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1 ecretion of SlpA from the cell is relatively delocalized.
2 riplet state is again found to be completely delocalized.
3 r being highly molecular and the latter more delocalized.
4 ontrast, nucleosomes in MIC are dramatically delocalized.
5 n which the unpaired electron is extensively delocalized.
6 -GlcNAc levels are increased and OGT and OGA delocalized.
7 hroism spectroscopy that Cu(A)CcP is valence delocalized.
8 Au, bonding of the latter two being broadly delocalized.
9 O analysis shows that the aromatic system is delocalized.
10 excited states of these nanorings are highly delocalized.
12 protonation of N-(aryloxy)imines generates a delocalized 2-azaallyl anion-type nucleophile that engag
15 s on the ability (or not) of electrons to be delocalized across heterometallic bonds, allowing for ra
16 ne axes, while their LUMOs remain relatively delocalized across the molecule, except in cruciforms su
17 or and reveal that one of the spins is fully delocalized across up to five adjacent guanines in a G-t
19 yeast lacking Nup132 (Sc/HuNUP133), Ulp1 is delocalized and can no longer antagonize sumoylation of
20 ecular packing leads to (i) the formation of delocalized and emissive excitons that enable small non-
21 ined states to band-like charge transport in delocalized and hybridized states of strongly coupled QD
22 elding pattern implies the existence of both delocalized and localized currents that have a dominant
23 he self-assembly of diamondoids, form highly delocalized and symmetric electron-deficient structures.
24 kinase previously found to be overexpressed, delocalized, and constitutively active in CLL cells.
26 gy transfer mechanism leads to excitation of delocalized, anticorrelated vibrational wavepackets on t
27 that benzocarbatriphyrins are 14pai electron delocalized aromatic systems that bypass the fused arene
29 e for collective behavior of macroscopically delocalized atomic states, a crucial element for new pro
30 ewed as a tetravalent superatom forming four delocalized Au-H-Au bonds, similar to the quadruple bond
31 s (COEs), molecules that are defined by a pi-delocalized backbone and terminal ionic pendant groups,
34 ed as either localized on one sulfur atom or delocalized between two indistinguishable sulfur atoms.
35 experiments show that electronic excitation delocalizes between the two perpendicular nanorings of t
37 parameters that describes both localized and delocalized binding to various biological systems is use
38 in an effective Hamiltonian that couples the delocalized Bogoliubov modes of the two mechanical oscil
40 chemical bond is generally given in terms of delocalized bonding orbitals, or, alternatively, in term
42 Bonding and charge density analyses indicate delocalized bonding within the gold host and the (Au,T)3
43 lar we find that single point defects do not delocalize, but remain compact near the interfacial plan
47 te that electrons exhibit both localized and delocalized character, with a maximum Curie constant and
48 in the droplets) yielding anions with highly delocalized charge [quantified by the weighted average p
49 nd physical or chemical properties of excess delocalized charge carriers in semiconductor nanocrystal
50 Photoexcitation leads to the formation of a delocalized charge resonance state (S1) that relaxes qui
53 charge separation involving intermolecularly delocalized charges in nonpolar media, an integral proce
54 nction as molecular wires with transport via delocalized charges, rather than the hopping mechanism t
55 omatic and antiaromatic molecules-which have delocalized circuits of [4n + 2] or [4n] electrons, resp
56 esults in electron localized Class II-III or delocalized Class III structures that display distinct N
57 re discussed within the framework of a fully delocalized cluster exhibiting strong double and direct
59 ong contributions to the binding energy from delocalized, collective charge fluctuations-in contrast
61 -type) colloidal ZnO nanocrystals possessing delocalized conduction-band (CB) electrons can be formed
62 nanocrystals (NCs) involves recombination of delocalized conduction-band electrons with copper-locali
64 composed of localized quantum dot states and delocalized continuum states, arising from ultra-strong
65 f the two boron pz-type orbitals, with small delocalized contributions of the 9-borafluorenyl pi syst
68 und that CT at the interface first populates delocalized CT excitons with a coherent size of 4 nm.
70 lts support a model of charge separation via delocalized CT states independent of excess heterojuncti
72 nitial bright singlet state (species I) to a delocalized dark state (species II), driven by interacti
73 on in zebrafish hepatocytes destabilizes and delocalizes Dnmt1 and causes DNA hypomethylation and Tp5
77 mplexes lead to highly coherent domains with delocalized electronic states displaying metallic behavi
79 s owe their optoelectronic properties to the delocalized electronic structure along their conjugated
80 ast ET and PT chemistry is attributed to the delocalized electronic structure of [Co(13)C(2)(CO)(24)]
81 (4)](2+) clusters typically exhibit pairwise delocalized electronic structures in which each Fe has a
83 p at the top of the occupied manifold of the delocalized electronic superatom spectrum of the inner c
84 pitaxial connections will lead to completely delocalized electrons and may enable the observation of
85 as YbAl3, interactions between localized and delocalized electrons can lead to fluctuations between t
86 highly stabilizing feature of molecules with delocalized electrons in closed circuits, is generally r
87 ational studies indicate that 2 features the delocalized electrons in the part of the sigma-framework
89 ysics supports this view, demonstrating that delocalized electrons make a static macroscopic polariza
90 ized status (e.g., polyaromatics), with more delocalized electrons obtained for enhanced Maxwell-Wagn
91 results demonstrate that the ability to add delocalized electrons to polyoxometalate clusters can be
94 ied a structural motif that more effectively delocalizes electrons during lithiation events in batter
96 ering alloys because it ensures that flow is delocalized, enhances tensile ductility and inhibits cat
97 ination of differently planarized and charge-delocalized enolate tautomers by anion-pi interactions.
99 find that on a 50 fs time scale an initially delocalized excess electron localizes on a single [Tf2N(
101 timize energy transport via the formation of delocalized excited states (excitons), which are critica
102 ceptor structures are observed to facilitate delocalized excited states for enhanced mixing between c
104 circular dichroism, superradiance, and fast delocalized exciton transfer, consistent with our quantu
105 l spectroscopic signatures of the multipolar delocalized exciton, including the S(2) <- S(1) electron
107 insights indicate the outstanding promise of delocalized excitonic processes available in 2D COFs, wh
109 cylinders' soft mesoscopic structure, robust delocalized excitons are retained: Internal order and st
110 r between clusters of a few pigments sharing delocalized excitons has been challenged by ultrafast op
113 , our analysis identifies a solvent exposed, delocalized Fe(2.5+) pair and a buried Fe(2+) pair.
114 he double exchange parameter, B, for valence-delocalized [Fe2S2](+) centers and demonstrate that vari
115 ) provide the only known examples of valence-delocalized [Fe2S2](+) clusters, which constitute a fund
116 rve as a sensitive probe for correlations in delocalized fermionic quantum states and for quantum met
118 cked orientation results in the emergence of delocalized Frenkel/mixed-Frenkel-CT character and the c
119 enocopies one another in causing Xist RNA to delocalize from the Xi and disperse into the nucleoplasm
120 ype claudin-16, phosphomimetic claudin-16 is delocalized from the tight junction but relocated to the
121 ional results indicate a unique role for the delocalized frontier molecular orbitals of the Fe(NO)2 u
122 d to increase electron affinity and maintain delocalized frontier orbitals while significantly decrea
124 AM, but do not produce large, electronically delocalized groups or change other aspects of the tunnel
125 n of CBP-1 in cec-4 mutants is sufficient to delocalize heterochromatin in an ATF-8-dependent manner.
126 the Lys1901 or Arg1914 binding determinants delocalize heterodimeric envoplakin from intracellular v
127 re carried out to determine how localized or delocalized holes on a polymer chain are and to compare
128 otogeneration occurs predominately via these delocalized hot exciton states in competition with relax
129 arge generation across large polymer phases, delocalized hot excitons may also account for the crucia
130 , and those whose O-H stretch vibrations are delocalized, i.e., shared between multiple O-H bonds.
131 -linked peptidoglycan, because StkP and PhpP delocalize in the presence of antibiotics that target th
134 phy suggests that the unpaired electrons are delocalized in each case across two inner 4,4'-bipyridin
135 ules showed that their pi electrons remained delocalized in individual benzenoid-type rings rather th
137 a Ni(III) complex with one unpaired electron delocalized in the ligands surrounding the metal center.
138 that a significant fraction of the charge is delocalized in the tert-butyl group of the radical catio
139 ed molecular orbital (LUMO) band is strongly delocalized in two-dimensions, which is unprecedented fo
140 duced structural changes result in local and delocalized increases in Tpm flexibility and prominent c
141 oring HRAS, NRAS or KRAS mutations, SCH66336 delocalized, inhibited signaling and preferentially inhi
142 r interaction with Ag (or Cu) as involving a delocalized interaction with contributions from the carb
143 synergy between the bond-forming and charge-delocalizing interactions lead to a dramatic (>hundred-b
144 molecular nature of the exciton and the more delocalized intermolecular nature of electrons and holes
145 he radical cation in the ring-closed form is delocalized into the phenyl ring, and/or (ii) the lowest
149 d organic ligand shell by so-called "exciton-delocalizing ligands (EDLs)" is a promising strategy to
150 , in particular, dipolar ligands and exciton-delocalizing ligands, on their electronic energies; (ii)
151 tment process is often required to remove or delocalize lignin, which may also generate inhibitors th
153 ork, previously shown to give rise to highly delocalized low-lying (3)MLCT states for other Group VII
154 ) Mes, including a low-lying and extensively delocalized LUMO and a wide HOMO-LUMO gap, which arise f
157 ximal tryptophan (0.4 ps) and is followed by delocalized migration of the produced WH(*+) radical alo
159 ipolar and quadrupolar electric and magnetic delocalized modes, only dipolar electric and quadrupolar
160 mpounds correlated well with the energy of a delocalized molecular orbital first appearing on an arom
161 overturn the well-known conclusion that both delocalized molecular orbitals and localized molecular o
163 into the origin of the far-IR localized and delocalized motions present in peptides and where they c
164 ranched donor-acceptor molecules varies from delocalized/multipolar to localized/dipolar depending on
166 functional theory calculations highlight the delocalized nature of the low energy singlet excited sta
167 studies have been complicated by the highly delocalized nature of the porphyrin, and calculations re
169 nyl group especially effective at helping to delocalize negative charge due to some cyclopentadienide
170 Loss of the dystrophin-sarcoglycan complex delocalizes nitric oxide synthase (NOS) to alter its sig
173 xygen lone pair on flat sites, whereas it is delocalized on both C and O atoms on concave sites, incr
174 e cyclohexene-bridged Z-derivatives are spin-delocalized on the EPR time scale but charge-localized o
175 r C-S bond cleavage, and the charge and spin delocalized on their structures, were also useful to end
177 ulations demonstrate that the electron spins delocalized onto the thiophene unit lead to the accelera
179 ws that the photogenerated plasmon is highly delocalized onto TiO2, and thus, it is shared by the ele
180 on the possible role of charge transfer and delocalized or excitonic states in the photophysics of t
184 and IR spectra indicates that the polaron is delocalized over 2-3 porphyrin units in the linear oligo
185 sfer includes the fact that the excitons are delocalized over a few neighboring sites, but the role o
186 ons, it is proposed that the MLCT states are delocalized over both benzoate Cr(CO)(3) groups, as supp
188 ying states, in which molecular orbitals are delocalized over Chl(D1) and Phe(D1) as well as one weak
193 ound 2, the unpaired electron is also partly delocalized over the CAAC ligand (carbene) C and N atoms
194 The unpaired electron in this molecule is delocalized over the entire helical core composed of six
197 ex suggests the formation of a radical anion delocalized over the neighboring PDI units, and this res
199 One of these VTs has the charge and spin delocalized over the porphyrin and the styrylruthenium m
201 but for P-TMI the NTOs have electron density delocalized over the two units as a result of extensive
204 les of sigma-bonds made of a single electron delocalized over two neighboring atoms were until recent
205 s, the excess charge carrier forms a polaron delocalized over up to 10-20 molecules in the most condu
206 referential formation of interchain excitons delocalizing over more than one polymer backbone in the
209 smaller electronic couplings for the highly delocalized P3DT anions as enabling the inverted behavio
211 as from single-molecule spectroscopy, single delocalized pai-electron dye systems are isolated in rel
212 that both ReB(4)(-) and ReB(4) possess four delocalized pai-electrons, including two pai-electrons i
213 oelectronic properties owing to their highly delocalized pai-systems, low-lying frontier orbitals tha
214 s is especially so in systems of interacting delocalized particles, for which a direct experimental m
218 theoretical model that explores how coherent delocalized phonon-like modes in DNA provide single-stra
219 results support the conclusion that coherent delocalized phonon-like modes play an important role in
220 by invoking exciton self-trapping, in which delocalized photogenerated holes contract in response to
221 e highly stable and doubly aromatic with six delocalized pi and six delocalized sigma electrons and s
222 und to exhibit triple pi aromaticity with 11 delocalized pi bonds, analogous to benzo(g,h,i)perylene
225 ent with charge separation through access to delocalized pi-electron states in ordered regions of the
226 carbon basal plane, conferred upon it by the delocalized pi-electrons, (i) causes a downshift of e(g)
232 ton-localization microscopy reveals that the delocalized plasmons are capable of focusing multiple na
234 ormation of e(-) and h(+) pairs that lead to delocalized polaronic V(3+) and V(5+) cation states.
235 the core-localized electron density, highly delocalized polarons with mobilities equivalent to films
237 nodal excitations from gapped (localized) to delocalized quasiparticles characterized by a longer lif
238 upon deprotonation is largest when a highly delocalized radical is combined with an initially less s
241 CD saturation magnetization data for valence-delocalized S = 9/2 [Fe2S2](+) centers facilitated deter
242 and investigating the properties of valence-delocalized S = 9/2 [Fe2S2](+) fragments in higher nucle
243 imilar valence-localized S = 1/2 and valence-delocalized S = 9/2 forms as a function of pH, with pKa
244 s in partial or full conversion from valence-delocalized S = 9/2 to valence-localized S = 1/2 [Fe2S2]
245 rates that are characteristic of a circular delocalized S(1) excited state are preserved in the low-
247 he all-boron fullerene, bonded uniformly via delocalized sigma and pi bonds, is not perfectly smooth
248 hey satisfy the 4n+2 rule of aromaticity for delocalized sigma electrons and fulfill other requiremen
249 bly aromatic with six delocalized pi and six delocalized sigma electrons and should exist for a serie
251 es at the Au-thiol interface, and not by the delocalized sigma states in the C-C backbones, clarifyin
252 perature, long-range incoherent transport of delocalized singlet excitons on pico- to nanosecond time
253 ry photoexcitations in conjugated dimers are delocalized singlets that enable fast and efficient iSF.
254 re therefore converted into relatively inert delocalized species A(*) and/or B(*) that inhibit the ch
255 ronic structure with an unexpected partially delocalized spin, as evidenced by electron paramagnetic
257 Cu-Cu spectroscopic features, and a valence delocalized state of Cu(A) are difficult to reproduce in
259 nfined state and a nearby Fermi reservoir of delocalized states has underpinned many advances in spin
260 onally to localized surface states or to the delocalized states of the QD core, (ii) energy or electr
261 fur ions on the surfaces of the QDs (and not delocalized states within the QDs) are the electron dono
265 rporation of targeting moieties into the non-delocalized structure of pentamethine and heptamethine i
266 high-quality DFT calculations, a symmetric, delocalized structure with no difference in bond length
268 th possess a 13-atom icosahedral core with 8 delocalized superatomic electrons (8e), but their emissi
269 ity of electronic structure in this strongly delocalized superchromophore and reflect the complicatio
270 esonances transitions to that from spatially delocalized surface plasmon excitations, exhibiting mult
271 the addition and removal of electrons from a delocalized system should lead to considerable increases
273 r complex (1(2-)) featuring an extended, pai-delocalized, tetra-amidate macrocyclic ligand (TAML) as
274 eutral triplet exciton is substantially more delocalized than the positive polaron, exceeding 10 mono
276 The ability of the twisted helicene frame to delocalize the negative charge was probed as a perturbat
278 degree of conjugation and the capability to delocalize the pi-electrons which contribute to the stab
281 s attributed to the inability to efficiently delocalize the spin on a phenyl unit, starkly contrary t
282 en-shell molecules, in which spin density is delocalized through a helical conjugated backbone, hold
283 ybrid theory, the parent radicals of AOs are delocalized through allylic rearrangement, and as a cons
284 isotopic labeling shows that the radical is delocalized throughout the adenine ring of A2503, althou
289 h transiently expressed SEC6A1A variants are delocalized to the Golgi, a finding confirmed in a renal
291 6 gene expression in transgenic mouse kidney delocalizes Trpv5 from the luminal membrane in the DCT.
297 monoradicals, based on either a localized or delocalized view, whichever is suitable, are then discus
299 converge toward a picture of electrons being delocalized within crystalline domains of increased size