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1 nds in certain AFFF formulations can inhibit dechlorination.
2 s when Fe(0) is used to facilitate microbial dechlorination.
3 usand, confirming the predominance of biotic dechlorination.
4 curring in BTES systems on cis-DCE reductive dechlorination.
5 min), to produce cobalamin as a cofactor for dechlorination.
6 correlated with the growth of D. mccartyi by dechlorination.
7 reaction mechanisms underlying PCE reductive dechlorination.
8 ime have served to mimic microbial reductive dechlorination.
9 Dehalococcoides could be responsible for PCB dechlorination.
10 d aid in the modeling of anaerobic reductive dechlorination.
11 nts, which may be degraded through reductive dechlorination.
12 moiety being a preferential site for initial dechlorination.
13 ect indicator to assess the effectiveness of dechlorination.
14 turn to a high internal supply of Cl(-) upon dechlorination.
15 sotope fractionation to evaluate PCE and TCE dechlorination.
16 nsformation of ethene rather than incomplete dechlorination.
17 matic chlorines and are subject to microbial dechlorination.
18 lture were strategies implemented to enhance dechlorination.
19 d to be the dominant mechanism for reductive dechlorination.
20 rals, and C2H2 is known to inhibit bacterial dechlorination.
21 dation, and particularly anaerobic reductive dechlorination.
22 he most plausible explanation for failure of dechlorination.
23 tool for describing transport and reductive dechlorination.
24 on, while DDE degradation involves reductive dechlorination.
25 tamination, and recalcitrance toward abiotic dechlorination, 1,2-DCA remains a challenging compound f
26 and NZVI induction can increase the rate of dechlorination, according to Arrhenius' equation, and in
27 s well as proteins involved in the reductive dechlorination activity (i.e., FdhA, TceA, and BvcA).
28 de cell lysate from PCE grown cells revealed dechlorination activity against both PCE and 2,2',3,4,4'
29 lated to an enhanced cell decay or a reduced dechlorination activity at increasing TCE concentrations
30 consortium SDC-9 to 76 muM CFC-113, cis-DCE dechlorination activity did not recover after CFC-113 re
31 serial dilutions to extinction and recovered dechlorination activity from transfers of 10(-7) and 10(
32 demonstrated positive effects on Dhc in situ dechlorination activity in the vicinity of well PW4.
33 TCE self-inhibition is related to a reduced dechlorination activity rather than to an enhanced cell
34 on Dehalococcoides mccartyi (Dhc) reductive dechlorination activity remains a cornerstone approach t
35 oaches and provide a more reliable proxy for dechlorination activity, we sought to demonstrate a targ
40 strategies is the possibility of incomplete dechlorination and accumulation of toxic daughter produc
41 nto field sites, resulting in incomplete TCE dechlorination and accumulation of vinyl chloride (VC).
42 nd porewater, indicating that both anaerobic dechlorination and aerobic degradation occurred concurre
43 umn indicating that both anaerobic reductive dechlorination and aerobic degradation occurred concurre
44 ctual mass balance deficits during reductive dechlorination and apparent lack of mass balance that is
47 Cl bond cleavage in Fe(0)-mediated reductive dechlorination and E1CB elimination mechanism during alk
51 ggesting the cometabolic microbial reductive dechlorination and reductive defluorination of CFC-113 t
53 a=0.01) indicate that transformation of TCC (dechlorination) and TCS (methylation) occurred during se
54 loroethene and vinyl chloride production and dechlorination, and ethene generation were all inhibited
56 Both nucleophilic substitution and reductive dechlorination are the proposed mechanisms for 1,2-DCA d
58 ocumenting long-term continuous Pd-catalyzed dechlorination at high surface loading with minimal loss
61 ying effective mechanisms for chloroaromatic dechlorination but also for understanding the functions
64 ironmental factors, we conclude that lindane dechlorination by Anabaena sp. requires a functional nir
67 ral pH, Acetobacterium supports complete TCE dechlorination by Dehalococcoides at millimolar levels w
70 ed congeners, indicating that both anaerobic dechlorination by DF1 and aerobic degradation by LB400 o
71 Dhc. mccartyi 195, and of VC on PCE and TCE dechlorination by Dhb. restrictus, were compounded when
72 s CTFE, TFE, and cis-DFE did not inhibit TCE dechlorination by Dhc, indicating that the initial reduc
73 The inhibition effects of PCE and TCE on VC dechlorination by Dhc. mccartyi 195, and of VC on PCE an
74 and 13.0 +/- 0.8, respectively) vs reductive dechlorination by Fe(0) (8 +/- 2) establish a base to id
75 pathways of contaminant removal, such as (i) dechlorination by reductive elimination rather than hydr
76 ation during oxidative 2,4,6-trichlorophenol dechlorination by representative soil enzymes (C. fumago
79 s, an approach was evolved that ensured that dechlorination carried out during sample processing did
80 pyrazole, sequential catalytic C4 arylation, dechlorination, catalytic C5 arylation reactions allowed
81 rom fractionation at positions away from the dechlorination center (secondary isotope effects), furth
82 the reactants and products in the reductive dechlorination chain offers a potential tool for differe
86 perfluoroalkyl acids (PFAAs) indicated that dechlorination could be inhibited by PFASs but that the
90 points and avoids the potential for stalled dechlorination due to inhibitory levels of NH(4)(+) or t
92 n indigenous diazotrophs can achieve similar dechlorination end points and avoids the potential for s
93 phase liquids (DNAPL) by enhanced reductive dechlorination (ERD) can be limited by contaminant toxic
95 d at high flow velocity (0.51 m/d), but that dechlorination failed at medium or low flow velocity (0.
98 US watershed in which PCBs appear to undergo dechlorination in an environment other than sediment, su
99 loroform concentration effectively inhibited dechlorination in Dehalococcoides strains ANAS2, 11a, an
100 occoides mccartyi (Dhc) growth and reductive dechlorination in enrichment cultures derived from groun
101 approach that can characterize Dhc mediated dechlorination in groundwater contaminated with chlorina
102 bolic) and their interactions with reductive dechlorination in relation to riverbed sediment geochemi
105 e of N(2) fixation were responsible for cDCE dechlorination in TC cultures, and diazotrophic communit
106 We developed a method to measure rate of dechlorination in the aqueous phase at very low PCB conc
107 aced over 20 years using a case study of PCB dechlorination in the Housatonic River (Massachusetts) a
109 ok for evidence that these compounds undergo dechlorination in the sewers of the New York/New Jersey
110 s up to 200 muM did not initially impact TCE dechlorination, inhibition was observed in cultures amen
111 competing metabolic processes or inhibitory dechlorination intermediate products, is sufficient to a
112 entify reasons for the accumulation of toxic dechlorination intermediates and could become a useful t
115 ehalose, implying that the rate of enzymatic dechlorination is controlled by chemical events in catal
116 first stages of the treatment suggested that dechlorination is preferred over deacylation with the co
118 bic microbial polychlorinated biphenyl (PCB) dechlorination is traced over 20 years using a case stud
120 an accurate measurement of the aqueous-phase dechlorination kinetics and an understanding of the site
121 , it has been recognized that PCB and PCDD/F dechlorination may also occur in other anaerobic environ
129 showed that, for all rock types studied, TCE dechlorination occurred, as evidenced by generation of a
130 formulations, including the products of PCB dechlorination occurring in sewers, do not accumulate ap
136 to accurately measure the biological rate of dechlorination of 2,3,4,5-tetrachlorobiphenyl (PCB 61) t
138 culated with the DCB enrichment culture, and dechlorination of 2,7-DiCDD almost exclusively in bottle
139 In this work, we investigated the photolytic dechlorination of 2-Cl- and 3-Cl-aniline to aminophenols
142 m of the organisms responsible for extensive dechlorination of Aroclor 1260, and finally to the ident
145 first enzyme, AtzA, catalyzes the hydrolytic dechlorination of atrazine, yielding hydroxyatrazine.
146 are formed in up to 45% yields by reductive dechlorination of carboalkoxy-N,N,N'-trichloroformamidin
149 Unlike 1,1,1-TCA and 1,1-DCA, reductive dechlorination of CF by the Dehalobacter-containing cult
150 oid (i.e., vitamin B(12)) mediated reductive dechlorination of CFC-113 to CTFE and trifluoroethene (T
151 Methylophilus sp. strain DM11 catalyzes the dechlorination of CH(2)Cl(2) to formaldehyde via a highl
152 ics of successful and unsuccessful reductive dechlorination of chlorinated ethenes in groundwater und
154 strains are keystone bacteria for reductive dechlorination of chlorinated ethenes to nontoxic ethene
156 , GRs) are promising reactants for reductive dechlorination of chlorinated solvents due to high react
157 s in this area have focused on the reductive dechlorination of chlorinated solvents, the degradation
159 that coupling a culture capable of reductive dechlorination of chlorobenzene to benzene with a second
161 d previously), it was observed that complete dechlorination of cis-dichloroethene to ethene was susta
163 atalyzes the deamination of melamine and the dechlorination of deethylatrazine and desisopropylatrazi
165 Using ZVI and NZVI with AC EMF enhanced dechlorination of dissolved TCE (no soil) up to 4.96-fol
166 ope fractionation originate from heterolytic dechlorination of excited triplet and singlet states of
167 ize alternative mechanisms for the reductive dechlorination of hexachloroethane (HCA) to perchloroeth
168 nvironments well poised to support anaerobic dechlorination of highly chlorinated congeners; products
169 ranil), accompanied by a two-step hydrolytic dechlorination of highly toxic TCBQ into the much less t
171 nder alkaline conditions, N-chlorination and dechlorination of N-chlorinated amide links by hydroxyl
172 either other chlorination pathways, or that dechlorination of naturally produced organochlorines can
173 nzo-p-dioxin (HpCDD), a known product of the dechlorination of octachlorodibenzo-p-dioxin (OCDD), and
175 C7120 and Nostoc ellipsosporum, as it is for dechlorination of other organic compounds by heterotroph
176 f the Delaware River basin and that advanced dechlorination of PCB mixtures is more likely to occur i
177 than sediment, suggesting that the microbial dechlorination of PCBs and PCDD/Fs is more common than p
178 esults indicate that a factor related to the dechlorination of PCBs and PCDD/Fs was present in the wa
180 evealed a factor indicative of the microbial dechlorination of PCBs, and this factor also contained a
182 ) to determine whether peri and peri/lateral dechlorination of PCDD/Fs occurs in these environments.
183 xt of environmental studies on B12-catalyzed dechlorination of PCE and TCE and investigations of the
188 o-17 and DF-1, that link their growth to the dechlorination of several PCB congeners belong to a nove
189 mulation inhibits the sustainable growth and dechlorination of strain 195 maintained in pure cultures
191 concentrations reversibly inhibit reductive dechlorination of TCE by Dehalococcoides mccartyi isolat
192 erage initial rate coefficients for complete dechlorination of TCE to acetylene, ethene, and ethane w
193 n (H) isotope effects were determined during dechlorination of TCE to ethene by a mixed Dehalococcoid
194 alogenases are important to achieve complete dechlorination of tetrachloroethene (PCE) and trichloroe
196 igand 1 was successfully synthesized via the dechlorination of the corresponding {[Si(II)(Xant)Si(II)
201 e at 25 degrees C for spontaneous hydrolytic dechlorination of trans-3-chloroacrylic acid is 10,000 y
203 dynamic isotopic shifts during the reductive dechlorination of trichloroethene (TCE) indicate that fr
205 nd selectivity of SNZVI during the reductive dechlorination of trichloroethylene (TCE), a hydrophobic
207 nt monooxygenase that can catalyze oxidative dechlorination of various CPs, and as such it will serve
209 ,6-TCP) 4-monooxygenase catalyzes sequential dechlorinations of 2,4,6-TCP to 6-chlorohydroxyquinol.
210 nd previous work illustrates that photolytic dechlorinations of 2-Cl-, 3-Cl-, and 4-Cl-aniline isomer
217 processes at the OAI and that high reductive dechlorination potential suppresses development of aerob
218 sfully predicted the 3-month-ahead reductive dechlorination potential with 75.8% and 69.5% true posit
219 yed significant correlations (p < 0.01) with dechlorination potential, with NO3(-), NO2(-), and Fe(2+
223 h an inverse H effect in TCE) suggested that dechlorination proceeded through nucleophilic reactions
224 sms (e.g., aerobic degradation and reductive dechlorination proceeding via outer sphere mechanisms),
225 and penta-chlorinated PCDD/Fs suggested that dechlorination proceeds to PCDD/F congeners with less th
226 eudomonad growing in these soils, hydrolytic dechlorination proceeds with a half-time of 0.18 s.
231 l(-) levels may be controlled by supply from dechlorination processes and can explain why soil Cl(-)
235 D/Fs was analyzed, the factor containing PCB dechlorination products also contained high proportions
236 ) degrees values of chlordecone and selected dechlorination products and used these data to calculate
239 2'-hydroxy-TCC (r=0.84), and between the TCC-dechlorination products dichlorocarbanilide (DCC) and mo
240 mining three samples that contained >90% PCB dechlorination products from the Fresh Kills Landfill an
243 The resulting model predicted the sum of dechlorination products vinyl chloride (VC) and ethene (
245 c profiles illustrated that the distinct PCB dechlorination profile of each strain was predominantly
247 ased cis-1,2-dichloroethene (cDCE)-to-ethene dechlorination rates about 5-fold (20.6 +/- 1.6 versus 3
250 ns, shows that sulfidation usually increases dechlorination rates, and simultaneously hydrogen produc
251 tion with NH(4)(+) can enhance Dhc reductive dechlorination rates; however, a "do nothing" approach t
253 ceeded in predicting the reactivation of the dechlorination reaction in treatments in which the inhib
255 between an enzyme that catalyzes a reductive dechlorination reaction relevant to bioremediation effor
256 itiated by a LiP- or MnP-catalyzed oxidative dechlorination reaction to produce 2,6-dichloro-1,4-benz
257 erbicide atrazine by catalyzing a hydrolytic dechlorination reaction to produce hydroxyatrazine.
263 ated biphenyl (PCB) mixtures via 85 distinct dechlorination reactions, suggesting that it has great p
266 chlorinated ethenes via anaerobic reductive dechlorination relies upon the activity of specific micr
267 nzene derived electrons fueled chlorobenzene dechlorination removing the need to provide exogenous el
270 vidence consistent with an initial reductive dechlorination step to form 4-chlorobenzoate was found i
273 chloronitromethane decay occurs by reductive dechlorination, suggesting that CMPs are electron donors
274 results for both successful and unsuccessful dechlorination, suggesting the model is a valid tool for
275 ut the addition of a second equiv results in dechlorination to 1,2,3,4,5,6,7-heptachloroazulene as we
279 synergistically promoted microbiological TCE dechlorination to ethene while achieving complete ClO(4)
280 hways: it either undergoes further reductive dechlorination to yield 1, 4-hydroquinone, which is orth
281 identification of four distinct types of PCB dechlorination, to a successful field test, to the culti
283 meta-analysis of available kinetic data for dechlorination under anoxic conditions, shows that sulfi
285 nated quinones undergo a rapid, nonenzymatic dechlorination upon reaction with GSH opens a different
287 per thousand), whereas reductive diclofenac dechlorination was associated with significant carbon is
296 ater concentrations of chloride-a product of dechlorination-was observed in most wells; in addition,
297 Dehalococcoidia associated with organohalide dechlorination were differentially enriched in DCB versu
298 A two-step process was proposed for TCP dechlorination, which is initiated by reductive B-elimin
299 entable components of AFFF can stimulate TCE dechlorination, while some of the fluorinated compounds
300 tion of FdhA peptides, which revealed active dechlorination with Dhc strain-level resolution, and the