ライフサイエンスコーパス: enantiopure

1 ks of larger arrays that become increasingly enantiopure.

2 (2-PET = 2-phenylethylthiolate) clusters and enantiopure 1,1'-binaphthyl-2,2'-dithiol (BINAS) was mon

3 The preparation of diastereo- and enantiopure 1,2-amino alcohols is also realized using th

4 the products are useful for the synthesis of enantiopure 1,2-diamine and alpha-amino acid derivatives

5 The synthesis of enantiopure 1,2-diaminobicyclo[2.2.2]octane (DABO, 1) an

6 most convenient methods for the synthesis of enantiopure 1,4,5-trisubstituted 1,2,3-triazoles where t

7 successfully employed for the production of enantiopure 1-(2-bromophenyl)ethan-1-amine, thus enablin

8 alcohols generated during the hydrolysis of enantiopure 1-(4-chlorophenyl)-3-phenylallyl and 3-(4-ch

9 concise synthesis of (+)-swainsonine, and an enantiopure 1-substituted quinolizidine of utility in ta

10 Highly enantiopure (1-aryl)- and (1-naphthyl)-1-ethylamines wer

11 w and known calcimimetic analogues employing enantiopure (1-naphthalen-1-yl)ethylamine as chiral prec

12 the (c-Hex)(2)B and Ti(IV) "ate" enolates of enantiopure (+)-1a (R = MOM) with (+/-)-5c (R(2) = Me, X

13 al flexibility has been synthesized from the enantiopure (1S,2S)-2-(1-H-imidazol-1-yl)-cyclohexanol.

14 The synthesis of 14 enantiopure 2,4-syn-Glu analogues 2b-p is accessed by a

15 onality to the distal allene carbon to yield enantiopure 2,5-dihydro-1H-pyrroles, whereas their palla

16 vel methodology has been developed to obtain enantiopure 2-C-glycosyl-3-nitrochromenes.

17 I2-promoted beta-elimination, yielded chiral enantiopure 2-C-glycosyl-3-nitrochromenes.

18 '-biaziridine with Grignard reagents affords enantiopure 2-imidazolidinones in a desymmetrizing, casc

19 Enantiopure 2-methyl-3-substituted tetrahydrofurans are

20 of an L-threonine-derived tetramic acid with enantiopure 2-methyloct-(6E)-enoic acids.

21 Protected enantiopure 2-pyrrolylalanine was synthesized for applic

22 alkenes with o-hydroxybenzaldehydes afforded enantiopure (2S,3S,4S)-3-bromo-3,4-dihydro-4-hydroxy-3-n

23 n was developed for the one-pot synthesis of enantiopure 3,4-dihydrospiro[benzo[b][1,4]oxazine-2,3'-o

24 pproach described here can be used to access enantiopure 3,4-disubstituted prolinols, which are frequ

25 Moreover, virtually enantiopure 3-amino-1,2-diols could be obtained by the s

26 s selectively at the alpha-position to yield enantiopure 3-pyrroline products.

27 dy immunoassays suggest that a vaccine using enantiopure (-)-3'-AmNic hapten imparts superior capacit

28 Enantiopure 4-formyl-beta-lactams were deployed as synth

29 as based on the N-Boc-directed metalation of enantiopure 4-piperidone (-)-11, which was prepared in f

30 l-derived oxazolopiperidone lactams leads to enantiopure 4-substituted-5-aminopentanols, which are us

31 d on-surface coordination is studied for the enantiopure 6,13-dicyano[7]helicene building block.

32 Enantiopure acceptors (R,R)M and (S,S)M [where M = (N1,N

33 ion-controlled arylation reaction of chiral, enantiopure acyclic alpha-amino aldehydes enabled by a B

34 ) occurred with KR to give the corresponding enantiopure adducts with the expected stereoselectivity.

35 rom statistical predominance of mixed versus enantiopure aggregates, must be in action during the ear

36 e provided an alternative access to the same enantiopure alcohol previously obtained through lipase-c

37 Catalytic assembly of enantiopure aliphatic amines from abundant and readily a

38 Enantiopure alkaloid mimics are synthesized via high yie

39 Enantiopure alleno-acetylenic cage (AAC) receptors with

40 I) alkoxide, generated from (S)-5a, with the enantiopure allylic carbonates (R)-9a,b has been develop

41 The synthesis of six enantiopure alpha,alpha,alpha',alpha'-tetrakis(perfluoro

42 (S)-N-benzyl-N-(alpha-methylbenzyl)amide to enantiopure alpha,beta-unsaturated esters (beta-substitu

43 dazolidinones may be formed selectively from enantiopure alpha-amino acids.

44 enantioenriched hydroazulenone enolate to an enantiopure alpha-bromocyclopentenone.

45 val of the chiral auxiliary, highly valuable enantiopure alpha-fluorocarboxylic acids and beta-fluoro

46 rmation provides a straightforward access to enantiopure alpha-methyl alpha-arylglycine esters.

47 igram to kilogram scale to provide three key enantiopure alpha-methyl-beta-cyclopropyldihydrocinnamat

48 A new method for the synthesis of enantiopure alpha-substituted piperazines via direct fun

49 bond of the derivative was shown to generate enantiopure amine starting materials without racemizatio

50 eas diol enantiomers form complexes with the enantiopure amine-type fluorescent ligand tryptophanol.

51 chanisms and are converted to diastereo- and enantiopure amines bearing adjacent stereocenters.

52 e, and a catalase leads to the production of enantiopure amines.

53 ent and environmentally benign production of enantiopure amines.

54 ine nanocrystals grown in the presence of an enantiopure amino acid auxiliary, which binds to the fas

55 In the case of adequately substituted enantiopure amino alcohols, up to 95:5 of diastereoisome

56 ed by its application to the synthesis of an enantiopure analogue of the bioactive 2,3,4,4a,5,9b-hexa

57 A series of racemic and enantiopure analogues of CJ-16,264 was designed and synt

58 We synthesized enantiopure analogues of paroxetine containing either br

59 to the construction of a variety of designed enantiopure analogues of viridicatumtoxin B led to the d

60 crystal structures allows the analysis of 13 enantiopure and 30 racemic crystal structures of 21 (F/C

61 toins under basic conditions gave a range of enantiopure and enantioenriched quaternary alpha-aryl pr

62 e structures with no distinction between the enantiopure and racemic forms.

63 conducted with enantioenriched mixtures both enantiopure and racemic phases are obtained.

64 The development of large scale synthesis of enantiopure and thermally stable (R)- and (S)-BINOL mole

65 -chloromandelic acid, which has at least two enantiopure and three racemic crystal polymorphs, reveal

66 cluding alkyl-substituted, aryl-substituted, enantiopure, and tertiary allenols.

67 ture of multiple homochiral assemblies to an enantiopure architecture through the interaction of a ch

68 Selective formation of an enantiopure assembly in such processes is very challengi

69 Our work also predicts that enantiopure Au(144)(SR)(60) clusters would be promising

70 After only 10 min of reaction, the original enantiopure aza-tricyclic scaffolds bearing a trifluorom

71 Enantiopure aziridin-2-yl methanols 3-7 are used as high

72 ome of these modified carbohydrates afforded enantiopure aziridines, nitrocyclopropane, and dihydrofu

73 Moreover, C3 symmetric and enantiopure basket 3, containing (S)-alanine groups at t

74 o biological activity and behavior in soils, enantiopure (-)-beflubutamid definitively has the potent

75 The agricultural use of enantiopure (-)-beflubutamid rather than the racemic com

76 Direct access to complex, enantiopure benzylamine architectures using a synergisti

77 three steps from 2-iodo-1-naphthoic acid and enantiopure beta-amino alcohols.

78 Enantiopure beta-amino ketone derivatives were synthesiz

79 direct asymmetric epoxidation to produce an enantiopure beta-epoxyaldehyde that can be appended to t

80 ere subsequently converted in high yields to enantiopure beta-functionalized cysteines suitable for n

81 ss with retention of stereochemistry to form enantiopure beta-hydroxy esters.

82 rase that can be used for the preparation of enantiopure beta-Phe and derivatives thereof.

83 Previously unknown, enantiopure, beta-amino ketones were prepared in modest

84 Thus, practical methods to synthesize enantiopure betahAAs are desirable.

85 synthesis of a representative example of the enantiopure biaryl-like CATPHOS class of diphosphines, (

86 aylis-Hillman reaction catalyzed by a chiral enantiopure bifunctional phosphine.

87 Condensation reactions of enantiopure bis-3,4-diazaphospholanes (BDPs) that are fu

88 A novel enantiopure bis-helicenic 2,2'-bipyridine system was pre

89 Reaction of an enantiopure bisdiazaphospholane tetraacyl fluoride with

90 quent application of this methodology to two enantiopure bishomoallylic amines (which were produced v

91 (BTA) ligand, coordinated to copper, and an enantiopure BTA comonomer.

92 The enantiopure building block was employed in the synthesis

93 triquinacenes were converted into four other enantiopure building blocks, which are valuable precurso

94 Enantiopure C(1)-symmetric bis(imino)pyridine cobalt chl

95 A new family of air- and moisture-stable enantiopure C,N-palladacycles (PIN-acac complexes) were

96 carbon nucleophiles to produce a variety of enantiopure C-P building blocks.

97 The chiral, enantiopure C2 -symmetric silanediol 1 catalyzes enantio

98 As an example, enantiopure C7-fluorinated derivatives of the clinical a

99 s of the host leading to the formation of an enantiopure cage is noteworthy.

100 This mild cyclization can also be applied to enantiopure camphanyldiamine derivatives, and the produc

101 In the presence of enantiopure camphoric acid, the crystallization process

102 Enantiopure carbo[6]helicenyl boronates were synthesized

103 Highly functionalized enantiopure carbocycles and heterocycles were prepared u

104 is, and evaluation of a synthetic, cationic, enantiopure carbohydrate polymer inspired by the structu

105 icture that, in isolation or in concert with enantiopure catalysts, the "even-handed" approach has mu

106 hat it is possible to replace a conventional enantiopure chemical reagent by spin-polarized electrons

107 hout the radical cascade rearrangement of an enantiopure chiral enyne-allene (bearing one stereogenic

108 The first enantiopure chiral-at-rhenium complexes of the form fac-

109 Using toluene dioxygenase as biocatalyst, enantiopure cis-dihydrodiol and cis-tetrahydrodiol metab

110 Preliminary degradation studies using enantiopure Co(salen) catalysts are also reported.

111 urity (diluted majority-rules effect) of the enantiopure comonomer are modest in this initial system.

112 achiral rhodium complex of BTA(PPh2) and the enantiopure comonomer BTA Ile as confirmed by various sp

113 %) or a small bias from a racemic mixture of enantiopure comonomers (10% ee).

114 ree components, i.e. the two achiral and the enantiopure comonomers, highlighting a synergistic effec

115 CH2NH2 (or (S,S)-Ph2PCH(Ph)CH(Me)NH2 for the enantiopure complex) in THF under a CO atmosphere to pro

116 With the enantiopure complex, alcohols are produced with an enant

117 ing on the ratio in which they are combined: enantiopure components form M(4)L(4) assemblies, whereas

118 The quest for enantiopure compounds raises the question of which facto

119 Racemates often have lower solubility than enantiopure compounds, and the mixing of enantiomers can

120 analyzing high-resolution complexes with the enantiopure compounds, we determined that both enantiome

121 novel catalysts for use in the synthesis of enantiopure compounds.

122 aces, where 9-EP monomers that are in nearly enantiopure configuration, dimerize without enantiomeric

123 Enantiopure cryptophane derivatives bearing nine (2, 3)

124 s was achieved in aqueous solution using two enantiopure cryptophanes.

125 real chiral molecules, including racemic and enantiopure crystals, as well as amorphous solids.

126 chanism generates single-handed columns from enantiopure CTVs and mixtures of right- and left-handed

127 axially chiral lithiated alkoxyallene to an enantiopure cyclic nitrone.

128 enables the conversion of racemic allene to enantiopure cyclopentenone product in a dynamic kinetic

129 urther, the chemical utility of the obtained enantiopure cyclopentenones is demonstrated.

130 Racemic 7-16 and the enantiopure derivative (R)-22 proved to be potent inhibi

131 ene do not differentiate between racemic and enantiopure dimers and also suggest that the phenyl ring

132 arious stereoregular forms of iPPO including enantiopure, enantioenriched, racemic, and stereoblock w

133 onding (1S)-camphanic esters, achieving both enantiopure enantiomers (>99% ee) in 35% and 32% yields.

134 e its isotactic counterpart synthesized from enantiopure epoxide and catalyst is semicrystalline with

135 onalization (IEG+) strategy that begins with enantiopure epoxides and facilitates the efficient synth

136 Enantiopure epoxides were demonstrated to undergo the ca

137 lude N-aryl pyrrolidinone substrates with an enantiopure ester group at the 5-position, and alpha-ami

138 e of chirality along the whole process is an enantiopure ferrocenyl pyrrolidine catalytic ligand.

139 scence wavelength/intensity originating from enantiopure fluorescent ligands.

140 pressed alcohol dehydrogenases to synthesize enantiopure fluorinated alcohols is shown.

141 A range of unnatural enantiopure fluorinated alpha-amino acids were obtained

142 rmediate, finally yielding (R)-ramatroban in enantiopure form by the formation of the corresponding a

143 of new compounds, which were obtained in its enantiopure form either through direct asymmetric synthe

144 hesis of an azepane quaternary amino acid in enantiopure form is described.

145 lized, a scalable and practical route to the enantiopure form of this ligand class is described utili

146 blocks, which are difficult to synthesize in enantiopure form using other methods.

147 h as biaryl amino phenols known as NOBINs in enantiopure form, however, still remains a challenge.

148 noboronic acids in their racemic or in their enantiopure form.

149 choice to access planar chiral pCps in their enantiopure form.

150 moiety in spiro-fashion is synthesized in an enantiopure form.

151 e (1R,2S)-(-)-norephedrine furnished L-45 in enantiopure form.

152 nes A-C has been accomplished in racemic and enantiopure forms in 11-13 and 12-14 steps, respectively

153 to resolve rac-[(Ir(ppy)(2)Cl)(2)] into its enantiopure forms, homochiral Ir(6)L(4) octahedra where

154 reocontrolled total syntheses of racemic and enantiopure frog alkaloid 205B (1) were accomplished in

155 methodology for the preparation of uniformly enantiopure fully aromatic [5]-, [6]-, and [7]helicenes

156 t and highly efficient synthetic approach to enantiopure functionalized amino acids (FAAs) 1 skeleton

157 eric polymer chains produced from respective enantiopure, fused six-five bicyclic lactones.

158 be useful substrates for the preparation of enantiopure gamma-lactams and gamma-lactones via N1-C2 b

159 one via stereospecific glycosylation with an enantiopure glycosyl donor followed by separation of the

160 Two-step redox switching in enantiopure helquat system [P-1](2+) right harpoon over

161 This methodology gave access to enantiopure, highly functionalized 5-(trifluoromethyl)py

162 provide direct access to a number of nearly enantiopure homoallylic boronates, which are not readily

163 the highest degree of stereochemical purity, enantiopure homochiral dendritic dipeptides, exhibits th

164 h chiral acceptors (R,R)M and (S,S)M yielded enantiopure homochiral tetrahedral cages (LambdaLambdaLa

165 rminated PdGa{111} surfaces into essentially enantiopure, homochiral 9-EP propellers.

166 In the presence of an enantiopure host, these molecules undergo a deracemizati

167 A method of preparing enantiopure hydroxy-gamma-butyrolactones containing mult

168 A family of racemic and enantiopure indium complexes 1-11 bearing bulky chiral d

169 arbocyclization reaction to the synthesis of enantiopure InoAz analogues starting from readily availa

170 regation occurs via symmetry breaking of the enantiopure intrinsically C2-symmetric monomer brought a

171 Herein, four new fluorinated diastereo- and enantiopure isatin sulfonamide-based potent and selectiv

172 ger monooxygenase enabling the production of enantiopure lactones or esters used in pharmaceutical in

173 e, with a preference toward the formation of enantiopure layers, and a steady-state effect seen after

174 ctronically very different in situ silylated enantiopure Lewis acid organocatalysts: i.e., binaphthyl

175 l ligand monomer (BTA(PPh2), 2 mol %) and an enantiopure ligand-free comonomer (ester BTA, 2.5 mol %)

176 approach is applied, in which samples using enantiopure ligands are compared with samples using enan

177 Enantiopure ligands, each containing H-bond donors and a

178 With complexes of enantiopure ligands, perturbation may involve either dyn

179 he functionalization of a readily accessible enantiopure lithium phosphinoamide with chlorophosphorid

180 ) an ideal sensitizer for the preparation of enantiopure luminescent supramolecular energy-converting

181 n of a double-helical superstructure from an enantiopure macrocyclic dimer which adopts two diastereo

182 eridinols are readily crystallized to obtain enantiopure material.

183 eric strain, will dimerize more readily than enantiopure materials and by a mechanism that preferenti

184 ds; these promote the selective formation of enantiopure MBs.

185 Enantiopure Me(2)-CATPHOS is obtained in an operationall

186 As an extension, one enantiopure Michael adduct has been utilized to synthesi

187 tial racemic mixture and without the need of enantiopure modifier molecules.

188 by chiral HPLC, giving an easy access to the enantiopure molecular cages of which absolute configurat

189 water can be promising for the synthesis of enantiopure molecules and are also important for the und

190 thodologies for the construction of valuable enantiopure molecules, including various heterocycles.

191 enzoates, we have prepared a range of highly enantiopure mono- and disubstituted alpha-sulfinyl benzo

192 an achiral metal complex and a complementary enantiopure monomer provided a good level of enantioindu

193 Iridium(I)-catalyzed allylation of the enantiopure monoprotected copper(I) alkoxide, generated

194 aboration of l-serine gave the corresponding enantiopure N,N-dibenzyl-protected gamma-amino-alpha,bet

195 been developed via SN2-type ring opening of enantiopure N-activated aziridines with 2-bromoindoles f

196 Here, we report the discovery of a enantiopure nanocapsule that is formed through the self-

197 a convenient two-step protocol provided the enantiopure natural product in three steps with an overa

198 X-ray structures of both the racemic and the enantiopure natural products 9, 11, and 13 were obtained

199 en applied to the total synthesis of various enantiopure natural products and commercial drugs, reduc

200 al amplification in the synthesis leading to enantiopure NC samples, spontaneous symmetry breaking, t

201 An exceptionally hindered class of enantiopure NHC ligands has been developed.

202 ompounds reported herein represent the first enantiopure non-natural carbocyclic fenestranes isolated

203 acids, thus providing access to a variety of enantiopure nonsteroidal anti-inflammatory drugs and to

204 fect in the visible spectrum is observed for enantiopure NP, with |Deltaepsilon| values of 1182 and 1

205 mbly induced selective formation of a single enantiopure octahedral cage.

206 ds of preparation of sulfinyl derivatives in enantiopure or enantiomerically enriched form.

207 ndly and highly efficient route to producing enantiopure organosilicon molecules.

208 improved methodology for the preparation of enantiopure oxabicyclo[3.2.1]octadienes via a stereodive

209 e asymmetric synthesis of the diastereo- and enantiopure oxahelicenes.

210 hrough specific isolation of a diastereo and enantiopure oxime, 2-phenylpropanaldehyde oxime, from pr

211 Finally, starting from enantiopure oxiranylpropargylic ester 13, a racemate of

212 A convenient synthesis of enantiopure P-chirogenic diphosphazanes incorporating bu

213 Enantiopure (P)(4)- and (M)(4)-configured alleno-acetyle

214 Furthermore, the use of enantiopure P4 (labeled P4') demonstrates the potential

215 nsible for PAHSA biosynthesis, and access to enantiopure PAHSAs will elucidate the role of stereochem

216 oved thermal properties in comparison to the enantiopure parent polymers.

217 amine)Pd(NO(3))(2)] have been used to design enantiopure Pd(II) tetrahedral cages.

218 ted postsynthetic modification method yields enantiopure peptides anchored inside MOF cavities.

219 The required enantiopure phenyl propanoid unit was prepared from read

220 Purely synthetic enantiopure phorbol has remained elusive, and biological

221 um complexes, most of which are derived from enantiopure phosphorus ligands, have been employed for t

222 th a 2-formylphenylboronic acid template and enantiopure pinanediol to afford a mixture of diastereom

223 Here, we synthesize a series of enantiopure, pinene-derived carboxylic acid and dimer es

224 associated with the economical production of enantiopure planar chiral compounds.

225 Novel enantiopure policyclic nitrogen heterocycles have been o

226 Enantiopure poly-amido-saccharides (PASs) with a defined

227 joined by an alpha-1,2 amide linkage to give enantiopure poly-amido-saccharides (PASs).

228 iopure tetrahydropyridines and deprotection, enantiopure polyhydroxylated piperidines were isolated a

229 A range of enantiopure polyhydroxylated piperidines, including (2R,

230 n by high-performance liquid chromatography, enantiopure precursor compounds, (R)-NB1 and (S)-NB1, we

231 practical methods that allow isolation of an enantiopure product in high yield.

232 They include enantiopure products and the first example of an isolate

233 dma ripening in particular enables access to enantiopure products in a reliable way, simply through g

234 Hydrolysis of the enantiopure products under acid conditions reveals quate

235 Using enantiopure propylene oxide, we synthesized semicrystall

236 Novel enantiopure pseudopeptide models containing a central -(

237 Racemic PSMalpha3 is similarly toxic to enantiopure PSMalpha3 (L or D) under some conditions, bu

238 ic kinetic resolution to access a variety of enantiopure pyranones, one of which served as a versatil

239 tic activity, has been accomplished using an enantiopure pyrroline N-oxide building block derived fro

240 onstrate how the described catalysis affords enantiopure quaternary lactams that intercept synthetic

241 r achiral peripheral alkyl chains, including enantiopure R and S branched alkyls, "racemic by mixture

242 s chiral HPLC methods were developed to give enantiopure R- and S-enantiomers of the four lead compou

243 f-organization behavior of uracil-conjugated enantiopure (R)- or (S)-1,1'-binaphthyl-2,2'-diol (BINOL

244 Thus, we introduced the enantiopure (R)-2-methyl-2-isocyano-3-(tritylthio)propan

245 xternal cofactor was necessary to obtain the enantiopure (R)-derivatives.

246 atic asymmetric route for the preparation of enantiopure (R)-ramatroban has been developed for the fi

247 where the sensitivity of crystallized forms (enantiopure/racemic compound/polymorphs) to both conditi

248 nantioselective kinetic resolution (KR) (one enantiopure reactant) if the relative topicity is highly

249 abled separation and identification by using enantiopure reference compounds of eleven racemic TAGs w

250 derived sulfinate or the alpha-alkylation of enantiopure S-chiral alpha-sulfinyl benzoates, we have p

251 ented syntheses, allowing the preparation of enantiopure (S)- and (R)-coniceine in five steps from co

252 xy)propan-2-ones allowed the recovery of the enantiopure (S)-alcohols in high yields using the alcoho

253 -alpha-amino-beta-nitro-phosphonate 2d gives enantiopure (S)-alpha,beta-diaminophosphonate 3.

254 New fluorous enantiopure (S)-alpha-aminated beta-keto esters were pre

255 hydrolysis of their nitrile groups to afford enantiopure (S)-alpha-arylglycines.

256 the catalytic enantioselective syntheses of enantiopure (S)-econazole and (R)-mirabegron a late-stag

257 it was possible to achieve the synthesis of enantiopure (S)-fluorohydrins at a 0.5 M substrate conce

258 Enantiopure (S,S) and (R,R) dimethyl-ethylenedithio-tetr

259 The monoclinic enantiopure salts, containing four independent donors in

260 d theoretical comparison between racemic and enantiopure samples revealed that the two enantiomers (1

261 that the alcohol stereocenter of silylated, enantiopure secondary alcohols can transmit chirality to

262 A short, concise synthesis of enantiopure, side chain-modified alpha-amino acids such

263 The highest order Phi(h)(k) consists of enantiopure single-handed columns that are slightly dist

264 y novel organic molecules can be obtained in enantiopure solid form.

265 The enantiopure starting material for the rearrangement step

266 Enantiopure stereomers of rosaprostol 1, an antiulcer dr

267 ng motifs between some groups of racemic and enantiopure structures, although they show very differen

268 ion conditions were also found suitable with enantiopure substrates and furnished products without an

269 ve addition of lithiated vinyl sulfoxides to enantiopure sulfinimines provides direct access to a wid

270 d intramolecular cyclization of a variety of enantiopure sulfinyl dienyl amines provides novel sulfin

271 bonding and strategies for the synthesis of enantiopure sulfoxides.

272 nally, the biocatalytic approach resulted in enantiopure syn-(3 R,4 S) 1,3,4-trihydroxypentan-2-ones.

273 hout any metal/Lewis acid activation for the enantiopure synthesis of spiro[dihydropyrrole-3,3'-oxind

274 and controlling the helical organization of enantiopure synthetic molecular systems, rationally dict

275 do-saccharides (PAS) are carbohydrate-based, enantiopure synthetic polymers in which sugar repeat uni

276 The synthesis features the use of the enantiopure synthon, prepared in a set of highly stereos

277 determined by chemoenzymatically synthesised enantiopure TAGs with a co-injection method.

278 Enantiopure TBTQ derivatives of this sort are considered

279 Subsequent deprotection of these enantiopure templates gave (-)-ADMJ and (+)-ADANJ as sin

280 An optimized route to enantiopure tetra-carboxylic acid and tetra-carboxamide

281 o resulted in the formation of water-soluble enantiopure tetrahedral cages (LambdaLambdaLambdaLambda)

282 present cages represent unusual examples of enantiopure tetrahedral cages of square-planar metal ion

283 th (R,R)M and (S,S)M to obtain water-soluble enantiopure tetrahedral nanocages (LambdaLambdaLambdaLam

284 elective olefinic oxidation of the resultant enantiopure tetrahydropyridines and deprotection, enanti

285 oselective olefinic oxidations of a range of enantiopure tetrahydropyridines as the key step.

286 An efficient construction of enantiopure tetramethyloctahydronaphthalenes was develop

287 an expeditious and efficient preparation of enantiopure (thiolan-2-yl)diphenylmethanol (2) featuring

288 The synthesis of enantiopure thiols is of significant interest for indust

289 Enantiopure tosylate precursors for radiolabeling were o

290 Enantiopure trans-2,5-disubstituted trifluoromethylpyrro

291 as a single stereoisomer (de, ee >99%) from enantiopure trans-disubstituted aziridine.

292 Furthermore, one of the enantiopure trans-spiranes bearing an additional alpha-s

293 scription of the self-assembly process of an enantiopure trianglimine macrocyclic host from gel to si

294 The enantiopure tribenzofenestrenes were then separately con

295 The enantiopure trihydroxytribenzotriquinacenes were convert

296 e further elaborated to furnish a variety of enantiopure trisubstituted cyclopropanes.

297 e further elaborated to furnish a variety of enantiopure trisubstituted cyclopropanes.

298 ith a wide range of organic azides to afford enantiopure trisubstituted triazoles.

299 e solubility is enhanced) and can synthesize enantiopure Trp analogues substituted at the 4-, 5-, 6-,

300 enolates can be readily converted into novel enantiopure vinyl triflates, a class of highly versatile