ライフサイエンスコーパス: cyclohexene

1 otetramerization occurs giving a substituted cyclohexene.

2 obutane and its structural isomerizations to cyclohexene.

3 while in contact with a solution of EtOH and cyclohexene.

4 ctural isomerizations of vinylcyclobutane to cyclohexene.

5 st for 1BpCMe relative to reaction with neat cyclohexene.

6 favored boat-like transition state leads to cyclohexene.

7 f toluene, ethylbenzene, cumene, indene, and cyclohexene.

8 during the catalytic bromoesterification of cyclohexene.

9 ma-dehydrogenation to form chiral beta,gamma-cyclohexene.

10 n over allylic oxidation in the oxidation of cyclohexene.

11 a majority of cyclohexanol is dehydrated to cyclohexene.

12 emonstrated for a diene and a trisubstituted cyclohexene.

13 n, butadiene and ethylene combine to produce cyclohexene.

14 of Mo-SIM was tested for the epoxidation of cyclohexene.

15 discrete stereoisotopomers of functionalized cyclohexenes.

16 iaries provided access to chiral, nonracemic cyclohexenes.

17 dol cascade is an underdeveloped approach to cyclohexenes.

18 iastereoselective double Heck cyclization of cyclohexenes 1 and 3 that form contiguous quaternary ste

19 electivity for epoxide (CzFe(III)/C(6)F(5)IO/cyclohexene (1:100:1000) in CH(2)Cl(2)/CH(3)OH (3:1 v:v)

20 (2)C) with six alkenes (tetramethylethylene, cyclohexene, 1-hexene, methyl acrylate, acrylonitrile, a

21 bitor, guanosine 5'-[1D-(1,3,4/2)-5-methyl-5-cyclohexene-1,2,3,4-tetrol 1-diphosphate] (1) have been

22 effects on the (13)C NMR chemical shifts of cyclohexene-1,2-dicarboxylate monoanion in chloroform-d

23 he symmetry of the hydrogen bond in hydrogen cyclohexene-1,2-dicarboxylate monoanion was determined i

24 e racemic 1,2-syn-2,3-anti-3-(hydroxyaryl)-4-cyclohexene-1,2-diols, whereas exhaustive osmoylation gi

25 2-Alkylated cyclohexene-1,4-diones were obtained when the 1,4-quinon

26 ,4-Grignard addition-methylations to 3-oxo-1-cyclohexene-1-carbonitrile.

27 m(II)-catalyzed oxidative dehydrogenation of cyclohexene-1-carbonyl indole amides yielding the corres

28 is solvent system naphthalene and 3-methyl-2-cyclohexene-1-one were reduced to isotetralin (74%) and

29 e epoxidation (323 K, 0.05 mM Ti(IV), 160 mM cyclohexene, 24 mM tert-butyl hydroperoxide) are 9 +/- 2

30 xene epoxidation and hydroxylation to give 1-cyclohexene-3-ol, and cis- or trans-butene epoxidation (

31 (R) derivatives of 1-thyminyl and 9-adeninyl cyclohexene: 3 --> T-4a + T-4b and 3 --> A-5a + A-5b.

32 Vicinal dibromide 30b gave the Zaitsev cyclohexene 45 as the only product.

33 yl cyclobut-1-ene-1,2-dicarboxylate (1) with cyclohexene (7) afforded two photoadducts 8 and 9 in 44%

34 3LYP theory) to be 62.4 kcal/mol, with trans-cyclohexene (7) lying 53.3 kcal/mol above cis isomer 9.

35 s-trans-1,3-butadiene (1) should yield trans-cyclohexene (7), just as reaction of the s-cis conformer

36 The barrier to pi-bond rotation in cis-cyclohexene (9) is predicted (B3LYP theory) to be 62.4 k

37 as reaction of the s-cis conformer gives cis-cyclohexene (9).

38 CIs from the ozonolysis of cyclohexene, acting as surrogate for cyclic terpenes, ar

39 At 100 K, cyclohexene adsorbs as intact di-sigma bonded cyclohexen

40 rom a mixture of the seven deuterium-labeled cyclohexenes allow quantitative analytical assessments o

41 Four cyclohexene analogues of gamma-aminobutyric acid (GABA)

42 uated a novel series of fluorine-substituted cyclohexene analogues, thereby identifying 8 and 9 as no

43 of enthalpic barriers for CCl2 additions to cyclohexene and 1-hexene.

44 The catalytic hydrogenation of cyclohexene and 1-methylcyclohexene is investigated expe

45 long with decreased allylic hydroxylation of cyclohexene and butene.

46 Fully deuterated cyclohexene and cis-6-nonenal ozonolysis, as well as the

47 ions between thiiranium ion 11 (m/z 213) and cyclohexene and cis-cyclooctene resulted in the formatio

48 The lifetime of 1BpCMe is the same in cyclohexene and cyclohexane.

49 exenone and cyclopentenone) and symmetrical (cyclohexene and cyclopentene) ethene bridges.

50 with respect to increasing concentrations of cyclohexene and H2O2.

51 d similar to that found in the ozonolysis of cyclohexene and limonene.

52 shifts leading to carbene intermediates from cyclohexene and norbornene have been studied using CASSC

53 rifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics.

54 Bronsted acid sites hinder the adsorption of cyclohexene and the formation of a carbenium ion.

55 .0]nonane complex remains in the presence of cyclohexene and the ring contracts to yield methylenecyc

56 y phosphine oxides gives 3,4-bis(phosphinoyl)cyclohexenes and 2,3-bis(phosphinoyl)cyclohexenes throug

57 nd selective access to highly functionalized cyclohexenes and cyclohexadienes and is orthogonal to ex

58 ed by mixtures of the four isomeric 3,4-d(2)-cyclohexenes and the three isomeric 3,6-d(2)-cyclohexene

59 nd 3,5-dinitro-PhCCl to tetramethylethylene, cyclohexene, and 1-hexene have been determined in decane

60 tions to three alkenes (tetramethylethylene, cyclohexene, and 1-hexene).

61 (3,5-DN-PhCCl) to tetramethylethylene (TME), cyclohexene, and 1-hexene.

62 nes such as trans-methylstilbene, 1-methyl-1-cyclohexene, and 2,3-dimethyl-2-butene, representing one

63 ethylsilyloxy)ethylene, 1-(trimethylsilyloxy)cyclohexene, and 2-(trimethylsilyloxy)furan underwent cl

64 moallylic amines (derived from cyclopentene, cyclohexene, and cycloheptene) have been investigated, a

65 alytic behavior, hydrogenations of ethylene, cyclohexene, and cyclooctene as model reactions were car

66 n part by design since only acetone solvent, cyclohexene, and H(2) are possible ligands in the result

67 ation reactions of styrene, phenylacetylene, cyclohexene, and hex-5-en-2-one in a microfluidic contex

68 for styrene, k = 2.5 x 10(6) M(-1) s(-1) for cyclohexene, and k = 7.7 x 10(4) M(-1) s(-1) for ethylbe

69 are also effective in selective oxidation of cyclohexene, and that solubilized Pt clusters are also c

70 f Delta(f)H298 for monosubstituted benzenes, cyclohexenes, and cyclohexanes, 24 of which are not in t

71 reactive site but different molecular size (cyclohexene approximately 0.5 nm, cholesteryl acetate ap

72 In total, 52 unique stereoisotopomers of cyclohexene are available, in the form of ten different

73 s between this substituent and the C3 of the cyclohexene are avoided in the favored insertion topogra

74 The SE for E-cycloheptene and E-cyclohexene are calculated to be 25.2 and 49.3 kcal/mol

75 t the adsorption and subsequent reactions of cyclohexene are unique on the monolayer Ni surface as co

76 relative to the corresponding 4-substituted cyclohexenes are presented for benzene, toluene, aniline

77 zed the dehydrogenation and hydrogenation of cyclohexene as probe reactions to compare the chemical r

78 We use substituted cyclohexenes as analogues for atmospherically important

79 In addition, complex 2 reacts with excess cyclohexene at -42 degrees C to give 1.

80 Based on these advantages, diene- and cyclohexene-based nucleotide triphosphates are expected

81 Polysubstituted cyclohexenes bearing 1,3 (meta) substitution patterns ar

82 Derivatizations avail cyclohexenes bearing four contiguous stereogenic centers

83 ization of alpha,omega-heptadienes to afford cyclohexenes bearing quaternary carbon centers.

84 Kinetic studies on the oxidations of cyclohexene, benzyl alcohol, phenol, and trans-stilbene

85 d with the first-order transition states for cyclohexene boat-to-boat inversions enables quantificati

86 ns of the E and the configurationally stable cyclohexene-bridged Z-derivatives are spin-delocalized o

87 the enantiomerically pure cyclopentenone and cyclohexene building blocks 5 and 6, which constitute A

88 roduct when the photolysis is carried out in cyclohexene but the carbene-alkene cycloadduct could be

89 mal reactions converting vinylcyclobutane to cyclohexene, butadiene, and ethylene.

90 us oxidations of a substituted phenol and of cyclohexene by molecular O(2) using transition metal cat

91 dized organic compounds in the ozonolysis of cyclohexene (C6H10) was investigated by means of laborat

92 tion enthalpy of benzene relative to that of cyclohexene, called for many years the "resonance energy

93 exene carbonate) and the cyclic side product cyclohexene carbonate are calculated, by determining the

94 f poly(cyclohexene carbonate-b-decalactone-b-cyclohexene carbonate) [PCHC-PDL-PCHC].

95 ctivation energies for the formation of poly(cyclohexene carbonate) and the cyclic side product cyclo

96 aterials improve upon the properties of poly(cyclohexene carbonate) and, specifically, they show good

97 as a renewable chain transfer reagent, poly(cyclohexene carbonate) polyols are synthesized with high

98 spectrometry are employed to study the poly(cyclohexene carbonate) produced, and reveal bimodal mole

99 n the case of CHO perfectly alternating poly(cyclohexene carbonate) were obtained and TON values were

100 ioxide and cyclohexene oxide to produce poly(cyclohexene carbonate), catalyzed by a dizinc acetate co

101 nd one of the most widely investigated, poly(cyclohexene carbonate), is limited by its low elongation

102 and carbon dioxide to make a series of poly(cyclohexene carbonate-b-decalactone-b-cyclohexene carbon

103 Biaryl cyclohexene carboxylic acids were discovered as full and

104 In the case of cyclohexene, complex 1 performs on a par with one of the

105 Analogous eta(2)-ethylene and eta(2)-cyclohexene complexes were also synthesized, and the lat

106 ng cis-3,4- and cis-3,6-disubstituted eta(2)-cyclohexene complexes were prepared with high regio- and

107 These TAK-242-based cyclohexene compounds demonstrated robust reactivity, an

108 ) was observed in monosubstituted alkene and cyclohexene concentrations.

109 Additionally, HSA-cyclohexene conjugates maintained higher levels of stabi

110 ng a mixture of vinylcyclobutane (2 + 2) and cyclohexene-containing cycloadducts (4 + 2).

111 y transformation in the biosynthesis of many cyclohexene-containing secondary metabolites.

112 )) added stereospecifically to cyclopentene, cyclohexene, cycloheptene, and 1,5-cyclooctadiene to giv

113 ween the ion 5 (m/z = 261) and cyclopentene, cyclohexene, cycloheptene, and cyclooctene resulted in t

114 ies for pi-ligand exchange for cyclopentene, cyclohexene, cycloheptene.

115 At 281 K, cyclohexene dehydrogenates upon adsorption, forming adso

116 1 from Eyring plots for the hydrogenation of cyclohexene (DeltaG() = 17.2 +/- 1.0 kcal/mol) and 1-met

117 ation of cyclobutene 1-carboxylic esters and cyclohexene derivatives with the precatalyst [(H(2)IMes)

118 ns to access a range of valuable substituted cyclohexene derivatives.

119 erived allylic amines as compared with their cyclohexene-derived allylic and homoallylic amine counte

120 tigations indicate a different reactivity of cyclohexene-derived CIs compared with that of simple CIs

121 ficantly influences the CI reactivity of the cyclohexene-derived CIs.

122 to the formation of previously inaccessible cyclohexene-derived silacyclopropanes.

123 undergo hydrogenation much more readily than cyclohexene, despite the less favorable thermodynamics o

124 astereoselective double Heck cyclizations of cyclohexene diamides 1 and 3 form contiguous quaternary

125 N,N'-bis(3,5-di-tert-butyl-salicylidene)-1,2-cyclohexene diamine, has been shown to be an effective c

126 entyne, but those involving spirodiene 2 and cyclohexene do.

127 epared from the pendent alkenyl chain of the cyclohexene domain was reacted with the (E)-iodoalkene a

128 and R,R-1,2-di(2'-diphenylphosphinobenzamido)cyclohexene efficiently induced the alkylation process w

129 ype-(i) environments, the rate constants for cyclohexene epoxidation (323 K, 0.05 mM Ti(IV), 160 mM c

130 that these group IV and V materials catalyze cyclohexene epoxidation and H2O2 decomposition through l

131 Styrene epoxidation, cyclohexene epoxidation and hydroxylation to give 1-cycl

132 ng TiSi3 on the SBA-15 affords highly active cyclohexene epoxidation catalysts (0.25-1.77 wt % Ti loa

133 Kinetic analyses of cyclohexene epoxidation confirmed that the active sites

134 numbers greater than four, and 20-fold lower cyclohexene epoxidation rate constants (per Ti) than on

135 d with a silanol on a SiO2 surface increases cyclohexene epoxidation rates with tert-butyl hydroperox

136 The reaction kinetics of cyclohexene epoxidation using aqueous H2O2 oxidant and t

137 ants were independent of surface density for cyclohexene epoxidation with tert-butyl hydroperoxide (1

138 The carboborative ring contraction of cyclohexenes exhibits an abnormal selectivity pattern in

139 s employed for synthesis of activated 2-halo-cyclohexene F-ring fragments.

140 ion provides good yields of optically active cyclohexenes featuring diverse substitution patterns and

141 (R) derivatives of 1-thyminyl and 9-adeninyl cyclohexene from 3 is most probably a rearrangement mech

142 ohexanol from cyclohexane hydroxylation, and cyclohexene from cyclohexane carboxaldehyde deformylatio

143 Removal of the volatile cyclohexene from the reaction mixture into an evacuated

144 for the synthesis of di- and trisubstituted cyclohexenes from an arene.

145 mical methodology to access substituted acyl-cyclohexenes from pentamethylacetophenone and 1,5-diols

146 cid fluorides and TMS dienol ethers provides cyclohexene fused beta-lactone intermediates stable belo

147 ong one-electron oxidant, in the presence of cyclohexene gives an efficient synthetic route to 1,2-su

148 Interestingly, treatment of 1 with cyclohexene gives cyclohexane and 4 via a titanium-media

149 reagents to produce diastereomerically pure cyclohexenes (>20:1 dr) with up to four contiguous stere

150 A wide range of cyclohexenes (>40 examples) have been prepared, many in

151 gh oxidative dehydrogenation (ODH) of phenyl cyclohexene has been investigated.

152 cyclohexenes and the three isomeric 3,6-d(2)-cyclohexenes has been solved through a novel one-dimensi

153 ghly strained cyclopropene to the unstrained cyclohexene, have been studied with density functional t

154 ived catalyst in the simple test reaction of cyclohexene hydrogenation and in comparison to two liter

155 However, the same methods reveal that the cyclohexene hydrogenation catalyst derived from 1 at the

156 problem of identifying the true benzene and cyclohexene hydrogenation catalysts derived from [Rh(eta

157 old question of whether the true benzene and cyclohexene hydrogenation catalysts derived from the org

158 st could be successfully monitored by a fast cyclohexene hydrogenation catalytic reporter reaction me

159 s were also successfully monitored using the cyclohexene hydrogenation reporter reaction method previ

160 Different activation energies for cyclohexene hydrogenation were obtained for nanostructur

161 lifetime (> or = 220,000 total turnovers of cyclohexene hydrogenation) are observed, in part by desi

162 ults show high activity for the ethylene and cyclohexene hydrogenations but not in the cyclooctene hy

163 glet fluorenylidene reacts with methanol and cyclohexene in competition with relaxation to 3Fl.

164 yzed phenol alkylation with cyclohexanol and cyclohexene in the apolar solvent decalin has been studi

165 tive bromine species that can be captured by cyclohexene in two-phase systems.

166 d the Heck reaction between dihydrofuran and cyclohexene in up to 86% ee.

167 ra substituents hydroaminate olefins such as cyclohexene in yields greater than 95% at 90 degrees C.

168 al assessments of the four possible 3,4-d(2)-cyclohexenes in the mixture.

169 generate a wide variety of amine-substituted cyclohexenes including new hydrindan and decalin derivat

170 The faster k(pol) value for the 5-cyclohexene-indole derivative indicates that pi-electron

171 ic efficiency for the incorporation of the 5-cyclohexene-indole derivative opposite an abasic site is

172 olled synthesis of the highly functionalized cyclohexene inhibitor that features an asymmetric aldol

173 -Br(-) system generated a gas that converted cyclohexene into 1-bromo-2-chlorocyclohexane, implicatin

174 The partial hydrogenation of benzene to cyclohexene is an economically interesting and technical

175 Cyclohexene is converted into enantiomerically pure cis-

176 Above ~80 degrees C, cyclohexene is ejected to give W(NAr)(OSiPh(3))(2)(C(2)H

177 uilibrium, a secondary product, cyclohexyl-1-cyclohexene is formed.

178 s directly formed in a protonation step when cyclohexene is the coreactant.

179 iazeniumdiolate derived from 1-(N-morpholino)cyclohexene is unique among the new compounds in that it

180 HREELS and NEXAFS studies show that cyclohexene is weakly pi-bonded on monolayer Ni/Pt(111)

181 ynthesis of functionalized cyclopentenes and cyclohexenes is described.

182 The catalytic dehydrogenation of cyclohexenes is showcased in an efficient route to a pht

183 reactions were performed in cyclohexane and cyclohexene, isomerization of 3 was favored.

184 asymmetric epoxidation of cyclic enones and cyclohexene ketones with aqueous hydrogen peroxide, prov

185 leotide carrying a peptide via a Diels-Alder cyclohexene linkage was prepared and sequence-specifical

186 While it has long been speculated that the cyclohexene moiety found in many secondary metabolites i

187 m the inability of the cyclobutene ester and cyclohexene monomers to undergo homopolymerization in co

188 2)Cl(2) solvent reveal that DMDO reacts with cyclohexene much faster than peracetic acid/acetic acid

189 ds (FANAs), hexitol nucleic acids (HNAs) and cyclohexene nucleic acids (CeNAs), which require approxi

190 acids, FANA; hexitol nucleic acids, HNA; and cyclohexene nucleic acids, CeNA) directly from random XN

191 as the stable end products, with benzene and cyclohexene observed as intermediates.

192 ard enthalpy of formation of di-sigma bonded cyclohexene on Pt(111) at low coverages of -135 kJ/mol a

193 s below 0.10 ML, the sticking probability of cyclohexene on Pt(111) is close to unity (>0.95), indepe

194 at of adsorption and sticking probability of cyclohexene on Pt(111) were measured as a function of co

195 yclohexene adsorbs as intact di-sigma bonded cyclohexene on Pt(111), and the heat of adsorption is we

196 f precursor porphyrins, annealed with either cyclohexene or dihydronaphthalene fragments.

197 ding on the nature of the substrate (ethene, cyclohexene, or diethyl 2-benzylidenesuccinate) and the

198 Copolymerizations of cyclohexene oxide (CHO) and CO2 with (BDI-1)ZnX [(BDI-1)

199 and copolymerization behavior with CO(2) and cyclohexene oxide (CHO) are reported.

200 liodonium-induced cationic polymerization of cyclohexene oxide (CHO) or THF.

201 mers made of CO2 and propylene oxide (PO) or cyclohexene oxide (CHO) were indeed obtained.

202 rizations of (rac)-beta-butyrolactone (BBL), cyclohexene oxide (CHO), and carbon dioxide were realize

203 The mechanism of the copolymerization of cyclohexene oxide and carbon dioxide to afford poly(cycl

204 be an effective catalyst for the coupling of cyclohexene oxide and carbon dioxide to afford poly(cycl

205 nesium catalysts for the copolymerization of cyclohexene oxide and carbon dioxide, active under just

206 Near-quantitative yields of cyclohexene oxide and the ring-opened 1,2-cyclohexanedio

207 ocatalyst in the copolymerization of CO2 and cyclohexene oxide catalyzed by chromium salen derivative

208 arbonate selectivity) for carbon dioxide and cyclohexene oxide copolymerization.

209 nium salts toward the photopolymerization of cyclohexene oxide depend on the counterion and the sulfo

210 d as a tool for access to highly substituted cyclohexene oxide derivatives.

211 of 2-cyclohexenone and 2-cycloheptenone open cyclohexene oxide in 60-62% yields and with 32-95:1 dias

212 Cyclohexene oxide is known to rearrange via a syn beta-e

213 he reaction of carbon dioxide with epoxides (cyclohexene oxide or propylene oxide) using the (salen)C

214 Cyclohexene oxide polymerization could be "switched off"

215 f the copolymerization of carbon dioxide and cyclohexene oxide to produce poly(cyclohexene carbonate)

216 ere synthesized via the terpolymerization of cyclohexene oxide with a mixture of CO(2) and COS in the

217 A common reaction pathway for alicyclic (cyclohexene oxide) and aliphatic (propylene oxide) carbo

218 ferent classes of epoxides, i.e., alicyclic (cyclohexene oxide) and aliphatic (propylene oxide).

219 r 1 h, resulting in a 78% conversion to poly(cyclohexene oxide) with an average molecular weight (MW)

220 xide, butylene oxide, isobutylene oxide, and cyclohexene oxide).

221 In solutions containing cyclohexene oxide, [CpFebz]+ generates several photoprod

222 n of 17AAG with human hepatic microsomes and cyclohexene oxide, a known inhibitor of microsomal epoxi

223 zinc catalyst and a mixture of caprolactone, cyclohexene oxide, and carbon dioxide enables the select

224 together with biobased epsilon-decalactone, cyclohexene oxide, and carbon dioxide to make a series o

225 ethenation of benzene, the polymerization of cyclohexene oxide, and the oligomerization of ethene to

226 xides at ambient conditions, specifically to cyclohexene oxide, indicating that the structure of HPs

227 of four model monomers-epsilon-caprolactone, cyclohexene oxide, phthalic anhydride, and carbon dioxid

228 catalyst concentration and concentration of cyclohexene oxide.

229 , is only a weak Lewis acid, and polymerizes cyclohexene oxide.

230 Unlike the cyclohexene oxide/carbon dioxide reaction catalyzed by c

231 As previously demonstrated for the cyclohexene oxide/CO(2) reaction in the presence of comp

232 nones nucleophilically open cyclopentene and cyclohexene oxides in 57-76% yields and with 4-8:1 diast

233 catalyzed isomerization of cyclopentene- and cyclohexene oxides.

234 Deuterated cyclohexene ozonolysis resulted in a less oxidized produ

235 1 in monomers and O/C > 0.55 in dimers) from cyclohexene ozonolysis was determined as (4.5 +/- 3.8)%.

236 ylation of monosubstituted cyclopentenes and cyclohexenes proceeds with excellent regio- and diastere

237 ucts and a wide range of functionalized acyl-cyclohexene products can be synthesized using this metho

238 The highly substituted cyclohexene products could be functionalized stereoselec

239 latter species led to cis-3,5-disubstituted cyclohexene products exclusively.

240 Oxidative decomplexation afforded the free cyclohexene products in moderate yield (37-68%).

241 d by a beta-dicarbonyl Michael donor to form cyclohexene products.

242 In contrast, a trapping experiment with cyclohexene provided no evidence to support an alternati

243 [graph: see text] The vinylcyclobutane-cyclohexene rearrangement has been studied computational

244 A high-yielding base-mediated dihydropyran-cyclohexene rearrangement of 9-deacetoxy-14,15-deepoxyxe

245 cycloaddition followed by a vinylcyclobutane-cyclohexene rearrangement.

246 ies of 57 and 62 kJ/mol for cyclopentene and cyclohexene, respectively, with transition states for pi

247 of 17.8 and 19.3 kJ/mol for cyclopentene and cyclohexene, respectively.

248 cycloalkenes increases from cyclopropene to cyclohexene, resulting in an increase in activation barr

249 de reagents, the deuterated positions on the cyclohexene ring can be controlled precisely.

250 talytic system progressively desaturates the cyclohexene ring en route to the aniline.

251 Halogen exchange and cyclohexene ring epoxidation were well tolerated, while

252 ylate, resulting in a densely functionalized cyclohexene ring formation.

253 transannular [4+2] cycloaddition to form the cyclohexene ring in spinosyn A.

254 o calculate the possible orientations of the cyclohexene ring in the membrane.

255 is a [4+2] cycloaddition reaction in which a cyclohexene ring is formed between a 1,3-diene and an el

256 carotenols, where Glc is bound either to the cyclohexene ring or the butane side chain.

257 ted enyne-allenes, fused to cyclopentene and cyclohexene ring systems, were synthesized and treated w

258 ne of the geminal methyl groups on C1 of the cyclohexene ring.

259 ents at 2' (R2) and 3' (R1) positions on the cyclohexene ring.

260 ent at each position around the newly forged cyclohexene ring.

261 ents at 2' (R1) and 3' (R2) positions on the cyclohexene ring] as cancer chemopreventive agents.

262 e olefin metathesis reaction to deliver both cyclohexene rings of the target.

263 influenza neuraminidase inhibitors with the cyclohexene scaffold containing lipophilic side chains h

264 , cyclopentene, 1,4-cyclohexadiene (CHD), or cyclohexene-showed that, with the exception of cyclohexe

265 The kinetic order in cyclohexene silacyclopropane 1 and cyclohexene were dete

266 Kinetic studies of the reactions of cyclohexene silacyclopropane 1 and monosubstituted alken

267 nd thermodynamic studies of the reactions of cyclohexene silacyclopropane 1 and monosubstituted alken

268 Di-tert-butylsilylene was transferred from cyclohexene silacyclopropane 1 to an alkene through the

269 The kinetic order in cyclohexene silacyclopropane 1 was determined to be one.

270 antially decreases the binding energy of the cyclohexene species which desorb from the cluster at low

271 A cyclohexene subunit corresponding to the C1-C8, C19-C24

272 In contrast, poly(cyclohexene sulfone) appears as a collection of Pt-C-coa

273 ions of poly(1-tetradecene sulfone) and poly(cyclohexene sulfone) cast from very dilute solutions (0.

274 In cyclohexene, the lifetime of 1BpCH is shortened relative

275 11) surface to D2 prior to the adsorption of cyclohexene, the total yield of the normal and deuterate

276 clohexene-showed that, with the exception of cyclohexene, they react readily, affording C-H activatio

277 e Diels-Alder reactions of the cycloalkenes, cyclohexene through cyclopropene, with a series of diene

278 phinoyl)cyclohexenes and 2,3-bis(phosphinoyl)cyclohexenes through an in situ isomerization of one of

279 on pathway for the complete decomposition of cyclohexene to atomic carbon and hydrogen, which has a s

280 nonane complex forms slowly upon addition of cyclohexene to the ethylene complex, W(NAr)(OSiPh(3))(2)

281 d for aerobic dehydrogenation of substituted cyclohexenes to the corresponding arene derivatives.

282 sing hydrogenation of the hydrogen acceptor (cyclohexene) to generate a Rh(I)-silyl species, followed

283 ng the intermolecular sp(3) C-H amination of cyclohexene using unprotected anilines to provide access

284 ohexylidene complex could also form from two cyclohexenes via a newly proposed "alkyl/allyl" mechanis

285 Cyclohexene was reduced to cyclohexane by 8 at 80 degree

286 s well as in their subsequent epoxidation of cyclohexene, was examined in aqueous acetonitrile.

287 order in cyclohexene silacyclopropane 1 and cyclohexene were determined to be 1 and -1, respectively

288 The reaction pathways of cyclohexene were investigated using temperature-programm

289 aromatization agent was used, the elaborated cyclohexenes were able to be synthesized in enantioenric

290 but not bulkier alkenes such as 2-butene or cyclohexene, were catalyzed by 1-H+ and the edt (SCH2CH2

291 xidative cleavage of extensively substituted cyclohexenes, which have in turn been assembled in a ste

292 ivity and selectivity for the epoxidation of cyclohexene with cumene hydroperoxide as oxidant.

293 rimer effect" observed in the bromination of cyclohexene with H(2)O(2) and NaBr catalyzed by the addi

294 ion energy DeltaG() for the hydrogenation of cyclohexene with precatalyst 2 was determined to be 21.1

295 group in cyclohexanol and the double bond in cyclohexene with respect to the (13) C label.

296 nstrate a four-step conversion of benzene to cyclohexene with varying degrees of deuterium incorporat

297 hich was elaborated into cyclohexadienes and cyclohexenes with ee's ranging from 92 to 99%.

298 o-1,3-diene, affording highly functionalized cyclohexenes with high endo diastereoselectivity.

299 y of 1,3-disubstituted and 1,6-disubstituted cyclohexenes with the stereogenic centers at allylic pos

300 eaction that generates highly functionalized cyclohexenes with up to four stereocenters, in up to 97%