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1 c control has been proposed as the source of diastereoselectivity.
2 rates and proceeded with high efficiency and diastereoselectivity.
3 ide lactams with high levels of enantio- and diastereoselectivity.
4 ne oxidation levels with complete control of diastereoselectivity.
5 four contiguous stereocentres, all with high diastereoselectivity.
6 chains with very high levels of enantio- and diastereoselectivity.
7 loss of enantioselectivity and with complete diastereoselectivity.
8 y functionalized cyclohexenes with high endo diastereoselectivity.
9 phosphoric acids that proceed with excellent diastereoselectivity.
10 nes and aliphatic ketones possible with high diastereoselectivity.
11 -trisubstituted 4-hydroxypiperidines in high diastereoselectivity.
12 including heteroatoms with high enantio- and diastereoselectivity.
13 wide range of cyclobutenes with exceptional diastereoselectivity.
14 keleton of the target compound with complete diastereoselectivity.
15 highly substituted azetidines with excellent diastereoselectivity.
16 nteractions over C-H...pi is responsible for diastereoselectivity.
17 thylated adducts in good yield and excellent diastereoselectivity.
18 ylenedicarboxylate to form adducts with high diastereoselectivity.
19 of two isomeric products with good yield and diastereoselectivity.
20 s by a simple procedure with high yields and diastereoselectivity.
21 hydes all couple in good yield and with high diastereoselectivity.
22 (BH4)2 gives a 1,3-amino alcohol with modest diastereoselectivity.
23 h levels of substrate-controlled (undesired) diastereoselectivity.
24 in high to excellent yields with exclusive Z diastereoselectivity.
25 ienophile and a borole that shows remarkable diastereoselectivity.
26 ditives have changed the regioselectivity or diastereoselectivity.
27 reocenters with good to excellent regio- and diastereoselectivity.
28 odel can be used to rationalize the observed diastereoselectivity.
29 bstitution pattern and also with predictable diastereoselectivity.
30 tiguous stereocenters with high enantio- and diastereoselectivity.
31 yl group to control the regio-, enantio- and diastereoselectivity.
32 tion states, leading to remarkable levels of diastereoselectivity.
33 s in excellent yields, with total chemo- and diastereoselectivity.
34 types, and may exhibit enantiospecificity or diastereoselectivity.
35 tion mechanism and observed regioselectivity/diastereoselectivity.
36 rahydroindolizidines in high yield with high diastereoselectivity.
37 ing stereogenic centers in high enantio- and diastereoselectivity.
38 tions of secondary C-H bonds occur with high diastereoselectivity.
39 eaturing an alkenyl side chain with complete diastereoselectivity.
40 nding dienylboronates in high efficiency and diastereoselectivity.
41 the alkene insertion step determines product diastereoselectivity.
42 d]pyran derivatives in good yields with high diastereoselectivity.
43 F bond formation occurs with full regio- and diastereoselectivity.
44 stereoelectronic rationale for the observed diastereoselectivity.
45 pled product in high chemical yield and good diastereoselectivity.
46 lins in high yields and with high regio- and diastereoselectivity.
47 ly matched, affords the highest enantio- and diastereoselectivity.
48 ins in excellent yield and high enantio- and diastereoselectivity.
49 ctively, in good yield with moderate to good diastereoselectivity.
50 pyrrolidines with moderate to complete trans diastereoselectivity.
51 rates adamantylethylenes in 6% yield with no diastereoselectivity.
52 tives in high yield and with high regio- and diastereoselectivity.
53 aldol-aldol reaction sequence with excellent diastereoselectivity.
54 substituted tetrahydrofurans with excellent diastereoselectivity.
55 -sulfinamido ynones in a very good yield and diastereoselectivity.
56 5.3.0] azabicyclic structures with excellent diastereoselectivity.
57 tetrahydro-1,2-oxazines with high levels of diastereoselectivity.
58 ds and excellent levels of catalyst-directed diastereoselectivity.
59 ined in up to 80 per cent yield and 98:2 Z:E diastereoselectivity.
60 d decalin derivatives with good to excellent diastereoselectivity.
61 ituted cyclobutanes (>50 examples) with high diastereoselectivity.
62 radamantylethylenes in 11% yield with slight diastereoselectivity.
63 nary centers with good to complete levels of diastereoselectivity.
64 8/5-tricyclic ring system proceeds with high diastereoselectivity.
65 hydrofurans with high levels of enantio- and diastereoselectivity.
66 o proceed efficiently with high enantio- and diastereoselectivity.
67 ave been prepared in a single step with high diastereoselectivity.
68 dienyl ligand drastically improves yield and diastereoselectivity.
69 od functional group tolerance, and excellent diastereoselectivity.
70 th excellent enantioselectivity and complete diastereoselectivity.
71 yclobutyl boronic esters with high levels of diastereoselectivity.
72 able step with excellent turnover number and diastereoselectivity.
73 the anti-chlorocyclopropane product in high diastereoselectivity.
74 transformation exhibits excellent regio- and diastereoselectivity.
75 ing dimer with a syn-head-to-tail regio- and diastereoselectivity.
76 yl-substituted beta-lactams with outstanding diastereoselectivity.
77 ion of two dienes that determines regio- and diastereoselectivity.
78 o high yields and with moderate to excellent diastereoselectivity.
79 ith good to excellent enantioselectivity and diastereoselectivity.
80 as isolated as a unique product with a total diastereoselectivity.
81 rnishing phosphinates with high enantio- and diastereoselectivity.
82 high yield, with high enantioselectivity and diastereoselectivity.
83 3) coupling products in good yields and high diastereoselectivity.
84 ol, in directing cyclopropanation to control diastereoselectivity.
85 ylated products in good yields and with high diastereoselectivity.
86 are obtained in good yield with up to >20:1 diastereoselectivity.
87 syn 2,5-disubstituted pyrrolidines with high diastereoselectivity.
88 of these compounds with high efficiency and diastereoselectivity.
89 nd indolines with high enantio-, regio-, and diastereoselectivity.
90 drobenzofurans in good yields with excellent diastereoselectivity.
91 tained with high enantioselectivity and good diastereoselectivity.
92 ns-cyclopropylamines in good yields and high diastereoselectivities.
93 tituted borocyclopropanes in high yields and diastereoselectivities.
94 of substrates with excellent yields and good diastereoselectivities.
95 ,1-b]oxazoles with good yields and excellent diastereoselectivities.
96 rovided beta-lactones with high enantio- and diastereoselectivities.
97 l difluoride products are produced with high diastereoselectivities.
98 ess aspidosperma-type alkaloids in excellent diastereoselectivities.
99 a (syn, anti)-mode with excellent regio and diastereoselectivities.
100 ined in high yields, regioselectivities, and diastereoselectivities.
101 e desired products in excellent enantio- and diastereoselectivities.
102 as major compounds with very high regio- and diastereoselectivities.
103 eogenic centers were prepared with excellent diastereoselectivities.
104 es often undergo cascade reactions with high diastereoselectivities.
105 erate chlorocyclopropanes in high yields and diastereoselectivities.
106 plays an important role in promoting reverse diastereoselectivities.
107 tuted cyclopentanones with high enantio- and diastereoselectivities.
108 cally good yields and with good to excellent diastereoselectivities.
109 r to excellent yields, moderate to excellent diastereoselectivities (2:1 to >99:1), and low to good e
113 tained in 27-45% yields, with high levels of diastereoselectivity (93:7 to 100:0 dr) and generally go
114 els-Alder reaction to afford 22 in excellent diastereoselectivity, a one-step gold-catalyzed propargy
115 omeric ratios (up to 98.5:1.5) and excellent diastereoselectivities (all >99:1) were observed employi
116 chemo- and regioselectivity as well as high diastereoselectivity, allowing for the synthesis of func
117 moderate-to-good yields (up to 81%) in high diastereoselectivities and enantioselectivities (dr up t
118 btained in high yields and good to excellent diastereoselectivities and enantioselectivities (up to 9
119 ith anti- and syn-diastereomers both in good diastereoselectivities and enantioselectivities from the
120 an-7-carboxylates have been obtained in high diastereoselectivities and enantioselectivities from the
122 g a fully substituted stereocenter with good diastereoselectivities and excellent enantioselectivitie
123 their respective alkanes in high yields and diastereoselectivities and introduces a new approach to
126 s of pyrrolidino[60]fullerenes with complete diastereoselectivities and very high enantioselectivitie
127 reaction were obtained in high enantio- and diastereoselectivities and were converted to a variety o
134 and-Claisen rearrangement proceeds with high diastereoselectivity and chirality transfer to afford al
138 -Napieralski-reduction reactions with a high diastereoselectivity and high enantioselectivities (up t
139 5- and 6-membered ring systems with perfect diastereoselectivity and high enantioselectivity under c
142 mediates occurred with high to excellent syn diastereoselectivity and led, in most cases, to oxazolin
143 have been made, but exceptional and tunable diastereoselectivity and regioselectivity (head-to-head
145 t the tetracyclic spirooxindole core in high diastereoselectivity and the use of Bosch's chiral lacta
148 itution patterns are obtained with excellent diastereoselectivities, and the bioactive C20-oxidized a
149 ompeting annulation processes, exclusive cis-diastereoselectivity, and distinct regioselectivity for
150 l ketones, esters, and amides in high yield, diastereoselectivity, and enantioselectivity (generally
152 transformation proceeds with high regio- and diastereoselectivity, and is effective for a broad range
155 e replicator forms efficiently and with high diastereoselectivity, and this replication process bring
156 omoallylic alcohols in high yield, excellent diastereoselectivity, and usually high enantioselectivit
157 n 2- and 2,3-positions of anthracenes on the diastereoselectivity (anti vs syn dimer) of the [pai(4s)
159 , the catalysts/solvent-dependent switchable diastereoselectivities are proposed to be the result of
162 1S,3S)-3-arylphospholane 1-oxide 4 with high diastereoselectivity as well as high enantioselectivity.
163 1,2,4-naphthotriones, such as small endo/exo diastereoselectivity, as well as pronounced ortho/meta r
164 activation as well as origin of enantio- and diastereoselectivities, both of which are central to the
165 not only proceeded with excellent regio- and diastereoselectivity but also delivered the respective c
166 while electrostatic interactions control the diastereoselectivity by selectively stabilizing the endo
168 e cage's microenvironment also promotes high diastereoselectivity compared to a conventional base-cat
171 perimentally observed enantioselectivity and diastereoselectivity data, as well as the origin of the
174 n good to excellent yields (45-99%) and high diastereoselectivities (dr >99/1, (1)H NMR) via intercep
176 roducts were obtained with an extremely high diastereoselectivity (dr >99:1), and the newly formed sy
177 71% for 13 examples), with good to very good diastereoselectivity (dr 5:1 to 10:1 for 20 examples), f
178 st in terms of effecting both good yield and diastereoselectivity (dr from 3:1 to 32:1 for 8 examples
179 s are formed in this key step with excellent diastereoselectivity due to the conformational bias of t
181 Notably, the reaction proceeds with good diastereoselectivity, favoring the symmetrical product.
183 o ester provided arylglycines with very high diastereoselectivities for a range of directing groups i
184 on structures determines high trans- and syn-diastereoselectivities for aldol reactions of SF5-acetat
185 p to 98% switchable regioselectivity and 98% diastereoselectivity for the previously minor syn-cyclob
187 puts, with the reaction proceeding with high diastereoselectivity for those substrate combinations th
188 ofurans were obtained with good to excellent diastereoselectivity from readily available acyclic prec
191 stilbene products were formed with excellent diastereoselectivity (>/=50:1) in all cases, and it is c
193 fashion via the NCAL process with excellent diastereoselectivity (>19:1) utilizing 4-pyrrolidinopyri
194 This reaction proceeds with high levels of diastereoselectivity (>20:1) and high levels of enantios
198 for 16 examples), with excellent Z:E isomer diastereoselectivity (>=19:1 for 16 examples), and with
200 single transformation, high levels of double diastereoselectivity have been achieved in a synthesis o
204 eaction proceeds with good yield and in high diastereoselectivity in favor of the more stable isomer.
205 nctional groups, and can achieve exceptional diastereoselectivity in functional-group-directed hydrog
208 I) to the Et(3)N N-ligand efficiently alters diastereoselectivity in Pd(0)/InI-mediated allylations o
209 clization to give phostones with a very high diastereoselectivity in the formation of the new chiral
213 iral amino acids were transformed, with high diastereoselectivity, into either cis or trans 5-substit
214 The TBAF-catalyzed VMMR afforded high anti-diastereoselectivity irrespective of the solvents used.
219 very efficiently to provide high control of diastereoselectivity (</=100% de) under mild conditions.
220 gioselectivity (crossed product) and perfect diastereoselectivity (nine examples, 34-99% yield).
221 reover, our calculations nicely fit with the diastereoselectivities observed experimentally for potas
223 catalyst was found to override the inherent diastereoselectivity observed during a reductive radical
228 -ray structures of quaternized products, the diastereoselectivity observed may be rationalized via a
229 formed to explore the origin of the high syn diastereoselectivity obtained through the preferred 5-ex
230 ll, the high levels of enantio-, regio-, and diastereoselectivity obtained, in concert with the abili
232 , and also by the turning on by light of the diastereoselectivity of a peptide chain extension reacti
233 this article, stereochemical effects on the diastereoselectivity of arabinofuranosidation are invest
236 a cyclopropane molecule together with a high diastereoselectivity of further C-C bond formation facil
237 ns/cis amide bond ratio and the enantio- and diastereoselectivity of structurally related peptidic ca
239 lfides intermediates in order to improve the diastereoselectivity of the cyclization step and, hence,
245 de additive was found to be critical for the diastereoselectivity of the reaction, which is proposed
252 rity of the products, resulting in excellent diastereoselectivities, often with final dr > 99:1.
255 s were investigated, giving products in high diastereoselectivity, over 99% ee in several cases and f
256 ionally, the reaction featured excellent cis-diastereoselectivity providing access to C6-carbon-funct
257 which yielded products in 27-83% yield with diastereoselectivities ranging from 5:1 to 20:1 (11 exam
259 meric excess) or cis isomer (with yields and diastereoselectivity ranging from modest to excellent de
260 ispheres, the products were formed with full diastereoselectivity regarding all porphyrin-porphyrin a
261 ded insights into the origin of the high syn diastereoselectivity resulting from the radical cyclizat
263 ential component of anticoagulant drugs with diastereoselectivity superior to previously published pr
264 oupling strategy that proceeds with a higher diastereoselectivity than found for the natural product
265 rates undergo 5-exo cyclization, with higher diastereoselectivity than the analogous all-carbon radic
266 s were prepared in good yields and excellent diastereoselectivities through the first reported [3+3]-
267 ree contiguous stereogenic centers with high diastereoselectivity through a rhodium-catalyzed intramo
270 on proceeds with high levels of enantio- and diastereoselectivity to afford unique cyclopropanes that
271 dihydropyridine, steric factors allowed the diastereoselectivity to be modulated to favor either end
272 lity, lead to a significant breakdown of the diastereoselectivity to generate a mixture of (DeltaDelt
274 scaffold with excellent chemo-, regio-, and diastereoselectivity under exceptionally mild conditions
277 nation products were obtained with excellent diastereoselectivities (up to 98:2 d.r.) and in high yie
279 utenes in good yields with high enantio- and diastereoselectivities (up to 99 % ee, and >20:1 d.r.).
280 d independently in good yields and excellent diastereoselectivity (up to >20:1 dr) for a wide scope o
281 s in very high yields (up to 95%), with high diastereoselectivity (up to >99:1) and with up to 97% ee
283 ve a mixture of diastereomers with excellent diastereoselectivity (up to dr = 99:1), which were isola
285 ring scaffold, an enhancement of epoxidation diastereoselectivity was not observed, while introductio
286 ution pattern of the starting material, high diastereoselectivity was observed in the aryl migration,
289 tional theory calculations, and the observed diastereoselectivity was rationalized in the context of
290 ent reducing agent because it exhibited high diastereoselectivity, we observed various behaviors of t
292 In reactions at a prochiral center, modest diastereoselectivities were observed with the formation
294 chanism and reasons for regioselectivity and diastereoselectivity were analyzed using theoretical cal
295 ed as single diastereomers or with excellent diastereoselectivities when benzo-15-crown-5 in CH2Cl2 w
296 the Diels-Alder reaction only displays high diastereoselectivity when the diene bears an additional
297 molecular Friedel-Crafts reaction, with high diastereoselectivity, where only the trans product was o
298 dithioacetal substrates resulted in 1,2-syn diastereoselectivity, which is consistent with the C2-F
299 inylogous Mannich products in good yield and diastereoselectivity with excellent enantioselectivity (
300 ropyridine derivatives were obtained in high diastereoselectivity with good functional group compatib