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1 ide-involved pathway that is predicted to be endothermic.
2 her parameters was feasible, spontaneous and endothermic.
3 ested that the adsorption is spontaneous and endothermic.
4 hen conventional electron transfer is highly endothermic.
5 s general-base catalysis and the reaction is endothermic.
6 Above 30 degrees C the reactions are endothermic.
7 tions of 1-4d were found to be substantially endothermic.
8 xpansion of 1c to 3c is computed to be quite endothermic.
9 es such that the reaction is predicted to be endothermic.
10 bond, with the enolate addition being highly endothermic.
11 scission with the loss of SO(2) is generally endothermic.
12 on center, rendering attack at that position endothermic.
13 nd cationic heavy metals (Cd, Pb, and Zn) is endothermic.
14 e to an inefficient intersystem crossing, an endothermic 1,5-hydrogen atom transfer (HAT) step, and a
15 ndent, avian-style acclimatization, becoming endothermic.(1)(,)(2) The ability of warm-blooded dinosa
16 Differential scanning calorimetry showed endothermic (123 degrees C) and exothermic peaks (192 de
17 ntities change sign with DeltaHpart becoming endothermic (+70 kJ/mol) and entropically favored (Delta
19 in the carboxyl-terminal domain so that the endothermic, allosteric activation mechanism of CRP by c
20 xidation by IV(H(2)O), is found to be highly endothermic and cannot occur; this finding is different
21 its constituent monomer, ethylene, is highly endothermic and conventionally accessible only through u
22 Paracoccus cytochrome c-550, the binding is endothermic and driven by a large entropy change, a patt
24 reviously, arguments have been made for both endothermic and ectothermic metabolisms on the basis of
25 n the thermodynamics of the reaction that is endothermic and enthalpically driven in PF6- and TF2N-ba
26 es was characterized by a relatively greater endothermic and entropic profile as compared with those
27 The interactions between FasDD and CaM are endothermic and entropically driven, suggesting that hyd
28 he interactions between CaM and myr(+)MA are endothermic and entropically driven, suggesting that hyd
30 hat LA adsorption on OVAn was a spontaneous, endothermic and entropically-driven process, highlightin
33 e organometallic complex in the cavitand was endothermic and exclusively driven by entropy (DeltaH =
34 Relative trends for a significant range of endothermic and exothermic [1,5]-shifts with different i
35 SN2 reactions in three solvents that lead to endothermic and exothermic reaction processes, and we sh
36 al noncovalent ligand makes protonation very endothermic and greatly raises the reduction potential.
37 a a stepwise pathway is 21 kcal mol(-1) less endothermic and has a 12 kcal mol(-1) lower barrier heig
39 demonstrated that the dissolution process is endothermic and non-spontaneous and includes an entropy
40 hat the overall photoreduction of Pchlide is endothermic and that rapid dynamic searches are required
41 first tension-generating step may be weakly endothermic and that the rise of tension with temperatur
42 step(s) in the crossbridge cycle was highly endothermic and was therefore itself directly targeted b
47 ) with both P-110 and M-200 was spontaneous, endothermic, and majorly driven by hydrophobic interacti
49 eta-sheet aggregates underwent a reversible, endothermic, and very asymmetric thermal transition with
50 advantages of hypothermia risk reduction for endothermic animals and spore spreading enhancement for
52 rance of various states of dormancy, such as endothermic animals sacrificing high body temperature th
54 d its corollaries state that pigmentation of endothermic animals will increase from more polar to equ
63 s substitution of His64 with Gln leads to an endothermic association of CO with the five-coordinate h
64 calorimetry showed the binding was weak and endothermic at 15 degrees C, with a total DeltaH of > or
67 ilamellar EDOPC vesicles and plasmid DNA was endothermic at both physiological and low ionic strength
70 atio together with the reaction heat for the endothermic bi-reforming can be conveniently obtained by
73 s of environmental temperature fluctuations, endothermic birds and mammals maintain a relatively warm
74 nsfer lays the foundation for explaining how endothermic birds and mammals maintain their high, relat
75 ng (TAP) and class Ia has been documented in endothermic birds and two mammals, lineages of LMP7 are
77 the dissociation reaction coordinate through endothermic bond breaking and concomitant gain in config
78 At lower temperatures the second phase is endothermic but gradually decreases with increasing temp
79 of 5 to form 6 was, however, computed to be endothermic by 122.0 kcal/mol whereas protonation of 6 t
80 athway for rearrangement of 6 to 8, which is endothermic by 14.5 kcal/mol, involves ring opening to Z
82 form UO(NO)Cl2(-) and N2 was computed to be endothermic by 169 kJ/mol, which is energetically more f
83 e to form aspirin and benzene is found to be endothermic by 2.7 kcal/mol and provides compelling evid
87 he parent Bergman reaction is computed to be endothermic by 5 kcal/mol) and associated with a signifi
93 attachment of other C atoms, which requires endothermic C-H activation and H* desorption steps that
98 essures will be substantially limited by the endothermic chemical reactions of the polyatomic species
99 ese systems, thermal energy is used to drive endothermic chemical reactions, which can subsequently r
101 The first step in H2O oxidation involves the endothermic cleavage of a strong O-H bond (BDFE = 122.7
103 solvent, bis-guanidinium receptors form more endothermic complexes with dicarboxylates, with a favora
104 salt concentrations were dissected into its endothermic components, yielding the enthalpy change and
106 nge is different from the well-characterized endothermic conformational transition believed to gate t
107 the lowest temperature of SWCNT growth using endothermic decomposition of CH4 gas on a specially acti
112 t CO photodissociation is associated with an endothermic (DeltaH = 8 +/- 3 kcal mol(-1)) volume expan
115 drolysis reaction in beta(TP) is found to be endothermic, demonstrating that the catalytic site is ab
117 escence anisotropy experiments to reverse an endothermic domain-dissociation reaction hypothesized to
118 iganded TRPM2, pore opening is intrinsically endothermic, due to ~10-fold larger activation enthalpy
119 iation over this temperature range showed an endothermic effect below 17 degrees C and an exothermic
120 According to the nanoflake based theory, the endothermic effect of glasses is caused by the transitio
121 that these glasses exhibited characteristic endothermic effects in a particular temperature range.
122 on capture is driven by solar thermal heated endothermic electrolyses of concentrated reactants occur
123 , and V(+), intact ligand loss competes with endothermic elimination of purine and of HCN to form MNH
124 ature increments reflected in the associated endothermic energies were determined with differential s
126 For both proteins, association involves endothermic enthalpy and positive entropy changes; thus,
133 Because the binding of myosin to actin is an endothermic, entropically driven reaction, work must be
136 omplexes was also exothermic, but additional endothermic events occurred at both lower and higher hos
137 active than that at 700 degrees C due to the endothermic feature of reaction which promotes efficient
140 physiology, the thermal physiology of large endothermic fishes, reproductive physiology of air breat
141 bining chemical stabilisation with efficient endothermic fission provides a promising avenue towards
142 the DFT calculations, this reaction is more endothermic for 1 due to the reduced stabilization of th
143 f NHC-boryl radicals to alkenes are probably endothermic for alkyl-substituted alkenes, but exothermi
144 ctron transfer was found to be significantly endothermic for all five CuRe(2) complexes: this fact, c
145 This latter reaction is even predicted to be endothermic for substituents with Hammett constant sigma
146 he fast/slow fiber difference in the rate of endothermic force generation (three- to fourfold) is con
150 nd the basic effects of increased [MgADP] on endothermic force, can be qualitatively simulated using
151 e that the two irreversible high-temperature endothermic HDL transitions involve particle enlargement
152 d that binding of WT apoA-I to SEM generates endothermic heat (DeltaH approximately 30 kcal/mol) in c
153 plex is more stable and unfolds with a lower endothermic heat and lower release of counterion and wat
154 loss around 220 degrees C associated with an endothermic heat effect accompanied by amorphization; an
155 hermal titration calorimetry demonstrates an endothermic heat for the binding of heparin to CLDCs at
157 showing that crossbridge force generation is endothermic (heat absorbed) and associated with increase
159 t is argued that a commitment to life in the endothermic hepatic portal system favored a filiform bod
160 sed in the sequence: ectothermic herbivore > endothermic herbivore > ectothermic carnivore > endother
162 t, growth, fecundity, and development within endothermic hosts and may thus potentially influence tra
163 The DeltaH of binding comprises both an endothermic hydrophobic interaction and exothermic hydro
164 nge in the reaction energetics from strongly endothermic in betaTP to approximately equienergetic in
166 Both proton-transfer events are found to be endothermic in the oxyferrous state, suggesting that the
167 ding whether O. megalodon was ectothermic or endothermic (including regional endothermy), and whether
171 t two-site binding mechanism at pH 7.0 to an endothermic interacting two-site mechanism at pH 5.2, si
172 t two-site binding mechanism at pH 7.0 to an endothermic, interacting two-site binding mechanism at p
174 e of the meso-substituent is able to turn an endothermic interconversion process with a high energy b
177 identified several genes under selection in endothermic lineages, including carnmt1 (involved in fat
178 gh Cu(+), the primary product corresponds to endothermic loss of the intact adenine molecule, whereas
183 ted with the oxygen demands of flying, their endothermic metabolism and unusual pulmonary architectur
186 d temperature; the findings indicate that an endothermic molecular step underlies muscle force genera
187 forms ranging from single atom (N) to highly endothermic molecules (N2, N3, N4, N5, N6) and chains (N
188 units, with the ultimate goal of performing endothermic, multielectron transformations that are coup
189 ug molecules throughout the body; how fish's endothermic nature and the varied expression and activit
190 hat nonavian dinosaur metabolism was neither endothermic nor ectothermic but an intermediate physiolo
191 at of reaction of the hydrogenation with the endothermic one of the CO2 release from the capturing re
194 Cd(II) exhibited a characteristic exothermic-endothermic pattern that was used to infer the metal bin
197 ons in the differential scanning calorimetry endothermic peak enthalpies and loss of birefringence in
199 often appears as splitting of the respective endothermic peak in its thermal (DSC) fingerprint, while
201 tion was observed in the region of the first endothermic peak where the two thermolabile domains melt
202 e inclusion complexes showed the presence of endothermic peaks between 80 degrees C and 150 degrees C
204 d the exothermic phase without affecting the endothermic phase, but it was regained upon addition of
207 inding data conformed to both exothermic and endothermic phases with magnitudes of DeltaG degrees , D
208 rd characteristics such as feathers, flight, endothermic physiology, unique strategies for reproducti
209 shown to be the driving interaction for the endothermic physisorption process of organic vapor parti
210 s were generally higher for ectothermic than endothermic predators, although dietary patterns were si
212 from state A to state B) was found to be an endothermic process (positive DeltaHswitching) for both
213 e dry reforming of methane (DRM) is a highly endothermic process conducted under harsh conditions; he
214 light alkanes via C-H activation is a highly endothermic process that generally requires high tempera
220 action, F(-) with dimethyl sulfoxide, and an endothermic proton-transfer reaction with a competing ex
222 low catalyst durability, resulting from the endothermic reaction and coke deposition, are two main c
226 force generation step is an entropy driven, endothermic reaction that accompanies a burial of large
227 f 16.4 microM at 25 degrees C, pH 6.0, in an endothermic reaction that is driven by a large entropy c
229 he energy barrier as much as possible for an endothermic reaction without yielding a significant conc
230 and free energy of inactivation indicated an endothermic reaction, not spontaneous degradation, where
232 xceptional support for highly exothermic and endothermic reactions that operate above 700 degrees C i
234 he air-exposed reaction proceeds via slight, endothermic rearrangements of crystalline intermediates
238 s the photoluminescent state of CdSe through endothermic reverse triplet-triplet energy transfer.
241 es of linear perylene oligomers that undergo endothermic singlet fission and have endothermicities in
242 er of coupled chromophores needed to undergo endothermic singlet fission is three, which provides suf
244 sion, whereas crystalline tetracene displays endothermic singlet fission with near-unity quantum yiel
245 ate warming creates energetic challenges for endothermic species by increasing metabolic and hydric c
246 suggest that adsorption of Sb(III) ions was endothermic, spontaneous and a thermodynamically feasibl
248 Gibbs energy and dissolution entropy showed endothermic, spontaneous and entropy-driven dissolution
249 olutionary transitions leading to the modern endothermic state of birds and mammals is incomplete, pa
251 largely driven by the preceding two strongly endothermic steps of ATP hydrolysis and attachment of M.
252 substrate reveal a binding reaction that is endothermic, suggesting that cobB recognition of substra
253 ergy of electron transfer (DeltaGET) becomes endothermic, syn-anti isomerization is the dominant path
255 mic isotherms with (dm(5)C-dG)(4) being more endothermic than (dC-dG)(4) by 700 cal/mol basepair.
256 action, is computed to be only slightly more endothermic than the comparable cyclization reaction of
257 0.3 kcal.mol(-1), a value significantly less endothermic than those values suggested from gas-phase m
259 es C, the first DSC heating scan exhibits an endothermic transition at 46.7 degrees C, a small hump n
260 On heating, anhydrous C16:0-SM exhibits an endothermic transition at 75 degrees C (delta H = 4.0 kc
262 exhibited a scan-rate-dependent irreversible endothermic transition at all stages of solubilization.
263 ding site by scanning calorimetry showing an endothermic transition beginning around 725 degrees C ac
264 t 1 deg.C/minute it exhibits an irreversible endothermic transition between 35 and 42 degrees C depen
265 s melt and dissociate reversibly in a second endothermic transition between 60 and 90 degrees C also
266 the low-affinity site strongly inhibits the endothermic transition but does not reduce the rate of A
267 ic binding site on SecA does not perturb the endothermic transition but produces a 10-fold accelerati
268 Data are discussed which indicate that the endothermic transition in the complex is consistent with
269 nd bithiazole-thiophene oligomers display an endothermic transition in their DSC trace below their re
272 that polymorph alpha irreversibly undergoes endothermic transition to polymorph beta much before its
273 ed C16:0-LacCer undergoes a complex two-peak endothermic transition with maxima at 69 degrees C and 7
274 y (DSC), anhydrous C16:0-GalSulf exhibits an endothermic transition, T(M) = 93 degrees C (DeltaH = 5.
276 gelation (dynamic rheology); and (3) protein endothermic transitions (differential scanning calorimet
278 slower heating rate (1.5 degrees C/min), two endothermic transitions are observed at 66 degrees C and
279 y heating curve of the emulsion showed three endothermic transitions at 24.3 degrees C, 33.0 degrees
280 bsequent heating run shows three overlapping endothermic transitions at 66 degrees C, 69 degrees C, a
281 C investigations reveal the presence of four endothermic transitions between 50 and 300 degrees C.
282 reversible melting processes and undergo two endothermic transitions each, at 189/237 and 59/80 degre
285 itation fusion process: this process enables endothermic upconversion and allows efficient upconversi
287 results suggest that the modern dichotomy of endothermic versus ectothermic is overly simplistic.
288 However, lymph nodes are only present in endothermic vertebrates (ie, mammals and possibly some b
290 habitats impose severe metabolic demands on endothermic vertebrates, and understanding how high-alti
292 calculations show C-CN bond activation to be endothermic, which contradicts the observation of therma
293 he attachment process was nonspontaneous and endothermic, which may be associated with structural cha
294 gomerization leading to a neutral product is endothermic, while the analogous one-electron reductive
295 We found that the Mg2+ binding reaction is endothermic with a binding constant (Kb) = 142 +/- 4 M(-
296 fully cNMP-ligated CRP-mutant complexes were endothermic with binding constants as high as 6.6 +/- 1.
297 .0 pM, the reaction releases 3.8 protons, is endothermic with DeltaHrxn of +6.4 kcal mol-1, and entro
299 nthalpy of the binding reaction changes from endothermic with the wild-type hSBDb to exothermic with
300 eleased upon Zn(II) binding, the reaction is endothermic, with DeltaHrxn of +7.7 kcal mol-1, and entr