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1 e if both the N(3)(-) and d-G reactions were diffusion limited.
2 tant, regardless of whether enzyme action is diffusion limited.
3 ried to determine if the folding reaction is diffusion limited.
4 r enzymes where reaction rates are typically diffusion limited.
5 whereas below S*, uptake rates are strictly diffusion limited.
6 that detection and capture is predominantly diffusion limited.
7 te binding to single-molecule probes becomes diffusion-limited.
8 wth kinetics from edge-attachment-limited to diffusion-limited.
9 ier, and the rate of monomer addition is not diffusion-limited.
10 ents no energetic barrier and, therefore, is diffusion-limited.
11 second-order rate constant was approximately diffusion-limited.
12 tranded 30-mer/36-mer complex) appears to be diffusion-limited.
13 as the substrate, chemistry is thought to be diffusion-limited.
14 P2 concentration and appeared to be largely diffusion-limited.
15 strates and the overall in vitro reaction is diffusion-limited.
16 of small-molecule and protein materials are diffusion-limited.
17 anded polypyrimidine sequences appears to be diffusion-limited.
18 that the action of cytidine deaminase is not diffusion-limited.
19 led and whether the rates are activation- or diffusion-limited.
20 e, whereas the binding rate is assumed to be diffusion-limited.
21 which the transport of passive substances is diffusion-limited.
22 Presteady state analysis demonstrates rapid diffusion-limited A3G-ssDNA binding, a slower salt-depen
25 s, such as activation of the Ras GTPase, the diffusion-limited activation rate constant increases wit
27 -assembled irregular Au nano-mounds based on diffusion limited agglomeration at comparatively low ann
29 th numerical simulations based on a model of diffusion limited aggregation (DLA), to show that for vi
30 gurations that correspond to two-dimensional diffusion limited aggregation structures, suggesting tha
32 seudoisocyanine dye, an equation derived for diffusion-limited aggregation of a fractal object satisf
33 nsion of [Formula: see text], reminiscent of diffusion-limited aggregation of nonliving colloidal par
34 ronts and the ensembled average shape of the diffusion-limited aggregation pattern, have been shown t
35 ed surfaces and exhibited both reaction- and diffusion-limited aggregation regimes with rates depende
37 been proposed to model landforms, including diffusion-limited aggregation, self-avoiding percolation
39 on, we show that the dynamics of fission are diffusion limited and enable the isolation of an interme
41 um corneum allows one to distinguish between diffusion-limited and dissolution rate-limited kinetics.
42 of the complex we conclude that catalysis is diffusion-limited and does not depend on protein flexibi
44 nitial Cry1Ab adsorption rates were close to diffusion-limited and resulted in extensive adsorption,
45 at many enzymes are reaction limited and not diffusion limited, and our results suggest that the infl
48 g, it is important to know if a reaction is 'diffusion-limited' as, if this speed limit is reached, t
49 The association process is significantly diffusion-limited, as indicated by the viscosity depende
50 devices with thin enzyme layers that are not diffusion-limited, as it is the case for the PenFETs dis
52 labeled PAI-1s with trypsin suggested that a diffusion-limited association of PAI-1 and trypsin and r
54 hese simulations, combined with estimates of diffusion-limited association rates, suggest a short lif
55 nce information necessary to direct the near-diffusion-limited association reaction in a TR folding r
56 dimeric intermediate that forms in a nearly diffusion-limited association reaction in the stopped-fl
57 repressor, [2-66]2 TR, consists of a nearly diffusion-limited association reaction to form a dimeric
60 w that while vesicle reloading at AZs is not diffusion-limited at the onset of release, diffusion lim
61 der harsher SALE conditions, deviations from diffusion-limited behavior are found due to etching and
64 nce and labeling studies are consistent with diffusion-limited bimetallic self-quenching by electron
66 d immunoassay has been developed to overcome diffusion-limited binding kinetics that often impedes ra
67 ructural recognition, based on a fundamental diffusion-limited binding model, facilitates the tip tra
69 rotein CD63 were analyzed by measuring their diffusion-limited binding rate to an SPR sensor surface
70 ion in solution using a formalism describing diffusion-limited binding under controlled flow conditio
72 ch polyelectrolyte complexes facilitates (i) diffusion-limited binding, (ii) transient ternary comple
76 dynamics-is developed for the calculation of diffusion-limited biomolecular association reaction rate
77 ts indicates that the release of Zn2+ is not diffusion limited but is instead kinetically controlled
78 Thus, intramembrane proteolysis is naturally diffusion-limited, but cells mitigate this constraint by
80 es at or within the surface of the MCLW, the diffusion-limited capture rate has been replaced by fast
81 stable beta-barrel fold and dimer assembly, diffusion-limited catalysis, and electrostatic guidance
82 s to such a degree that activation rates are diffusion limited, causing the two time scales to merge.
84 enerate virtual aggregates formed via either diffusion limited cluster aggregation or reaction limite
86 r results reveal ensilication to be a staged diffusion-limited cluster aggregation (DLCA) type reacti
88 Monte Carlo simulations, based on a modified diffusion-limited cluster aggregation model, strongly su
89 accord with expectation, varied from 1.7 for diffusion-limited cluster aggregation to 2.3 for reactio
91 ransfer is often slow because it is gated by diffusion-limited collisions between sensitizer and cata
93 nd compared CRM, resolving power (R(m)), and diffusion-limited conditional theoretical reduced mobili
94 tion reaction (ORR) was studied under proton diffusion-limited conditions in slightly acidic electrol
100 s constant value is the same as that for the diffusion limited current in a semi-infinite medium.
109 (<100 fs) in blends prepared without ODT or diffusion-limited dissociation in samples prepared with
111 rization of tumor hypoxia as being primarily diffusion-limited does not accurately portray the tumor
116 -consistently explained by load-insensitive, diffusion-limited elongation of (+)-end-tethered actin f
117 interplay between two competing processes: a diffusion-limited encounter between proteins, and the ex
118 14) binding to a Pm kringle accompanies near-diffusion-limited encounter complex formation followed b
119 o-state model for helix formation yields the diffusion-limited end-to-end contact rate of the coil st
120 ical, whereas the chlorine exchange presents diffusion-limited exchanges proceeding through a more co
122 is close to that of the source; in contrast, diffusion-limited export leads to small phloem concentra
123 ve between membrane compartments in part via diffusion-limited, fluid phase transfer through the cyto
124 s assembly proceeds through the formation of diffusion-limited, fractally patterned aggregates on the
129 that lead to divergent predictions: either a diffusion-limited growth model in which plaques grow by
130 cture that strongly resembles a self-similar diffusion-limited growth pattern, with strongly preferre
132 tion process of oxidized species following a diffusion-limited growth regime for DOPC and in the case
133 ally observed presence of a sub-exponential, diffusion-limited growth regime in colonies, which is ab
134 characterized by a rate that is greater than diffusion limited (>10(10) s(-1) M(-1)) and the second p
135 rapping single cells with blood in an oxygen-diffusion-limited high-density microwell array and by us
136 croarray gap height would delay the onset of diffusion-limited hybridization by increasing the amount
137 ular factor will find its mass transfer rate diffusion-limited if it is stationary with respect to it
140 n the length scale at which oxygen supply is diffusion-limited, its occurrence requires very high cel
141 ylammonium as the redox mediator exhibited a diffusion-limited k degrees for the previously KCl-prote
142 )) can be decomposed into contributions from diffusion-limited (k(D)) and reaction-limited (k(R)) rat
143 exchange, consistent with mixed surface- and diffusion-limited kinetics arising from prominent partic
144 n to metallic nanoparticles with essentially diffusion-limited kinetics in a laboratory microwave rea
150 ilibrium and the kinetic competition between diffusion-limited lateral lattice growth versus fluctuat
151 While single cell suspensions can improve diffusion-limited mass transfer, direct cell-cell intera
152 de sensor that alleviates the limitations of diffusion-limited mass transport and non-specific signal
153 his can be achieved by measuring the rate of diffusion-limited mass uptake to a sensor surface modifi
154 sing these array electrodes for steady-state diffusion-limited measurements in electroanalytical appl
155 independent of the tip diameter, indicating diffusion-limited membrane transport of the redox molecu
156 crystal structures employing controlled and diffusion-limited microfluidic environments is demonstra
159 ith transport, whilst the former may include diffusion-limited movement of lactate into the bulk cyto
161 leads to an approximately 10,000-fold longer diffusion-limited observation time per molecule than is
162 e stalk as a morphological adaptation to the diffusion-limited, oligotrophic environments where C. cr
163 ations that are prone to bind NTRs with near diffusion-limited on rates, as shown by stopped-flow kin
164 ion of the copper phyllosilicate followed by diffusion-limited or reaction-limited growth of the copp
165 ed with the highest OV exhibited the highest diffusion-limited ORR current (5.5 mA cm(-2) ) among a s
166 of the corresponding current images for the diffusion-limited oxidation of the redox mediator indica
168 citation of phenanthrene at 256 nm enables a diffusion-limited photoinduced electron transfer to 1,4-
169 ition new Glu's for catalysis is as rapid as diffusion-limited positioning of a small substrate, and
171 y experiments gave results consistent with a diffusion-limited process and revealed a working electro
172 h explosive materials that precedes the slow diffusion-limited process of forming the bulk solid from
173 he volume phase transition of hydrogels is a diffusion-limited process the size of the synthesized hy
174 PRM displays the features consistent with a diffusion-limited process within our experimental condit
175 sed) complex is close to that expected for a diffusion-limited process, (2) the extent of activation
176 eceptors that are slower than expected for a diffusion-limited process, suggesting that agonist bindi
177 ults, the rate constant is undervalued for a diffusion-limited process, suggesting that functional ad
180 Besides the fast complexation reactions, diffusion-limited processes, especially lateral diffusio
182 physical time scales of protein folding and diffusion-limited protein-protein encounter has suggeste
183 (i.e. Microtox((R))) or low sensitivity and diffusion limited protocols (i.e. amperometric microbial
185 in the absence of nucleotides binds DNA at a diffusion limited rate but cannot efficiently cleave DNA
189 sicles, and calcium ions approached the same diffusion-limited rate (>10(7) m(-1) s(-1)) that has bee
190 at the scissile phosphate, reacts at a fully diffusion-limited rate (k2/K1/2 = 1.1 x 10(9) M-1 s-1).
191 r, with a slope of -1, and extrapolated to a diffusion-limited rate at pK(a)(app) approximately 1.
192 f Rho hexamer interact with poly(C) RNA at a diffusion-limited rate constant close to 8 x 10(8) m(-1)
193 t reacts rapidly with N3- with an apparently diffusion-limited rate constant of (6.6 +/- 0.2) x 10(9)
194 ith [NO] = 200 muM) forming a 6c heme with a diffusion-limited rate constant of 2 x 10(8) M(-1)s(-1).
196 quantity k(lim) represents approximately the diffusion-limited rate constant, and s the free energy d
197 energy but also substantially increases the diffusion-limited rate for complexes in which long-range
198 posed of earth-abundant materials and with a diffusion-limited rate in acidified water, is efficient
199 in the inner vestibule, occurred at the same diffusion-limited rate in both open and closed states.
200 peptides containing the myo1c IQ motifs at a diffusion-limited rate in the presence and absence of ca
202 urrent densities over 8-fold larger than the diffusion-limited rate of HOR catalysis at a singular Pt
205 ccus furiosus rubredoxin range from near the diffusion-limited rate to a billion-fold slower for the
208 he wild-type substrate reacts at a partially diffusion-limited rate, and a faster-reacting SRL, conta
210 Since *NO reacts with LOO* at an almost diffusion-limited rate, steady state concentrations of 3
216 e ions to move across cell membranes at near diffusion-limited rates and with very high selectivity.
218 For long chains, both reaction-limited and diffusion-limited rates are significantly smaller in den
219 end diffusion coefficients obtained from the diffusion-limited rates are smaller than the sum of the
220 s to actively elongating complexes at nearly diffusion-limited rates but remains bound for only 0.3-0
223 een used to measure the reaction-limited and diffusion-limited rates of loop formation in disordered
224 A Stern-Volmer analysis yielded much larger diffusion-limited rates than simple kinetic theory predi
226 pport transmembrane ion conduction at nearly diffusion-limited rates while discriminating for K+ over
227 on ribosome-bound nascent chains approaches diffusion-limited rates, allowing immediate methionine e
228 , a product of NO and O2- that forms at near diffusion-limited rates, and rapidly decomposes upon pro
229 tic efficiency of 2.6 x 10(8) M(-1) s(-1), a diffusion limited reaction indicating catalytic perfecti
230 A and H2B polypeptides associate in a nearly diffusion limited reaction to form a dimeric ensemble, d
232 oxidizing species as a result of the nearly diffusion-limited reaction between tyrosyl radical and s
233 a transition state model by a switch from a diffusion-limited reaction in native RCs, where electron
235 and nitrating species, is formed by the near diffusion-limited reaction of .NO and O2.- during activa
236 of peroxynitrite (ONOO(-)) arising from the diffusion-limited reaction of exogenous NO and endogenou
237 ynitrite (ONOO(-)/ONOOH), the product of the diffusion-limited reaction of nitric oxide (*NO) with su
238 eroxynitrite is formed in macrophages by the diffusion-limited reaction of superoxide and nitric oxid
241 ensions serves as a model for predicting the diffusion-limited reaction rate, as first discussed by v
242 s within such nanodomains are known to shape diffusion-limited reaction rates, less is understood abo
247 Northrup and Erickson model of docking-type diffusion-limited reactions and yields reaction rate con
248 ificant enhancement can only be achieved for diffusion-limited reactions or at high concentrations of
250 nity (at both redox states of copper) during diffusion-limited reduction and oxidation of superoxide.
253 , despite having a k(+) in the often-quoted 'diffusion-limited' regime (10(5)-10(6) M(-1) s(-1) at hi
254 n and changes in cation concentration in the diffusion limited region above the RTN is measured due t
256 ide linear range of 0.8-200mM chloride and a diffusion-limited response time; sweat chloride levels c
257 lso showed the reduced iR drop, steady-state diffusion-limited response, and reduced sensitivity to c
258 erent redox systems; well-defined and stable diffusion-limited responses were obtained in all but two
259 RPLC adsorption of hemoglobin (a system with diffusion-limited retention) was found to give 95% bindi
260 ant folate in plasma) is also a potent, near diffusion limited, scavenger of singlet oxygen and quenc
261 rofile and the simulated results for a fast, diffusion-limited second-order annihilation process (k(a
262 west central Colorado contains fine-grained, diffusion-limited sediment lenses that are substantially
263 nomer folding reaction is followed by a near diffusion-limited self-association reaction to form the
264 isopropylethoxysilane (APDIPES) yielded near diffusion-limited separations and exhibited little chang
265 eory to biological problems in 2D shows that diffusion-limited signalling is an efficient mechanism o
268 tent species can bind ligand at or very near diffusion-limited speeds, suggesting that the binding po
269 lection mode revealed that, under apparently diffusion-limited steady-state conditions, there was a s
270 cal equations were developed to describe the diffusion-limited steady-state current and steady-state
273 chemical events in catalysis rather than by diffusion-limited substrate binding or product release.
275 ertebrate nervous system, ions accumulate in diffusion-limited synaptic clefts during ongoing activit
276 Here we explore the hypothesis that oxygen diffusion limited the evolution of retinal morphology by
277 l tert-butyl ether, methyl isobutyl ketone), diffusion-limited (theoretical), R d, conditional, R c,
280 depletion zone, which is associated with the diffusion-limited transport and the consequent nonlinear
281 or pyrene accumulation were much slower than diffusion-limited transport of solute in solution to the
282 ceptors into the clusters is consistent with diffusion-limited trapping with D approximately 10(-1) m
284 addition to contaminant uptake limitations, diffusion-limited turnover ((-)-alpha-HCH), substrate di
285 aw suggests that catalysis will be about 50% diffusion limited under conditions where [substrate] <<
293 ,4'-trihydroxychalcone are approximately 50% diffusion-limited, whereas the reactions of both dihydro
294 of cGMP hydrolysis by light-activated PDE is diffusion limited, which is not the case for spontaneous
295 actions, the product formation appears to be diffusion limited, with a number of intermediate phases
299 Geochemical gradients that developed in the diffusion-limited zones led to locally supersaturated co
300 nerals that form in dead-end one-dimensional diffusion-limited zones that are connected to a larger r