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1  of the peroxo intermediate in CYP-catalyzed deformylation.
2  us to investigate regulation of delta-toxin deformylation.
3 hionine excision of optimal substrates after deformylation.
4 2 proved to be a capable oxidant in aldehyde deformylation.
5 cids is decreased, but the rates of aldehyde deformylation and mechanism-based inactivation of the cy
6 t any functional role in protein formylation/deformylation and validates PDF as an excellent target f
7 ant of this cytochrome, the rate of aldehyde deformylation, as determined by formation of the alcohol
8 n synthesis does not involve formylation and deformylation at the N-terminus, there has been increasi
9 l in part because it obstructs their ensuing deformylation by peptide deformylase (PDF) and hydrolysi
10 kinetics and computational study on aldehyde deformylation by two side-on manganese(III)-peroxo compl
11 tic iron-porphyrin complexes during aldehyde deformylation clearly establishes nucleophilic attack of
12 ibitors and the necessity of the formylation/deformylation cycle in bacteria.
13 further reactions, either cycloannulation or deformylation, depending on the substrate employed.
14 nalysis of the heme adduct formed shows that deformylation does not occur.
15 htar and colleagues proposed that in steroid deformylation effected by P450 aromatase an iron-peroxo
16 E anthraquinone moiety assists in catalyzing deformylation, epoxidation and oxidative ring cleavage w
17 te with acrylate/acrylamide, followed by the deformylation in one-pot.
18 te significant attempts in modeling aldehyde deformylation in synthetic heme systems, both reactivity
19 ossible explanation for the apparent lack of deformylation in the mammalian mitochondria.
20 ings and our previous evidence that aldehyde deformylation is supported by added H202, but not by art
21 for neutrophils, suggesting that delta-toxin deformylation may have functional consequences.
22 etal provides a branch point for a concerted deformylation mechanism; however, a stepwise mechanism i
23                                      Herein, deformylation mechanisms of the sterol 14alpha-demethyla
24 several technical improvements, to study the deformylation of 19-oxo-androstenedione by human P450 19
25 tal-induced P450 2B4, catalyze the analogous deformylation of a series of xenobiotic aldehydes with o
26 on may proceed via the ionization and formal deformylation of an aldol intermediate.
27 heses also feature stereospecific photolytic deformylation of beta,gamma-unsaturated aldehydes 46, 70
28                       In sharp contrast, the deformylation of cyclohexane carboxaldehyde by the T302A
29 ved from molecular oxygen, promotes aldehyde deformylation of different aldehyde substrates via the f
30 ative active DNA demethylation mechanism via deformylation of fdC or decarboxylation of cadC.
31 The deformylase is also capable of efficient deformylation of formyl-Phe-Tyr-(Phe/Tyr) peptides.
32 peroxy species is apparently involved in the deformylation of many aldehydes with desaturation of the
33         Importantly, akuammicine arises from deformylation of preakuammicine, which is the central bi
34 omplex with lanosterol), we demonstrate that deformylation of the 14alpha-carboxaldehyde intermediate
35 r mechanism for compound I (Cmpd I) mediated deformylation of the geminal diol was considered in the
36 Cmpd I states failed to initiate a concerted deformylation of the geminal diol.
37 wever, with both methacrylate and crotonate, deformylation of the initially formed alkylation product
38 sis in bacteria involves the formylation and deformylation of the N-terminal methionine.
39 ive other products, all of which result from deformylation of the sterol side chain.
40  intermediate that carries out the oxidative deformylation of the substrate.
41 Escherichia coli deformylase resulted in the deformylation of those peptides that are the most potent
42 that the 1beta-hydrogen atom abstraction and deformylation or decarbonylation occur in a nonsynchrono
43 or substrates for PDF and exhibit incomplete deformylation, particularly when they are overproduced.
44  synthetic analogues have suggested that the deformylation proceeds most likely via aldehyde C-H atom
45                                          The deformylation products arise by addition of the same fer
46 he conventional acid metabolite and the five deformylation products.
47  acid (Compound I pathway) at the expense of deformylation products.
48 h hydration at the nitrile group faster than deformylation, protecting aminonitrile derivatives from
49 says using a series of substrates of varying deformylation rates indicate that Co-PDF has the same su
50 dehyde inactivation of P450 2B4 involves the deformylation reaction and is unrelated to carboxylic ac
51                                     Aldehyde deformylation reaction by heme and nonheme enzymes in bi
52  shows a nucleophilic reactivity in aldehyde deformylation reaction, demonstrating that 1 has an amph
53 rimary kinetic isotope effect of 5.4 for the deformylation reaction.
54 es of experiments aimed at understanding the deformylation reaction.
55 uct for the latter, while the former gives a deformylation reaction.
56 plex, to have enhanced activity in oxidative deformylation reactions believed to involve FeO2+.
57 ion of some carbonyl compounds, particularly deformylation reactions.
58 we report on nucleophilic oxidative aldehyde deformylation reactivity by the peroxo-dicopper(II) spec
59 mylase, the bacterial enzyme responsible for deformylation, represents a potential target for antibio
60         Mechanisms for the aromatization and deformylation sequence which are initiated by 1beta-hydr
61 ipient alkyl radical formed in the oxidative deformylation step in competition with the oxygen reboun
62  reaction and concludes with a light-induced deformylation step.
63 rgo both pyrone and oxirane ring-opening via deformylation to produce hydroxylated 2-pyrones or 4-pyr
64  of several substrates and enhanced aldehyde deformylation via a presumed peroxo intermediate.
65                                              Deformylation was for a long time thought to be a featur
66                    Inhibition of delta-toxin deformylation was relieved by TCA cycle inactivation or
67  cyclohexene from cyclohexane carboxaldehyde deformylation, were determined with P450s 2B4, 2B4 (delt
68 (2)OH)(2)]Cl can be separated by a selective deformylation with aqueous NaOH.
69 re sensitive to non-enzymatic acid-catalyzed deformylation, yielding 19-norsteroids, and conditions w
70 ehyde to give a peroxyhemiacetal, which upon deformylation yields the alkyl radical.