ライフサイエンスコーパス: dipolar coupling

1 ts of local backbone structure (NMR residual dipolar couplings).

2 on despite having a larger cross-section for dipolar coupling.

3 at approximately 165 ppm and lacks (15)N for dipolar coupling.

4 dipolar coupling, and solution NMR residual dipolar coupling.

5 et of experimental NMR methyl group residual dipolar couplings.

6 , as manifested by their strong (19)F-(29)Si dipolar couplings.

7 s constraints, including the methyl residual dipolar couplings.

8 uring NMR relaxation parameters and residual dipolar couplings.

9 tive magnitude of the respective (15)N-(17)O dipolar couplings.

10 l shifts as well as (1)H-(15)N heteronuclear dipolar couplings.

11 using NMR spectroscopy by employing residual dipolar couplings.

12 tra suitable for the measurement of residual dipolar couplings.

13 lies on the basis of statistical analysis of dipolar couplings.

14 ct 1JCalphaC' scalar and 1DCalphaC' residual dipolar couplings.

15 nd accurately measure numerous heteronuclear dipolar couplings.

16 13C and 15N) and refinement against residual dipolar couplings.

17 by complete cross-validation of the residual dipolar couplings.

18 aints in the form of backbone (15)N residual dipolar couplings.

19 x orientations were determined from residual dipolar couplings.

20 ear Overhauser enhancement data and residual dipolar couplings.

21 aeolicus LpxC-TU-514 complex using residual dipolar couplings.

22 ion of holo-ACPP to ACPS by fitting residual dipolar couplings.

23 using NMR order tensor analysis of residual dipolar couplings.

24 rder parameters from the (13)C-(1)H residual dipolar couplings.

25 AF) allowed us to measure 86 N-H(N) residual dipolar couplings.

26 Residual dipolar couplings ( (1) D HN and (1) D CalphaHalpha) ind

27 ed via 2H quadrupolar couplings, C-H and N-H dipolar couplings, 13C chemical shift anisotropies, and

28 hemical shifts are encoded by the (1)H-(15)N dipolar couplings, 2D dipolar-encoded HETCOR (i.e., de-H

29 ombination of DNA hybridization and particle dipolar coupling, a property dependent on particle compo

30 The measured 1H-15N residual dipolar coupling agrees with the atomic coordinates from

31 Residual dipolar couplings allowed not only the identification of

32 easurement of a broad range of heteronuclear dipolar couplings, allowing for a complete mapping of pr

33 Dipolar coupling also dominates for the axial boron atom

34 emical shift analysis, backbone N-H residual dipolar couplings, amide proton NOEs, and R(2) relaxatio

35 Six dipolar couplings among five resolved (13)C-labeled atom

36 Our residual dipolar coupling analysis reveals nonrandom conformation

37 According to residual dipolar coupling analysis, the gross structures of the A

38 Using the solution NMR methods of residual dipolar coupling analysis, we determine that significant

39 sive set of hetero- and homonuclear residual dipolar coupling and 31P chemical shift anisotropy restr

40 utilize the PISEMA pulse sequence to measure dipolar coupling and chemical shift, the two key paramet

41 ngle, small-angle X-ray scattering, residual dipolar coupling and inter-domain NOE nuclear Overhauser

42 r of RNA elements was determined by residual dipolar coupling and paramagnetic relaxation experiments

43 ed in aqueous solution by using NMR residual dipolar coupling and spin labeling methods and is based

44 stants are proportional to the square of the dipolar coupling and the spectral overlap integral betwe

45 se of the 19F spin increases the homonuclear dipolar coupling and thus the distance reach.

46 Cross validation against both the dipolar coupling and X-ray scattering data suggests that

47 upolar splittings together with (1)(5)N/(1)H dipolar couplings and (1)(5)N chemical shifts, using two

48 d with measurements of long-range (1)H-(13)C dipolar couplings and (13)C relaxation times.

49 However, so far only (1) H-(15) N dipolar couplings and (15) N chemical shifts have been r

50 Structural refinement of (1)H-(15)N dipolar couplings and (15)N chemical shifts measured by

51 NMR data including residual dipolar couplings and (15)N relaxation data demonstrated

52 surement of previously inaccessible residual dipolar couplings and (15)N relaxation parameters.

53 ndent 13C and 15N spectra, 13C-1H and 15N-1H dipolar couplings and 1H rotating-frame spin-lattice rel

54 ing an extensive set of restraints including dipolar couplings and backbone torsion angles.

55 loyed oriented solid-state NMR data, such as dipolar couplings and chemical shift anisotropy measured

56 NMR observables such as dipolar couplings and chemical shift anisotropy, which a

57 culated by linear regression of the residual dipolar couplings and chemical shifts at increasing alig

58 of membrane proteins, the angular-dependent dipolar couplings and chemical shifts provide a direct i

59 h distance- and mobility-dependent (1)H-(1)H dipolar couplings and detecting it through polysaccharid

60 ta on the two proteins derived from residual dipolar couplings and distance restraints from site-spec

61 istic APP-TM population observed by residual dipolar couplings and double electron-electron resonance

62 parable accuracy in back-calculated residual dipolar couplings and J-couplings across hydrogen bonds

63 troscopy, including measurements of residual dipolar couplings and molecular dynamics simulations, to

64 n excellent agreement with measured residual dipolar couplings and order parameter S(2).

65 Compared to residual dipolar couplings and PRE, modulation of the helical pro

66 Residual dipolar couplings and residual chemical shift anisotropy

67 e revealed by distance-dependent (13)C-(13)C dipolar couplings and spin diffusion.

68 segment (P2a.1-J2a.1 refined using residual dipolar couplings and the modeling program MC-Sym) we ha

69 nnealing driven by experimental NMR residual dipolar couplings and X-ray scattering data.

70 in, and distance, hydrogen bonding, residual dipolar coupling, and dihedral angle constraints were us

71 s transitions between qubit states, a strong dipolar coupling, and leading-order protection from elec

72 recently measured chemical shift anisotropy, dipolar coupling, and residual dipolar coupling data.

73 olid-state NMR chemical shift anisotropy and dipolar coupling, and solution NMR residual dipolar coup

74 equence was used to measure the internuclear dipolar coupling, and the results demonstrate (1) the me

75 (3)JH(N)H(alpha) scalar couplings, residual dipolar couplings, and (1)H-(15)N NOEs, we have optimize

76 rporating backbone chemical shifts, residual dipolar couplings, and amide proton distances into the R

77 rrelation experiments, (1)H-(17)O scalar and dipolar couplings, and plane-wave DFT calculations provi

78 d peptide would be evident in local residual dipolar couplings, and possibly differences in homonucle

79 spectroscopy using chemical shifts, residual dipolar couplings, and spin relaxation.

80 the measurement of long-range heteronuclear dipolar couplings, and that they provide inaccurate valu

81 order parameters are based on heteronuclear dipolar couplings, and they are correlated to assigned c

82 However, in these experiments, all weak dipolar couplings are suppressed.

83 Residual dipolar couplings are used in a new way for residue sele

84 Here we use NMR chemical shifts and residual dipolar couplings as structural restraints in replica-av

85 ether with spectroscopic selections based on dipolar couplings as well as two-dimensional spin-diffus

86 By measuring (1)H-(15)N dipolar-coupling as well as (15)N R1 and R1rho relaxatio

87 ed additional structural information through dipolar couplings, as follows: (1) to the nearest proton

88 Based on intermolecular dipolar coupling at positions 26, 44, and 64, these seco

89 inction spectra of coupled resonators is the dipolar coupling band.

90 A residual-dipolar-coupling-based refinement approach can be used t

91 The 700 Hz dipolar coupling between (13)C(alpha) and its directly b

92 gnetic behavior by effective lowering of the dipolar coupling between particles.

93 Dipolar coupling between spin labels across the dimer re

94 duced changes in distance as measured by the dipolar coupling between spin labels introduced onto the

95 ally, measurements of the distance-dependent dipolar coupling between the two spins are used to obtai

96 owerful structural biology tool in which the dipolar coupling between two unpaired electron spins (si

97 tional resonance SSNMR measurements of (13)C dipolar couplings between backbone F23 and I26 of hIAPP

98 s to accurately measure strong heteronuclear dipolar couplings between directly bonded nuclei.

99 fsets of 13C carbonyl resonances and 13C-13C dipolar couplings between the labeled methyl and carbony

100 Averaging of the homonuclear (13)C/(13)C dipolar couplings, by MAS of the sample, enables the use

101 lution due to the efficient averaging of the dipolar couplings can be attained at MAS frequencies of

102 er alignment media, but the magnitude of the dipolar couplings can be easily scaled up by increasing

103 On the other hand, weak heteronuclear dipolar couplings can be measured using laboratory-frame

104 We used NMR residual dipolar couplings, carbon spin relaxation (R(1) and R(2)

105 Further, NMR residual dipolar couplings collected under three anisotropic cond

106 NMR residual dipolar couplings confirm the crystal structures to be a

107 The value of the dipolar coupling constant, 5250 +/- 90 Hz, corresponds t

108 e resolved and well simulated using distinct dipolar coupling constants DCalphaH and DCalphaD for the

109 specific (1)H-(13)C/(1)H-(15)N heteronuclear dipolar coupling constants for CAP-Gly and CTD CA, repor

110 one-shot determination of accurate residual dipolar coupling constants from a single NMR spectrum.

111 e a helical structure that predicts residual dipolar coupling constants that are incompatible with th

112 0 experimental nuclear Overhauser effect and dipolar coupling constraints ( approximately 17 constrai

113 coupling constants ((1) J(OH)) or (1)H-(17)O dipolar couplings ( D(OH)), respectively, the latter of

114 The residual dipolar coupling data and NMR chemical shift data sugges

115 mall angle X-ray scattering and NMR residual dipolar coupling data demonstrates unambiguously that th

116 -H, N-C', Calpha-Halpha, Calpha-C') residual dipolar coupling data in five independent alignment medi

117 d diubiquitin, characterized by the residual dipolar coupling data measured at several pH conditions.

118 NMR chemical shifts and residual dipolar coupling data reveal Ca(2+)-dependent difference

119 al contributions; when coupled with residual dipolar coupling data, a KGSrna ensemble revealed a prev

120 The collection of residual dipolar coupling data, amide protection factors, and par

121 present NMR resonance assignments, residual dipolar coupling data, functional analysis, and a struct

122 As judged from the dipolar coupling data, the remainder of the structure is

123 t anisotropy, dipolar coupling, and residual dipolar coupling data.

124 using nuclear Overhauser effect and residual dipolar coupling data.

125 NMR dipolar couplings (DCs) depend intrinsically on both mol

126 e difference between two successive residual dipolar couplings (DeltaRDCs) involving C6/8-H6/8, C3'-H

127 Through measurements of dipolar-coupling derived order parameters of bond motion

128 agreement with (+/-20%) the root-sum-squared dipolar couplings determined from the crystal structure.

129 ttering, nuclear magnetic resonance residual dipolar couplings, dipolar electron-electron resonance s

130 ng 2D NMR NOESY, ROESY, T-ROESY and residual dipolar coupling experiments in a range of solvents, alo

131 (13)C relaxation and residual dipolar coupling experiments revealed interhelical flexi

132 MR chemical shift perturbation, and residual dipolar coupling experiments support the idea that the d

133 and (13)C-(1)H, (15)N-(1)H, and (13)C-(15)N dipolar couplings for all labeled residues.

134 shifts and paramagnetically induced residual dipolar couplings for six different lanthanide ions.

135 Measuring residual dipolar couplings for the different bound states clearly

136 Measurements of (1)H-(13)C dipolar couplings for the two species of Ala-PLB showed

137 chemical shift and (1)H-(15)N heteronuclear dipolar coupling frequencies as orientation constraints

138 ependent (15)N chemical shift and (1)H-(15)N dipolar coupling frequencies.

139 omain walls, but their density is limited by dipolar coupling from their fringing magnetic fields.

140 somers to deconvolve the influence of SAM-LC dipolar coupling from variations in molecular geometry,

141 ited not only from the inclusion of residual dipolar couplings from partially aligned samples but als

142 hyperpolarized LLS, induced by heteronuclear dipolar couplings, generates strongly enhanced antiphase

143 5)N chemical shift anisotropy and (1)H/(15)N dipolar couplings have been analyzed using short-time av

144 sly inaccessible (1) H(alpha) -(13) C(alpha) dipolar couplings have been measured, which make it poss

145 erived data (relaxation parameters, residual dipolar couplings, hydrogen exchange rates, pK(a) values

146 Backbone amide chemical shifts, residual dipolar couplings, hydrogen-deuterium exchange, and (15)

147 gree of headgroup mobility that averages the dipolar coupling in the liquid crystalline phase.

148 sample was determined by measuring the 15N-H dipolar coupling in the triflic acid salt of the complet

149 ial buildup (DeltaS/S < 0.2) yield effective dipolar couplings in agreement with (+/-20%) the root-su

150 clude the measurement of (1)H-(13)C residual dipolar couplings in Ala(beta) methyls, characterization

151 landscape of the complex using NMR residual dipolar couplings in replica-averaged metadynamics simul

152 tion was made possible by measuring residual dipolar couplings in weakly oriented micelle samples of

153 Finally, distributions of residual dipolar couplings indicate that the two domains tumble a

154 Measurements of C-H and N-H dipolar couplings indicate that, on the sub-microsecond

155 al transition moment and the axis of maximum dipolar coupling, is also confirmed by magnetophotoselec

156 ution NMR methodology that combines residual dipolar couplings, J-couplings, and intramolecular hydro

157 n arranged in such a way that their in-phase dipolar coupling leads to a collective excitation of the

158 w that 15N chemical shift anisotropy and N-H dipolar coupling measured on these powder samples can be

159 Furthermore, residual dipolar couplings measured for MBD3 bound to methylated

160 fragments that are consistent with multiple dipolar couplings measured in a single alignment medium

161 teronuclear relaxation experiments, residual dipolar coupling measurements and analytical ultracentri

162 Spin-spin dipolar coupling measurements confirmed that in the nano

163 NMR analysis and residual dipolar coupling measurements indicate that the isolated

164 Residual dipolar coupling measurements indicate that the structur

165 NMR carbon spin relaxation data and residual dipolar coupling measurements reveal a flexible yet stac

166 roximity between V3 and K17, and (13)C-(13)C dipolar coupling measurements reveal proximity between t

167 ve to the unphosphorylated complex, residual dipolar coupling measurements reveal that the structures

168 Residual dipolar coupling measurements, however, demonstrate unam

169 S(2) order parameters derived from residual dipolar coupling measurements.

170 troscopy, supplemented by extensive residual dipolar coupling measurements.

171 ng chemical shift perturbations and residual dipolar coupling measurements.

172 asis of this information and of NMR residual dipolar couplings measurements.

173 analysis and by application of the residual dipolar coupling method, the rearrangement occurs withou

174 Residual dipolar coupling methods have revealed the presence of e

175 Heteronuclear dipolar coupling modulation schemes allowed to character

176 rge g-anisotropy is shown to result in large dipolar couplings near g( parallel) and uniquely anisotr

177 infer that water exhibits distinct (1)H-(1)H dipolar coupling networks with the backbone and side-cha

178 h measurements of intermolecular (13)C-(13)C dipolar couplings observed in PITHIRDS-CT experiments.

179 teraction strength, we elucidate the role of dipolar coupling of molecular monolayers to their enviro

180 Residual dipolar coupling of partially aligned protein and the NM

181 cular alignment model that predicts residual dipolar couplings of small molecules aligned by poly(gam

182 ), the close to zero values for the residual dipolar couplings of the backbone amides, and minimal de

183 15)N spin relaxation and (15)N,(1)H residual dipolar couplings of the covalent ChVLig-AMP intermediat

184 veal enantiotopic recognition using residual dipolar couplings or to determine the absolute configura

185 sites based on either spatial proximity (via dipolar couplings) or through-bond connectivity (via sca

186 his study is in good agreement with residual dipolar coupling, paramagnetic resonance enhancement, sm

187 f the proteins and chemical shifts, residual dipolar couplings, paramagnetic relaxation enhancement,

188 Refinement of this library with NMR residual dipolar couplings provided an atomistic ensemble model f

189 NMR residual dipolar coupling (RDC) analysis of GGC in a DNA-origami

190 rget site have been investigated by residual dipolar coupling (RDC) and paramagnetic relaxation enhan

191 -coupling((3)J(H(N))(H(alpha))) and residual dipolar coupling (RDC) data calculated from the REMD tra

192 to best reproduce the experimental residual dipolar coupling (RDC) data for this system, as both che

193 only unassigned chemical shifts and residual dipolar coupling (RDC) data.We introduce a geometric opt

194 -D exchange, backbone dynamics, and residual dipolar coupling (RDC) experiments reveal regions of fle

195 g internal from overall motions and residual dipolar coupling (RDC) measurements for determining the

196 also supported by the results from residual dipolar coupling (RDC) measurements obtained using Pf1-p

197 on CEACAM1-IgV dimerization and use residual dipolar coupling (RDC) measurements to characterize the

198 k alignment of soluble proteins for residual dipolar coupling (RDC) measurements.

199 l hexaphosphate (IHP), using 15N-1H residual dipolar coupling (RDC) measurements.

200 dynamics (MD) trajectories and NMR residual dipolar coupling (RDC) measurements.

201 We have applied the residual dipolar coupling (RDC) method to investigate the solutio

202 ow the plasticity in the model-free residual dipolar coupling (RDC) order parameters and in an ensemb

203 ports the acquisition of (1)H-(15)N residual dipolar coupling (RDC) values for individual subunits in

204 The residual dipolar coupling (RDC) values of the two tripeptide unit

205 nd complexed to HPr), combined with residual dipolar coupling (RDC), small- (SAXS) and wide- (WAXS) a

206 me P450(cam) (CYP101) obtained from residual dipolar coupling (RDC)-restrained molecular dynamics (MD

207 ethodology that simultaneously uses residual dipolar couplings (RDC) and the small-angle X-ray scatte

208 dynamics (MD) simulations with NMR residual dipolar couplings (RDC) measured in elongated RNA.

209 , is known from an extensive set of residual dipolar couplings (RDC), previously used to refine its s

210 Using NMR residual dipolar coupling (RDCs), we characterized Na+-induced ch

211 n of orientational constraints from residual dipolar couplings (RDCs) and chemical shift anisotropy (

212 spectroscopy (NOESY) spectroscopy, residual dipolar couplings (RDCs) and paramagnetic relaxation enh

213 se of anisotropic NMR data, such as residual dipolar couplings (RDCs) and residual chemical shift ani

214 ntation restraints derived from NMR residual dipolar couplings (RDCs) and semiquantitative distance r

215 NMR residual dipolar couplings (RDCs) are exquisite probes of protein

216 Experimentally measured residual dipolar couplings (RDCs) are highly valuable for atomic-

217 Residual dipolar couplings (RDCs) are important probes in structu

218 Residual Dipolar Couplings (RDCs) are integral to the refinement

219 Residual dipolar couplings (RDCs) can provide a means of assignin

220 NMR residual dipolar couplings (RDCs) carry rich dynamics information

221 tural abundance one-bond (1)H-(13)C residual dipolar couplings (RDCs) for menthol measured in the gel

222 Alternatively, one can measure residual dipolar couplings (RDCs) for natural abundance lipid sam

223 ents and the experimentally derived residual dipolar couplings (RDCs) for the complex.

224 measurement of backbone (1)H-(15)N residual dipolar couplings (RDCs) from samples of two different c

225 re multiple independent sets of NMR residual dipolar couplings (RDCs) has made it possible to charact

226 Residual Dipolar Couplings (RDCs) have become an alternate approa

227 Residual Dipolar Couplings (RDCs) have emerged in the past two de

228 xperiment was applied for measuring residual dipolar couplings (RDCs) in an 8 kDa protein Z-domain al

229 The invariance of NMR residual dipolar couplings (RDCs) in denatured forms of staphyloc

230 proach based on measurement of many residual dipolar couplings (RDCs) in differentially orienting aqu

231 Residual dipolar couplings (RDCs) measured for internally rigid m

232 High precision residual dipolar couplings (RDCs) measured for the backbone (1)H-

233 rotein that NMR and, in particular, residual dipolar couplings (RDCs) measured for the folded portion

234 S data, supplemented by NMR-derived residual dipolar couplings (RDCs) measured in a weakly aligning m

235 However, NMR residual dipolar couplings (RDCs) measured under three different

236 tes between dipolar interactions to residual dipolar couplings (RDCs) of individual consecutive H(N)-

237 rs such as chemical shifts (CSs) or residual dipolar couplings (RDCs) on structural propensity are kn

238 In principle, residual dipolar couplings (RDCs) provide a useful complement to

239 Analysis of residual dipolar couplings (RDCs) shows that binding of MalF-P2 i

240 pproach based on the measurement of residual dipolar couplings (RDCs) to probe the structural and mot

241 Residual dipolar couplings (RDCs) were measured for (15)N-(1)H am

242 domain orientation restraints from residual dipolar couplings (RDCs) without a need for a previously

243 Y spectrum revealed many long-range residual dipolar couplings (RDCs), and detailed analysis of magne

244 , as mapped by NMR spin relaxation, residual dipolar couplings (RDCs), and scalar couplings, illustra

245 ramagnetic relaxation enhancements, residual dipolar couplings (RDCs), chemical shifts, and small-ang

246 Residual dipolar couplings (RDCs), commonly measured for biologic

247 The use of NMR-derived residual dipolar couplings (RDCs), in magnetically aligned media,

248 entional 1D and 2D NMR spectra, and residual dipolar couplings (RDCs), is reported.

249 an ideal model alpha-helix for its residual dipolar couplings (RDCs), measured in a filamentous phag

250 EST) NMR spectroscopy for measuring residual dipolar couplings (RDCs), which provide unique long-rang

251 a SMM with the evaluation of large residual dipolar couplings (RDCs).

252 tively with NMR chemical shifts and residual dipolar couplings (RDCs).

253 ally enriched RNA samples using NMR residual dipolar couplings (RDCs).

254 other, using 'relativistic' sets of residual dipolar couplings (RDCs).

255 can be achieved by refinement with residual dipolar couplings (RDCs).

256 many of the analogous amides in the residual dipolar coupling-restrained ubiquitin ensemble are subst

257 hydrogen bond constraints, and 362 residual dipolar coupling restraints derived from a series of two

258 , a nearly complete set of backbone residual dipolar coupling restraints was recorded for the fusion

259 60-kDa protein has been built using residual dipolar coupling restraints.

260 alone, but the addition of NMR RDC (residual dipolar coupling) restraints improves the structure mode

261 The direction of maximum dipolar coupling shifts from the out-of-plane direction

262 did not result in a loss of the (13)C-(13)C dipolar couplings, showing that these couplings are prim

263 Analysis of NMR residual dipolar couplings shows that CBD12 assumes on average an

264 ased on NOE distance restraints and residual dipolar couplings, shows that the NHR and CHR helices re

265 our unfolded ensemble dominate the residual dipolar coupling signal, whereas the uniformity of the s

266 f scalar couplings and additional long-range dipolar couplings significantly enhances signal to noise

267 )N relaxation rates, and (1)H-(15)N residual dipolar couplings suggest structural changes and rapid m

268 olution NMR study of unbound Ly49A, aided by dipolar coupling technology.

269 he basis of a very extensive set of residual dipolar couplings, than for any single static NMR struct

270 -sweep spectra show evidence of intercluster dipolar coupling that can be simulated using an uncouple

271 Many of these same residues have residual dipolar couplings that deviate from structural predictio

272 r ensemble consistent with measured residual dipolar couplings that revealed dynamic motions up to mi

273 iment DROSS, we resolved (13)C-(1)H residual dipolar couplings that were interpreted with a statistic

274 ha, HN-N, and Calpha-C' J-modulated residual dipolar couplings, the backbone rmsd improves to 0.22 A.

275 By examining the (13)C-(14)N dipolar coupling through low-field (B0 = 3 T) (13)C{(1)H

276 Hamiltonian for the hydride electron-nuclear dipolar coupling to its "anchoring" Fe ions, an approach

277 f water protons through their time-dependent dipolar coupling to paramagnetic probes, here nitroxide

278 ulations on Cu(phacac)(2), indicate enhanced dipolar coupling to the d(xz) --> d(xy) transition of th

279 transfer (DREPT), allows for a wide range of dipolar couplings to be encoded, providing high resoluti

280 We obtained these results by using residual dipolar couplings to characterize the dynamics of ubiqui

281 ly improves the fit of experimental residual dipolar couplings to structural coordinates.

282 shifts, nuclear Overhauser effects, residual dipolar couplings) to predictions from molecular dynamic

283 13)C chemical shifts and (13)C-(1)H residual dipolar couplings under magic-angle spinning.

284 the issue, we have measured the NMR residual dipolar couplings using alignment media of stretched gel

285 ng chemical shift perturbations and residual dipolar couplings was employed to obtain a structural mo

286 agnetic relaxation enhancement, and residual dipolar couplings, we have characterized structural and

287 Using residual dipolar couplings, we show that the four structural unit

288 Large, well-resolved (1)H and (11)B dipolar couplings were also observed.

289 rotational Overhauser effects, and residual dipolar couplings were constructed.

290 Data from NMR chemical shifts and residual dipolar couplings were used to guide the construction of

291 Backbone residual dipolar couplings were used to provide long range orient

292 NMR chemical shift data and residual dipolar couplings were used to show that the local secon

293 e experimental data afforded by NMR residual dipolar couplings (which yield both orientational and sh

294 s alignment-inducing agents to gain residual dipolar couplings, which are valuable restraints for mac

295 c relaxation enhancements (PRE) and residual dipolar couplings, which reveal an additional long-range

296 lations with various data sets indicate that dipolar couplings will be critical for obtaining accurat

297 al field spectroscopy correlating (15)N-(1)H dipolar coupling with (15)N chemical shift to determine

298 SR) signal of N@C(60) through intramolecular dipolar coupling with a strength of 27.0 MHz.

299 paring calculated (1)H-(13)C methyl residual dipolar couplings with measured values, and the level of

300 Measurement of (19)F-(19)F dipolar couplings within each CF(3) moiety revealed that