 ter correction for the one-half of the SE of cyclohexane.

19 (A/K) ratios of around 1 in the oxidation of cyclohexane.

20 xidation by Fe(V)O of hydrocarbons including cyclohexane.

21 ther was observed to selectively encapsulate cyclohexane.

22 over a multifunctional Pt/NbOPO4 catalyst in cyclohexane.

23 complexes that can preferentially halogenate cyclohexane.

24 in nonaromatic hydrocarbon solvents such as cyclohexane.

25 and examined all-cis 1,2,3,4,5,6-hexafluoro-cyclohexane.

26 ricted surrogates of trans-1,3-disubstituted cyclohexanes.

27 tionalization selectivity of monosubstituted cyclohexanes.

28 ene derivatives to the corresponding all-cis-cyclohexanes.

29 etracyclic structure composed of fused chair cyclohexanes.

30 y are higher than expected for "strain-free" cyclohexanes.

31 The complex ( OC-6-44)-acetatodichlorido(cyclohexane-1 R,2 R-diamine)( rac-2-(2-propynyl)octanoat

32 anoato, namely, ( OC-6-44)-acetatodichlorido(cyclohexane-1 R,2 R-diamine)( rac-2-(2-propynyl)octanoat

33 characterization, and in vitro activity of a cyclohexane-1 R,2 R-diamine-based Pt(IV) derivative cont

34 R,2S,3R,4S,5S,6R)-5-(nonylamino)-6-(nonyloxy)cyclohexane-1,2,3,4-tetraol had a K(i) of 1 nM using iso

35 selective mono-N-pyridylation of trans-(R,R)-cyclohexane-1,2-diamine is described here.

36 Oligoureas (up to n=6) of meso cyclohexane-1,2-diamine were synthesized by chain extens

37 N, N'-dimethyl- N, N'-bis(pyridin-2-ylmethyl)cyclohexane-1,2-diamine, OTf = trifluoromethanesulfonate

38 trans-Cyclohexane-1,2-diamine-a common component of chiral sal

39 The cyclohexane-1,2-diamine-based bisbinaphthyl macrocycles

40 bolites of eight phthalates and di(isononyl) cyclohexane-1,2-dicarboxylate (DINCH) in 656 urine sampl

41 use of copper(I) iodide (5 mol %) and trans-cyclohexane-1,2-diol as ligand under basic conditions an

42 In vivo labelling with 4-(3-azidopropyl)cyclohexane-1,3-dione (DAz-2) shows that Cys420 also for

43 lation of easily accessible 2-(2-bromobenzyl)cyclohexane-1,3-diones to provide the corresponding 2,3,

44 -Wittig reaction of 2-alkyl-2-(3-azidopropyl)cyclohexane-1,3-diones, delivering the highest ee's yet

45 ), 4, [Re(O)(NAr)(saldach)+] (saldach = N,N'-cyclohexane-1,3-diylbis(salicylideneimine)), 5, and [Re(

46 As demonstrated for poly(ethylene-co-cyclohexane-1,4-dimethanol terephthalate) (PETG), this a

47 ermine whether they undergo cyclization to a cyclohexane-1,4-diyl anion structure by examining chemic

48 oparticles, formulated from the polymer poly(cyclohexane-1,4-diylacetone dimethylene ketal) (PCADK),

49 linker, N-succinimidyl-4-(N-maleimidomethyl)cyclohexane-1-carboxylate (SMCC), and the resulting ADC,

50 lar linker N-succinimidyl-4-(maleimidomethyl)cyclohexane-1-carboxylate (SMCC).

51 rain SB syntrophically degrades benzoate and cyclohexane-1-carboxylate and catalyses the novel synthe

52 (13) C]-acetate into crotonate, benzoate and cyclohexane-1-carboxylate during growth on these differe

53 atalyses the novel synthesis of benzoate and cyclohexane-1-carboxylate from crotonate.

54 ogenase genes during syntrophic benzoate and cyclohexane-1-carboxylate growth, one of which (fdhA2) w

55 All three inhibitors halted syntrophic cyclohexane-1-carboxylate metabolism.

56 lic acid degradation versus for benzoate and cyclohexane-1-carboxylate synthesis.

57 spirillum hungatei on crotonate, benzoate or cyclohexane-1-carboxylate.

58 cyclohexane derivative cis-2-(carboxymethyl)cyclohexane-1-carboxylic acid [(1R,2R)-/(1S,2S)-2-(carbo

59 ylic acid [(1R,2R)-/(1S,2S)-2-(carboxymethyl)cyclohexane-1-carboxylic acid] has previously been ident

60 ,N'-bis(3,5-di- tert-butylhydroxybenzyl)-1,2-cyclohexane-(1R,2R)-diamine) exists as a temperature-inv

61 N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-(1R,2R)-diamine) with a non-innocent salen l

62 )(3)N)U(IV)}(2)(mu-eta(2):eta(1)-1,2-(CH)(2)-cyclohexane)] (2) and [{(((Ad)ArO)(3)N)U(IV)}(2)(mu-eta(

63 shows excellent selectivity of benzene over cyclohexane (20:1 for vapors, 92:1 for liquid phase), wh

64 ne 22a and 2.0 kcal/mol for the formation of cyclohexane 22b.

65 s strong as 100 kcal mol(-1) and reacts with cyclohexane a hundred- to a thousand-fold faster than mo

66 In cyclohexane, a (C5Me5)2Y(mu-eta(8):eta(1)-C8H7)Y(C5Me5)

67 ution of Grubbs first-generation catalyst in cyclohexane, a nonsolvent for PLA.

68 -acylestrones under a nitrogen atmosphere in cyclohexane, acetonitrile (MeCN), and methanol (MeOH) wa

69 henols under N(2) atmosphere in homogeneous (cyclohexane, acetonitrile, and methanol) and micellar (S

70 On the other hand, in homogeneous media (cyclohexane, acetonitrile, and methanol) the observed pr

71 Cyclohexane adlayers form crystal-like faceted islands a

72 selectivities arise from differences in the cyclohexane adsorption enthalpies of these frameworks, w

73 Bu and (Ph(Me)2CO)2 at 100 degrees C without cyclohexane afforded N-methylphthalimide (Me-phth) from

74 onformationally restricted cis- or trans-1,4-cyclohexane alpha to the urea were prepared and tested a

75 In contrast, the cyclohexane analogue 2b treated with MeLi underwent a sm

76 dergo rearrangement by 4.0 kcal/mol than the cyclohexane analogues.

77 ingly, treatment of 1 with cyclohexene gives cyclohexane and 4 via a titanium-mediated transfer hydro

78 innamyloxy silanes has been examined in both cyclohexane and acetonitrile solvents.

79 m a high-valent oxidant capable of effecting cyclohexane and benzene hydroxylation within seconds at

80 lites produced C6-cyclic hydrocarbons (i.e., cyclohexane and benzene) most dominantly.

81 y to C6-cyclic products (62.4% and 28.6% for cyclohexane and benzene, respectively) without acyclic i

82 rrelated with the selectivity change between cyclohexane and benzene.

83 ar ratios <or=1:1, the rate of metabolism of cyclohexane and benzphetamine is enhanced, whereas at hi

84 owever, when the reactions were performed in cyclohexane and cyclohexene, isomerization of 3 was favo

85 ring structures are most likely dominated by cyclohexane and cyclopentane rings and not larger cycloa

86 ium kinetic isotope effect from reactions of cyclohexane and d12-cyclohexane in separate vessels show

87 Separate reactions of cyclohexane and d12-cyclohexane with benzamide showed th

88 bicyclic fragment 22 consisting of the fused cyclohexane and dihydropyran rings was constructed via t

89 rapidly (t(1/2) approximately 0.2 h) to form cyclohexane and fluoride (F(-)) as the stable end produc

90 lifetime of 1BpCMe and 1BpCH are the same in cyclohexane and in cyclohexane-d12.

91 on reaction efficiencies for two substrates, cyclohexane and isopropyl alcohol, were measured for 23

92 Cyclohexane and methylcyclohexane can be also dehydrogen

93 chains) in nonpolar organic liquids such as cyclohexane and n-decane.

94 esicles in nonpolar organic liquids, such as cyclohexane and n-hexane.

95 er displayed superior affinity compared to a cyclohexane and phenyl linker.

96 ompany the placement of axial fluorines on a cyclohexane and the unusual property of a facially polar

97 5 orders of magnitude in nonpolar solvents, cyclohexane and toluene, resulting in a radical ion-pair

98 lectivities of C-H oxidations of substituted cyclohexanes and trans-decalins by dimethyldioxirane (DM

99 tion of rapid and catalytic hydroxylation of cyclohexane, and a million-fold acceleration in the deca

100 clopentane (MCP) to acyclic isomer, olefins, cyclohexane, and benzene.

101 Similarly, cyclopentane, cyclohexane, and cycloheptane rings were constructed fro

102 econd pulses of UV light in acetonitrile, in cyclohexane, and in methanol.

103 state of the diazo compound in acetonitrile, cyclohexane, and methanol with lambdamax = 490 nm and li

104 rmodynamics of the encapsulation of benzene, cyclohexane, and norbornadiene are compared.

105 redicted similar lifetimes for cyclopentane, cyclohexane, and, to a lesser extent, cycloheptane, sugg

106 cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated.

107 energies for cyclopropane, cyclobutane, and cyclohexane are 3 to 4 kcal mol-1 too small and their pi

108 he heights of the second adlayers of THF and cyclohexane are measured to be 0.44 +/- 0.02 and 0.50 +/

109 a single photochemical step, with the use of cyclohexane as a solvent providing optimal yields.

110 We have studied trans-1,2-disubstituted cyclohexanes as model systems with carboxamide, thioamid

111 lic molecules (dioxane, tetrahydrofuran, and cyclohexane), as well as chlorinated and aromatic pollut

112 ither 1-phth nor 1-phth2 reacted with excess cyclohexane at 100 degrees C without tBuOOtBu.

113 onium salt of neopentyl phosphate enters wet cyclohexane at concentrations sufficient to allow determ

114 which three thiourea groups are mounted on a cyclohexane-based scaffold.

115 s, including THF (BDE = 92 kcal mol(-1)) and cyclohexane (BDE = 99 kcal mol(-1)).

116 triplet ground state (3Fl) in acetonitrile, cyclohexane, benzene, and hexafluorobenzene.

117 iciencies of >95% were observed for propane, cyclohexane, benzene, isoprene, aerosol particle mass, a

118 ology for the synthesis of 4,4-disubstituted cyclohexane beta-keto esters from benzylic nitriles or e

119 tion of beta-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (beta-TBECH).

120 O) and beta-1,2-dibromo-4-(1.2-dibromoethyl)-cyclohexane (beta-TBECH).

121 C(2)H(6)) and larger hydrocarbons (benzene, cyclohexane) both in liquid and vapor phases was thoroug

122 singlet-triplet gap that is close to zero in cyclohexane, but the triplet is the ground state.

123 ging of the dissolution process of urea in a cyclohexane/butanol solution with nanometer topographica

124 The oxidation of cyclohexane by 2 occurs at a rate comparable to that of

125 he catalytic reaction is the C-H cleavage of cyclohexane by a tert-butoxy radical.

126 nitrile ylide (lambdamax = 370 nm), and with cyclohexane by C-H insertion 1-20 ns after the laser pul

127 reaction barriers for H-atom abstraction of cyclohexane by the ground state of 7-coordinate CNTs and

128 l-cis 1,2,3,4,5,6-hexakis (trifluoromethyl)- cyclohexanes by direct hydrogenation of precursor tetrak

129 ange of geminal C H bonds of the methane and cyclohexane C H sigma adducts, is observed before loss o

130 f ring strain energies (RSEs) of substituted cyclohexanes c-C6H(x)R(12-x) (R = F, Cl, Me; x = 0, 2, 4

131 Derivative 5-bromo-3'-(cyclohexane carbonyl)-1-methyl-2-oxospiro[indoline-3,2'-

132 trometric techniques and reaction rates with cyclohexane carboxaldehyde (CCA) are measured.

133 xyphenyl) piperazin-1-yl]ethyl-N-(2-pyridyl) cyclohexane carboxamide ((18)F-FCWAY) PET and CMRglc mea

134 phenyl)-1-piperazinyl)ethyl)-N-(2-pyridinyl) cyclohexane carboxamide] [WAY100635] 0.5 mg/kg, intraven

135 key steps involved in benzoate breakdown and cyclohexane carboxylate formation are unclear.

136 y diffraction reveals some distortion of the cyclohexane chair conformation in the solid state.

137 Crude 4-MCHM is comprised of several major cyclohexane components, four of which have distinct isom

138 t with100-fold (k = 0.15 +/- 0.05 s(-1)) and cyclohexane congruent with10-fold (k = 2.5 +/- 0.35 s(-1

139 uinoline (compound 3) rings around a central cyclohexane core for use in molecular recognition of mon

140 of structurally different substrates, viz., cyclohexane, cyclic ethers, arenes, alkyl aromatic syste

141 nt to cleave C-H bonds as strong as those in cyclohexane (D(C-H) = 99.3 kcal mol(-1)).

142 tes benzene or benzene-d6 and dehydrogenates cyclohexane-d12.

143 and 1BpCH are the same in cyclohexane and in cyclohexane-d12.

144 ix different amine scaffolds: linear acenes, cyclohexane, decalin, triptycene, adamantane, and [2.2]p

145 10 mol %, the SFG signals for 1-hexanol and cyclohexane decrease with increasing concentration of 1-

146 a completely unactivated C(sp(3))-H bond of cyclohexane demonstrate the broad implications of this m

147 character of carbene 22a as compared to the cyclohexane derivative 22b.

148 The cyclohexane derivative cis-2-(carboxymethyl)cyclohexane-

149 ketones affords functionalized 3,5-dihydroxy cyclohexane derivatives as the kinetically controlled pr

150 Spirobenzothiophenonic cyclohexane derivatives containing three stereocenters w

151 cyclopropane affords either cyclopentane or cyclohexane derivatives in which the C6F5 and B(C6F5)2 a

152 ical shifts in chair conformationally locked cyclohexane derivatives readily secured from a mixture o

153 .2 kcal/mol for dioxane and 6.4 kcal/mol for cyclohexane derivatives than for the formation of the bi

154 stricted surrogates of cis-1,4-disubstituted cyclohexane derivatives.

155 goethylene functionalized benzaldehyde and a cyclohexane-derived trishydrazide--in the presence of ac

156 In cyclohexane, DHNA shows the lowest lying S0 -->S1 (pi-pi

157 from triphenyl amine-based trialdehydes and cyclohexane diamine building blocks utilizing the dynami

158 ates of pentetic acid (Fe-DTPA) and of trans-cyclohexane diamine tetraacetic acid (Fe-tCDTA) were syn

159 In 2002, the plasticizer 1,2-cyclohexane dicarboxylic acid diisononyl ester (DINCH) w

160 Metabolites of the phthalate alternative 1,2-cyclohexane dicarboxylic acid, diisononyl ester (DINCH),

161 Crotepoxide (a substituted cyclohexane diepoxide), isolated from Kaempferia pulchra

162 2008, 47, 7321) with cyclohexane, dihydroanthracene (DHA), and xanthene (Xan)

163 all-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)cyclohexane displays a flattened chair conformation and

164 id side-chain as represented by its water-to-cyclohexane distribution coefficient, and this relations

165 h side-chain, as represented by its vapor-to-cyclohexane distribution coefficient.

166 g the frequency range of 500-4000 cm(-1) for cyclohexane, DMSO, acetonitrile, methanol, water, benzen

167 r activation barrier for ring inversion than cyclohexane due to BN/CC isosterism.

168 t appears to be the reductive elimination of cyclohexane during the hydrogenation process.

169 e opening of hydroxyl protected forms of the cyclohexane epoxides cyclophellitol and 1,6-epi-cyclophe

170 lar to that afforded by the nonpolar solvent cyclohexane (epsilon = 2).

171 onstants (e.g., benzene, epsilon of 2.27, or cyclohexane, epsilon of 2.02) as studied via emulsion dr

172 pesticides were extracted from the sample by cyclohexane-ethyl acetate mixture (1:1 v/v) and cleaned

173 rogenated by transient A, and in the case of cyclohexane, ethylene (1 atm) can trap the [(PNP)Ti(CH2(

174 ericyclic transition state is reported for a cyclohexane featuring opposing methylene and a vinyliden

175 s the first reported parental BN isostere of cyclohexane featuring two BN units, is thermally stable

176 and TL205 (a mixture of mesogens containing cyclohexane-fluorinated biphenyls and fluorinated terphe

177 placement of the aromatic ring of Phe1579 by cyclohexane, for example, strongly reduces use-dependent

178 ively smaller B/L ratio is effective for the cyclohexane formation, whereas more Bronsted acidic zeol

179 method for the synthesis of enantioenriched cyclohexanes from 1,5-diols via hydrogen borrowing catal

180 Synthetic access to the fully charged BN cyclohexane fuels will now enable investigations of thes

181 ation of 2 with sec-butyllithium (s-BuLi) in cyclohexane gave poly-2 in quantitative yield, with a na

182 ric HIV-1 protease inhibitors that contain a cyclohexane group at P1 and/or P1'.

183 We also demonstrate that 1,2-BN cyclohexane has a lower activation barrier for ring inve

184 tereodivergent synthesis of tetrasubstituted cyclohexanes has been achieved using modularly designed

185 The resultant cyclohexanes have a stereochemistry such that all the CF

186 cal shift perturbations in deuterium-labeled cyclohexanes have been identified and quantified.

187 A series of enantioenriched cyclohexanes have been prepared and the mode of enantioi

188 For deuterium-labeled cyclohexanes held in a chair conformation at -80 degrees

189 covered oxidative esterification reaction of cyclohexane hexacarboxylic acid with phosphorus pentachl

190 l CO 520 (nonionic head group) in 50/50 wt % cyclohexane/hexane are prepared to have the same diamete

191 materials for the preparation of substituted cyclohexanes; however, the synthetic tools available for

192 (BpCCF3) which absorbs strongly at 385 nm in cyclohexane, immediately after the 300 fs laser pulse.

193 yridine in water as well as acetonitrile and cyclohexane in 1,2-dichloroethane (DCE).

194 Mixtures of 40% benzene or 40% cyclohexane in 50% isopropanol and 10% water showed no b

195 2 undergo selective ionic hydrogenation with cyclohexane in CF3SO3H-SbF5, HBr-AlBr3-CH2Br2, or HCl-Al

196 HCN products of reaction of CN radicals with cyclohexane in chlorinated organic solvents exhibit pref

197 ccommodating guests such as cyclopentane and cyclohexane in its internal cavity (red).

198 effect from reactions of cyclohexane and d12-cyclohexane in separate vessels showed that the turnover

199 gated to prepare a collection of substituted cyclohexanes in a diastereoselective fashion.

200 rbene BpCCOCH3 has a singlet ground state in cyclohexane, in dichloromethane, and in acetonitrile and

201 roperties of these molecules in deoxygenated cyclohexane, including their absorption spectra, steady-

202 1,2-BN cyclohexane is an air- and water-stable compound that cl

203 at the turnover-limiting step for the ODC of cyclohexane is C-H bond cleavage.

204 f 1-hexanol, consistent with the notion that cyclohexane is excluded from the interfacial region whil

205 and tetrahydropyranyl cations from water to cyclohexane is predicted by B3LYP/6-31+G(d) calculations

206 All-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)cyclohexane is the most sterically demanding of the all-

207 f their side-chains from neutral solution to cyclohexane (K(w > c)).

208 for the stereoselective construction of the cyclohexane-lactone C,D-rings.

209 These data on the ODC of cyclohexane led to preliminary investigation of copper-c

210 ction structure reveals that 1 0 has a chair-cyclohexane-like core and a [6]radialene structure.

211 e that the transfer energetics of alkanes to cyclohexane measure the release of these shells.

212 flat to most likely tilted, suggesting that cyclohexane mediates the adsorption of 1-hexanol via int

213 2 Despite the high relative concentration of cyclohexane, minimal quantities of borylated cyclohexane

214 nol and 10% water showed no bound benzene or cyclohexane molecules, but did reveal bound isopropanol.

215 esis of chemicals like ethylbenzene, cumene, cyclohexane, nitrobenzene and alkylbenzene.

216 rphyrin) were trapped in a mixed benzene (or cyclohexane) oil-in-water emulsion using an ionic liquid

217 y thin adlayers of tetrahydrofuran (THF) and cyclohexane on atomically flat mica substrates, thus per

218 nt is close to Theta-conditions, e.g., PS in cyclohexane or PPO/PEO in water.

219 01 [(S)-1] by phenyl, or by ortho,meta-fused cyclohexane, or especially by ortho,meta-fused benzene p

220 ted toward 2 in the highly nonpolar solvent, cyclohexane, or toward 3 in the more polar solvents.

221 rates unprecedented adsorption preference of cyclohexane over benzene (selectivity up to 5:1).

222 Mixtures of 1-hexanol in cyclohexane over the (0001) alpha-Al(2)O(3) surface were

223 demanding of the all-cis hexakis substituted cyclohexanes prepared to date, with a barrier (DeltaG) t

224 water were sources of hydrogen in the final cyclohexane product.

225 cyclohexane, minimal quantities of borylated cyclohexane products are observed.

226 cyclization pathway, where cyclopentane and cyclohexane repeat units are likely formed.

227 etimes are 200 and 77 ps in acetonitrile and cyclohexane, respectively, and are controlled by intersy

228 ith hydrocarbons R-H (R-H = ethylbenzene and cyclohexane) reveals inefficient stoichiometric C-H amin

229 cocrystal structure with gp120 revealed the cyclohexane ring buried within the gp120 hydrophobic cor

230 on reactions until full aromatization of the cyclohexane ring is achieved.

231 Using this asymmetric catalysis, the cyclohexane ring is constructed with two chiral centers

232 ostulate that the constraints imposed by the cyclohexane ring of OX affect the DNA conformations expl

233 ive study of the conformational landscape of cyclohexane ring of TFC and DFCs revealed that TFC is a

234 e-dependent dioxygenase that closes the core cyclohexane ring of the aryltetralin scaffold.

235 According to the model, the central cyclohexane ring of the linker connecting the two NDI un

236 s did not affect membrane leakage, whereas a cyclohexane ring reduced leakage by an additional 40 %.

237 cture-activity relationship (SAR) within the cyclohexane ring showed the cis-isomers to be more poten

238 was simplified even further by replacing the cyclohexane ring with an isobutyl group attached either

239 y could be replaced by a simpler, less rigid cyclohexane ring without compromising the S1P receptor a

240 mino-4-hydroxybenzoic acid core component, a cyclohexane ring, two triene polyketide chains, and a 2-

241 ts because of the constraints imposed by its cyclohexane ring, which may explain the negligible bindi

242 n in these helical foldamers is coupled with cyclohexane ring-flipping, and results in a reversal of

243 moiety, O-demethylation, hydroxylation, and cyclohexane ring-opening were identified as major reacti

244 e ortho versus para position on the pyrylium cyclohexane ring.

245 th up to eight cyclopentane rings and/or one cyclohexane ring.

246 Although carboxylic acid groups in cyclohexane rings are generally believed to be far more

247 In cyclohexane rings with alpha-substituents the net effect

248 s are more favored for cyclopentane than for cyclohexane rings.

249 ete single bond (in DMSO) or double bond (in cyclohexane) rotation can be induced by visible light.

250 The spiro[benzopyran-1,1'-cyclohexane] scaffold and the cyclohexylmethyl moiety oc

251 similarity between the spiro[3.3]heptane and cyclohexane scaffolds.

252 stry (SMOM-chem), well-defined isobutane and cyclohexane sigma-complexes, [Rh(Cy(2)PCH(2)CH(2)PCy(2))

253 mechanism of oxygenated organic species from cyclohexane solution at the liquid/solid interface of op

254 f methane with bis-pinacolborane (B2pin2) in cyclohexane solvent at 150 degrees C under 2800 to 3500

255 1-hexanol is an orientational change of the cyclohexane solvent from flat to most likely tilted, sug

256 t substrate and under atypical conditions in cyclohexane solvent.

257 ation of methane using bis(pinacolborane) in cyclohexane solvent.

258 a diverse series of carbamates at C6 of the cyclohexane spiroepoxide.

259 The structure and stereochemistry of the cyclohexane substituents of analogues of arterolane (OZ2

260 l mixture of 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH or DBE-DBCH) and the pure beta-TBECH

261 ound EFR was 1,2-dibromo-4-(1,2 dibromoethyl)cyclohexane (TBECH or DBE-DBCH), which was found in near

262 cane (HBCD), 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH), and hexachlorocyclopentadienyl dibr

263 ha- and beta-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH), beta-1,2,5,6-tetrabromocyclooctane

264 s (i.e., CO2, O2, NO2, NO, SO2, H2O, H2, and cyclohexane, tested at the same concentration as SO2).

265 The rate of WR of BpCCOCH3 is faster in cyclohexane than in dichloromethane and acetonitrile bec

266 de clusters for oxidative dehydrogenation of cyclohexane that are active at lower temperatures than r

267 ted structure containing a penta-substituted cyclohexane that is generated by oxidative cleavage of t

268 ields in solution and in the solid state: in cyclohexane the value are 14 and 36%, but in the thin fi

269 is and characterization of the parent 1,2-BN cyclohexane, the BN-isostere of cyclohexane.

270 For cyclohexane, the deuterium kinetic isotope effect (k(H)/

271 3-Sc can initiate tosylamination of cyclohexane, thereby suggesting Cu(II)N(*)Ts cores as vi

272 lycol) diacrylate (PEGDA) hydrogel sample in cyclohexane to create two-dimensional images with high c

273 in the lifetimes of the sigma-complexes from cyclohexane to cycloheptane was predicted to be due to t

274 uteration is coupled with dehydrogenation of cyclohexane to cyclohexadiene, this allows for two succe

275 Here, the oxidation of cyclohexane to cyclohexanol and cyclohexanone is used as

276 tic performance achieved in the oxidation of cyclohexane to cyclohexanone/cyclohexanol (100 degrees C

277 e 2b reacts with the unactivated CH bonds of cyclohexane to form adduct 8b in 46% yield.

278 lyzed oxidative dehydrogenative amination of cyclohexane to generate a mixture of N-alkyl and N-allyl

279 city, spanning an overall range from 363 nm (cyclohexane) to 595 nm (acetonitrile).

280 ion energies ranging from 99.3 kcal mol(-1) (cyclohexane) to 84.5 kcal mol(-1) (cumene).

281 c structures (cyclobutane, cyclopentane, and cyclohexane) to improve tRNA charging.

282 ications and demonstrates the possibility of cyclohexane-to-benzene conversions under relatively mild

283 hobicity, but when free energies of vapor-to-cyclohexane transfer (corresponding to size) are taken i

284 with DBU, followed by hydrogenation, gave a cyclohexane triflate, which, on fluorination, gave the a

285 ) model complexes produces 6-membered FeS2C3 cyclohexane-type rings that produce substantial distorti

286 nd 97.5% selective for hydrodeoxygenation to cyclohexane under mild conditions in a batch reaction; t

287 and tetramethylethylene in water, DMSO, and cyclohexane using novel 3-dimensional potentials of mean

288 1-(Chloromethylidene)-4-tert-butyl-cyclohexane was also coupled with thiols, giving the tar

289 duct selectivity than their constituents; no cyclohexane was produced, while benzene was the dominant

290 nsistent with product studies (ethanol-OD in cyclohexane) which indicate that there is an approximate

291 eacts with solvents such as acetonitrile and cyclohexane, while t-butyloxycarbonylnitrene undergoes a

292 served for the C-H bonds of cyclopentane and cyclohexane, while the tertiary C-H bond of methylcyclop

293 essed in the catalytic C-H etherification of cyclohexane with (t)BuOO(t)Bu at rt employing [Cu(I)] (5

294 This generates a cyclohexane with a high molecular dipole (mu = 6.2 D), u

295 l was evidenced by the catalytic reaction of cyclohexane with benzamide in the presence of CBr4, whic

296 Separate reactions of cyclohexane and d12-cyclohexane with benzamide showed that the turnover-limi

297 A set of spirocyclic cyclohexanes with diverse O-heterocycles and amino moiet

298 idation of the substrates, benzphetamine and cyclohexane, with rate constants of 18 +/- 2 and 29 +/-

299 s catalytic activity toward the oxidation of cyclohexane, with turn-over numbers, to the best of our

300 ination of a variety of hydrocarbons such as cyclohexane without the need of prefunctionalization or