ライフサイエンスコーパス: dichloroethane

1 ubmerged in an organic continuous phase (1,2-dichloroethane).

2 ions of cis-enediynes (see scheme; DCE = 1,2-dichloroethane).

3 singlet oxygen quantum yield obtained in 1,2-dichloroethane.

4 crometer water nanodroplets suspended in 1,2-dichloroethane.

5 ingle aqueous microdroplets suspended in 1,2-dichloroethane.

6 etween aqueous LiCl and LiTFSI solutions and dichloroethane.

7 and selectively convert chloroethane to 1,2-dichloroethane.

8 arison to other chlorinated solvents such as dichloroethane.

9 BF3.Et2O and excess pyrrole in refluxing 1,2-dichloroethane.

10 ing of Zn(II) tetraphenylporphyrin to CN- in dichloroethane.

11 ecursors to water nanodroplets emulsified in dichloroethane.

12 c solvents benzene, dichloromethane, and 1,2-dichloroethane.

13 on of 10 mM valinomycin and 10 mM ETH 500 in dichloroethane.

14 r results were observed for 1,2-dibromo- and dichloroethanes.

15 ; 1,1,1-trichloroethane (1,1,1-TCA); and 1,1-dichloroethane (1,1-DCA), range from -26.5 per thousand

16 CP) to 4-CP, and tetrachloroethene (PCE)/1,2-dichloroethane (1,2-DCA) completely to ethene.

17 1,2-Dichloroethane (1,2-DCA) is a chlorinated solvent classi

18 aerobic and anaerobic biodegradation of 1,2-dichloroethane (1,2-DCA) using five microbial cultures.

19 ation during anaerobic biodegradation of 1,2-dichloroethane (1,2-DCA) via dihaloelimination by Dehalo

20 onation during aerobic biodegradation of 1,2-dichloroethane (1,2-DCA) via oxidative cleavage of a C-H

21 tants under laboratory conditions, e.g., 1,2-dichloroethane, 1,2,3-trichloropropane and gamma-hexachl

22 The presence of 1,2-dichloroethane (10mgL(-1)) was proved unambiguously on o

23 f other environmental pollutants such as 1,2-dichloroethane (72 years), paraoxon (13 months), atrazin

24 However, monomerization of CP 3 in dry 1,2-dichloroethane affords bright green diamagnetic Co(III)(

25 ements were also obtained in the solvent 1,2-dichloroethane, although the analysis of the system is c

26 l chloride and hydroxide ion and between 1,2-dichloroethane and acetate in solution.

27 fer voltammetry at the interface between 1,2-dichloroethane and an aqueous buffer solution or undilut

28 1, that reductively dechlorinates TCA to 1,1-dichloroethane and chloroethane.

29 synthesis of N-arylsaccharin derivatives in dichloroethane and methyl 2-(N-arylsulfamoyl)benzoates i

30 We demonstrate the quantification of 1,2-dichloroethane and nitrobenzene into water, yielding dif

31 ditions induced by osmocene dissolved in 1,2-dichloroethane and the subsequent water splitting by the

32 ion of 1,1,2-TCA, which can produce both 1,2-dichloroethane and vinyl chloride, was assessed for each

33 ate daughter products DDD (dichloro-diphenyl-dichloroethane) and DDE (dichloro-diphenyl-dichloroethyl

34 t were made for 4-chlorotetrahydropyran, 1,2-dichloroethane, and benzyl alcohol have also confirmed u

35 IEs measured in CCl(4), CHCl(3), CH(2)Cl(2), dichloroethane, and chlorobenzene at -23 degrees C showe

36 of water-solvent systems, viz: octanol, 1,2-dichloroethane, and cyclohexane.

37 ylsulfoxide, acetonitrile, nitromethane, 1,2-dichloroethane, and dichloromethane, carried out using v

38 the DhlA structures using the substrate, 1,2-dichloroethane, and halide ions as probes.

39 toluene, THF, tetrahydropyran, i-PrOAc, 1,2-dichloroethane, and MeCN with k(rel) of 7-16.

40 In 1 M triflic acid/dichloroethane, anthracene is protonated at C9, and the

41 heated as a dilute solution in triflic acid/dichloroethane, anthracene undergoes conversion to phena

42 nconclusive results in another case with 1,2-dichloroethane as substrate.

43 sence of oxidants with either DCP or TBHP in dichloroethane as the solvent at 110 degrees C for 16 h,

44 uncompetitive inhibitors of XaDHL with 1, 2-dichloroethane as the varied substrate at pH 8.2 (Cl-, K

45 (p-cymene)}2], AgSbF6, and (NH4)2S2O8 in 1,2-dichloroethane at 100 degrees C for 24 h to afford ortho

46 termined for the duplex trimer by ITC in 1,2-dichloroethane at 20 degrees C.

47 termined for the duplex trimer by ITC in 1,2-dichloroethane at 20 degrees C.

48 ) catalyst and the t-BuOOt-Bu oxidant in 1,2-dichloroethane at 70 C, affords 3-alkyl-3-(hydroxyaryl)o

49 in the presence of 30 mol % BF3.OEt2 in 1,2-dichloroethane at 80 degrees C affords a novel class of

50 sence of stoichiometric amounts of Et(3)N in dichloroethane at 80 degrees C.

51 lar aza-6pai-annulation/aromatization in 1,2-dichloroethane at 80 degrees C.

52 ic pollutants, including vinyl chloride, 1,2-dichloroethane, benzene, and toluene.

53 of the nucleophilic substitution reaction of dichloroethane by a carboxylate group in haloalkane deha

54 The S(N)2 displacement of Cl(-) from 1,2-dichloroethane by acetate (CH(3)CO(2)(-)) in water and b

55 ical isotope effects in the reduction of 1,2-dichloroethane by Dehalococcoides and cobalamin (Dehaloc

56 ic tests revealed that dechlorination of 1,2-dichloroethane by the consortium was strongly inhibited

57 At 348 K in dichloroethane C-H activation of the aryl with the more

58 emically stable solution of this salt in 1,2-dichloroethane can be used as "diazonium ink".

59 reaction of the nucleophilic displacement of dichloroethane catalyzed by haloalkane dehalogenase.

60 trifluoromethanesulfonic acid (TfOH), 1 M in dichloroethane, catalyzes these rearrangements, with slo

61 croclouds with alternating voltage cause 1,2-dichloroethane (ClH(2)C-CH(2)Cl) to be converted to viny

62 Although both vinyl chloride and 1,2-dichloroethane could be simultaneously transformed to et

63 chlorinated intermediate from the H(2)-MPfR, dichloroethane (DCA) and monochloroethane (MCA), were fu

64 for breaking the aliphatic C-Cl bonds in 1,2-dichloroethane (DCA) and trichloroethylene (TCE), are co

65 r (MBR) was tested for bioremediation of 1,2-dichloroethane (DCA) in groundwater.

66 ver, the electrochemical valorization of 1,2-dichloroethane (DCA) is currently challenged by the lack

67 2 displacement reaction of chloride from 1,2-dichloroethane (DCE) by nucleophilic attack of the carbo

68 xychlorocarbene (1-AdOCCl) were generated in dichloroethane (DCE) by photolysis of the appropriate di

69 ylamine, and DABSO under argon atmosphere in dichloroethane (DCE) for 1 h.

70 wire electrode is placed across a H(2)O/1,2-dichloroethane (DCE) interface, creating a Pt-Ir/H(2)O/D

71 alenesulfonate (DNNS) at polarized water/1,2-dichloroethane (DCE) interfaces, i.e., sDNNS(-) (DCE) +

72 ssolved in a tetrahydrofuran (THF) and a 1,2-dichloroethane (DCE) solution, respectively, using pulse

73 of dimethyl sulfoxide (DMSO) along with 1,2-dichloroethane (DCE) was exploited for the incorporation

74 been used to elucidate the reaction of 1, 2-dichloroethane (DCE) with the carboxylate of Asp-124 at

75 ns carried out in CD2Cl2/CD3OD (9/1, v/v) or dichloroethane (DCE), as well as single crystal X-ray di

76 luoromethanesulfonic acid (TfOH), ca. 1 M in dichloroethane (DCE), provides reliable catalytic reacti

77 methanol (MeOH), acetonitrile (ACN), and 1,2-dichloroethane (DCE).

78 well as acetonitrile and cyclohexane in 1,2-dichloroethane (DCE).

79 tential window distinct from that of the 1,2-dichloroethane (DCE)/water ITIES.

80 nides (1.0 equiv) and FeCl(3) (3.0 equiv) in dichloroethane (DCE, 3 mL), at room temperature.

81 nides (1.0 equiv) and FeCl(3) (3.0 equiv) in dichloroethane (DCE, 3 mL), at room temperature.

82 reported in the current-time response of 1,2-dichloroethane(DCE)|water(W) submilli-interfaces after i

83 and 1,2,4,5-tetracyanobenzene (TCNB) in 1,2-dichloroethane (DCLE) exhibit a mirror image relationshi

84 In the case of 1,2-dichloroethane dechlorination, a 6-fold improvement in F

85 at the interface for various oil phases (1,2-dichloroethane, dichloromethane, chloroform, and nitrobe

86 sformed to ethene, prolonged exposure to 1,2-dichloroethane diminished the vinyl chloride transformin

87 most quantitative yield in nonpolar solvent (dichloroethane-DMF, 9:1).

88 =1,8-diazabicyclo[5.4.0]undec-7-ene, DCE=1,2-dichloroethane, DMS=dimethylsulfide).

89 ethane droplet, CO(2) accumulates in the 1,2-dichloroethane droplet.

90 arying polarities: cyclohexane, toluene, 1,2-dichloroethane, ethyl acetate, acetone, acetonitrile, an

91 Upon heating dimethyl sulfoxide (DMSO) with dichloroethane, expectedly unstable chlorine cation pool

92 etectable reductive dehalogenases during 1,2-dichloroethane exposure, suggesting that it catalyzes th

93 en two immiscible electrolyte solutions, 1,2-dichloroethane-H2O.

94 Organic haloalkanes, such as 1,2-dichloroethane, have a negligible interfering effect.

95 idation of the quinoidal bisdithiazole BT in dichloroethane in the presence of [Bu4N][GaBr4] affords

96 r time, given the relative solubility of 1,2-dichloroethane in the water continuous phase, the change

97 u(bpy)(3)(2+) transfer through the water/1,2-dichloroethane interface and (2) electrodeposition of Pd

98 and is surprisingly trapped at the water|1,2-dichloroethane interface and continues to grow.

99 osition of Pd nanoparticles at the water/1,2-dichloroethane interface.

100 in transfer of propranolol at an aqueous-1,2-dichloroethane interface.

101 -)) salt with phosphine oxides OPR(3) in 1,2-dichloroethane is exothermic and leads to the population

102 he pesticide DDT (1,1-(dichlorobiphenyl)-2,2-dichloroethane), is used as the standard treatment, but

103 By precisely positioning a 1,2-dichloroethane microdroplet onto the ultramicroelectrode

104 nce of scandium or ytterbium triflate in 1,2-dichloroethane or a cosolvent mixture of 1/9 THF/dichlor

105 The transformations were performed in 1,2-dichloroethane or acetonitrile under reflux and gave the

106 detains three molecules each of CHCl(3), 1,2-dichloroethane, or isopropyl chloride.

107 er reaction (DeltaG('aq->org)) and water-1,2-dichloroethane partition coefficient (logP(DCE)(')) were

108 er reaction (DeltaG('aq->org)) and water-1,2-dichloroethane partition coefficient (logP(water/DCE)(PE

109 The combination of solvents (dichlorobenzene-dichloroethane) plays a crucial role in achieving quanti

110 (PVC) synthesis, yet selectivity toward 1,2-dichloroethane remains challenged by uncontrolled over-c

111 yl adducts starting from CD(2) Cl(2) and 1,1-dichloroethane, respectively.

112 In this process, dichloroethane serves as an activator of DMSO, effective

113 s a function of the mole fraction of MeOH in dichloroethane showed that the homoadamantyl chloride io

114 A 1,2-dichloroethane solution containing a commercially availa

115 in good to excellent yield by stirring a 1,2-dichloroethane solution of the starting triazene with Cu

116 en studied by IR spectroscopy in benzene and dichloroethane solution.

117 Cl(-)] ion pairs were generated in methanol/dichloroethane solutions, with R(+) as the 1-bicyclo[2.2

118 monoxide) chloride] ion pairs in MeCN or 1,2-dichloroethane solutions.

119 The cascade reactions proceed in 1,2-dichloroethane solvent under visible-light irradiation,

120 In the more polar solvent 1,2-dichloroethane, some salts form both contact and solvent

121 e haloalkane dehalogenase (DhlA), with a 1,2-dichloroethane substrate.

122 In 1,2-dichloroethane the solution is heterogeneous, while the

123 In toluene and dichloroethane, the ee and branched/linear ratios dimini

124 reochemical memory effect in toluene and 1,2-dichloroethane, the reactions in these solvents can be c

125 Cp*=C(5)Me(5), DCE=1,2-dichloroethane, THF=tetrahydrofuran.

126 acid-tolerant OHRB, capable of respiring 1,2-dichloroethane to ethene across a broad pH range, with d

127 lyzes the reductive dihaloelimination of 1,2-dichloroethane to ethene.

128 nmentally important dihaloelimination of 1,2-dichloroethane to ethene.

129 tates product distribution shifting from 1,2-dichloroethane to trichloroethane.

130 ed that increasing the influent ratio of 1,2-dichloroethane to trichloroethene was associated with ec

131 trachloromethane) and on TDIROF for 90% (1,2-dichloroethane) to 100% (trichloromethane) of what was p

132 of chlorinated organic compounds such as 1,2-dichloroethane, trichloroethylene, and tetrachloroethyle

133 c amount of anhydrous FeCl3 in refluxing 1,2-dichloroethane underwent tandem Conia-ene and Friedel-Cr

134 and subsequent exposure of the films to 1,2-dichloroethane vapor led to a significant increase in th

135 ination, promote bidentate adsorption of 1,2-dichloroethane via hydrogen-bond networks, thereby activ

136 al extraction of rubidium at micro water|1,2-dichloroethane (w|DCE) and water|room-temperature ionic

137 hannel deformation when the welding solvent (dichloroethane) was applied between the two chips during

138 arbon tetrachloride-water (CCl4-H2O) and 1,2-dichloroethane-water (DCE-H2O).

139 The transfer of these analytes across a 1,2-dichloroethane/water interface was studied by cyclic vol

140 er of tetraethylammonium (TEA(+)) at the 1,2-dichloroethane/water interface.

141 poly(vinyl chloride) membrane/water and 1,2-dichloroethane/water interfaces.

142 s across the interface between water and 1,2-dichloroethane were measured by steady-state voltammetry

143 r chained OCBPs (1,2-dichloropropane and 1,2-dichloroethane) were more frequently found on TDIROF.

144 bacco resulting in the dehalogenation of 1,2-dichloroethane, which was otherwise recalcitrant.

145 different isotope effects in reaction of 1,2-dichloroethane with Dehalogenimonas (epsilon(C) = -23.0