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1 ty as hydrogenation catalysts for hexene and cyclooctene.
2 though they are not directly attached to the cyclooctene.
3 llylic C-H bonds, going from cyclopentene to cyclooctene.
4 polymerization of an industrial monomer, cis-cyclooctene.
5 on Grubbs catalyst in the ethenolysis of cis-cyclooctene.
6 oss-metathesis of Z-1,2-dichloroethylene and cyclooctene.
7 cycloaddition reactions faster than a trans-cyclooctene.
8 c alkenes such as 1,5-cyclooctadiene and cis-cyclooctene.
9 60 times more reactive than the parent trans-cyclooctene.
10 e and 3.1 kcal/mol lower for reaction with E-cyclooctene.
11 he ene reaction of singlet oxygen with trans-cyclooctene.
12 ed ring-opening metathesis polymerization of cyclooctenes.
13 cycloaddition with dienophiles such as trans-cyclooctenes.
14 thogonal reaction between azides and alkynes/cyclooctenes.
15 AEMs from the living polymerization of trans-cyclooctenes.
16 addition of s-tetrazines with strained trans-cyclooctenes.
17 ctyne is 2.0 kcal/mol greater than that of E-cyclooctene (17.9 kcal/mol) but only 7.7 kcal/mol greate
19 equimolar mixture of cis-2-octene 20 and cis-cyclooctene 21 via promotion of the transformation in it
20 ering cis-cyclooctene (COE) and 3-methyl-cis-cyclooctene (3MCOE) as monomers and W(N-t-Bu)(CH-t-Bu)(O
21 The A:B monomer pairs copolymerized by 1 are cyclooctene (A):2,3-dicarbomethoxy-7-isopropylidenenorbo
23 t metallic gold surfaces, proceeding through cyclooctene activation, while epoxidation at gold oxide
24 ism, wherein the roles are reversed, a trans-cyclooctene activator reacts with a tetrazine linker tha
25 zine-linked antibody-drug conjugate by trans-cyclooctenes, affording efficient drug liberation in pla
26 99% syndiotactic poly(DCMNBD), while ROMP of cyclooctene and 1,5-cyclooctadiene (300 equiv) with init
31 oorthogonal cleavage reaction based on trans-cyclooctene and tetrazine, which allows the use of highl
34 o give first (PNP)ReH(2)(eta(2)-pyridyl) and cyclooctene and then, when not sterically blocked, (PNP)
35 markers of interest were modified with trans-cyclooctene and used as scaffolds to couple tetrazine-mo
36 actions of strained alkenes, including trans-cyclooctenes and norbornenes, with tetrazines, the BCN-t
37 mand Diels-Alder cycloaddition between trans-cyclooctenes and tetrazines is biocompatible and excepti
38 (300 equiv) with initiator 2a leads to poly(cyclooctene) and poly(cyclooctadiene) that have cis cont
40 dienophiles such as cyclopropenes and trans-cyclooctenes, and we demonstrate their application for l
41 eveal an overall reaction in which water and cyclooctene are converted to cyclooctene oxide and hydro
42 the trans-five-membered cyclic acetal fused cyclooctenes are found to reduce the ceiling temperature
43 }(C(8)H(14))(2)] precursors (C(8)H(14) = cis-cyclooctene), are air-sensitive, and can be electrochemi
45 hydrogenations of ethylene, cyclohexene, and cyclooctene as model reactions were carried out over the
46 wing that the use of a highly reactive trans-cyclooctene as the activator leads to a complete cycload
47 elerated click reaction with cleavable trans-cyclooctenes, as exemplified by click-triggered activati
49 we study the electrocatalytic epoxidation of cyclooctene at the surface of gold in hybrid organic/aqu
50 emand Diels-Alder cycloaddition with a trans-cyclooctene attached to 6-(18)F-fluoronicotinoyl moiety
51 Here, we address this challenge by using a cyclooctene-based depolymerization system, in which the
52 ng state as [Ir(dtbpy)(COE)(Bpin)(3)] (COE = cyclooctene, Bpin = 4,4,5,5-tetramethyl-1,3,2-dioxaborol
54 tathesis polymerization of 3-substituted cis-cyclooctenes by monoaryloxide pyrrolide imido alkylidene
55 ent hemicyanine and doxorubicin from a trans-cyclooctene-caged prodrug to detect and eliminate senesc
57 rong confinement effect was observed for cis-cyclooctene (cCOE), 1,5-cyclooctadiene (COD), (+)-2,3-en
58 ries such as azide-cyclooctyne and tetrazine-cyclooctene chemistries only allow for one-time use of c
59 ons occur with a catalyst generated from [Ir(cyclooctene)Cl]2, sterically hindered and electron-rich
60 ine-triggered elimination of cleavable trans-cyclooctenes (click-to-release) stands out due to high r
63 s ferrocene was applied to a solution of cis-cyclooctene (COE) in dichloromethane/[NBu(4)][B(C(6)F(5)
64 ective (p-XPCP)IrH(2) complexes 4a-f and the cyclooctene (COE) olefin complexes (p-XPCP)Ir(COE) (6a-f
65 n, Ru1 was evaluated using norbornene (NBE), cyclooctene (COE), and cyclooctadiene (COD) as model sub
66 etathesis polymerization (ROMP) reactions of cyclooctene (COE), bulk-ROMP reactions of COE and norbor
67 y activated and covalently modified by trans-cyclooctene conjugates of small molecules, peptides, and
68 a BCN-containing amino acid, 1, and a trans-cyclooctene-containing amino acid 2 (which also reacts e
69 thod is based on two novel reagents: a trans-cyclooctene-containing ceramide lipid (Cer-TCO) and a hi
71 able discovery that bulky, hydrophilic trans-cyclooctene-containing primary alcohols can supplant wat
74 stigation of the transannular cyclization of cyclooctene, cyclodecene, and cycloundecene derivatives
77 cid ligase site-specifically ligates a trans-cyclooctene derivative onto a protein of interest in the
79 bioorthogonal and mutually orthogonal: trans-cyclooctene derivatives greatly prefer to react with tet
80 e containing cyclopentene, cycloheptene, and cyclooctene derivatives in good to excellent yields.
85 yclooctene reduces the ring strain energy of cyclooctene, enabling the corresponding polymers to depo
86 functionalized by dihydrotetrazine and trans-cyclooctenes, enabling 3D culture of human prostate canc
88 t a sacrificial mechanism is responsible for cyclooctene epoxidation at metallic gold surfaces, proce
89 n conducted of the mechanism and kinetics of cyclooctene epoxidation by hydrogen peroxide catalyzed b
90 de nanoparticles (NPs) are shown to catalyze cyclooctene epoxidation with Faradaic efficiencies above
92 de, whereas the other diastereomer undergoes cyclooctene formation via an ene-ene RCM, likely lies in
95 e responses to the ethylene antagonist trans-cyclooctene, have mutations in the RAN1 copper-transport
97 change in mechanism arises because the trans-cyclooctene imposes a substantial strain in the transiti
98 n be switched off upon the addition of trans-cyclooctene in live cells, converting the dynamic thiome
99 ligated to a conformationally strained trans-cyclooctene in vitro and in vivo with reaction rates sig
100 usefully functionalized derivatives of trans-cyclooctene, including a derivative of 5-aza-trans-cyclo
103 hich allows the use of highly reactive trans-cyclooctenes, leading to 3 orders of magnitude higher cl
106 d and synthesized a new C(2)-symmetric trans-cyclooctene linker (C(2)TCO) that exhibits excellent bio
107 eaction between an allylic substituted trans-cyclooctene linker and a tetrazine activator has enabled
109 thermodynamics relationships of a series of cyclooctene monomers that contain an additional ring fus
111 l is strongly suggested by the conversion of cyclooctene monoxide to an aryl [3.3.0]bicyclooctanol.
112 )imidazol-2-carbene, py = pyridine, olefin = cyclooctene or ethylene) are highly active catalysts for
115 rmation of thioanisole oxide (100% yield) or cyclooctene oxide (30% yield), respectively; thus [Fe(IV
120 ons, including azide-alkyne, tetrazine-trans-cyclooctene, oxime, reductive amination, native chemical
121 ond was directly observed with [(PONOP)Ir(I)(cyclooctene)][PF(6)] at ambient temperature, resulting i
122 thioetherification, whereas "ordinary" trans-cyclooctenes react only slowly with sulfenic acids.
123 four- and five-membered rings trans-fused to cyclooctene reduce the ring strain energies of the monom
124 cyclobutane fused at the 5,6-position of the cyclooctene reduces the ring strain energy of cycloocten
125 ium ion 11 (m/z 213) and cyclohexene and cis-cyclooctene resulted in the formation of addition produc
126 cyclopentene, cyclohexene, cycloheptene, and cyclooctene resulted in the formation of the seleniraniu
128 to prepare functionalized macrocyclic oligo(cyclooctene)s (cOCOEs) in high purity and high yield by
130 complexes of conformationally strained trans-cyclooctenes should greatly expand their usefulness espe
131 oisoning tests using mercury and dibenzo[a,e]cyclooctene show that dynamic Pd nanoclusters maintain t
132 azine obtained from reaction with a strained cyclooctene shows a residual fluorescence quenching effe
133 e the incorporated Tet with a strained trans-cyclooctene (sTCO) tethered to a neosubstrate protein bi
134 ts selectively with cyclopropane-fused trans-cyclooctene (sTCO) with a bimolecular rate constant of 7
135 ins by developing a series of strained trans-cyclooctene (sTCO)-functionalized nitroxides-including a
137 ization of the trans-cyclobutane fused trans-cyclooctene system holds promise for developing chemical
138 usly reported strained alkenes such as trans-cyclooctene (TCO) and 1,3-disubstituted cyclopropene, Sp
139 ectron-demand Diels-Alder reactions of trans-cyclooctene (TCO) and endo-bicyclo[6.1.0]nonyne (BCN) wi
141 by a bioorthogonal interaction between trans-cyclooctene (TCO) and tetrazine would provide higher acc
142 bioorthogonal modification of CV with trans-cyclooctene (TCO) can be used to render gram-positive ba
143 f orthogonal inhibitors that contain a trans-cyclooctene (TCO) click handle, we are able to enrich an
145 leavage reaction between tetrazine and trans-cyclooctene (TCO) is a powerful way to control the relea
147 ed 1,2,4,5-tetrazine (Tz) tracer and a trans-cyclooctene (TCO) modified antibody, imaging and therapy
148 Results: Modification of 4AH29 with trans-cyclooctene (TCO) moieties did not modify the sdAb pharm
149 ated on the in vivo ligation between a trans-cyclooctene (TCO)-bearing antibody and a tetrazine (Tz)-
150 group, DOTA, was attached via a novel trans-cyclooctene (TCO)-caged self-immolative para-aminobenzyl
151 n the bioorthogonal reaction between a trans-cyclooctene (TCO)-functionalized TAG72 targeting diabody
153 the synthesis of both fluorescent- and trans-cyclooctene (TCO)-tagged probes, which demonstrated dire
154 s-Alder reaction between tetrazine and trans-cyclooctene (TCO)-to develop a novel strategy for pre-ta
158 mall molecule, bisphosphonate-modified trans-cyclooctene (TCO-BP, 2) that binds to regions of active
159 esigned by conjugating a bioorthogonal trans-cyclooctenes (TCO) group into the ligand of the VHL E3 u
160 nes have also been shown to react with trans-cyclooctenes (TCO) in strain-promoted TCO-nitrone cycloa
165 on reacting over 260 times faster toward cis-cyclooctene than the thiiranium ion rationalized by calc
166 ctene, including a derivative of 5-aza-trans-cyclooctene that underwent transannular cyclization upon
168 omer (from 8.2 kcal mol(-1) in unsubstituted cyclooctene to 4.9 kcal mol(-1) in the fused ring).
170 receptor binding of (19/18)F-tetrazine trans-cyclooctene (TTCO)-Cys(40)-exendin-4 was evaluated in vi
171 vity of films of 1 toward the epoxidation of cyclooctene using iodosylbenzene as the oxidant was comp
172 18)F]BIO-687, bearing a click-reactive trans-cyclooctene was developed and tested in conjunction with
173 that was site-selectively modified by trans-cyclooctene was quantitatively conjugated upon exposure
174 eniranium ions, R-c-SeCH(2)CH(2)(+), and cis-cyclooctene were used to probe electronic and steric eff
175 tions are responsible for the epoxidation of cyclooctene, whereas the iron(IV) oxo species are respon
176 gh ring-opening metathesis polymerization of cyclooctene with a trans-cyclobutane installed at the 5