ライフサイエンスコーパス: decarboxylation

1 adducts, demethylation, dehydrogenation, and decarboxylation).

2 o reactive iron-oxo species during substrate decarboxylation.

3 hich serves to activate the substrate toward decarboxylation.

4 addition mechanism that underpins reversible decarboxylation.

5 ubstrates proceed through silver(I)-assisted decarboxylation.

6 involving ring fission, dehydroxylation and decarboxylation.

7 activates the biosynthetic intermediate for decarboxylation.

8 olylquinolines via [4 + 2] HDA and oxidative decarboxylation.

9 iety at the 3-OH position and (2) subsequent decarboxylation.

10 oth phenylacetate and p-hydroxyphenylacetate decarboxylation.

11 ion step, yet retains its ability to perform decarboxylation.

12 bstrate hydrogen atom to initiate fatty acid decarboxylation.

13 acetyl-CoA is commonly generated by pyruvate decarboxylation.

14 ups, we propose an inner-sphere mechanism of decarboxylation.

15 s hydroxylation of fatty acids as opposed to decarboxylation.

16 to the free energy of activation for direct decarboxylation.

17 ganometallic complex, [(phen)M(CH3)](+), via decarboxylation.

18 transfer from the triplet state followed by decarboxylation.

19 transition state for the phosphite-activated decarboxylation.

20 the rate of biotin-independent oxaloacetate decarboxylation.

21 activity from decarboxylation-deamination to decarboxylation.

22 rus functionalization is shown to facilitate decarboxylation.

23 enes via an allylic ring opening followed by decarboxylation.

24 release of isobutylene, followed by a rapid decarboxylation.

25 edure and current transition-metal-catalyzed decarboxylations.

26 late efflux from the vacuole set the pace of decarboxylation?

27 ify residues responsible for differentiating decarboxylation AAADs from aldehyde synthase AAADs.

28 butyrate oxidation; faster leucine oxidative decarboxylation; accelerated glutamine conversion to glu

29 neering to improve catalysis or to introduce decarboxylation activity into P450s with different subst

30 B originates from a previously undetected 10-decarboxylation activity of DnrK.

31 mino acid decarboxylases changes the enzymes decarboxylation activity to a primarily decarboxylation-

32 n isochelidonic acid and indoles followed by decarboxylation afforded biologically important (E)-6-in

33 e, whose corresponding acid that is prone to decarboxylation, allowed for the synthesis of 5-bromo-1H

34 followed by a late-stage palladium-catalyzed decarboxylation-allylation procedure.

35 re characterized by a lower O/C ratio due to decarboxylation and a higher content of C=C bonds.

36 water molecule is essential to maintain the decarboxylation and aromatization activities and avoid r

37 the BPCA concentrations decrease, suggesting decarboxylation and conversion to carbon dioxide and wat

38 The final structure is formed by decarboxylation and cyclisation.

39 eviously proposed pathway involving separate decarboxylation and deamination enzymatic steps from tyr

40 in the acid-treated nontronite, triggered by decarboxylation and deamination processes.

41 Product release proceeds through decarboxylation and dehydration independent of the thioe

42 ing interactions with the common portions of decarboxylation and deprotonation transition states that

43 The Pd-catalyzed decarboxylation and dual C(sp(3))-H bond functionalizati

44 substrates undergo a palladium(II)-catalyzed decarboxylation and electron-deficient substrates procee

45 spholipids caused a shift of pyruvate toward decarboxylation and energy production away from the carb

46 scope revealed some selectivity between the decarboxylation and esterification pathways under therma

47 Results show that 2-furoic acid decarboxylation and furfuryl alcohol dehydration are act

48 nthesis have been reinvestigated, the Barton decarboxylation and Giese radical conjugate addition.

49 We propose a successive decarboxylation and intramolecular hydroxylation mechani

50 formal [4+2] cycloaddition with concomitant decarboxylation and loss of acetone, proceeds in high yi

51 idation of the carboxylate followed by rapid decarboxylation and oxidation by Cu(OAc)(2).

52 allyl esters, in combination with subsequent decarboxylation and oxidative cleavage of the double bon

53 proteins are responsible for the subsequent decarboxylation and PEP regeneration steps has been elus

54 c oxindole derivative, isamic acid 1, led to decarboxylation and ring expansion to quinazolino[4,5-b]

55 he carbon-carbon bond formation precedes the decarboxylation and the reaction occurs in an outer-sphe

56 as a hydrogen atom donor in Barton reductive decarboxylations and to determine the scope of this proc

57 lyze the ring closure (i.e. condensation and decarboxylation) and dehydration steps, respectively.

58 romatic carbon degradation, oxygenation, and decarboxylation, and (ii) releasing low molecular weight

59 lite l-kynurenine via methylation, oxidative decarboxylation, and amide hydrolysis reactions.

60 o intermediates in a series of condensation, decarboxylation, and dehydration steps.

61 for investigating the catalytic mechanism of decarboxylation are complicated by the difficulty of ass

62 Two different conditions for decarboxylation are discussed for substrates with neutra

63 lase (OMPDC) with enhanced reactivity toward decarboxylation are reported: 1-(beta-d-erythrofuranosyl

64 (*)OH (e.g., addition of one oxygen atom and decarboxylation) are observed and produce highly oxidize

65 ring cleavage, loss of carbamoyl group, and decarboxylation, as well as O-methylation.

66 ontaining lipopeptides, is biosynthesized by decarboxylation-assisted -N=C group (isonitrile) formati

67 It is likely followed by decarboxylation-assisted desaturation to complete isonit

68 Notably, the decarboxylation-assisted release of the catalyst enables

69 e the transition state for ScOMPDC-catalyzed decarboxylation at a nonpolar enzyme active site dominat

70 carboxylate group but also by its oxidative decarboxylation at the underlying poly(3-octylthiophene)

71 C-catalyzed deuterium exchange compared with decarboxylation, because of the stronger apparent side c

72 oxidative addition at a gold(I) cation with decarboxylation being viable at either a gold(I) or a si

73 endocrine tumors is mainly attributed to its decarboxylation by aromatic amino acid decarboxylase (AA

74 Mechanisms proposed for initiation of decarboxylation by cleavage of the C3-H bond using a mon

75 ones has also been demonstrated by a one-pot decarboxylation by employing tert-butyl diazoester.

76 he transport of this lipid to endosomes, and decarboxylation by PtdSer decarboxylase 2 (Psd2p) to pro

77 and ligand-free carbonylation/cycloaddition/decarboxylation cascade synthesis of sulfonyl amidines f

78 conditions via a Michael/aldol/lactonization/decarboxylation cascade.

79 During the light period, malate decarboxylation concentrates CO(2) around Rubisco for se

80 The conserved Glu212 underwent decarboxylation concomitantly with an extensive rearrang

81 ymes decarboxylation activity to a primarily decarboxylation-deamination activity.

82 able of catalyzing either decarboxylation or decarboxylation-deamination on various combinations of a

83 primarily converts the enzymes activity from decarboxylation-deamination to decarboxylation.

84 ted group of examples is presented including decarboxylation, dehalogenation, nucleophilic addition,

85 tion appears to proceed via an unprecedented decarboxylation-dehydrogenation-monooxygenation cascade.

86 in the target molecules via electrochemical decarboxylation/deoxygenation to improve the stability o

87 AAADs catalyze either the decarboxylation or decarboxylation-dependent oxidative deamination of aroma

88 However, pyruvate decarboxylation during acetyl-CoA formation limits the t

89 on (Pmax ), but transcripts for archetypical decarboxylation enzymes phosphoenolpyruvate carboxykinas

90 guiding the evolutionary choice of possible decarboxylation enzymes.

91 This remarkable transformation involves decarboxylation followed by an oxidation reaction enable

92 a Knoevenagel condensation, C-arylation, and decarboxylation, followed by aromatization, is developed

93 rate-limiting step from the chemical step of decarboxylation for the phosphite-activated reaction of

94 at the decomposition process is a reversible decarboxylation forming the corresponding N-heterocyclic

95 sodium borohydride and subsequent hydrolysis decarboxylation generated the corresponding 3-propanoic

96 alternative pathway is also found where the decarboxylation happens concertedly with an aryl migrati

97 cteria, oxaloacetate is subject to enzymatic decarboxylation; however, oxaloacetate decarboxylases (O

98 Our analogs inhibit decarboxylation/hydrolysis activity with low micromolar

99 hat phenylacetate and p-hydroxyphenylacetate decarboxylation in complex cell-free extracts were catal

100 t a ca. 20 kcal/mol change in the barrier to decarboxylation in going from the gas phase to (SMD-simu

101 cycloaddition chemistry supports reversible decarboxylation in these enzymes.

102 Agmatine (AGM), a product of arginine decarboxylation, influences multiple physiologic and met

103 actylThDP (PLThDP), mimicking the native pre-decarboxylation intermediate C2alpha-lactylThDP (LThDP),

104 A reaction mechanism for the reversible decarboxylation involving an intermediate with a single

105 This TclP-mediated oxidative decarboxylation is a required step for the peptide to pr

106 now demonstrate that in extreme acidophiles, decarboxylation is carried out by two separate steps: pr

107 stance and the Gibbs free energy barrier for decarboxylation is demonstrated.

108 ion as a carboxy-lyase (i.e. decarboxylase), decarboxylation is not a completely essential step in it

109 e event involves sequential imine formation, decarboxylation, isonitrile insertion, and hydrolysis to

110 ation to form beta-hydroxy acids, which upon decarboxylation led to hemiketal FR901464.

111 r reactions (e.g., oxidation, demethylation, decarboxylation) led to the formation of extremely polar

112 Q2: Do the enzymes responsible for malate decarboxylation limit daytime mobilisation from the vacu

113 Position-specific decarboxylation measurements and NMR analysis of metabol

114 kcal/mol for activation of ScOMPDC-catalyzed decarboxylation of 1-beta-d-erythrofuranosyl)orotic acid

115 two partially rate-determining steps in the decarboxylation of 1: transfer of the second carboxyl pr

116 The decarboxylation of 2,4-dimethoxybenzoic acid (1) is acce

117 The rate of decarboxylation of 2,4-dimethoxybenzoic acid (1) is acce

118 dicates that the free energy requirement for decarboxylation of 2,6-dimethoxybenzoic acid and especia

119 of a bistable rotaxane are triggered by the decarboxylation of 2-cyano-2-phenylpropanoic acid and de

120 ports the heat-induced formation of furan by decarboxylation of 2-furoic acid, and 2-methylfuran by d

121 e the mechanisms underlying ring-opening and decarboxylation of 2-pyrones, including the degree of ri

122 of the transition state for the unactivated decarboxylation of 2.9 kcal/mol.

123 f l-arginine (l-Arg) driven by the oxidative decarboxylation of 2OG to form succinate and CO2.

124 boxylase activity and catalyzed in vitro the decarboxylation of 4-hydroxy-3-prenylbenzoate with diffe

125 A chemical reaction mechanism for the decarboxylation of 5-carboxyvanillate by LigW was propos

126 c activity and the kinetic constants for the decarboxylation of 5-carboxyvanillate by the enzymes fro

127 hosphate decarboxylase (OMPDC) catalyzes the decarboxylation of 5-fluoroorotate (FO) with kcat/Km = 1

128 y studies suggest that the LA assists in the decarboxylation of a key iron formate intermediate and c

129 Oxidative decarboxylation of a lysine fragment of the luciferin su

130 larly, the microscopic reverse reaction, the decarboxylation of a metal formate to form a metal hydri

131 nd a hydrogen atom donor in Barton reductive decarboxylation of a range of carboxylic acids was recen

132 ecarboxylase that catalyzes proton-dependent decarboxylation of a substrate amino acid to product and

133 rough oxidative ring cleavage and subsequent decarboxylation of acridine, a well-known phototransform

134 rmationally rigid amines and heterocycles by decarboxylation of adamantane-oxazolidine-2-one.

135 Enol ethers are formed by radical decarboxylation of alpha-alkoxy beta-phenylthio acids vi

136 Although the decarboxylation of aqueous phase PA through UV excitatio

137 hanism studies of a mild palladium-catalyzed decarboxylation of aromatic carboxylic acids are describ

138 n implicated in the non-oxidative reversible decarboxylation of aromatic substrates, and play a pivot

139 AgF2 induces decarboxylation of aryloxydifluoroacetic acids, and AgF,

140 Our data showed that the decarboxylation of aspartate was the only source of beta

141 Isotope effects in the decarboxylation of benzoylacetic acid support a transiti

142 mammalian C5-MTases can catalyze the direct decarboxylation of caC yielding unmodified cytosine in D

143 lation mechanism via deformylation of fdC or decarboxylation of cadC.

144 The photochemical decarboxylation of carboxylic acids is a versatile route

145 roving upon the utility of Kochi's oxidative decarboxylation of carboxylic acids.

146 ormation can be explained via acid triggered decarboxylation of cinnamic acid esters and subsequent i

147 known as methylenesuccinic acid) through the decarboxylation of cis-aconitate, a tricarboxylic acid c

148 as 7-heptadecene, an isomer likely formed by decarboxylation of cis-vaccenic acid.

149 orption spectroscopy experiment to track the decarboxylation of cyclohexanecarboxylic acid in acetoni

150 drogenase superfamily catalyze the oxidative decarboxylation of D-malate-based substrates with variou

151 dibromomethane, which could be generated by decarboxylation of dibromoacetic acid during ionization,

152 lmalate dehydrogenase catalyze the oxidative decarboxylation of different beta-hydroxyacids in the le

153 enzyme that activates oxygen to catalyze the decarboxylation of dodecanoic acid to undecene and carbo

154 wn mevalonate pathways involve ATP dependent decarboxylation of either mevalonate 5-phosphate or meva

155 xide-driven oxidase that catalyzes oxidative decarboxylation of fatty acids, producing terminal alken

156 n III via ferrochelatase HemH, and oxidative decarboxylation of Fe-coproporphyrin III into protohaem

157 The transition state for OMPDC-catalyzed decarboxylation of FO is stabilized by 5.2, 7.2, and 9.0

158 least three catalytic cycles, involving the decarboxylation of formic acid, hydration of the alkyne,

159 Herein, we report the catalytic decarboxylation of gamma-valerolactone (GVL) over Zn/ZSM

160 c acid (GABA) metabolism as it catalyses the decarboxylation of glutamic acid to form GABA.

161 Histamine produced by bacteria through decarboxylation of histidine in spoiled foods such as fi

162 DC), which is responsible for catalysing the decarboxylation of histidine to histamine.

163 IDH1/2 normally catalyse the oxidative decarboxylation of isocitrate into alpha-ketoglutarate (

164 nd carbon kinetic isotope effects (CKIE) for decarboxylation of isomeric sets of heterocyclic carboxy

165 mumol min(-1) mg(-1) at 70 degrees C for the decarboxylation of l-aspartate was measured for the reco

166 to the open conformation that coincides with decarboxylation of LThDP and DXP release.

167 ion experimental observations that correlate decarboxylation of LThDP with protein conformational cha

168 A-1, and undergo deacylation followed by the decarboxylation of Lys-70, rendering OXA-1 inactive.

169 nhibitor = 1:2000), OXA-24 was inhibited via decarboxylation of Lys-84; however, the enzyme could be

170 ME 1-4) to catalyze the reversible oxidative decarboxylation of malate in the presence of NADP.

171 method has been applied to the direct double decarboxylation of malonic acid derivatives, which allow

172 Decarboxylation of malonyl-CoA to acetyl-CoA by malonyl-

173 -Diaminopimelate decarboxylase catalyzes the decarboxylation of meso-diaminopimelate, the final react

174 hosphate, the classical MVA pathway involves decarboxylation of mevalonate diphosphate, while an alte

175 ternate pathway has been proposed to involve decarboxylation of mevalonate monophosphate.

176 ses (MDDs) catalyze the ATP-dependent-Mg(2+)-decarboxylation of mevalonate-5-diphosphate (MVAPP) to p

177 A and Y217F substitutions on k(cat)/K(m) for decarboxylation of OMP are expressed mainly as an increa

178 ol stabilization of the transition state for decarboxylation of OMP provided by OMPDC represents the

179 al/mol smaller than the transition state for decarboxylation of OMP, and ca. 8 kcal/mol smaller than

180 ncrease in (k(cat))(obs) for OMPDC-catalyzed decarboxylation of OMP, and the 4 kcal/mol of binding en

181 of pyruvate, enhances the rate of enzymatic decarboxylation of oxaloacetate in the carboxyl transfer

182 ted in situ in a tandem mass spectrometer by decarboxylation of oxo[4-(trimethylammonio)phenyl]acetic

183 Ferulic acid decarboxylase catalyzes the decarboxylation of phenylacrylic acid using a newly iden

184 mitochondrion and parasitophorous vacuole by decarboxylation of phosphatidylserine (PtdSer) and in th

185 dylserine decarboxylases (PSDs) catalyze the decarboxylation of phosphatidylserine to generate phosph

186 A similar pathway is proposed for decarboxylation of propionate 4, but with a lysine resid

187 ority of alanine enters into the pathway via decarboxylation of pyruvate in promastigotes, whereas pa

188 The decarboxylation of pyruvate loses a carbon equivalent, a

189 rd of sugar carbon is lost to CO2 due to the decarboxylation of pyruvate to acetyl-CoA and limitation

190 t pyruvate decarboxylases (PDC) catalyze the decarboxylation of pyruvate to form acetaldehyde and CO(

191 ormate lyase (PFL)-enzymes that catalyze the decarboxylation of pyruvate to form acetaldehyde and for

192 he oxidation of ethanol and the nonoxidative decarboxylation of pyruvate, with acetaldehyde being the

193 olved in energy generation through oxidative decarboxylation of pyruvate.

194 reaction proceeding via a mild photoinduced decarboxylation of redox-activated aromatic carboxylic a

195 nd to generate alkyl radicals upon reductive decarboxylation of redox-active esters without auxiliary

196 Decarboxylation of rifamycin provides salinisporamycin,

197 SABRE is used here to monitor the decarboxylation of sodium pyruvate-1,2-[(13)C(2)] at a 1

198 ing ubiX and ubiD, which are responsible for decarboxylation of the 3-octaprenyl-4-hydroxybenzoate pr

199 Decarboxylation of the amino acid sarcosine resulted in

200 mine is a biogenic compound derived from the decarboxylation of the amino acid tyrosine, and is there

201 cadaverine, which are generated by bacterial decarboxylation of the basic amino acids ornithine and l

202 this cluster, MftC, catalyzes the oxidative decarboxylation of the C-terminal Tyr of the substrate p

203 been shown that MftC catalyzes the oxidative decarboxylation of the C-terminal tyrosine (Tyr-30) on t

204 corresponding maleic anhydride, followed by decarboxylation of the diacid leads to the pathway's fin

205 and a bicyclic enamine derived from in situ decarboxylation of the diastereomeric tricyclic beta-lac

206 f FEO is not limited by the chemical step of decarboxylation of the enzyme-bound substrate.

207 the methoxypyridine, accompanied by in situ decarboxylation of the intermediate carbamic acid, gave

208 Decarboxylation of the intermediate occurs spontaneously

209 A mechanism for the decarboxylation of the kinetically stable carboxyl group

210 : (1) The orotate binding domain carries out decarboxylation of the orotate ring.

211 etical simulations reveal that the efficient decarboxylation of the primarily generated phenyl cation

212 Reaction profiles for the direct decarboxylation of trichloroacetate were generated with

213 5'-monophosphate decarboxylase catalyzes the decarboxylation of truncated substrate (1-beta-D-erythro

214 phan 2-monooxygenase catalyzes the oxidative decarboxylation of tryptophan to yield indole-3-acetamid

215 me PaaA catalyzes the double dehydration and decarboxylation of two glutamic acid residues in the 30-

216 order rate constants for the OMPDC-catalyzed decarboxylations of FEO (10 M(-)(1) s(-)(1)) and 1-(beta

217 The OMPDC-catalyzed decarboxylations of FEO and EO are both activated by exo

218 The experimentally observed decarboxylations of these molecules are found to proceed

219 ttributed to pyroglutamic acid formation and decarboxylation on the primary structure of the mAb thro

220 AD) enzymes are capable of catalyzing either decarboxylation or decarboxylation-deamination on variou

221 Plant AAADs catalyze either the decarboxylation or decarboxylation-dependent oxidative d

222 mations, including cyclic enamine formation, decarboxylation or esterification, isomerization, and la

223 Understanding mechanisms that favor decarboxylation over fatty acid hydroxylation in OleTJE

224 tterns suggest the existence of an alternate decarboxylation pathway in which an unstable intermediat

225 of excess ZnCl2 , thus avoiding the typical decarboxylation pathway of these substrates.

226 slowing the decarboxylation process and likewise the overall decompo

227 amined including a newly developed catalytic decarboxylation process.

228 uric acid ring hydrolytically and subsequent decarboxylation produces carbon dioxide and biuret.

229 ng the reaction in boiling water yielded the decarboxylation products exclusively.

230 alladium-catalyzed reaction through a tandem decarboxylation, proton abstraction, and nucleophilic ad

231 two solvents, this compound suffers a rapid decarboxylation/protonaton reaction, forming 1,3-dimethy

232 by visible-light-driven, acridine-catalyzed decarboxylation, provides access to N-alkylated secondar

233 Decarboxylation rates were significant at low light (inc

234 ence for hemiketal biosynthesis by oxidative decarboxylation rather than the previously hypothesized

235 al thiazoline to a thiazole via an oxidative decarboxylation reaction and provides stereochemical res

236 reduces the C-H activation barrier over the decarboxylation reaction barrier and can act as a potent

237 to catalyze the 2-hydroperoxycoelenterazine decarboxylation reaction by protonation of a dioxetanone

238 e clues to the stereochemical control of the decarboxylation reaction catalyzed by these eukaryotic p

239 (2+) photocages that utilizes a light-driven decarboxylation reaction in the metal ion release mechan

240 ate salts by employing an interrupted Barton decarboxylation reaction is reported.

241 In the first case, we monitored the decarboxylation reaction of 4-mercaptobenzoic acid on Ag

242 The decarboxylation reaction provides a route for the produc

243 abilize the Michaelis complex to OMP for the decarboxylation reaction, compared with the complex to F

244 oduct and thereby accelerating the enzymatic decarboxylation reaction.

245 ate-determining process, intrinsic CKIEs for decarboxylation reactions are typically greater than 1.0

246 from sugar fermentations are limited by the decarboxylation reactions involved in Embden-Meyerhof-Pa

247 inetic evidence suggests that acid-catalyzed decarboxylation reactions of aromatic carboxylic acids c

248 Patterns in the observed catalysis of decarboxylation reactions required us to conclude that t

249 yruvate carboxylation followed by subsequent decarboxylation reactions.

250 re synthesized by cross coupling followed by decarboxylation reactions.

251 form complementary functions in catalysis of decarboxylation reactions: (1) The orotate binding domai

252 edivoxetine is also described using this new decarboxylation-recombination protocol.

253 on, can subsequently undergo metal insertion-decarboxylation-recombination to generate Csp(2)-Csp(3)

254 ranssulfuration (cystathionine), and glycine decarboxylation (serine and glycine).

255 The carboxylic acid, which is removed by decarboxylation, serves as a traceless activating group,

256 computational study here of a beta-ketoacid decarboxylation shows how the distinction between the tw

257 The decarboxylation stage of this tandem sequence is envisio

258 2alpha-lactylThDP (LThDP), and a native post-decarboxylation state with a bound enamine intermediate.

259 This decarboxylation step is coupled to a proton transfer fro

260 olyketide chain, together with an intriguing decarboxylation step, indicating a hypervariable biosynt

261 a proton to C5 of the substrate prior to the decarboxylation step.

262 o)aryl bromides followed by an acid-mediated decarboxylation step.

263 ential role for the follower sequence in the decarboxylation step.

264 nt model system to test the necessity of the decarboxylation step.

265 o give malate, which undergoes two oxidative decarboxylation steps to regenerate acetyl-CoA.

266 (TclIJN) is followed by C-terminal oxidative decarboxylation (TclP).

267 in diphosphate (LThDP), which has subsequent decarboxylation that is triggered by d-glyceraldehyde 3-

268 he pyrrole ring of the indole, followed by a decarboxylation that restores the aromaticity of the phe

269 yze two key steps during light-period malate decarboxylation that underpin secondary CO(2) fixation i

270 f oxidative decarboxylases catalyzes a novel decarboxylation that uses NAD(+) catalytically.

271 Upon decarboxylation the enolate intermediate is protonated b

272 adaptation to acidic environments, as lysine decarboxylation to cadaverine.

273 collision-induced dissociation, 4 undergoes decarboxylation to form 5.

274 dative radical followed by rearrangement and decarboxylation to form an aryl radical anion which is t

275 of tartrates to oxaloacetate and an ensuing decarboxylation to form pyruvate are known processes tha

276 rom the active site, likely triggering LThDP decarboxylation to form the enamine intermediate.

277 oxylate radicals, with the latter undergoing decarboxylation to generate methyl radicals.

278 The adducts could further undergo hydrolysis/decarboxylation to generate the products which are equiv

279 on of self-assembled diacids with subsequent decarboxylation to give polymeric bisnaphthyl-Cu species

280 d with fructose to form a Schiff base before decarboxylation to produce acrylamide without Amadori re

281 oxidation, the carboxylate undergoes radical decarboxylation to site-specifically generate radical in

282 and photoredox catalysis to affect a facile decarboxylation to the CF3 radical.

283 esters but also were the key to avoid facile decarboxylation to the parent drugs from the carboxylic

284 the 5'-deoxyadenosine followed by oxidative decarboxylation to the product.

285 e putative dehydrogenase EryC and subsequent decarboxylation to yield triose-phosphates.

286 ino acids at their rim, undergo photoinduced decarboxylations to give baskets 4-6 forming a solid pre

287 th asparagine to form the Schiff base before decarboxylation, to generate acrylamide without the Amad

288 sociation of terminal functional groups, and decarboxylation-triggered HF elimination and hydrolysis,

289 ontal lineCH(COO-t-Bu) with enynal undergoes decarboxylation under the [Au]/[Ag] catalysis and forms

290 ic acids was shown to be the case, and their decarboxylation was found to follow a complex, "forked"

291 During this exploration, a facile decarboxylation was noted and was exploited as a novel p

292 xylase does not prevent gut microbial l-dopa decarboxylation, we identified a compound that inhibits

293 molecular condensation, tautomerization, and decarboxylation, which led to the formation of acridones

294 2] cycloaddition with amides and subsequent decarboxylation, which liberates the desired sulfonyl am

295 C and F, and an unexpected one-pot oxidative decarboxylation, which may prove general, led to xiamyci

296 alation has a comparably high barrier as the decarboxylation, which was previously believed to be sol

297 n ascorbate peroxidase is essential for both decarboxylations, while a lysine that salt bridges to pr

298 boxylic acids was realized through oxidative decarboxylation with 1,4-dicyanoanthracene as an organic

299 undergoes a concerted Eschweiler-Clarke type decarboxylation with alkynoic acids.

300 rboxylase catalyzes two sequential oxidative decarboxylations with H2O2 as the oxidant, coproheme III