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1 ied to a bis(dipyrromethane) and a porphyrin-dipyrromethane.
2 a 1-acyldipyrromethane in the presence of a dipyrromethane.
3 the availability of multigram quantities of dipyrromethanes.
4 the availability of multigram quantities of dipyrromethanes.
5 , and trace scrambling for alkyl-substituted dipyrromethanes.
7 dehyde followed by hydrodesulfurization gave dipyrromethane-1,9-(13)C, which upon condensation with a
8 at the 5-position or carbinol position, or a dipyrromethane-1,9-dicarbinol bearing an acetal group at
9 ne-1,9-(13)C, which upon condensation with a dipyrromethane-1,9-dicarbinol bearing three pentafluorop
10 es of the existing "2 + 2" (dipyrromethane + dipyrromethane-1,9-dicarbinol) method, such as absence o
11 of a 1-acyldipyrromethane and a 9-protected dipyrromethane-1-carbinol (derived from a 9-protected 1-
12 bearing an acetal group at the 5-position, a dipyrromethane-1-carbinol bearing an acetal group at the
14 alkylboron motif bound to the pyrrole of the dipyrromethane and coordinated to the imidazole imino ni
15 with the anticipated nucleophilicity of the dipyrromethane and dipyrromethanemonocarbinol precursors
17 [2+2] condensation between thioglycosylated dipyrromethanes and aromatic aldehydes in 15-21% yields.
18 1-(p-Bromophenyl)nitrosoethylene reacts with dipyrromethanes and pyrrole to afford two isomeric oxime
19 by [2 + 2] condensation of the corresponding dipyrromethanes and subsequent oxidative aromatization.
21 able scrambling (LD-MS) for aryl-substituted dipyrromethanes, and trace scrambling for alkyl-substitu
22 a new method for effecting the oxidation of dipyrromethane-based macrocycles in organic solvents has
23 hydrodipyrrin-carboxaldehyde (AD half) and a dipyrromethane bearing a 3-methoxy-1,3-dioxopropyl group
25 eso-formyl substituents entails the use of a dipyrromethane bearing an acetal group at the 5-position
27 substituted bis-formyldihydrodipyrrins 6 and dipyrromethane bis-carboxylic acids 7 in 5% TFA/CH2Cl2 (
28 eport here a neural stem cell specific boron-dipyrromethane (BODIPY) derivative compound of designati
29 aride (LPS) fluorescently labeled with boron dipyrromethane (BODIPY) first binds to the plasma membra
32 NaBH(4), acid-catalyzed condensation with a dipyrromethane, DDQ oxidation) afforded the desired free
33 )dipyrromethane or via presynthesis of a bis(dipyrromethane) derivative 22 (from bisnaphthaldehyde 12
34 esults in the formation of 5-alkoxy-5-phenyl dipyrromethane derivatives, which function as ready prec
36 nyl-substituted azaBODIPY was condensed with dipyrromethane dicarbinol or 16-oxatripyrrane under mild
37 nvolves the acid-catalyzed condensation of a dipyrromethane-dicarbinol and a dipyrromethane followed
38 e diacyl dipyrromethane to the corresponding dipyrromethane-dicarbinol is achieved with NaBH(4) in me
39 desirable features of the existing "2 + 2" (dipyrromethane + dipyrromethane-1,9-dicarbinol) method,
41 tuents were prepared in yields of 24-49% via dipyrromethane + dipyrromethanedicarbinol routes, and th
44 We have generated a set of BODIPY (boron dipyrromethane) fluorophores, including one that is intr
49 for the preparation of unsymmetrical diacyl dipyrromethanes has been developed that involves (1) mon
51 based on the reactivity of azoalkenes toward dipyrromethanes, has been established with the aim of de
54 preparation of a set of 15 diverse monoacyl dipyrromethanes in good yield at the multigram scale.
58 ransition metal complexes (Mn --> Zn) of the dipyrromethane ligand, 1,9-dimesityl-5,5-dimethyldipyrro
61 examined for the direct 1,9-diacylation of a dipyrromethane or the 9-acylation of a 1-acyldipyrrometh
62 be achieved by employing (pentafluorophenyl)dipyrromethane or via presynthesis of a bis(dipyrrometha
63 rins, obtained in three steps from a 5-(aryl)dipyrromethane precursor, display remarkable features: (
66 er with readily available 5-aryl-substituted dipyrromethanes such as 5-mesityldipyrromethane to affor
70 pyridyl thioester, reduction of the monoacyl dipyrromethane to the corresponding carbinol, and self-c
74 hoxyphenylmethanol) with different meso-aryl dipyrromethanes under mild acid-catalyzed conditions.
78 1,9-bis(RS)dipyrrin or (ii) the 1,9-bis(RSO2)dipyrromethane, which underwent subsequent complexation
79 n good yields from a one-pot condensation of dipyrromethane with the aldehyde of a xanthene spacer fo
80 involves the selective monoacylation of the dipyrromethanes with a pyridyl thioester, reduction of t
81 tion of readily available 5-aryl-substituted dipyrromethanes with acenaphthenequinone leads to the tr