ライフサイエンスコーパス: energetically

1 nd these are related, both geometrically and energetically.

2 A(*+)-Im->AlPorF(n)-Ph-C(60)(*-), which lies energetically 1.50 eV above the ground state.

3 glycosidic linkage fundamentally alters the energetically accessible conformational space of a thiom

4 omputational methodology to predict multiple energetically accessible conformations for G protein-cou

5 ercury 6p1/2 and 6p3/2 orbitals, making them energetically accessible for chemical bonding.

6 times, enabled by the combination of vacant, energetically accessible heterocycle-based acceptor orbi

7 s reported in the literature are shown to be energetically accessible in the enzyme-substrate complex

8 omerization of {[LCu(III)]2-(mu-O)2}(2+) are energetically accessible pathways for O-O bond formation

9 ab initio calculations cannot identify any (energetically accessible) crossing points between the re

10 t behave well unless the axial conformer was energetically accessible, which is consistent with the t

11 where one or more repeats are unfolded to be energetically accessible.

12 ally expensive brains of Homo sapiens can be energetically afforded.

13 upied molecular orbital (LUMO) are generally energetically and chemically stable.

14 lindrical microtubule conformations are thus energetically and entropically penalized.

15 these inter-Landau-level states, being both energetically and spatially isolated quantum states, are

16 KCl is an energetically attractive alternative osmoprotectant, but

17 ects of palmitate and glucose on resting and energetically challenged mitochondria in DRG neurons.

18 o ammonia (NH3) is a kinetically complex and energetically challenging multistep reaction.

19 ER) stress and unfolded protein response are energetically challenging under nutrient stress conditio

20 LD) of hypersaline brines is technically and energetically challenging.

21 ciples calculations, showing these polytypes energetically comparable to the A7 structure under ambie

22 itio random structure search reveals all the energetically competitive monolayer configurations to be

23 quantitatively reconcile this contrast in an energetically consistent manner.

24 Here, we examine these interactions in a bio-energetically constrained, spatially and temporally reso

25 Since excessive stiffness is energetically costly and limits the flexibility of respo

26 ed response appears to divert resources from energetically costly biomass production to improve resil

27 Protein synthesis is an energetically costly cellular activity.

28 e ecosystems, where consumers must cope with energetically costly changes in CO(2) -driven carbonate

29 by trade-offs in resource allocation between energetically costly immunity and competing processes su

30 n one but keeping a steady head necessitates energetically costly kinematics.

31 gs (Lycaon pictus) are reported to hunt with energetically costly long chase distances.

32 reduced foraging time, especially during the energetically costly pup-rearing period.

33 whether virulence factor expression is truly energetically costly within host tissues and whether exp

34 Many such movements are energetically costly yet there is little consensus on wh

35 iables, if earlier, longer calling bouts are energetically costly, and therefore limited by overnight

36 ally encoded alphabet are extremely rare and energetically costly.

37 Pregnancy is characterized by extensive, energetically-costly changes across numerous physiologic

38 ences, we built a model of residues that are energetically coupled and that define molecular routes f

39 rwise mutations reveals that alphaAsp-138 is energetically coupled to alphaArg-209 in the neighboring

40 tructurally and functionally conserved while energetically coupled to each other.

41 e arm contains four antiporter-like domains, energetically coupled to the quinone site and involved i

42 cell function because membrane proteins are energetically coupled to their host lipid bilayer.

43 The transport and metabolism of lactate energetically couples astrocytes and neurons and support

44 th the GH loop, rather than the DE loop, are energetically critical and define the m4-1BB receptor se

45 They become energetically degenerate in the volume range, V ~ 250 an

46 ric DTE chromophore quickly converts between energetically degenerate P and M helical conformations.

47 Leveraging competition between energetically degenerate states to achieve large field-d

48 artitioning of PbTiO3 thin films into nearly energetically degenerate, hierarchical domain architectu

49 rt inter-birth intervals that make offspring energetically demanding [9] and have moved to a dietary

50 -deficient ECs is severely compromised under energetically demanding conditions, as revealed by signi

51 TIM is activated through an energetically demanding conformational change, which hel

52 al industrial process that relies largely on energetically demanding cryogenic distillation.

53 Flapping flight is the most energetically demanding form of sustained forwards locom

54 apes, humans are unique in rapidly producing energetically demanding offspring.

55 le in increased fat metabolism during highly energetically demanding periods, and that blubber concen

56 This energetically demanding process depends upon the ability

57 thesis of eukaryotic ribosomes is a complex, energetically demanding process requiring the aid of num

58 strocytes ensure local metabolic support for energetically demanding processes and enable coupling be

59 nse and reproduction are physiologically and energetically demanding processes and have been observed

60 daptive response featuring the inhibition of energetically demanding processes, including gluconeogen

61 trostatic interactions that could be used to energetically differentiate transition states.

62 nformation in the unpaired nucleotide to the energetically disfavored anti conformation required for

63 , carbon, but the mechanistic basis for this energetically disfavored regiostereochemistry has been l

64 chain of p-biphenylalanine is trapped in the energetically disfavored, coplanar conformation of the T

65 ker displacement during formate formation is energetically disfavored, in line with the excellent cat

66 ounts for the charge transport physics in an energetically disordered DOS and the Franck-Condon broad

67 t c intermediates and pathways during normal energetically downhill kinetic folding, the present work

68 Uphill glutamate uptake into cells is energetically driven by coupling to co-transport of thre

69 Fibril growth is disfavored energetically due to cancellation of direct peptide-pept

70 solid-like non-migratory state that is more energetically economical.

71 the high electron/energy costs, even when an energetically efficient alternative is available.

72 ke enzyme for reductive choline formation is energetically efficient compared with known pathways.

73 ttoral water temperatures reduces the use of energetically efficient habitats culminating in decrease

74 r sense, we have discovered a temporally and energetically efficient mechanism in which the innate im

75 this theory for designing and understanding energetically efficient nonequilibrium processes through

76 ogically-catalyzed reactions are likely more energetically efficient than abiotic reactions.

77 s leakage, making the CCM significantly more energetically efficient.

78 f the core states by a transiting carrier is energetically enabled, resulting in a sequential tunnell

79 reference for one particular state from many energetically equivalent available minima.

80 ng distinguishable geometric states that are energetically equivalent.

81 may result in cost-effective (mutualism) or energetically expensive (parasitism) interactions.

82 However, since protein translation is energetically expensive and tightly controlled, it is un

83 Exposure did not elicit energetically expensive behaviors, but scallops showed s

84 trategy by modulating taking-off, their most energetically expensive behaviour, to favourable wind co

85 ng, development, and plasticity, but is more energetically expensive compared with the jammed phase,

86 conserved mechanism well-suited to suppress energetically expensive correlated network events under

87 compound II state and reducing the need for energetically expensive electron donor molecules.

88 magnets suffer several drawbacks, including energetically expensive fabrication, limited availabilit

89 , the amino acid histidine is among the most energetically expensive for bacteria to synthesize; ther

90 d CO(2) capture processes are considered too energetically expensive for widespread deployment.

91 To minimize the loss of an energetically expensive metabolite and avoid host detect

92 ary carbon and energy substrate, whereas the energetically expensive NMG pathway plays a pivotal role

93 Flagella synthesis is a complex and energetically expensive process that is tightly regulate

94 s, translation of viral proteins is the most energetically expensive process.

95 rnative to modulating mitochondrial mass, an energetically expensive process.

96 on or Na(+) motive force and are, thus, less energetically expensive than the majority of other dicar

97 Energetically expensive vital functions such as immunolo

98 Host defenses against pathogens are energetically expensive, leading ecological immunologist

99 With protein synthesis being energetically expensive, the ribosome must balance the c

100 Heavier-than-air flight at any scale is energetically expensive.

101 However, producing wings is energetically expensive.

102 than for the Ag 4d(10) orbitals, Cu(I) atoms energetically favor 4-fold coordination, forming [CuX4 ]

103 to generate molecular conformations that are energetically favorable and more likely to be observed e

104 We find that it is both energetically favorable and robust for filaments to bind

105 hin film, which inhibits oxidation to a more energetically favorable and stable V2O5 phase.

106 t pools to generate hundreds of thousands of energetically favorable binding sites for a target ligan

107 Our study reveals that the energetically favorable biological mechanism can be leve

108 ecular oxidation of the phenol by Ru(III) is energetically favorable by both stepwise and concerted p

109 Energetically favorable cation-pi interactions play impo

110 oxidized to phosphate (PO4(3-)), is the most energetically favorable chemotrophic electron-donating p

111 otides inside a CA hexamer cavity results in energetically favorable conditions for passive transloca

112 t in the case of the six-membered lactone an energetically favorable conformer adopts a nearly synper

113 n active site could lead to structurally and energetically favorable coordination ready for the non-t

114 rization is the major hurdle in an otherwise energetically favorable cycloaddition.

115 Based on the known planar nature of energetically favorable domain boundaries in ferroelectr

116 We show that bulging can be energetically favorable due to the relaxation of the ent

117 Single-crystal structure is energetically favorable even for strong repulsion.

118 entially layered manner, thereby creating an energetically favorable gradient for charge separation.

119 olding into wild-type-like structures remain energetically favorable in cohesin-depleted cells, poten

120 h aspect ratio, electrically addressable and energetically favorable interfaces, and substantial enha

121 als, since an unoccupied d-shell provides an energetically favorable location for the electrons to oc

122 Thus, NFS could act as an energetically favorable moiety at the surface of silica

123 The most energetically favorable outcome is the production of met

124 to the tetragonal superlattice that becomes energetically favorable over its hexagonal counterpart.

125 ar spatial distributions of organics with an energetically favorable packing density that agrees with

126 thm is applied to search for the most common energetically favorable packing motifs in crystalline st

127 rangements, including a rearrangement to the energetically favorable para isomer.

128 The energetically favorable pathways for CH(3)COCH(3) produc

129 drophobic channel and observed that the most energetically favorable pose includes a TPN orientation

130 This leads to the emergence of a new type of energetically favorable quasiparticle: bielectron vortic

131 Our model shows that despite the more energetically favorable reaction pathways provided by th

132 e to limit a design to only the most stable, energetically favorable sequence possibilities.

133 s prepared by direct synthesis, are the most energetically favorable sites for reaction pathways lead

134 of pairs in dinucleotide steps, arising from energetically favorable stacking of the nitro group in w

135 ar concerted cycloaddition mechanism via the energetically favorable syn/endo-transition states.

136 rt against its concentration gradient to the energetically favorable transport of one or several ions

137 -pathway self-polymerization that results in energetically favorable trimers and could serve as a dri

138 experiments and DFT calculations support an energetically favorable type 1 cubane formation pathway

139 onstrates that voltage sensor return is less energetically favorable upon repolarization than pore ga

140 from inward occluded to inward open is more energetically favorable when E115 is deprotonated.

141 ce small lattice strain via the formation of energetically favorable {112}beta1/{100}Mg interfaces, a

142 We identify an energetically favorable, continuous ion pathway through

143 tition function calculation to only the most energetically favorable, effectively reducing runtime wh

144 Li and Na ions along the zigzag direction is energetically favorable, while Li/Na diffusion long the

145 (relatively) softer boundary region becomes energetically favorable.

146 tion with the aliphatic tails of lipids more energetically favorable.

147 onfirm that twin nucleation at Sr columns is energetically favorable.

148 findings, revealing the reaction cycle to be energetically favorable.

149 e hydrogenation of CO2 by PtH3 (-) is highly energetically favorable.

150 nonaxisymmetric ridge-shaped structures are energetically favorable.

151 in silico modeling of the predicted order of energetically favored binding.

152 hase separation and reconstruction, which is energetically favored compared to local rearrangements w

153 We find that a 2D bridging network is energetically favored over a 3D network, driving the for

154 thermore, the cubic phase is found to be the energetically favored polytype.

155 a metastable prefusion conformation into an energetically favored postfusion state.

156 the oxidative sorption of ferrous iron is an energetically favored process at several edge surfaces o

157 tions reveal that the phase transition is an energetically favored process.

158 y oxygenate primary C-H bonds over adjacent, energetically favored secondary C-H bonds, but the mecha

159 regular, polygonal-shaped tessellation is an energetically favored solution because it minimizes tota

160 g revealed that Pt NP growth is sufficiently energetically favored to enable displacement of linkers

161 entrations within hours of incubation and is energetically favored, in contrast to classical domain-s

162 Following extension, headpiece opening is energetically favored.

163 boosted catalytic performance stems from the energetically favourable adsorption of reaction intermed

164 The most energetically favourable E-centres have a Ge atom as a n

165 ion of domain walls in ferroelectrics is not energetically favourable in low-dimensional systems.

166 that permeation by dicationic pentamidine is energetically favourable in TbAQP2, driven by the membra

167 The beta polymorph exhibits the energetically favourable l2-l2 hydrogen-bonding arrangem

168 ory demonstrate that this process follows an energetically favourable path.

169 performed to determine the structures' most energetically favourable, biologically accessible motion

170 te and Si on the P site are calculated to be energetically favourable.

171 e, because the cleavage process is much less energetically favourable.

172 e as single anions in adjacent cages is also energetically favourable.

173 e transfer from nanocrystals to tetracene is energetically favoured, and hence triplet transfer proce

174 s demonstrate that this C-C bond cleavage is energetically feasible and thermodynamically favored thr

175 c-pVTZ//omegaB97X/6-31G(d)) identified three energetically feasible pathways.

176 calculations performed in order to evaluate energetically feasible reaction pathways revealed the in

177 with quantum chemical calculations to reveal energetically feasible synthetic disconnections, minimiz

178 n of a (4 + 3) cycloaddition product was not energetically feasible, but (3 + 2) cycloaddition produc

179 on in the tungsten(IV) silyl hydride is also energetically feasible.

180 lyses show that most elongation pathways are energetically feasible.

181 etermined by MD for ring configurations with energetically flat pseudorotational itineraries may not

182 and sequences of quantum states split away, energetically, from the degenerate bulk Landau levels.

183 nstrate that the contact line (CL) motion on energetically heterogeneous solid surfaces occurs in a c

184 motif of an apical silicon(II) atom with an energetically high lying lone pair of electrons that is

185 l-beta anti(G:C) system, whose open state is energetically higher than the closed state.

186 etween high-energy excited states, producing energetically hot states (>6.0 eV) that lead to molecula

187 s along the GammaK directions shift downward energetically in the presence of interlayer interactions

188 ysis of the uncatalyzed reaction predicts an energetically inaccessible iminium intermediate, and a l

189 nd breaking would produce protonated CO2, an energetically inaccessible species that can be avoided b

190 of common organic functional groups that are energetically inaccessible using traditional HAT-based a

191 nal search and compaction electrostatics are energetically independent from the formation of the tert

192 s has been puzzling since fixing nitrogen is energetically inefficient compared with using available

193 However, reward made it worthwhile to be energetically inefficient.

194 Chloroplasts and mitochondria are energetically integrated at the critical intersection of

195 rgetic deficits that conspire to make humans energetically interdependent.

196 it: Here, even infinitely slow protocols are energetically irreversible.

197 s occurs through a zero-energy state that is energetically isolated from a continuum, yielding unifor

198 onding facilitates alkyne slippage, which is energetically less costly for gold than for platinum and

199 enders membrane bending and tubule formation energetically less costly.

200 fibril morphology while omitting competing, energetically less favorable structural states.

201 ally smaller than those of nitrate, which is energetically less favorable.

202 s predict the hydrogen bonds to oxygen to be energetically less favored; however, their considerable

203 cularly serious problem when the E-alkene is energetically less favoured.

204 infrared spectra of all the ground state and energetically low lying structures presented.

205 We present the ground state and energetically low structures of BenH2n nanoclusters as p

206 Energetically low-lying electronic states were measured

207 Among the possible reaction pathways, the energetically low-lying reaction channel involves an int

208 The presence of energetically low-lying triplet states is a hallmark of

209 9 ring type and link type structures are the energetically lowest configurations.

210 known to generate triplet excitons that are energetically matched to the silicon bandgap(6-8).

211 Coffinite is energetically metastable with respect to a mixture of UO

212 required for the reaction to proceed via an energetically more accessible route.

213 tion like icefishes, pre-mating barriers are energetically more efficient than post-mating barriers t

214 thin limit above which the wurtzite phase is energetically more favorable according to the theoretica

215 he inter-atomic bonding contributions become energetically more favorable in that order for both C(2)

216 ed to be endothermic by 169 kJ/mol, which is energetically more favorable than formation of NUOCl2(-)

217 demonstrate that MOR on smaller PtZn iNPs is energetically more favorable than larger iNPs, due to th

218 CN states having a narrower distribution are energetically more favorable toward the WGD transition.

219 oxygen vacancies through making the reaction energetically more favorable via applying interfacial st

220 nism via an unstable Cu(III) intermediate is energetically more feasible than other possible mechanis

221 carbonate/sodium biphosphate) is found to be energetically more preferred over the analogous base-fre

222 azinylcarbenes, which often rearrange to the energetically more stable arylnitrenes.

223 onal H-bonds with the framework that lead to energetically more stable diastereomeric adducts.

224 at the branched head-to-tail vinyl cation is energetically more stable than the corresponding linear

225 let and triplet states of these carbenes are energetically nearly degenerate in the gas phase.

226 articles to reach regions in space which are energetically not accessible according to classical mech

227 Preferred asymmetric step times were energetically optimal across all speed-difference condit

228 nics of the body dominate in determining the energetically optimal course of action.

229 conclusions: (1) symmetry is not necessarily energetically optimal in constrained human walking, and

230 metries to determine whether symmetry is the energetically optimal strategy for walking on a split-be

231 that asymmetric gait may be adopted if it is energetically optimal under certain biomechanical and ne

232 novel perturbation during locomotion is also energetically optimal.

233 omic coordinates of this model we defined an energetically optimized K-PHI structure, in which the K

234 s binding to a MOR crystal structure suggest energetically preferred binding modes that differ from c

235 ations confirm that the quasi-AB stacking is energetically preferred over the AA stacking in solvated

236 ion, an eta(3) -allyl configuration on Mg is energetically preferred over the eta(1) - (sigma-bonded)

237 mmetry stabilized by pressure is found to be energetically preferred over the experimental NaCl-type

238 Importantly, an energetically preferred pathway has identified an intere

239 litate this event, an indentation pathway is energetically preferred to a hydrophobic defect.

240 nd formation energies, the MnOh2+ polaron is energetically preferred to the FeOh2+ polaron, resulting

241 The peroxo state is energetically preferred under any conditions relevant fo

242 ate) ligands causes the larger species to be energetically preferred, we are able to freeze the self-

243 t cluster consisting of few than three atoms energetically prefers a face-centered-cubic stacking, to

244 -bipyridine-5,5'-dicarboxylate linker; it is energetically prohibitive for it to adopt the twisted co

245 Cells habituated to hyperglycaemia were energetically quiescent.

246 xation suggesting that the two processes are energetically related.

247 Greater availability of energetically rich, difficult-to-acquire foods enhances

248 at Bacteroides species are metabolically and energetically robust and do not mount stress responses i

249 ch indicates that African wild dogs are more energetically robust than previously believed.

250 ed this observation and identified a second, energetically similar but conformationally distinct bind

251 fail when two or more potential products are energetically similar, but rational structural perturbat

252 the substrate-enolate, which is accessed via energetically small, escalating steps in which the groun

253 dation via the Psigma* pathway represents an energetically somewhat higher lying alternative; possibl

254 Some of the most energetically stable DFT structures are found to match w

255 Magnetic Skyrmions are energetically stable entities formed in a ferromagnet wi

256 ds through a triplet intermediate to form an energetically stable four-membered ring in the singlet s

257 nd then refold the trimeric assembly into an energetically stable post-fusion state, a process that d

258 culations show that all three clathrates are energetically stable with relaxed lattice constants matc

259 We introduce energetically stable, micrometer-sized knots in helical

260 Via 'phosphate steering', basic residues energetically steer an inverted ss 5'-flap through a gat

261 ur results suggest that the CD site is in an energetically strained configuration, and this helps dri

262 r food restricted (manipulations intended to energetically stress larvae) adopted a less twig-like po

263 etecting productive fruit patches during the energetically stressful dry season also benefits dichrom

264 tions revealed a distinct transition between energetically sustainable and unsustainable ATP concentr

265 conjugate addition pathway as more favorable energetically than an alternative electrocyclization pat

266 e North Pacific, may only be half as costly, energetically, than high-arctic residency or migration t

267 Energetically, the lesioned open states are similar in e

268 teractions in the native state are optimized energetically, thereby potentiating slow folding and mis

269 y which liquid water becomes water vapor and energetically this accounts for much of incoming solar r

270 as deep hole traps, with such trapped holes energetically unable to drive water oxidation.

271 ear by catalytic oxidation of methanol in an energetically unfavorable and atom-inefficient industria

272 of water, making the ring-opening of glucose energetically unfavorable and leaving a high coverage of

273 nd structural properties of siloxanes; it is energetically unfavorable and thus highly unlikely.

274 stasis by chaperoning mature factors through energetically unfavorable events, thereby maintaining th

275 ubstrates and firmly engages them during the energetically unfavorable extraction process remains a m

276 Vacancy sites that are energetically unfavorable for segregation are found in a

277 the ligand, but that proton transfer becomes energetically unfavorable in the presence of additional

278 of controllable amount of confined water is energetically unfavorable leading the enhancement of sel

279 that the tryptophan substitutions lower the energetically unfavorable residual hydrophobic mismatch

280 hin the alpha3 helix helps to stabilize this energetically unfavorable state to enable long-chain syn

281 DNA bases can adopt energetically unfavorable tautomeric forms that enable t

282 calcination and removal of the SDA to avoid energetically unfavorable three-rings.

283 multiexcitonic nature, which stabilizes the energetically unfavorable two-charge separated state by

284 contrast, charge transfer to naphthalene is energetically unfavourable and spectroscopy shows direct

285 uent ordered lipid domains are thought to be energetically unfavourable for membrane fusion, rafts ha

286 Charged ferroelectric walls, which are energetically unfavourable in general, were found to be

287 show that the guest-free CMOF-5 structure is energetically unstable, with either the achiral conventi

288 cleotide-binding domains (NBDs) to power the energetically uphill efflux of substrates by a dedicated

289 foldon-dependent pathway intermediates as in energetically uphill equilibrium unfolding.

290 ter from Escherichia coli, EmrE, couples the energetically uphill extrusion of hydrophobic cations ou

291 stry grants access to silyl radicals through energetically uphill reductive cleavage of strong Si-Cl

292 s engaged with natural logs, which contained energetically valuable honey that was only accessible th

293 e oxidation of reduced sulfur species was an energetically viable metabolism for life on early Mars.

294 t ab initio calculations that predict novel, energetically viable reaction mechanisms by which Al-O a

295 moting methylidene formation from carbide as energetically viable relative to the heterolytic cleavag

296 idiflorol, and related sesquiterpenes is not energetically viable.

297 hysisorbed pentene, establishing a series of energetically well-separated groups of reactive surface

298 ation of the observed indole is most favored energetically, while the potential pathway to the minor

299 nd tetrahedra, respectively, were quantified energetically, with the destabilization increasing linea

300 l Bi creates localised impurity states lying energetically within the GaP host matrix band gap.