ライフサイエンスコーパス: diatomic

1 emely rapid electronic dynamics in atoms and diatomics.

2 s close to that predicted (740 cm(-1)) for a diatomic (18)O-(18)O stretch.

3 tions defined by the contact between oxygen (diatomic) and the picket-fence porphyrin (macromolecule)

4 port a short H/H distance in the coordinated diatomic, and DFT calculations show that the transition

5 This remarkable diatomic anion has been the subject of study since the l

6 limidazol-2-ylidene (IMe) to coordinate with diatomic B(2) species afforded a tetrakis(N-heterocyclic

7 mal side of the heme rather than the typical diatomic binding pocket on the distal side when the 5-co

8 mal side of the heme rather than the typical diatomic binding pocket on the distal side.

9 have prepared and structurally characterized diatomic C(2) as a monoligated complex L C(2) using a bu

10 have prepared and structurally characterized diatomic C(2) as a monoligated complex L->C(2) using a b

11 to naturally occurring F(2), O(2) and N(2), diatomic C(2) is an intriguing species that has only bee

12 Here, we report a Fe/Cu diatomic catalyst on holey nitrogen-doped graphene which

13 ed on simple theoretical considerations of a diatomic cleavage of a stable covalent bond, for example

14 Two diatomic clusterfullerenes, viz.

15 rd-like coordination of the active site with diatomic CO and cyanide ligands.

16 the resonance Raman spectrum of 2 reveals a diatomic Co-O vibration band at 770 cm(-1), which provid

17 stimates are obtained for hydrogen-saturated diatomics composed of p-block elements coming from the s

18 lticentered cooperativity beyond established diatomic concepts.

19 The (2FeH) subsite features a diatomic coordination sphere composed of three CO and tw

20 Thus, the diatomic cyanide (-CN) and isocyanide (-NC) ligands are

21 We engineered diatomic dielectric metasurfaces supporting bound states

22 as set an expectation that the triple-bonded diatomic diphosphorus molecule (P(2)) should more closel

23 In this work, we design and propose a linear diatomic elastic metamaterial using dual-resonator conce

24 e composite carrier (CS) construct Cu and Sn diatomic electrocatalyst (CuSn/CS-1).

25 Diatomic elemental solids are highly compressible due to

26 ctron spin density localized on the internal diatomic gadolinium cluster and not on the heterofullere

27 In mammals, the diatomic gas is critical to the cyclic guanosine monopho

28 t study on the slow phase of the dynamics of diatomic gas molecule interaction with NPs comprises an

29 ternative to heme or flavin for redox and/or diatomic gas sensing and regulation of DGC activity.

30 ped-flow measurements with NO as a surrogate diatomic gas, we demonstrate up to 3.5-fold enhancement

31 Developing a means of delivering a diatomic, gaseous free radical has been a technical chal

32 essor activity, and undergoes reduction when diatomic gases are present.

33 vity to a heme-binding domain for sensing of diatomic gases such as oxygen, carbon monoxide, and nitr

34 to the control of gene networks by steroids, diatomic gases, and other small molecules.

35 lso show that E75-heme responds to the small diatomic gases, nitric oxide and carbon monoxide.

36 The diatomic [Ge2](4-) unit is characterized by the shortest

37 havior of MIWs has been limited to mono- and diatomic geometries.

38 nse to ligating the substrate complex with a diatomic, H-bond acceptor ligand.

39 the electronic and rotational shifts of the diatomic halides of Pb and Tl have been made by Tiemann

40 Nitric oxide, NO, the diatomic hybrid of dinitrogen and dioxygen, has extensiv

41 The influence of these diatomics identifies EG as the key catalytic intermediat

42 e interaction, and reactivity with exogenous diatomics) illustrating the utility of these non-native

43 of bimolecular reactions of silicon nitride diatomics in chemical vapor deposition techniques and in

44 nt analysis of bonding in a great variety of diatomics, including more or less polar ones.

45 eported that aimed at lowering the access of diatomic inhibitors to the active site pocket, but the m

46 By varying Cu and Y compositions, diatomic interactions were studied under H(2) and ethano

47 s and elucidated Cu speciation controlled by diatomic interactions.

48 atoms on different molecules combine to form diatomic ions that are detected with a NanoSIMS instrume

49 ved, wherein the electronic structure of the diatomic is observed to mimic that present in the isoele

50 he E7 channel that can accommodate an apolar diatomic ligand and enhances ligand uptake particularly

51 netics measurements, optical absorbance, and diatomic ligand binding studies.

52 -dependent kinetic measurements of ultrafast diatomic ligand binding to the "bare" protoheme (L(1)-Fe

53 ed by significant reductions in the rates of diatomic ligand binding to the heme iron.

54 s a significant influence on the kinetics of diatomic ligand binding to the heme.

55 firmed reduced redox state and the status of diatomic ligand complexes during X-ray diffraction data

56 Diatomic ligand discrimination by soluble guanylyl cycla

57 s also highlight the importance of the trans diatomic ligand in altering the binding and sensitivity

58 kyl isocyanides (CNRs) identify pathways for diatomic ligand movement into and out of Mb, with their

59 The nature of diatomic ligand recombination in heme proteins is elucid

60 otential interactions between the heme-bound diatomic ligand, substrate l-NHA, and the surrounding pr

61 .5 A to accommodate the presence of a mobile diatomic ligand, suggesting a mechanism for communicatio

62 KatG (compound III) also contains a low-spin diatomic ligand-heme adduct (heme-O2), it is reasonable

63 r the sGC heme pocket conformation to retain diatomic ligands and thus activate the enzyme alone or i

64 The diatomic ligands are sensitive reporter groups for struc

65 The structures of various diatomic ligands bound to the heme iron can mimic the di

66 Leu residue inhibits distal coordination of diatomic ligands by decreasing k(on) as well as increasi

67 provide unambiguous experimental proof that diatomic ligands can enter and exit a globin through an

68 key event in the mechanism of photolysis of diatomic ligands following a porphyrin ring pi-pi* trans

69 alculations yielded vibrational modes of the diatomic ligands for conceivable H-cluster structures.

70 bstrate binding event prevents the escape of diatomic ligands from the distal heme binding pocket, st

71 Diatomic ligands in hemoproteins and the way they bind t

72 Three unusual diatomic ligands in the form of two cyanides (CN(-)) and

73 We have probed the dynamics of the diatomic ligands NO and CO within the isolated heme doma

74 Therefore, the formation of the diatomic ligands relies on dedicated biosynthesis pathwa

75 The reduced heme iron binds diatomic ligands such as CO only under destabilizing con

76 vity, interactions between Tyr171 and distal diatomic ligands turn the kinase activity on and off.

77 all possible spin states of the three common diatomic ligands, CO, NO, and O2, and high-spin heme iro

78 ilities of the de novo heme proteins to bind diatomic ligands, we measured the affinity for CO, the k

79 or the increase in electron density on bound diatomic ligands, which is required for peroxidase funct

80 forms of EPO, LPO, and MPO toward binding of diatomic ligands.

81 dG lyses the substrate tyrosine to yield the diatomic ligands.

82 stimate the numbers of unpaired electrons in diatomic LnB clusters.

83 ur method of unidirectional waveguiding to a diatomic magnetoinductive array featuring both forward-w

84 ate atoms using a two-photon transition to a diatomic molecular state.

85 Electron density corresponding to a diatomic molecule (probably dioxygen) was sandwiched bet

86 mechanistic details for the activation of a diatomic molecule by a prototypical FLP.

87 example, the dissociative adsorption of the diatomic molecule H2--a central step in many industriall

88 orbit coupling show that the U[triple bond]C diatomic molecule has a quintet (Lambda = 5, Omega = 3)

89 h the ground-state reactant atom and product diatomic molecule have open-shell character, which intro

90 rong density, the right size and shape for a diatomic molecule is found between the other side of the

91 ms in two steps: first, the two atoms of the diatomic molecule undergo consecutive collisions with a

92 Boron monofluoride (BF) is a diatomic molecule with 10 valence electrons, isoelectron

93 uency ratio, which is appropriate for the UC diatomic molecule, and another new band at 891 cm(-1) gi

94 rom crystals soaked in H2O2 revealed a bound diatomic molecule, assigned to a cis-mu-1,2-peroxo bridg

95 As a homonuclear diatomic molecule, N(2) is difficult to detect spectrosc

96 As a small diatomic molecule, NO has been assumed to freely diffuse

97 For the excitation to a repulsive state of a diatomic molecule, one expects a single broad peak in th

98 The interstellar diatomic molecule, phosphorus mononitride (P=N), is high

99 ee-dimensional magneto-optical trapping of a diatomic molecule, strontium monofluoride (SrF), at a te

100 p orbitals of hydrogen and alkali atoms into diatomic molecule-like dimers and free-electron bands of

101 fically in real time for the carbon monoxide diatomic molecule.

102 function as gates for escape of the product diatomic molecule.

103 e-of-the-art variational ansatzes for atoms, diatomic molecules and a strongly correlated linear H(10

104 yond the hitherto achieved imaging of simple diatomic molecules and is based on the combination of a

105 Actinide diatomic molecules are ideal models to study elusive act

106 low 1 microkelvin have been demonstrated for diatomic molecules assembled from pre-cooled alkali atom

107 dely investigated, the valence isoelectronic diatomic molecules EX (E = group 13 element, X = group 1

108 eration and various quantum trajectories for diatomic molecules for the first time.

109 Recently, magneto-optical traps (MOTs) of diatomic molecules have been demonstrated(9-12), providi

110 tum chemistry and metrology, yet even simple diatomic molecules have historically been limited to 0.1

111 e actinide multiple bonds, but most of these diatomic molecules have so far only been studied in soli

112 The subnanoscale size of typical diatomic molecules hinders direct optical access to thei

113 For several diatomic molecules in a minimal basis set, we benchmark

114 is used to eject highly rotationally excited diatomic molecules into alcohols and water, rotational c

115 t highly mobile loops can limit diffusion of diatomic molecules into and out of a protein cavity, a r

116 The first row diatomic molecules N2 and CO have played central roles i

117 Isolated diatomic molecules of iodine monochloride (ICl) were pho

118 ulations suggest that rotational dynamics of diatomic molecules play an essential role in filamentati

119 bjFixLH, contains a heme cofactor that binds diatomic molecules such as carbon monoxide and oxygen an

120 hemical reactor, concentrating and orienting diatomic molecules such as NO, CO, O(2), and H(2)O(2) in

121 idence is particularly clear from studies of diatomic molecules that molecular vibration can be stron

122 is conserved over the entire range from its diatomic molecules to clusters and further to crystals.

123 created a quantum superposition of atoms and diatomic molecules two chemically different species.

124 ctronic early transition metal heterogeneous diatomic molecules, M-X- (M = Ti,Zr,W; X = O or C).

125 Of the simple diatomic molecules, oxygen is the only one to carry a ma

126 Compared with diatomic molecules, polyatomic molecules have distinct r

127 For diatomic molecules, these lines originate from points wh

128 ong-field processes is built upon studies of diatomic molecules, which typically have electronic stat

129 , in a pressure range between 50 and 94 GPa, diatomic nitrogen can be transformed into a non-molecula

130 The triple bond of diatomic nitrogen has among the greatest binding energie

131 eals precisely why; the triplet ground state diatomic O(2) molecule is paramagnetic and exists in air

132 sotropic (1)H/(2)H hyperfine coupling to the diatomic of Co-H2 is nearly 4-fold smaller than for Fe-H

133 As a result, the Ru-Ni diatomic one is identified as the best active center.

134 function of GCS-type transducers is to bind diatomic oxygen and perhaps other gaseous ligands, and t

135 exception being the formation of ozone from diatomic oxygen in the presence of UV radiation or elect

136 Uint is photogenerated from incorporation of diatomic oxygen to IPU and is subjected to thermolysis w

137 oral pathogen Streptococcus mutans to reduce diatomic oxygen to water while oxidizing NADH to NAD(+).

138 enabled by constructing Ni-partnered hetero-diatomic pairs, and thereby greatly enhancing CO(2)-to-C

139 ddress the issues, we design a catalyst with diatomic Pd-Cu sites on N-doped carbon by modulation of

140 ydrogel-based metamaterial (in the form of a diatomic phononic chain) as well as the effects of syste

141 A versatile diatomic physiological messenger, nitric oxide (NO), is

142 These diatomic products form an enzyme-bound Fe(CO)x(CN)y synt

143 ), S((3)P) and H(2) co-fragments, and in the diatomic products, inverted internal state population di

144 e pathway to the simplest silicon and sulfur diatomic provides compelling evidence for the origin of

145 ilylene, and L:Si=Si:L, a carbene-stabilized diatomic silicon molecule with the Si atoms in the forma

146 HOR catalytic activities of single-atom and diatomic sites as a function of *H and *OH binding energ

147 ubsequently synthesize a catalyst with Ru-Ni diatomic sites supported on N-doped porous carbon, which

148 ociation and strengthen OH adsorption at the diatomic sites, and thus enhance the kinetics of HOR.

149 es the HOR activity resulting from the Ru-Ni diatomic sites.

150 physically meaningful only for monatomic or diatomic solids.

151 s three-electron reduction gives an antimony diatomic species capped by two carbenes.

152 Herein, we report a charged U=N diatomic species captured in fullerene cages and stabili

153 ted to be viable for a significant number of diatomic species.

154 is acids to facilitate capture/activation of diatomic substrates.

155 Expulsion of diatomic sulfur, S(2), is unlikely from the unimolecular

156 We propose a simple diatomic system trapped inside an optical cavity to cont

157 resulting from cleavage of N(2) and CO, the diatomics with the two strongest bonds in chemistry.